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1. 发明申请

WO2019206412A1 FLAME RETARDANT ELECTRICAL CABLE 审中-公开
公开(公告)号：WO2019206412A1
公开(公告)日：2019-10-31
申请号：PCT/EP2018/060664
申请日：2018-04-26
申请人： PRYSMIAN S.P.A. , POLITECNICO DI MILANO
发明人： SCRIMA, Vito , CAIMI, Luigi , GOLA, Massimo , CITTERIO, Attilio
IPC分类号： H01B7/295 , C01B32/174 , H01B3/22 , C08K3/016 , H01B3/44 , C08L23/08 , C08K3/04
摘要： A flame-retardant electric cable (10) is disclosed, the cable having a core comprising an electric conductor (11) and an electrically insulating layer (12) made from a flame-retardant polyolefin-based composition comprising: a) a cross-linked polyolefin as base polymer; b) silica; and c) carbon nanotubes wherein the amount of silica is from 5wt% to 10wt% of the polyolefin- based composition, and the amount of carbon nanotubes is from 0.5wt% to 2wt% of the polyolefin-based composition. Such a cable has improved flame retardant performances, especially regarding a lower occurrence of droplets during burning, which render it capable of being certified in higher classes of the current international standards, for example of the standard EN 50399:2011/A1 (2016).

2. 发明公开

EP3785281A1 FLAME RETARDANT ELECTRICAL CABLE 有权
公开(公告)号：EP3785281A1
公开(公告)日：2021-03-03
申请号：EP18721995.1
申请日：2018-04-26
申请人： Prysmian S.p.A. , Politecnico di Milano
发明人： SCRIMA, Vito , CAIMI, Luigi , GOLA, Massimo , CITTERIO, Attilio
IPC分类号： H01B7/295 , C01B32/174 , H01B3/22 , C08K3/016 , H01B3/44 , C08L23/08 , C08K3/04

3. 发明申请

WO2016101979A1 FLAME-RETARDANT HEAVY METAL-FREE COATING FOR AN ELECTRICAL CABLE 审中-公开
标题翻译：用于电缆的阻燃重金属无金属涂层
公开(公告)号：WO2016101979A1
公开(公告)日：2016-06-30
申请号：PCT/EP2014/079023
申请日：2014-12-22
申请人： PRYSMIAN S.P.A.
发明人： SCRIMA, Vito , TOSI, Fabio
IPC分类号： C08K3/00 , C08K5/00 , C08K5/521 , C08K13/00 , H01B7/00 , C08K3/22 , C08K3/26 , C08K5/092 , C08K5/11 , C08K5/12
CPC分类号： C08K3/016 , C08J5/18 , C08K3/22 , C08K3/26 , C08K5/0016 , C08K5/11 , C08K5/12 , C08K5/38 , C08K5/523 , C08K2003/2224 , C08K2003/2227 , C08K2003/265 , C08K2003/267 , C08K2201/014 , H01B7/295 , C08L27/06 , C08L23/10
摘要： The present invention relates to an electrical cable comprising at least one conductor and at least one coating made from a flame-retardant heavy metal-free composition comprising (a) polyvinyl chloride (PVC) as polymer base material; (b) a calcium aluminum hydrate carbonate; (c) an aryl phosphate; (d) an inorganic flame-retardant filler; (e) a plasticizer.
摘要翻译：本发明涉及一种电缆，其包括至少一个导体和至少一个由阻燃重金属组合物制成的涂层，该组合物包含（a）聚氯乙烯（PVC）作为聚合物基材; （b）碳酸钙铝水合物; （c）磷酸芳基酯; （d）无机阻燃填料; （e）增塑剂。

