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1. 发明授权

US06924316B2 Method for producing hydrocarbons by Fischer-Tropsch process 失效
标题翻译：通过费 - 托法生产烃的方法
公开(公告)号：US06924316B2
公开(公告)日：2005-08-02
申请号：US10476131
申请日：2002-06-17
申请人： Osamu Iwamoto , Shigenori Nakashizu , Kinjiro Saito , Takashi Suzuki
发明人： Osamu Iwamoto , Shigenori Nakashizu , Kinjiro Saito , Takashi Suzuki
IPC分类号： B01J23/656 , B01J35/00 , B01J35/02 , B01J35/10 , B01J37/02 , C10G2/00 , C07C27/00
CPC分类号： C10G2/333 , B01J23/6562 , B01J35/0026 , B01J35/023 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J37/0205
摘要： A method for producing hydrocarbons, comprising: (I) subjecting to a reduction treatment a catalyst comprising a carrier having provided thereon: 0.1 to 10% by mass of at least one metal selected from an alkali metal, an alkaline earth metal, a rare earth metal and the Group III in the periodic table and 1 to 30% by mass of ruthenium, each based on the catalyst weight, the carrier comprising an aluminum oxide and a manganese oxide having an average number of charges of manganese of exceeding Mn2+, and the catalyst having a specific surface area of from 60 to 350 m2/g and a bulk density of from 0.8 to 1.8 g/ml; (II) dispersing the catalyst in liquid hydrocarbons in a concentration of from 1 to 50 w/v %; and (III) bringing the catalyst into contact with a gas mixture comprising hydrogen and carbon monoxide at a pressure of from 1 to 10 MPa, and (i) at a reaction temperature of from 170 to 300° C. under such conditions that carbon dioxide is substantially absent, or (ii) at a reaction temperature of from 200 to 350° C. under such conditions that carbon dioxide coexists in an amount of from 0.5 to 50% based on the total pressure of the hydrogen and the carbon monoxide.
摘要翻译：一种碳氢化合物的制造方法，其特征在于，含有：（I）还原处理含有载体的催化剂：0.1〜10质量％的选自碱金属，碱土金属，稀土金属和周期表中的III族和1〜30质量％的钌，各自以催化剂重量计，载体包含氧化铝和氧化锰，其平均锰电荷数超过Mn < 2 +，比表面积为60〜350m 2 / g，堆积密度为0.8〜1.8g / ml的催化剂; （II）将催化剂分散在浓度为1至50w / v％的液体烃中; 和（III）使催化剂与包含氢气和一氧化碳的气体混合物在1至10MPa的压力下接触，和（i）在170-300℃的反应温度下，在二氧化碳基本上不存在，或（ii）在200-350℃的反应温度下，在二氧化碳基于氢气和一氧化碳的总压力共存0.5至50％的量的条件下。

2. 发明申请

US20130289145A1 CATALYST FOR FISCHER-TROPSCH SYNTHESIS, PRODUCTION METHOD THEREFOR, AND PRODUCTION METHOD USING FISCHER-TROPSCH SYNTHESIS CATALYST 审中-公开
标题翻译：用于FISCHER-TROPSCH合成的催化剂，其制备方法和使用FISCHER-TROPSCH合成催化剂的生产方法
公开(公告)号：US20130289145A1
公开(公告)日：2013-10-31
申请号：US13978053
申请日：2012-01-24
申请人： Yasutomo Miura , Shigenori Nakashizu
发明人： Yasutomo Miura , Shigenori Nakashizu
IPC分类号： B01J31/32 , C10G2/00
CPC分类号： B01J31/32 , B01J23/462 , B01J23/6562 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J37/0009 , B01J37/0201 , B01J37/18 , C10G2/333
摘要： The catalyst for FT synthesis comprises manganese carbonate containing from 10 to 25% by mass of silica in terms of an oxide on the basis of the mass of the catalyst, not more than 6% by mass of an organic binder on the basis of the mass of the catalyst, and from 0.5 to 5% by mass of ruthenium in terms of a metal on the basis of the mass of the catalyst, wherein the catalyst has a surface area of 100 to 210 m2/g and a pore volume of 0.1 to 0.6 ml/g.
摘要翻译：用于FT合成的催化剂包括基于催化剂质量以氧化物计含量为10至25质量％的二氧化硅的碳酸锰，基于质量的不超过6质量％的有机粘合剂的催化剂，以催化剂的质量计，以金属计，以钌为0.5〜5质量％，其中，催化剂的表面积为100〜210m 2 / g，孔体积为0.1〜 0.6ml / g。

