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1. 发明申请

WO0153746B1 STERICALLY STABILIZED SECOND-ORDER NONLINEAR OPTICAL CHROMOPHORES AND DEVICES INCORPORATING THE SAME 审中-公开
标题翻译：非常稳定的二阶非线性光学色素和与其同时进行的器件
公开(公告)号：WO0153746B1
公开(公告)日：2001-09-07
申请号：PCT/US0101655
申请日：2001-01-17
申请人： PACIFIC WAVE IND INC , DALTON LARRY R , ZHANG CHENG , WANG CHUANGUANG , FETTERMAN HAROLD R , WANG FANG , STEIER WILLIAM , HARPER AARON W , REN ALBERT S , MICHAEL JOSEPH
发明人： DALTON LARRY R , ZHANG CHENG , WANG CHUANGUANG , FETTERMAN HAROLD R , WANG FANG , STEIER WILLIAM , HARPER AARON W , REN ALBERT S , MICHAEL JOSEPH
IPC分类号： C08K5/00 , C09B23/01 , C09B23/14 , G02F1/361 , F21V9/00 , G02F1/35
CPC分类号： C08K5/0041 , C09B23/0066 , C09B23/0075 , C09B23/0091 , C09B23/145 , G02F1/3612 , G02F1/3614 , G02F1/3615
摘要： Sterically stabilized second-order nonlinear optical chromophores and devices incorporating the same are embodied in a variety of chromophore materials. An exemplary preferred chromophore includes an electron donor group, an electron acceptor group and a bridge structure therebetween, with the electron acceptor group being double bonded to the bridge structure. In a preferred embodiment, the bridge structure also includes at least one bulky side group. Another exemplary preferred chromophore includes an electron donor group, an electron acceptor group and a ring-locked bridge structure between the electron donor group and the electron acceptor group. The bridge structure comprises, for example, two protected alicyclic rings or ring-locked trienone. Another exemplary preferred chromophore includes an electron donor group, a ring-locked tricyano electron acceptor group, and a bridge structure therebetween. In a preferred embodiment, the electron acceptor group comprises an isophorone structure. Another exemplary preferred chromophore includes an electron donor group, an electron acceptor group, and a bridge structure therebetween, with the bridge structure including a bithiophene unit. In a preferred embodiment, the bridge structure further includes a modified isophorone unit.
摘要翻译：具有稳定的二阶非线性光学发色团和包含其的装置体现在各种发色团材料中。示例性的优选发色团包括电子给体基团，电子受体基团和它们之间的桥接结构，电子受体基团与桥结构双键结合。在优选实施例中，桥结构还包括至少一个庞大的侧组。另一个示例性的优选发色团包括电子给体基团，电子受体基团和电子给体基团和电子受体基团之间的环形锁定桥结构。桥结构包括例如两个受保护的脂环族环或环状三烯酮。另一个示例性的优选发色团包括电子给体基团，环锁三氯乙烯电子受体基团和它们之间的桥接结构。在优选的实施方案中，电子受体基团包括异佛尔酮结构。另一示例性的优选发色团包括电子给体基团，电子受体基团和它们之间的桥接结构，桥结构包括双噻吩单元。在优选的实施方案中，桥结构还包括改性的异佛尔酮单元。

2. 发明申请

WO0237173A3 ELECTRODE POLING OF ELECTRO-OPTIC POLYMERS 审中-公开
标题翻译：电光聚合物的电极抛光
公开(公告)号：WO0237173A3
公开(公告)日：2002-09-06
申请号：PCT/US0146339
申请日：2001-10-22
申请人： PACIFIC WAVE IND INC
发明人： OH MIN-CHEOL , STEIER WILLIAM , ZHANG HUA , FETTERMAN HAROLD R , MICHAEL JOSEPH
IPC分类号： G02F1/065 , G02F1/355 , B29D11/00 , G02B6/10
CPC分类号： G02F1/065 , G02F1/3558
摘要： Method (400) for manufacturing an electro-optic polymer waveguide device (100) including the step of electrode poling (426) an electro-optic polymer material of the device in an oxygen-free environment. In a preferred embodiment, the electrode poling (426) is performed at a temperature close to a glass transition temperature of the electro-optic polymer material.
摘要翻译：一种用于制造电光聚合物波导器件（100）的方法（400），其包括在无氧环境中所述器件的电光聚合物材料的电极极化步骤（426）。在优选实施例中，电极极化（426）在接近电光聚合物材料的玻璃化转变温度的温度下进行。