4. 发明申请

WO2014076520A1 PROCESS FOR RECOVERING WASTES OF A POLYMERIC COMPOSITION INCLUDING A PEROXIDIC CROSSLINKING AGENT 审中-公开
标题翻译：用于回收包含过氧化物交联剂的聚合物的废物的方法
公开(公告)号：WO2014076520A1
公开(公告)日：2014-05-22
申请号：PCT/IB2012/056410
申请日：2012-11-14
申请人： PRYSMIAN S.P.A.
发明人： GALLETTI, Franco , SCRIMA, Vito
IPC分类号： C08K5/14 , C08J11/06 , C08K5/00 , H01B3/44
CPC分类号： C08J11/28 , C08J11/06 , C08J2315/00 , C08J2323/08 , C08J2323/16 , C08K5/005 , C08K5/14 , C08L2207/20 , H01B3/441 , H01B7/0045 , H01B7/17 , Y02W30/701
摘要： A process for recovering wastes of a polymeric composition including at least one peroxide-curable polymer and at least one peroxidic crosslinking agent, which comprises compounding the wastes with at least one antioxidant agent suitable for sulfur-vulcanized elastomeric compositions, at a temperature lower than the decomposition temperature of the at least one peroxide crosslinking agent. These above antioxidant agents are effective to quench the peroxide crosslinking agent, so as to avoid any substantial crosslinking of the composition during processing of the same. The compounding of the polymeric wastes with the antioxidant agent is carried out at a temperature lower than the decomposition temperature of the peroxide crosslinking agent, so as to avoid any premature activation of the crosslinking agent. This makes the process according to the present invention particularly suitable for compositions based on elastomeric polyolefins, more preferably for elastomeric ethylene copolymers such as ethylene-propylene copolymers (EPR) and ethylene-propylene-diene terpolymers (EPDM), which can be processed at relatively low temperatures, much lower than the decomposition temperatures of the most common peroxide crosslinking agents.
摘要翻译：一种用于回收包含至少一种可过氧化物固化的聚合物和至少一种过氧化交联剂的聚合物组合物的废物的方法，其包括将废物与至少一种适用于硫硫化弹性体组合物的抗氧化剂混合在低于所述至少一种过氧化物交联剂的分解温度。这些上述抗氧化剂有效地淬灭过氧化物交联剂，以避免组合物在其加工过程中发生任何实质性的交联。聚合物废物与抗氧化剂的配混在低于过氧化物交联剂的分解温度的温度下进行，以避免交联剂过早活化。这使得根据本发明的方法特别适合于基于弹性体聚烯烃的组合物，更优选用于弹性体乙烯共聚物如乙烯 - 丙烯共聚物（EPR）和乙烯 - 丙烯 - 二烯三元共聚物（EPDM），其可以相对加工低温，远远低于最常用的过氧化物交联剂的分解温度。

5. 发明申请

WO2017199060A1 FIRE RESISTANT CABLE WITH CERAMIFIABLE LAYER 审中-公开
标题翻译：耐腐蚀电缆与CERAMIFIABLE层
公开(公告)号：WO2017199060A1
公开(公告)日：2017-11-23
申请号：PCT/IB2016/052864
申请日：2016-05-17
申请人： PRYSMIAN S.P.A.
发明人： SCRIMA, Vito , TOSI, Fabio , ANDREOLETTI, Marco , CASTELLI, Carlo
IPC分类号： H01B7/295
摘要： A fire resistant cable comprising: a conducting element (2; 21); a layer, surrounding the conducting element, made of a ceramifiable composition comprising: - a thermoplastic polymer mixture comprising: (a) a copolymer of ethylene with a C 4 -C 12 alpha-olefin, having a density of from 0.860 to 0.910 g/cm 3 , a melt flow index not higher than 3 g/10 min and a melting point of 105°C at most; (b) an ethylene homopolymer or copolymer of ethylene with a C 4 -C 12 alpha-olefin, having a density of from 0.900 to 0.985 g/cm 3 , a melt flow index not higher than 5 g/10 min and a melting point of at least 110°C; and (c) a polyethylene grafted with an ethylenically unsaturated monomer; - at least 25 wt% of silica; - a fluxing agent selected from alkaline metal oxides or precursors thereof; - an inorganic hydroxide compound selected from magnesium hydroxide, aluminium hydroxide and mixtures thereof; - a stabilizing agent comprising a hydrated magnesium silicate in an amount of at least 5 wt%; weight percentages being based on the total weight of the ceramifiable composition. Upon exposure to elevated temperatures such as those encountered in case of fire, the ceramifiable composition is transformed into a ceramic material capable of protecting the conducting element from fire and mechanical stresses. The fire resistant cable of the present invention can continue operating under fire conditions for a certain period of time.
摘要翻译：一种耐火电缆，其包括：导电元件（2; 21）;和导电元件（2; 21）。围绕导电元件的由陶瓷组合物制成的层，所述组合物包含： - 热塑性聚合物混合物，其包含：（a）乙烯与C 4 -C 12 - α-烯烃，其密度为0.860-0.910克/立方厘米，熔体流动指数不高于3克/ 10分钟，熔点最高为105℃; （b）乙烯均聚物或乙烯与C 4 -C 12α-烯烃的共聚物，其密度为0.900-0.985g / cm 3 熔体流动指数不高于5克/ 10分钟且熔点至少为110℃; 和（c）用烯键式不饱和单体接枝的聚乙烯; - 至少25重量％的二氧化硅; - 选自碱金属氧化物或其前体的助熔剂; - 选自氢氧化镁，氢氧化铝及其混合物的无机氢氧化物化合物; - 包含至少5重量％的水合硅酸镁的稳定剂; 重量百分比基于可陶瓷化组合物的总重量。当暴露于升高的温度（例如遇火情况下）时，可陶瓷化组合物被转变成能够保护导电元件免受火灾和机械应力的陶瓷材料。本发明的耐火电缆可以在火灾条件下持续运行一段时间。

