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1. 发明授权

US06924316B2 Method for producing hydrocarbons by Fischer-Tropsch process 失效
标题翻译：通过费 - 托法生产烃的方法
公开(公告)号：US06924316B2
公开(公告)日：2005-08-02
申请号：US10476131
申请日：2002-06-17
申请人： Osamu Iwamoto , Shigenori Nakashizu , Kinjiro Saito , Takashi Suzuki
发明人： Osamu Iwamoto , Shigenori Nakashizu , Kinjiro Saito , Takashi Suzuki
IPC分类号： B01J23/656 , B01J35/00 , B01J35/02 , B01J35/10 , B01J37/02 , C10G2/00 , C07C27/00
CPC分类号： C10G2/333 , B01J23/6562 , B01J35/0026 , B01J35/023 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J37/0205
摘要： A method for producing hydrocarbons, comprising: (I) subjecting to a reduction treatment a catalyst comprising a carrier having provided thereon: 0.1 to 10% by mass of at least one metal selected from an alkali metal, an alkaline earth metal, a rare earth metal and the Group III in the periodic table and 1 to 30% by mass of ruthenium, each based on the catalyst weight, the carrier comprising an aluminum oxide and a manganese oxide having an average number of charges of manganese of exceeding Mn2+, and the catalyst having a specific surface area of from 60 to 350 m2/g and a bulk density of from 0.8 to 1.8 g/ml; (II) dispersing the catalyst in liquid hydrocarbons in a concentration of from 1 to 50 w/v %; and (III) bringing the catalyst into contact with a gas mixture comprising hydrogen and carbon monoxide at a pressure of from 1 to 10 MPa, and (i) at a reaction temperature of from 170 to 300° C. under such conditions that carbon dioxide is substantially absent, or (ii) at a reaction temperature of from 200 to 350° C. under such conditions that carbon dioxide coexists in an amount of from 0.5 to 50% based on the total pressure of the hydrogen and the carbon monoxide.
摘要翻译：一种碳氢化合物的制造方法，其特征在于，含有：（I）还原处理含有载体的催化剂：0.1〜10质量％的选自碱金属，碱土金属，稀土金属和周期表中的III族和1〜30质量％的钌，各自以催化剂重量计，载体包含氧化铝和氧化锰，其平均锰电荷数超过Mn < 2 +，比表面积为60〜350m 2 / g，堆积密度为0.8〜1.8g / ml的催化剂; （II）将催化剂分散在浓度为1至50w / v％的液体烃中; 和（III）使催化剂与包含氢气和一氧化碳的气体混合物在1至10MPa的压力下接触，和（i）在170-300℃的反应温度下，在二氧化碳基本上不存在，或（ii）在200-350℃的反应温度下，在二氧化碳基于氢气和一氧化碳的总压力共存0.5至50％的量的条件下。

2. 发明授权

US07612013B2 Hydrocarbon-producing catalyst, process for producing the same, and process for producing hydrocarbons using the catalyst 失效
标题翻译：生产烃的催化剂，其制备方法和使用该催化剂生产烃的方法
公开(公告)号：US07612013B2
公开(公告)日：2009-11-03
申请号：US10585109
申请日：2005-02-23
申请人： Kazuhito Sato , Shigenori Nakashizu , Osamu Iwamoto , Hiroaki Otsuka
发明人： Kazuhito Sato , Shigenori Nakashizu , Osamu Iwamoto , Hiroaki Otsuka
IPC分类号： B01J21/02 , B01J21/04 , B01J23/00 , B01J23/02 , B01J23/04 , B01J23/16 , B01J23/32 , B01J23/34 , B01J23/46 , B01J23/54 , B01J23/56 , B01J23/58 , B01J23/63 , B01J23/64 , B01J23/656
CPC分类号： B01J37/06 , B01J21/04 , B01J23/58 , B01J23/63 , B01J23/6562 , B01J35/1061 , B01J35/108 , B01J37/0205 , B01J37/08 , C10G2/333 , C10G2400/06 , C10G2400/08
摘要： An object of the present invention is to provide a catalyst which, in the FT process, exhibits a high chain growth probability, and a high catalytic activity, can stably and smoothly promote the reaction, exhibits a high productivity of C5+, and can efficiently produce liquid hydrocarbons, and a process therefore. The invention relates to a hydrocarbon-producing catalyst obtainable by supporting a ruthenium compound on a support composed of a manganese oxide and an aluminum oxide, and which satisfies at least one of characteristics (1) and (2): (1) the catalyst being treated with an aqueous alkaline solution and subsequently subjected to calcination treatment in the air at 150 to 500° C., (2) the aluminum oxide being an aluminum oxide wherein pore volume formed by pores having a pore diameter of 8 nm or more accounts for 50% or more of total pore volume.
摘要翻译：本发明的目的是提供一种催化剂，其在FT方法中表现出高链增长概率，并且具有高催化活性，可以稳定和平稳地促进反应，表现出高的C5 +的生产率，并能有效地生产液态碳氢化合物，以及一种方法。本发明涉及一种通过在由氧化锰和氧化铝构成的载体上负载钌化合物而得到的烃产生催化剂，其满足特征（1）和（2）中的至少一个：（1）催化剂为用碱性水溶液处理，随后在150〜500℃的空气中进行煅烧处理，（2）氧化铝为氧化铝，其中孔径为8nm以上的孔形成的细孔容积为总孔体积的50％以上。