3. 发明申请

WO0009613A2 NEW CLASS OF HIGH HYPERPOLARIZABILITY ORGANIC CHROMOPHORES AND PROCESS FOR SYNTHESIZING THE SAME 审中-公开
标题翻译：新型超高灵敏度有机色素及其合成方法
公开(公告)号：WO0009613A2
公开(公告)日：2000-02-24
申请号：PCT/US9916274
申请日：1999-07-26
申请人： PACIFIC WAVE IND INC
发明人： DALTON LARRY R , FETTERMAN HAROLD R , WANG FANG , STEIER WILLIAM , HARPER AARON W , REN ALBERT S , MICHAEL JOSEPH
IPC分类号： C08K5/00 , C09B23/01 , C09B23/14 , C09B
CPC分类号： C08K5/0041 , C09B23/0066 , C09B23/0075 , C09B23/0091 , C09B23/145
摘要： A new class of high hyperpolarizability organic chromophores and a process for synthesizing the same. The chromophores incorporate at least one organic substituent and are formed in consideration of molecular shapes and a spatial anisotropy of intermolecular interactions. The chromophores are processed into hardened material lattices to lock-in poling induced electric-optic activity. Preferred organic substituents are alkyl, aryl, and isophorone groups. A composite including the organic chromophore, in a preferred embodiment, includes a polymer such as a poly(methylmethacrylate), polyimide, polyamic acid, polystyrene, polycarbonate or polyurethane. The optimized chromophores result in hardened electro-optic polymers suitable for electro-optic modulators and other devices such as optical switches. These modulators can be configured to work at high frequencies and in arrays for applications in communications and network connections. In addition, they can be implemented in series and parallel combinations in phased array radar, signal processing and sensor technology applications.
摘要翻译：一类新的超超极化有机发色团及其合成方法。考虑到分子形状和分子间相互作用的空间各向异性，发色团引入至少一个有机取代基并形成。发色团被加工成硬化材料晶格以锁定极化诱导的电光活动。优选的有机取代基是烷基，芳基和异佛尔酮基团。在优选的实施方式中，包含有机发色团的复合物包括聚合物如聚（甲基丙烯酸甲酯），聚酰亚胺，聚酰胺酸，聚苯乙烯，聚碳酸酯或聚氨酯。优化的发色团产生适用于电光调制器和其他设备（如光开关）的硬化电光聚合物。这些调制器可以配置为工作在高频和阵列中，用于通信和网络连接的应用。另外，它们可以在相控阵雷达，信号处理和传感器技术应用中以串联和并联组合方式实施。

4. 发明专利

AU3284801A Sterically stabilized second-order nonlinear optical chromophores and devices incorporating the same 未知
公开(公告)号：AU3284801A
公开(公告)日：2001-07-31
申请号：AU3284801
申请日：2001-01-17
申请人： PACIFIC WAVE IND INC
发明人： DALTON LARRY R , ZHANG CHENG , WANG CHUANGUANG , FETTERMAN HAROLD R , WANG FANG , STEIER WILLIAM , HARPER AARON W , REN ALBERT S , MICHAEL JOSEPH
IPC分类号： C08K5/00 , C09B23/01 , C09B23/14 , G02F1/361 , F21V9/00 , G02F1/35