6. 发明申请

WO2016038427A1 FIRE RESISTANT CABLE WITH CERAMIFIABLE LAYER 审中-公开
标题翻译：具有可陶瓷层的耐火电缆
公开(公告)号：WO2016038427A1
公开(公告)日：2016-03-17
申请号：PCT/IB2014/064474
申请日：2014-09-12
申请人： PRYSMIAN S.P.A.
发明人： SCRIMA, Vito , TOSI, Fabio
IPC分类号： H01B13/14 , H01B7/295
CPC分类号： H01B7/295 , C08K3/08 , C08K3/36 , C08K2003/0818 , C08L23/0853 , G02B6/443 , G02B6/4432 , G02B6/4436 , H01B13/148
摘要： A fire resistant cable comprising: at least one conducting element; at least one layer, surrounding said conducting element, made of a ceramifiable composition comprising: a polymeric material comprising an ethylene/vinyl acetate copolymer as main polymer; at least 25 wt% of silica; a fluxing agent selected from alkaline metal oxides or precursors thereof; a stabilizing agent comprising at least one of MgO, CaO, PbO, B203, or a precursor thereof; from 0.1 wt% to 5 wt% of a hydroxide selected from magnesium hydroxide, aluminium hydroxide and mixtures thereof; the above percentages being expressed with respect to the weight of the ceramifiable composition. Upon exposure to elevated temperatures such as those encountered in case of fire, the ceramifiable composition is transformed into a ceramic material capable of protecting the conducting element from fire and mechanical stresses. The fire resistant cable of the present invention can continue operating under fire conditions for a certain period of time.
摘要翻译：一种防火电缆，包括：至少一个导电元件; 围绕所述导电元件的至少一层，由可陶瓷组合物制成，包括：包含乙烯/乙酸乙烯酯共聚物作为主要聚合物的聚合材料; 至少25wt％的二氧化硅; 选自碱金属氧化物或其前体的助熔剂; 包含MgO，CaO，PbO，B 2 O 3或其前体中的至少一种的稳定剂; 0.1重量％至5重量％的选自氢氧化镁，氢氧化铝及其混合物的氢氧化物; 相对于可陶瓷组合物的重量表示上述百分数。在暴露于诸如在火灾中遇到的高温的高温下，可陶瓷组合物被转化成能够保护导电元件免受火灾和机械应力的陶瓷材料。本发明的耐火电缆可以在火灾条件下持续一定时间。