3. 发明申请

US20080064769A1 Hydrocarbon-Producing Catalyst, Process for Producing the Same, and Process for Producing Hydrocarbons Using the Catalyst 失效
标题翻译：烃生产催化剂，其生产方法，以及使用催化剂生产烃的方法
公开(公告)号：US20080064769A1
公开(公告)日：2008-03-13
申请号：US10585109
申请日：2005-02-23
申请人： Kazuhito Sato , Shigenori Nakashizu , Osamu Iwamoto , Hiroaki Otsuka
发明人： Kazuhito Sato , Shigenori Nakashizu , Osamu Iwamoto , Hiroaki Otsuka
IPC分类号： C07C1/04
CPC分类号： B01J37/06 , B01J21/04 , B01J23/58 , B01J23/63 , B01J23/6562 , B01J35/1061 , B01J35/108 , B01J37/0205 , B01J37/08 , C10G2/333 , C10G2400/06 , C10G2400/08
摘要： An object of the present invention is to provide a catalyst which, in the FT process, exhibits a high chain growth probability, and a high catalytic activity, can stably and smoothly promote the reaction, exhibits a high productivity of C5+, and can efficiently produce liquid hydrocarbons, and a process therefor.The invention relates to a hydrocarbon-producing catalyst obtainable by supporting a ruthenium compound on a support composed of a manganese oxide and an aluminum oxide, and which satisfies at least one of characteristics (1) and (2): (1) the catalyst being treated with an aqueous alkaline solution and subsequently subjected to calcination treatment in the air at 150 to 500° C., (2) the aluminum oxide being an aluminum oxide wherein pore volume formed by pores having a pore diameter of 8 nm or more accounts for 50% or more of total pore volume.
摘要翻译：本发明的目的是提供一种催化剂，其在FT方法中表现出高链增长概率，并且具有高催化活性，可以稳定和平稳地促进反应，表现出高的C 5 可以有效地生产液态烃类及其工艺。本发明涉及一种通过在由氧化锰和氧化铝构成的载体上负载钌化合物而得到的烃产生催化剂，其满足特征（1）和（2）中的至少一个：（1）催化剂为用碱性水溶液处理，随后在150〜500℃的空气中进行煅烧处理，（2）氧化铝为氧化铝，其中孔径为8nm以上的孔形成的细孔容积为总孔体积的50％以上。