5. 发明专利

AU3462901A Ultraminiature fiber optic pressure transducer and method of fabrication 未知
公开(公告)号：AU3462901A
公开(公告)日：2001-08-14
申请号：AU3462901
申请日：2001-01-29
申请人： PACIFIC WAVE IND INC
发明人： FETTERMAN HAROLD R , BUKSHPUN LEONID , MICHAEL JOSEPH
IPC分类号： A61B5/00 , A61B5/0215 , A61B5/03 , G01L9/00 , A61B5/02 , G01L7/08
摘要： A method of batch fabrication of ultraminiature fiber optic pressure transducers including the steps of: providing a first substrate with a first sacrificial layer formed thereover; forming a plurality of light reflective diaphragm structures on the first sacrificial layer; forming a plurality of fiber stopper structures on the light reflective diaphragm structures; forming a plurality of fiber alignment cavity structures on the fiber stopper structures, the light reflective diaphragm structures, fiber stopper structures and fiber alignment cavity structures providing a plurality of fiber alignment assemblies; providing a second substrate with a second sacrificial layer formed thereover; forming a plurality of ferrule structures over the second sacrificial layer; inputting a plurality of fibers into the ferrule structures and sealing each of the ferrule structures to the fiber inserted therein, the ferrule structures and the fibers providing a plurality of fiber-ferrule assemblies; etching the second sacrificial layer releasing the fiber-ferrule assemblies; inputting the fiber-ferrule assemblies into the fiber alignment assemblies and sealing each of the fiber alignment assemblies to the fiber-ferrule assembly inserted therein, the fiber alignment assemblies and the fiber-ferrule assemblies providing a plurality of fiber optic pressure transducers; and etching the first sacrificial layer releasing the fiber optic pressure transducers.

6. 发明专利

AU9277901A Polymers containing polyene-bridged second-order nonlinear optical chromophores and devices incorporating the same 未知
公开(公告)号：AU9277901A
公开(公告)日：2002-04-15
申请号：AU9277901
申请日：2001-09-18
申请人： PACIFIC WAVE IND INC
发明人： ZHANG CHENG , FETTERMAN HAROLD R , STEIER WILLIAM , MICHAEL JOSEPH
IPC分类号： C08K5/00 , C09B23/01 , C09B23/14 , G02F1/065 , G02F1/21 , G02F1/225 , G02F1/361 , G02F1/35 , F21V9/00
摘要： Polymers containing polyene-bridged second-order nonlinear optical chromophores and devices incorporating the same are disclosed. The chromophores are functionalized and incorporated into a series of polymers ranging from linear polyesters, linear poly[ester-imide]s, chain-crosslinked polyesters/poly[ester-imide]s, to crosslinked star-shaped/dendritic macromolecules. An exemplary preferred polymer is a linear chain polymer formed from a dihydroxy-functionalized polyene-bridged chromophore, a diacid or diacid dichloride, and a diol. In a preferred embodiment, the diol structure also includes at least one imide group. Another exemplary preferred polymer is a crosslinked polymer comprised of a linear chain polymer formed from a dihydroxy-functionalized polyene-bridged chromophore, a diacid or diacid dichloride and a diol. The crosslinking is realized by thermally induced cyclolization of trifluorovinylethers which are attached to the diol co-monomer and/or chromophore in the linear chain polymer chain. In a preferred embodiment, the diol structure also includes at least one imide group. Another exemplary preferred polymer is a crosslinked polymer made from crosslinkable star-shaped high molecular weight (larger than 2,000) structure containing polyene-bridged chromophores. In a preferred embodiment, the crosslinking groups are multiple trifluorovinylether groups located at the periphery of the star-shaped structure. Another exemplary preferred polymer is a crosslinked polymer made from crosslinkable dendritic structure having a chromophore core and one or more dendrons. In a preferred embodiment, the crosslinking groups are multiple trifluorovinylether groups located at the periphery of the dendritic structure.

7. 发明专利

AU5331301A Sterically stabilized second-order nonlinear optical chromophores 未知
公开(公告)号：AU5331301A
公开(公告)日：2001-10-23
申请号：AU5331301
申请日：2001-04-09
申请人： PACIFIC WAVE IND INC
发明人： ZHANG CHENG , FETTERMAN HAROLD R , STEIER WILLIAM , MICHAEL JOSEPH
IPC分类号： C08K5/00 , C09B23/01 , C09B23/14 , G02F1/065 , G02F1/21 , G02F1/361 , G02F1/35 , F21V9/00
摘要： Sterically stabilized second-order nonlinear optical chromophores and devices incorporating the same are embodied in a variety of chromophore materials. An exemplary preferred chromophore includes an electron donor group, an electron acceptor group and a ring-locked bridge structure therebetween, with the bridge structure being directly connected to the electron donor via a single bond. Another exemplary preferred chromophore includes an electron donor group, an electron acceptor group and a ring-locked bridge structure between the electron donor group and the electron acceptor group, with two free double bonds, one located between the donor and the bridge and the other located between the (fused) ring bridge and the acceptor. Another exemplary preferred chromophore includes an electron donor group, an electron acceptor group, and a bridge structure therebetween, with the chromophores having no carbon-carbon double bond between the donor and the (fused) ring bridge. In this class, there is only one unlocked carbon-carbon double bond between the (fused) ring bridge and the acceptor. Another exemplary preferred chromophore includes an electron donor group, an electron acceptor group, and a ring-locked bridge structure therebetween, with a built-in electron-withdrawing cyano group on the last ring of the (fused) bridge. Another exemplary preferred chromophore includes any electron donor group, an electron acceptor group including a linear conjugated triene bearing four cyano groups, and any bridge structure therebetween.

