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    • 1. 发明授权
    • Process for preparing polysiloxane-containing resin
    • 制备含多羟基树脂的方法
    • US5079312A
    • 1992-01-07
    • US522401
    • 1990-05-11
    • Osamu IsozakiNoboru NakaiKoichiro Murata
    • Osamu IsozakiNoboru NakaiKoichiro Murata
    • C08F30/08C08F283/12C08F290/00C08F299/08C08G77/20C08G77/22C08G77/42
    • C08F283/124C08G77/20
    • The invention provides a process for preparing a polysiloxane-containing resin which comprises copolymerizing a polysiloxane-type macromonomer with a vinyl monomer, characterized in that the polysiloxane-type macromonomer is one prepared by reacting about 70 to about 99.999 mole % of a compound (A) represented by the formula ##STR1## wherein R.sub.1 represents aliphatic hydrocarbon group having 1 to 8 carbon atoms or phenyl group, and R.sub.2, R.sub.3 and R.sub.4 each represent alkoxyl group having 1 to 4 carbon atoms or hydroxyl group with about 30 to about 0.001 mole % of a compound (B) represented by the formula ##STR2## wherein R.sub.5 represents hydrogen atom or methyl group, R.sub.6, R.sub.7 and R.sub.8 each represent hydroxyl group, alkoxyl group having 1 to 4 carbon atoms or aliphatic hydrocarbon group having 1 to 8 carbon atoms with the proviso that R.sub.6, R.sub.7 and R.sub.8 can not be aliphatic hydrocarbon groups having 1 to 8 carbon atoms at the same time, and n is an integer of 1 to 6, the polysiloxane-type macromonomer having at least two free functional groups selected from hydroxyl groups and alkoxyl groups per molecule, and the macromonomer having a number-average molecular weight of about 400 to about 100,000.
    • 本发明提供一种制备含聚硅氧烷的树脂的方法,其包括将聚硅氧烷型大分子单体与乙烯基单体共聚,其特征在于,所述聚硅氧烷型大分子单体是通过使约70-约99.999摩尔%的化合物(A ),其中R 1表示具有1至8个碳原子的脂族烃基或苯基,R 2,R 3和R 4各自表示具有1至4个碳原子的烷氧基或羟基,其中约30至 约0.001摩尔%的由式(II)表示的化合物(B),其中R5表示氢原子或甲基,R6,R7和R8各自表示羟基,具有1至4个碳原子的烷氧基或脂族烃 具有1至8个碳原子的基团,条件是R 6,R 7和R 8不能同时为具有1至8个碳原子的脂族烃基,n为1至6的整数,聚硅氧烷型大分子量 具有至少两个选自每个分子的羟基和烷氧基的游离官能团,并且大分子单体的数均分子量为约400至约100,000。
    • 3. 发明授权
    • Dispersion-type resin composition, curable composition and coating
composition
    • 分散型树脂组合物,固化性组合物和涂料组合物
    • US5418293A
    • 1995-05-23
    • US117321
    • 1993-09-07
    • Nobushige NumaAkimasa NakahataMasahiro YamaneOsamu IsozakiNoboru Nakai
    • Nobushige NumaAkimasa NakahataMasahiro YamaneOsamu IsozakiNoboru Nakai
    • C08L27/12C08F2/08C08F2/14C08F2/44C09D127/12C09D127/16C08F259/08C08F259/00
    • C08F2/08
    • The invention provides: 1) a dispersion-type resin composition including polymer particles insoluble in an organic solvent, the resin composition being prepared by polymerizing a radically polymerizable unsaturated monomer in the organic solvent in the presence of a fluorine-type resin containing silane group and epoxy group; 2) a resin composition including polymer particles insoluble in an organic solvent, the resin composition being prepared by polymerizing a radically polymerizable unsaturated monomer in the organic solvent in the presence of a dispersion stabilizer comprising at least one of a component (I) having silane group, and a component (II) having epoxy group, at least one of components (I) and (II) being a fluorine-containing resin; 3) a curable composition including one of the resin compositions 1) and 2) and a metal chelate compound; and 4) a coating composition including one of the curable composition and the resin compositions.