7. 发明公开

EP4002395A1 FLAME-RETARDANT CABLE WITH SELF-EXTINGUISHING COATING LAYER 审中-实审
公开(公告)号：EP4002395A1
公开(公告)日：2022-05-25
申请号：EP21206417.4
申请日：2021-11-04
申请人： Prysmian S.p.A.
发明人： AUDEBET, Pauline , SCRIMA, Vito , CAIMI, Luigi , CASIRAGHI, Flavio
IPC分类号： H01B7/295 , C09K21/10 , C09D123/08 , C08K3/22 , C08K3/34 , C08K3/26 , C08K5/3492 , C09K21/00
摘要： 1. A flame-retardant cable (10;20;30;40) is disclosed, the cable having a core comprising at least one conductor (11;41), and a coating (13a;14;43a) made from a low smoke zero halogen flame-retardant polymer composition comprising a halogen free base polymer added with:
a) less than 170 phr of at least one metal hydroxide;
b) from 1 to 10 phr of a phyllosilicate clay;
c) at least 1 phr and less than 10 phr of melamine or a derivate thereof; and
d) an alkali or alkaline-earth metal carbonate.
Such a cable has improved reaction to fire performances, especially absence of dripping during burning, which render it compliant with the requirements of the more recent international standards.

8. 发明公开

EP3192082A1 FIRE RESISTANT CABLE WITH CERAMIFIABLE LAYER 有权
标题翻译：耐腐蚀电缆与CERAMIFIABLE层
公开(公告)号：EP3192082A1
公开(公告)日：2017-07-19
申请号：EP14792873.3
申请日：2014-09-12
申请人： Prysmian S.p.A.
发明人： SCRIMA, Vito , TOSI, Fabio
IPC分类号： H01B13/14 , H01B7/295
CPC分类号： H01B7/295 , C08K3/08 , C08K3/36 , C08K2003/0818 , C08L23/0853 , G02B6/443 , G02B6/4432 , G02B6/4436 , H01B13/148
摘要： A fire resistant cable comprising: at least one conducting element; at least one layer, surrounding said conducting element, made of a ceramifiable composition comprising: a polymeric material comprising an ethylene/vinyl acetate copolymer as main polymer; at least 25 wt % of silica; a fluxing agent selected from alkaline metal oxides or precursors thereof; a stabilizing agent comprising at least one of MgO, CaO, PbO, B2O3, or a precursor thereof; from 0.1 wt % to 5 wt % of a hydroxide selected from magnesium hydroxide, aluminium hydroxide and mixtures thereof; the above percentages being expressed with respect to the weight of the ceramifiable composition. Upon exposure to elevated temperatures such as those encountered in case of fire, the ceramifiable composition is transformed into a ceramic material capable of protecting the conducting element from fire and mechanical stresses. The fire resistant cable of the present invention can continue operating under fire conditions for a certain period of time.
摘要翻译：一种耐火电缆，包括：至少一个导电元件; 围绕所述传导元件的至少一层由可陶瓷组合物制成，所述可陶瓷组合物包含：包含作为主要聚合物的乙烯/乙酸乙烯酯共聚物的聚合物材料; 至少25重量％的二氧化硅; 选自碱金属氧化物或其前体的助熔剂; 包含MgO，CaO，PbO，B 2 O 3或其前体中的至少一种的稳定剂; 0.1重量％至5重量％的选自氢氧化镁，氢氧化铝及其混合物的氢氧化物; 上述百分比相对于可陶瓷化组合物的重量来表示。当暴露于升高的温度（例如遇火情况下）时，可陶瓷化组合物被转变成能够保护导电元件免受火灾和机械应力的陶瓷材料。本发明的耐火电缆可以在火灾条件下持续运行一段时间。

9. 发明授权

EP3459086B1 FIRE RESISTANT CABLE WITH CERAMIFIABLE LAYER 有权
公开(公告)号：EP3459086B1
公开(公告)日：2020-03-18
申请号：EP16729062.6
申请日：2016-05-17
申请人： Prysmian S.p.A.
发明人： SCRIMA, Vito , TOSI, Fabio , ANDREOLETTI, Marco , CASTELLI, Carlo
IPC分类号： H01B7/295

10. 发明授权

EP2920238B1 PROCESS FOR RECOVERING WASTES OF A POLYMERIC COMPOSITION INCLUDING A PEROXIDIC CROSSLINKING AGENT 有权转让
公开(公告)号：EP2920238B1
公开(公告)日：2019-10-30
申请号：EP12805471.5
申请日：2012-11-14
申请人： Prysmian S.p.A.
发明人： GALLETTI, Franco , SCRIMA, Vito
IPC分类号： C08K5/14 , C08J11/06 , C08K5/00 , H01B3/44

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