4. 发明授权

US08057744B2 Bubble column-type Fischer-Tropsch synthesis slurry bed reaction system 有权
标题翻译：泡沫塔型费 - 托合成浆床反应体系
公开(公告)号：US08057744B2
公开(公告)日：2011-11-15
申请号：US12097161
申请日：2005-12-14
申请人： Yasuhiro Onishi , Kenichiro Fujimoto , Masaru Ihara , Yoshifumi Suehiro , Yasumasa Morita , Kiyoshi Inaba , Toshio Shimizu , Osamu Iwamoto
发明人： Yasuhiro Onishi , Kenichiro Fujimoto , Masaru Ihara , Yoshifumi Suehiro , Yasumasa Morita , Kiyoshi Inaba , Toshio Shimizu , Osamu Iwamoto
IPC分类号： B01J8/18 , F27B15/08
CPC分类号： B01J8/228 , B01J8/007 , B01J8/085 , B01J8/1818 , B01J8/22 , B01J2208/00123 , B01J2208/00539 , B01J2208/0061 , C10G2/342 , C10G2300/4006 , C10G2300/805
摘要： According to an exemplary embodiment, a bubble column-type slurry bed Fischer-Tropsch synthesis reaction process can be provided, in which synthesis gas supplied continuously from the bottom of a reactor contacts suspended catalyst particles to form liquid hydrocarbons, gaseous hydrocarbons and water. Additionally, a slurry of suspended liquid products and catalyst particles can move from the reactor to the lower portion of a separation vessel to separate the catalyst particles and gaseous products. Further, a process can be provided in which the liquid products formed are sent to the separation vessel a process in which liquid products can be derived. Additionally, a process can be provided in which a slurry in which catalyst particles are concentrated is derived from the bottom of the separation vessel and circulated to the bottom of the reactor, are driven by the driving force of synthesis gas without using an external drive power source.
摘要翻译：根据示例性实施例，可以提供泡沫塔型浆料床费 - 托合成反应方法，其中从反应器底部连续供应的合成气与悬浮的催化剂颗粒接触以形成液体烃，气态烃和水。此外，悬浮液体产物和催化剂颗粒的浆料可以从反应器移动到分离容器的下部，以分离催化剂颗粒和气态产物。此外，可以提供将所形成的液体产品送到分离容器的方法，其中可以得到液体产物的过程。此外，可以提供一种方法，其中催化剂颗粒浓缩的浆料从分离容器的底部衍生并循环到反应器的底部，由合成气的驱动力驱动，而不使用外部驱动力资源。

5. 发明授权

US06565254B2 Infrared sensing element and temperature measuring device 有权
公开(公告)号：US06565254B2
公开(公告)日：2003-05-20
申请号：US09875343
申请日：2001-06-06
申请人： Shigemi Sato , Osamu Iwamoto , Yasuhiro Shiohara , Yuji Oda
发明人： Shigemi Sato , Osamu Iwamoto , Yasuhiro Shiohara , Yuji Oda
IPC分类号： G01J512
CPC分类号： G01J5/04 , G01J5/02 , G01J5/021 , G01J5/0225 , G01J5/045 , G01J5/048 , G01J5/049 , G01J5/08 , G01J5/0806 , G01J5/0818 , G01J5/12 , G01J5/16 , G01J2005/068
摘要： An infrared sensing element of the present invention includes a base including a thin film portion and a thick wall portion arranged around the thin film portion, and a thermopile including a plurality of thermocouples connected in series so that cold junctions are located on the thick wall portion and hot junctions are located on the thin film portion, wherein a thermosensitive portion is provided in contact with the thick wall portion so that a reference temperature with high accuracy can be used for determining temperature based on output from the thermopile. A PN junction formed on a semiconductor substrate serves as the thermosensitive portion, and it is used to provide for a compact infrared sensing element with high performance at low cost.

6. 发明授权

US5177548A Image recording apparatus with provision for blank binding space 失效
标题翻译：图像记录装置，提供空白结合空间
公开(公告)号：US5177548A
公开(公告)日：1993-01-05
申请号：US608831
申请日：1990-11-05
申请人： Shinichi Nakamura , Tomobumi Nakayama , Hisatsugu Tahara , Satoshi Kuroyanagi , Osamu Iwamoto
发明人： Shinichi Nakamura , Tomobumi Nakayama , Hisatsugu Tahara , Satoshi Kuroyanagi , Osamu Iwamoto
IPC分类号： G03G15/00
CPC分类号： G03G15/6541 , G03G15/6582 , G03G2215/00426 , G03G2215/0054 , G03G2215/00822 , G03G2215/00869
摘要： An image recording apparatus includes an input key for inputting a binding mode for binding a plurality of recording sheets; an image forming until for forming an image on the recording sheet, the image forming unit forming the image while providing a predetermined blank space when the binding mode is inputted from the input key; and a binding unit for binding a plurality of recording sheets ejected out from the image forming unit by adding a predetermined cover sheet when the binding mode is inputted from the input key.