3. 发明授权

US07612013B2 Hydrocarbon-producing catalyst, process for producing the same, and process for producing hydrocarbons using the catalyst 失效
标题翻译：生产烃的催化剂，其制备方法和使用该催化剂生产烃的方法
公开(公告)号：US07612013B2
公开(公告)日：2009-11-03
申请号：US10585109
申请日：2005-02-23
申请人： Kazuhito Sato , Shigenori Nakashizu , Osamu Iwamoto , Hiroaki Otsuka
发明人： Kazuhito Sato , Shigenori Nakashizu , Osamu Iwamoto , Hiroaki Otsuka
IPC分类号： B01J21/02 , B01J21/04 , B01J23/00 , B01J23/02 , B01J23/04 , B01J23/16 , B01J23/32 , B01J23/34 , B01J23/46 , B01J23/54 , B01J23/56 , B01J23/58 , B01J23/63 , B01J23/64 , B01J23/656
CPC分类号： B01J37/06 , B01J21/04 , B01J23/58 , B01J23/63 , B01J23/6562 , B01J35/1061 , B01J35/108 , B01J37/0205 , B01J37/08 , C10G2/333 , C10G2400/06 , C10G2400/08
摘要： An object of the present invention is to provide a catalyst which, in the FT process, exhibits a high chain growth probability, and a high catalytic activity, can stably and smoothly promote the reaction, exhibits a high productivity of C5+, and can efficiently produce liquid hydrocarbons, and a process therefore. The invention relates to a hydrocarbon-producing catalyst obtainable by supporting a ruthenium compound on a support composed of a manganese oxide and an aluminum oxide, and which satisfies at least one of characteristics (1) and (2): (1) the catalyst being treated with an aqueous alkaline solution and subsequently subjected to calcination treatment in the air at 150 to 500° C., (2) the aluminum oxide being an aluminum oxide wherein pore volume formed by pores having a pore diameter of 8 nm or more accounts for 50% or more of total pore volume.
摘要翻译：本发明的目的是提供一种催化剂，其在FT方法中表现出高链增长概率，并且具有高催化活性，可以稳定和平稳地促进反应，表现出高的C5 +的生产率，并能有效地生产液态碳氢化合物，以及一种方法。本发明涉及一种通过在由氧化锰和氧化铝构成的载体上负载钌化合物而得到的烃产生催化剂，其满足特征（1）和（2）中的至少一个：（1）催化剂为用碱性水溶液处理，随后在150〜500℃的空气中进行煅烧处理，（2）氧化铝为氧化铝，其中孔径为8nm以上的孔形成的细孔容积为总孔体积的50％以上。