    • 本发明提供:1)一种分散型树脂组合物,其包含不溶于有机溶剂的聚合物颗粒,该树脂组合物是通过在含有硅烷基团的含氟型树脂和含硅烷基团的存在下使有机溶剂中的可自由基聚合的不饱和单体聚合而制备的, 环氧基; 2)包含不溶于有机溶剂的聚合物颗粒的树脂组合物,所述树脂组合物通过在包含具有硅烷基的组分(I)中的至少一种的分散稳定剂的存在下在有机溶剂中聚合自由基聚合性不饱和单体而制备) ,和具有环氧基的组分(II),组分(I)和(II)中的至少一种是含氟树脂; 3)包含树脂组合物1)和2)和金属螯合物之一的可固化组合物; 和4)包含可固化组合物和树脂组合物之一的涂料组合物。
    • 6. 发明授权
    • Aqueous organosilicon resin coating compositions
    • 水性有机硅树脂涂料组合物
    • US5008328A
    • 1991-04-16
    • US313367
    • 1989-02-21
    • Noboru NakaiOsamu Isozaki
    • Noboru NakaiOsamu Isozaki
    • C08G77/14C08G77/22C08G77/28C08G77/388C09D183/04C09D183/06C09D183/08
    • C09D183/08C08G77/388C09D183/06
    • This invention provides an aqueous organosilicon resin coating composition comprising:(I) an aqueous organosilicon resin which is a condensation product and which contains a quaternary ammonium base, the condensation product being prepared from (i) an organosilicon compound represented by the formulaR.sup.1.sub.a Si(OR.sup.2).sub.4-a (A) wherein R.sup.1 is hydrocarbon group having 1 to 12 carbon atoms, R.sup.2 is hydrocarbon group having 1 to 8 carbon atoms and a is 0, 1 or 2, and/or a low condensate thereof and (ii) an organosilicon compound represented by the formula ##STR1## wherein R.sup.3 is hydrogen atom or methyl group, R.sup.4 is bivalent hydrocarbon group having 1 to 8 carbon atoms and R.sup.2 is as defined above, and/or a low condensate thereof and,(II) an aqueous medium.
    • 本发明提供一种水性有机硅树脂涂料组合物,其包含:(I)水性有机硅氧烷树脂,其为缩合产物并且含有季铵碱,所述缩合产物由(i)由式R 1a a(OR 2)表示的有机硅化合物 )4-a(A)其中R 1是具有1至12个碳原子的烃基,R 2是具有1至8个碳原子的烃基,a是0,1或2,和/或其低缩合物和(ii) 由式(B)表示的有机硅化合物,其中R 3为氢原子或甲基,R 4为碳原子数为1〜8的二价烃基,R 2如上所定义,和/或低级缩合物,(II) )水性介质。
    • 8. 发明授权
    • Hydroxyl and epoxy polymer, hydrolyzable silicone polymer, either
containing flourine monomer
    • 羟基和环氧聚合物,可水解的硅氧烷聚合物,含有含氟单体
    • US5525673A
    • 1996-06-11
    • US277429
    • 1994-07-18
    • Akimasa NakahataNobushige NumaMasahiro YamaneOsamu IsozakiNoboru Nakai
    • Akimasa NakahataNobushige NumaMasahiro YamaneOsamu IsozakiNoboru Nakai
    • C08L63/00C09D201/04C08F4/52C08F4/76C08F24/00C08F30/08
    • C08L63/00C09D201/04
    • Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two-component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.
    • 公开的是:1)包含含羟基的化合物(A),含环氧基的化合物(B)和含硅烷基的化合物(C)的三组分树脂组合物; 2)包含含羟基的化合物(A)和含硅烷基和含环氧基的化合物(D)的双组分树脂组合物; 3)包含含羟基和含硅烷基的化合物(E)和含环氧基的化合物(B)的双组分树脂组合物; 和4)包含含羟基和含环氧基的化合物(F)和含硅烷基化合物(C)的双组分树脂组合物; 其中,树脂组合物1)〜4)中的至少一种成分为含氟树脂, 5)包含树脂组合物1)至4)之一的可固化组合物和作为固化催化剂的金属螯合物; 和6)包含这种固化组合物和需要时颜料的涂料组合物。