7. 发明授权

US5092888A Hardening material 失效
标题翻译：硬化材料
公开(公告)号：US5092888A
公开(公告)日：1992-03-03
申请号：US524480
申请日：1990-05-17
申请人： Osamu Iwamoto , Yasuhiro Ogawa
发明人： Osamu Iwamoto , Yasuhiro Ogawa
IPC分类号： A61K6/033 , A61F2/00 , A61L24/00 , A61L24/02 , A61L27/00 , A61L27/12 , A61L27/46 , C04B12/02
CPC分类号： A61L27/46 , A61K6/0085 , A61K6/0091 , A61K6/0675 , A61L24/0084 , A61L24/02 , A61L27/12 , C04B28/344 , A61F2310/00293 , C04B2111/00836
摘要： Disclosed is a hardening material comprising (a) a powder component composed of a powdery mixture of tetracalcium phosphate and calcium phosphate having a Ca/P atomic ratio lower than 1.67 and (b) a liquid component composed of a colloidal aqueous solution comprising solid colloid particles dispersed in an aqueous medium, wherein said components (a) and (b) are independently packed and both the components are mixed for hardening.This hardening material can give a hardened body having a high strength without showing any harmful action on a living body. Accordingly, this hardening material is especially effectively used for the restoration of a hard tissue of a living body.
摘要翻译：公开了一种硬化材料，其包含（a）由Ca / P原子比低于1.67的磷酸四钙和磷酸钙的粉末状混合物构成的粉末成分，（b）由包含固体胶体粒子的胶体水溶液构成的液体成分分散在水性介质中，其中所述组分（a）和（b）被独立地包装，并且将两种组分混合以进行硬化。这种硬化材料可以赋予具有高强度的硬化体，而不会对生物体产生任何有害作用。因此，这种硬化材料特别有效地用于恢复生物体的硬组织。

8. 发明授权

US07393470B2 Process for producing synthesis gas for the fischer-tropsch synthesis and producing apparatus thereof 有权
标题翻译：用于制造费 - 托合成的合成气的方法及其制造装置
公开(公告)号：US07393470B2
公开(公告)日：2008-07-01
申请号：US11090393
申请日：2005-03-25
申请人： Masaru Ihara , Yoshifumi Suehiro , Yasumasa Morita , Kiyoshi Inaba , Toshio Shimizu , Osamu Iwamoto , Tomoyuki Mikuriya , Ryuichiro Kajiyama , Ken-ichiro Fujimoto , Yasuhiro Onishi
发明人： Masaru Ihara , Yoshifumi Suehiro , Yasumasa Morita , Kiyoshi Inaba , Toshio Shimizu , Osamu Iwamoto , Tomoyuki Mikuriya , Ryuichiro Kajiyama , Ken-ichiro Fujimoto , Yasuhiro Onishi
IPC分类号： C01B3/26
CPC分类号： C10G2/32 , B01D53/8603 , B01D2253/102 , B01D2257/306 , B01D2259/40 , B01J2219/00006 , C01B3/384 , C01B2203/0233 , C01B2203/0238 , C01B2203/04 , C01B2203/0475 , C01B2203/0495 , C01B2203/062 , C01B2203/0816 , C01B2203/0894 , C01B2203/1041 , C01B2203/1052 , C01B2203/1241 , C01B2203/127 , C01B2203/148 , Y02P20/124
摘要： Synthesis gas for FT synthesis is produced using a producing apparatus including an active carbon adsorbing vessel for adsorbing impurities in a natural gas, a hydro-desulfurizer for hydrogenating and desulfurizing sulfur content in the natural gas under a condition of a partial pressure of hydrogen of 100 to 200 kPa, a second hydrogen supplying line for supplying hydrogen to the natural gas between the hydro-desulfurizer and a reactor, the reactor for obtaining synthesis gas by reacting the natural gas, carbon dioxide and steam in the presence of a catalyst for reforming, and a heat recovering boiler for cooling the synthesis gas at a cooling rate of 2000 to 4000° C./second.
摘要翻译：用于FT合成的合成气体是使用包括在天然气中吸附杂质的活性炭吸附容器的制造装置，在氢气分压为100的条件下在天然气中氢化和脱硫硫含量的加氢脱硫剂用于向加氢脱硫剂和反应器之间的天然气供给氢的第二氢供给管线，所述反应器用于在重整催化剂存在下使天然气，二氧化碳和蒸汽反应获得合成气，以及以2000〜4000℃/秒的冷却速度冷却合成气的热回收锅炉。