4. 发明授权

US5444033A Catalyst compositions for hydrotreating of hydrocarbon oils and process for manufacturing the same. 失效
标题翻译：用于加氢处理烃油的催化剂组合物及其制造方法。
公开(公告)号：US5444033A
公开(公告)日：1995-08-22
申请号：US254424
申请日：1994-06-06
申请人： Kazushi Usui , Shigenori Nakashizu , Kentarou Ishida
发明人： Kazushi Usui , Shigenori Nakashizu , Kentarou Ishida
IPC分类号： B01J23/85 , B01J35/00 , C10G45/08 , B01J21/02 , B01J23/00
CPC分类号： B01J23/85 , B01J35/0006 , C10G45/08 , B01J35/0086
摘要： A catalyst composition for hydrotreating of hydrocarbon oils is disclosed. The composition comprises a Group VIB metal in an amount of 5-30% by weight, as oxide, and a Group VIII metal in an amount of 1-10% by weight, as oxide, wherein said Group VIB metal and said Group VIII metal are distributed with a concentration gradient which becomes higher from the surface toward the center of a catalyst particle according to the formulas, 0.9>h.sub.2 /h.sub.1 .gtoreq.0, wherein h.sub.1 is the Group VIB metal concentration at the center of the catalyst particle and h.sub.2 at the outermost surface of the catalyst particle, and 0.9>h.sub.4 /h.sub.3 .gtoreq.0, wherein h.sub.3 is the Group VIII metal concentration at the center of the catalyst particle and h.sub.4 at the outermost surface of the catalyst particle. The catalyst composition can be used for hydrodesulfurization, hydrodenitrification, hydrodemetalization, and hydrocracking of topping or vacuum distillates and residues, as well as hydrotreatments for the refining of such fractions as kerosene, gas oil, wax, and lubricating oil. It exhibits a high activity for a prolonged period of time. Processes for manufacturing the catalyst composition are also disclosed.
摘要翻译：公开了一种用于加氢处理烃油的催化剂组合物。组合物包含5-30重量％的氧化物的ⅤB族金属和1-10重量％的Ⅷ族金属作为氧化物，其中所述VIB族金属和所述VIII族金属以0.9> h2 / h1> / = 0的方式从催化剂颗粒的表面朝向中心变得更高的浓度梯度分布，其中h1是催化剂颗粒中心处的VIB族金属浓度， h2在催化剂颗粒的最外表面，0.9> h4 / h3> = 0，其中h3是催化剂颗粒中心处的Ⅷ族金属浓度，在催化剂颗粒的最外表面是h4。催化剂组合物可用于加氢脱硫，加氢脱氮，加氢脱矿，顶部或真空馏分和残余物的加氢裂化，以及用于精馏煤油，瓦斯油，蜡和润滑油等馏分的加氢处理。它长时间展现出高活性。还公开了制备催化剂组合物的方法。

5. 发明授权

US4981832A Catalyst composition for hydrogenation of heavy hydrocarbon oil and process for producing the catalyst 失效
标题翻译：用于重质烃油氢化的催化剂组合物和用于生产催化剂的方法
公开(公告)号：US4981832A
公开(公告)日：1991-01-01
申请号：US374805
申请日：1989-07-03
申请人： Kinya Tawara , Kazuyoshi Kudoh , Kazushi Usui , Tomohiro Yoshinari , Shigenori Nakashizu
发明人： Kinya Tawara , Kazuyoshi Kudoh , Kazushi Usui , Tomohiro Yoshinari , Shigenori Nakashizu
IPC分类号： B01J23/88 , B01J23/883 , B01J35/02 , B01J35/10 , C10G45/04 , C10G45/06 , C10G45/08
CPC分类号： B01J35/10 , B01J23/883 , C10G45/04 , B01J35/1042 , B01J35/1061 , B01J35/108
摘要： A catalyst composition for the hydrogenation of heavy hydrocarbon oil, where the catalyst composition comprises at least one active ingredient for hydrogenation supported on a porous alumina carrier and has the following characteristics: (1) the total volume of the pores therein is from 0.4 to 1.0 ml/g; (2) the mean pore diameter of pores having a pore diameter of from 5 to 400 .ANG. is from 60 to 140 .ANG.; (3) the volume of pores having a pore size within .+-.25% of the mean pore diameter of pores having a pore diameter of from 5 to 400 .ANG. is from 60 to 98% of the volume of pores having a pore diameter of from 5 to 400 .ANG.; (4) the volume of pores having a pore diameter of from 400 to 5000 .ANG. is from 2 to 9% of the total volume of the entire pores; (5) the ratio (mm.sup.2 /mm.sup.3) of the outer surface area of a molded catalyst powder to the volume thereof is from 4 to 8; and (6) all points in the interior of the molded catalyst particle are positioned within 0.05 to 0.6 mm from the outer surface thereof. A process for producing the catalyst composition is also disclosed. Further, a process for hydrogenating heavy hydrocarbon oil, which comprises contacting the heavy hydrocarbon oil with the catalyst composition in the presence of hydrogen is disclosed.
摘要翻译：一种用于重质烃油氢化的催化剂组合物，其中催化剂组合物包含至少一种负载在多孔氧化铝载体上的用于氢化的活性成分，并具有以下特征：（1）其中的孔的总体积为0.4-1.0 ml / g; （2）孔径为5至400埃的孔的平均孔径为60至140纳米; （3）孔径为孔径为5〜400的孔的平均孔径的+/- 25％以内的孔的体积为孔径为孔的体积的60〜98％从5到400 ANGSTROM; （4）孔径为400〜5000的孔的体积为整个孔的总体积的2〜9％（5）成型催化剂粉末的外表面积与其体积的比（mm2 / mm3）为4〜8; 和（6）模塑催化剂颗粒内部的所有点位于距其外表面0.05至0.6mm的范围内。还公开了一种制备催化剂组合物的方法。此外，公开了一种用于氢化重质烃油的方法，其包括在氢气存在下使重质烃油与催化剂组合物接触。

