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    • 2. 发明申请
    • BRANCHED NANOSCALE WIRES
    • 分支纳米线
    • WO2008033303A2
    • 2008-03-20
    • PCT/US2007/019669
    • 2007-09-11
    • PRESIDENT AND FELLOWS OF HARVARD COLLEGELIEBER, Charles, M.TIAN, BozhiJIANG, Xiaocheng
    • LIEBER, Charles, M.TIAN, BozhiJIANG, Xiaocheng
    • H01L21/20
    • B82Y30/00H01L21/02381H01L21/02428H01L21/02513H01L21/02521H01L21/02532H01L21/02603H01L21/02606H01L21/0262H01L21/02631H01L21/02639H01L21/02645
    • The present invention generally relates to nanotechnology and, in particular, to branched nanoscale wires. In some cases, the branched nanoscale wires may be produced using vapor-phase and/or solution-phase synthesis. In one set of embodiments, branched nanoscale wires may be grown by depositing nanoparticles onto a nanoscale wire, and segments or "branches" can then be grown from the nanoparticles. The nanoscale wire may be any nanoscale wire, for example, a semiconductor nanoscale wire, a nanoscale wire having a core and a shell, etc. The segments may be of the same, or of different materials, than the nanoscale wire, for example, semiconductor/metal, semiconductor/semiconductor (i.e., having different compositions, for instance, IV-IV, IV-III/V, IV-II/VI, etc.), etc. The junction between the segment and the nanoscale wire, in some cases, is epitaxial. In one embodiment, the nanoparticles are adsorbed onto the nanoscale wire by immobilizing a positively-charged entity, such as polylysine, to the nanoscale wire, and exposing it to the nanoparticles. In another embodiment, nanoparticles are deposited onto a nanoscale wire by etching the nanoscale wire to produce an H-terminated surface, then exposing the surface to a solution comprising a metal ion, which can be reduced by the surface to form nanoparticles. Segments or branches can then be grown from the deposited nanoparticles to form the branched nanoscale wire. Other aspects of the invention include assays, sensors, kits, and/or other devices that include such nanoscale wires, methods of making and/or using such nanoscale wires, or the like.
    • 本发明一般涉及纳米技术,特别涉及分支纳米尺寸的导线。 在一些情况下,可以使用气相和/或溶液相合成制备支化纳米线。 在一组实施方案中,可以通过在纳米级线上沉积纳米颗粒来生长分支纳米线,然后可以从纳米颗粒生长片段或“分​​支”。 纳米线可以是任何纳米尺寸的线,例如半导体纳米线,具有芯和壳的纳米线。等等。这些线可以是与纳米级线相同或不同的材料,例如, 半导体/金属,半导体/半导体(即,具有不同组成,例如IV-IV,IV-III / V,IV-II / VI等)等。该段和纳米线之间的连接处于 有些情况是外延。 在一个实施方案中,通过将带正电荷的实体(例如聚赖氨酸)固定到纳米线上并将其暴露于纳米颗粒,将纳米颗粒吸附到纳米级线上。 在另一个实施方案中,通过蚀刻纳米尺度线以产生H终止的表面,然后将表面暴露于包含金属离子的溶液,将纳米级纳米线沉积到纳米级线上,该溶液可以被表面还原以形成纳米颗粒。 然后可以从沉积的纳米颗粒生长段或分枝以形成分支的纳米级线。 本发明的其它方面包括测定,传感器,试剂盒和/或包括这种纳米线的其它装置,制造和/或使用这种纳米尺度线的方法等。