9. 发明申请

US20050220703A1 Process for producing synthesis gas for the fischer-tropsch synthesis and producing apparatus thereof 有权
标题翻译：用于制造费 - 托合成的合成气的方法及其制造装置
公开(公告)号：US20050220703A1
公开(公告)日：2005-10-06
申请号：US11090393
申请日：2005-03-25
申请人： Masaru Ihara , Yoshifumi Suehiro , Yasumasa Morita , Kiyoshi Inaba , Toshio Shimizu , Osamu Iwamoto , Tomoyuki Mikuriya , Ryuichiro Kajiyama , Ken-ichiro Fujimoto , Yasuhiro Onishi
发明人： Masaru Ihara , Yoshifumi Suehiro , Yasumasa Morita , Kiyoshi Inaba , Toshio Shimizu , Osamu Iwamoto , Tomoyuki Mikuriya , Ryuichiro Kajiyama , Ken-ichiro Fujimoto , Yasuhiro Onishi
IPC分类号： C10L3/10 , B01D53/86 , B01J8/04 , B01J10/00 , C01B3/24 , C01B3/26 , C01B3/32 , C01B3/38 , C01B32/40 , C01B32/50 , C10G2/00 , C10K1/02 , C10K1/04
CPC分类号： C10G2/32 , B01D53/8603 , B01D2253/102 , B01D2257/306 , B01D2259/40 , B01J2219/00006 , C01B3/384 , C01B2203/0233 , C01B2203/0238 , C01B2203/04 , C01B2203/0475 , C01B2203/0495 , C01B2203/062 , C01B2203/0816 , C01B2203/0894 , C01B2203/1041 , C01B2203/1052 , C01B2203/1241 , C01B2203/127 , C01B2203/148 , Y02P20/124
摘要： Synthesis gas for FT synthesis is produced using a producing apparatus including an active carbon adsorbing vessel for adsorbing impurities in a natural gas, a hydro-desulfurizer for hydrogenating and desulfurizing sulfur content in the natural gas under a condition of a partial pressure of hydrogen of 100 to 200 kPa, a second hydrogen supplying line for supplying hydrogen to the natural gas between the hydro-desulfurizer and a reactor, the reactor for obtaining synthesis gas by reacting the natural gas, carbon dioxide and steam in the presence of a catalyst for reforming, and a heat recovering boiler for cooling the synthesis gas at a cooling rate of 2000 to 4000° C./second.
摘要翻译：用于FT合成的合成气体是使用包括在天然气中吸附杂质的活性炭吸附容器的制造装置，在氢气分压为100的条件下在天然气中氢化和脱硫硫含量的加氢脱硫剂用于向加氢脱硫剂和反应器之间的天然气供给氢的第二氢供给管线，所述反应器用于在重整催化剂存在下使天然气，二氧化碳和蒸汽反应获得合成气，以及以2000〜4000℃/秒的冷却速度冷却合成气的热回收锅炉。

10. 发明申请

US20050084626A1 Method of forming inorganic alignment film, inorganic alignment film, substrate for electronic device, liquid crystal panel and electronic apparatus 有权
标题翻译：无机取向膜形成方法，无机取向膜，电子器件用基板，液晶面板及电子设备
公开(公告)号：US20050084626A1
公开(公告)日：2005-04-21
申请号：US10931813
申请日：2004-09-01
申请人： Hidenobu Ota , Yukihiro Endo , Osamu Iwamoto
发明人： Hidenobu Ota , Yukihiro Endo , Osamu Iwamoto
IPC分类号： C23C14/10 , C23C14/34 , C23C14/58 , G02F1/1337 , B05D3/00 , C09K19/00
CPC分类号： C23C14/10 , C23C14/5833 , G02F1/133734 , G02F1/13378 , G02F2001/133792 , G02F2202/09 , Y10T428/1009
摘要： A method of forming an inorganic alignment film on a base substrate is provided comprising forming a film made substantially of an inorganic material on the base substrate, and irradiating ion beams onto the surface of the film from a direction inclined at a predetermined angle θb with respect to the direction vertical to the surface. By irradiating the ion beams onto the film, concave portions having a predetermined directivity are formed on the film. The predetermined angle θb is preferably 2° or more.
摘要翻译：提供了在基底基板上形成无机取向膜的方法，包括在基底基板上形成基本上由无机材料制成的膜，并且从倾斜预定角度θ b 相对于垂直于表面的方向。通过将离子束照射到膜上，在膜上形成具有预定方向性的凹部。预定角度θB优选为2°以上。

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