6. 发明授权

US09656252B2 Catalyst composition for producing hydrocarbons and method for producing hydrocarbons 有权
公开(公告)号：US09656252B2
公开(公告)日：2017-05-23
申请号：US13503671
申请日：2010-12-07
申请人： Kazuhito Sato , Shigenori Nakashizu
发明人： Kazuhito Sato , Shigenori Nakashizu
IPC分类号： B01J29/48 , B01J29/076 , C10G2/00 , B01J23/656 , B01J23/889 , B01J27/232
CPC分类号： C10G2/334 , B01J23/6562 , B01J23/8892 , B01J27/232 , B01J29/076 , B01J29/48 , C10G2400/02
摘要： There are provided a catalyst composition for producing hydrocarbons and a method for producing hydrocarbons which exhibit a high CO conversion rate, generates minimal amount of gaseous components, and is also capable of efficiently obtaining, from a syngas, a gasoline fraction which is selective for and rich in the components having a high octane number, such as aromatic, naphthenic, olefinic and branched paraffinic hydrocarbons, by using a Fischer-Tropsch synthesis catalyst that contains at least one type of metal exhibiting activity in Fischer-Tropsch reaction and manganese carbonate and a zeolite serving as a solid acid.

7. 发明授权

US08906222B2 Management method for wax fraction storage tank 有权
$Management method for wax fraction storage tank$
标题翻译：蜡馏分储罐管理方法
公开(公告)号：US08906222B2
公开(公告)日：2014-12-09
申请号：US12735082
申请日：2008-12-11
申请人： Shigenori Nakashizu , Yutaka Miyata , Kazuhito Sato
发明人： Shigenori Nakashizu , Yutaka Miyata , Kazuhito Sato
IPC分类号： C10G47/00 , C10G47/36 , C10G73/44 , C10G2/00
CPC分类号： C10G2/30 , C10G2/32 , C10G47/00 , C10G2300/1022 , Y10T137/0324
摘要： The present invention relates to a management method for a wax fraction storage tank that stores a wax fraction produced by Fischer-Tropsch synthesis until the wax fraction is hydrocracked, the management method including maintaining the temperature inside the tank at 90° C. to 130° C. and maintaining the atmosphere inside the tank to be an inert gas atmosphere.
摘要翻译：本发明涉及一种蜡馏分储存罐的管理方法，其存储通过费 - 托合成制造的蜡馏分，直到蜡馏分被加氢裂化为止，所述管理方法包括将罐内的温度保持在90℃至130℃ 并且将罐内的气氛保持为惰性气体气氛。

8. 发明授权

US5494875A Alumina-containing carrier and hydrofining catalyst for hydrocarbon oils 失效
标题翻译：含氧化铝载体和烃油加氢精制催化剂
公开(公告)号：US5494875A
公开(公告)日：1996-02-27
申请号：US90451
申请日：1993-07-13
申请人： Kazushi Usui , Shigenori Nakashizu , Kentarou Ishida , Eiko Kogure
发明人： Kazushi Usui , Shigenori Nakashizu , Kentarou Ishida , Eiko Kogure
IPC分类号： B01J21/04 , B01J23/88 , B01J23/882 , B01J32/00 , B01J35/00 , C10G45/04 , C10G45/08 , C10G49/04 , B01J23/28
CPC分类号： C10G45/08 , B01J23/882 , B01J35/002
摘要： A carrier suitable for preparing a catalyst for hydrofining hydrocarbon oils which has a high ability to eliminate metals contained in the hydrocarbon oils and an improved metal tolerance as well as said catalyst are provided.The carrier of the present invention is an alumina-containing carrier which shows a peak at 2.theta. of 27.degree. in the powder X-ray diffraction pattern when carrying Mo and Co or one or more other metals selected from among metals of the groups VIA and VIII in the periodic table together with Mo and Co.
摘要翻译：提供了适用于制备用于加氢精制烃油的催化剂的载体，其具有高的消除烃油中所含金属的能力和改善的金属耐受性以及所述催化剂。本发明的载体是含氧载体，当携带Mo和Co或选自VIA族的金属中的一种或多种其它金属时，在粉末X射线衍射图中，在2θ处的峰值为27°，周期表中的VIII与Mo和Co.