8. 发明专利

AU1703400A New class of high hyperpolarizability organic chromophores and process for synthesizing the same 未知
公开(公告)号：AU1703400A
公开(公告)日：2000-03-06
申请号：AU1703400
申请日：1999-07-26
申请人： PACIFIC WAVE IND INC
发明人： DALTON LARRY R , FETTERMAN HAROLD R , WANG FANG , STEIER WILLIAM , HARPER AARON W , REN ALBERT S , MICHAEL JOSEPH
IPC分类号： C08K5/00 , C09B23/01 , C09B23/14

9. 发明专利

AU2589202A Techniques for electrode poling of electro-optic polymers to eliminate poling induced optical loss and poling induced damage to electro-optic chromophores 未知
公开(公告)号：AU2589202A
公开(公告)日：2002-05-15
申请号：AU2589202
申请日：2001-10-22
申请人： PACIFIC WAVE IND INC
发明人： OH MIN-CHEOL , STEIER WILLIAM , ZHANG HUA , FETTERMAN HAROLD R , MICHAEL JOSEPH
IPC分类号： G02F1/065 , G02F1/355
摘要： Method for manufacturing an electro-optic polymer waveguide device including the step of electrode poling an electro-optic polymer material of the device in an oxygen-free environment. In a preferred embodiment, the electrode poling is performed at a temperature close to a glass transition temperature of the electro-optic polymer material.

10. 发明专利

AU5355201A Sterically stabilized polyene-bridged second-order nonlinear optical chromophores and devices incorporating the same 未知
公开(公告)号：AU5355201A
公开(公告)日：2001-10-30
申请号：AU5355201
申请日：2001-04-16
申请人： PACIFIC WAVE IND INC
发明人： ZHANG CHENG , FETTERMAN HAROLD R , STEIER WILLIAM , MICHAEL JOSEPH
IPC分类号： C08K5/00 , C09B23/01 , C09B23/14 , G02F1/065 , G02F1/21 , G02F1/361 , F21V9/00 , G02F1/00 , G02F1/03
摘要： Sterically stabilized polyene-bridged second-order nonlinear chromophores and devices incorporating the same are embodied in a variety of chromophore materials, and particularly in chromophore materials are configured within an oxygen-free operating environment. An exemplary preferred chromophore includes an electron donor group, an electron acceptor group and a pi-conjugate bridge structure therebetween. The bridge is a polyene structure having a five-, six- or seven-membered ring to lock one carbon-carbon double bond. The bridge contains an unlocked conjugate diene unit which connects the bridge ring and the acceptor. Another exemplary preferred chromophore includes an electron donor group, an electron acceptor group and a ring-locked bridge structure between the electron donor group and the electron acceptor group. The bridge structure includes a fused double-or triple-ring structure which functions to lock two or three double bonds. The bridge also contains an unlocked conjugate diene unit to connect the the bridge ring and the acceptor. Another exemplary preferred chromophore includes an electron donor group, an acceptor, and a bridge structure therebetween, wherein the acceptor is a five- or six-membered ring locked tricyano electron acceptor. Another exemplary preferred chromophore includes an electron donor group, an electron acceptor group, and a bridge structure therebetween, with the bridge structure including a bithiophene unit. A preferred host polymer for the chromophores is poly[bisphenol A carbonate-co-4,4'-(3,3,5-trimethylcyclohexylidene)diphenol carbonate].

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