9. 发明授权

US08598063B2 Catalyst for Fischer-Tropsch synthesis and method for producing hydrocarbons 有权
标题翻译：费 - 托合成催化剂及其制备方法
公开(公告)号：US08598063B2
公开(公告)日：2013-12-03
申请号：US13000915
申请日：2009-05-15
申请人： Kazuhito Sato , Shigenori Nakashizu
发明人： Kazuhito Sato , Shigenori Nakashizu
IPC分类号： B01J21/18 , B01J27/20 , B01J23/32 , B01J23/40 , B01J23/42 , B01J23/58 , C07C27/00 , C07C27/06
CPC分类号： B01J23/8892 , B01J23/6562 , B01J23/8986 , B01J27/232 , B01J35/023 , B01J37/0009 , B01J37/0045 , B01J37/0201 , B01J37/0207 , B01J37/06 , B01J37/18 , C10G2/33
摘要： A catalyst for FT synthesis which, in the FT method, is high in a CO conversion and small in the formation of a gaseous component and can stably perform an FT synthesis reaction and enhance the productivity of hydrocarbons, and a method for producing hydrocarbons using the catalyst, are provided. A catalyst for Fischer-Tropsch synthesis comprising a support containing manganese carbonate as a main component, wherein the support contains at least one metal having an activity to the Fischer-Tropsch reaction; and a method for producing hydrocarbons using this catalyst.
摘要翻译：一种用于FT合成的催化剂，其在FT方法中CO转化率高，气态组分形成小，并且可以稳定地进行FT合成反应并提高烃的生产率，以及使用催化剂。一种用于费 - 托合成的催化剂，其包含含有碳酸锰作为主要成分的载体，其中所述载体含有至少一种对费 - 托反应具有活性的金属; 以及使用该催化剂制造烃的方法。

10. 发明申请

US20120208905A1 CATALYST COMPOSITION FOR PRODUCING HYDROCARBONS AND METHOD FOR PRODUCING HYDROCARBONS 有权
标题翻译：用于生产碳氢化合物的催化剂组合物和生产烃类的方法
公开(公告)号：US20120208905A1
公开(公告)日：2012-08-16
申请号：US13503671
申请日：2010-12-07
申请人： Kazuhito Sato , Shigenori Nakashizu
发明人： Kazuhito Sato , Shigenori Nakashizu
IPC分类号： B01J29/04 , C07C1/04 , B01J29/48
CPC分类号： C10G2/334 , B01J23/6562 , B01J23/8892 , B01J27/232 , B01J29/076 , B01J29/48 , C10G2400/02
摘要： There are provided a catalyst composition for producing hydrocarbons and a method for producing hydrocarbons which exhibit a high CO conversion rate, generates minimal amount of gaseous components, and is also capable of efficiently obtaining, from a syngas, a gasoline fraction which is selective for and rich in the components having a high octane number, such as aromatic, naphthenic, olefinic and branched paraffinic hydrocarbons, by using a Fischer-Tropsch synthesis catalyst that contains at least one type of metal exhibiting activity in Fischer-Tropsch reaction and manganese carbonate and a zeolite serving as a solid acid.
摘要翻译：提供了一种用于生产烃的催化剂组合物和一种生产碳氢化合物的方法，其表现出高CO转化率，产生最少量的气态组分，并且还能够从合成气中有效地获得选择性的汽油馏分富含高辛烷值的组分，如芳族，环烷烃，烯烃和支链链烷烃，通过使用费 - 托合成催化剂，其包含在费 - 托反应中表现出活性的至少一种金属和碳酸锰和沸石作为固体酸。

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