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1. 发明授权

US5408001A Hydroxyl and hydrolyzable groups-containing silicone resin with polyepoxy compound 失效
标题翻译：含羟基和可水解基团的硅氧烷树脂与聚环氧化合物
公开(公告)号：US5408001A
公开(公告)日：1995-04-18
申请号：US107580
申请日：1993-08-18
申请人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
发明人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
IPC分类号： C08L63/00 , C09D201/04 , C08L27/12 , C08L27/14 , C08L33/14 , C08L63/02
CPC分类号： C08L63/00 , C09D201/04
摘要： Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two-component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.
摘要翻译：公开的是：1）包含含羟基的化合物（A），含环氧基的化合物（B）和含硅烷基的化合物（C）的三组分树脂组合物; 2）包含含羟基的化合物（A）和含硅烷基和含环氧基的化合物（D）的双组分树脂组合物; 3）包含含羟基和含硅烷基的化合物（E）和含环氧基的化合物（B）的双组分树脂组合物; 和4）包含含羟基和含环氧基的化合物（F）和含硅烷基化合物（C）的双组分树脂组合物; 其中，树脂组合物1）〜4）中的至少一种成分为含氟树脂， 5）包含树脂组合物1）至4）之一的可固化组合物和作为固化催化剂的金属螯合物; 和6）包含这种固化组合物和需要时颜料的涂料组合物。

2. 发明授权

US5525673A Hydroxyl and epoxy polymer, hydrolyzable silicone polymer, either containing flourine monomer 失效
标题翻译：羟基和环氧聚合物，可水解的硅氧烷聚合物，含有含氟单体
公开(公告)号：US5525673A
公开(公告)日：1996-06-11
申请号：US277429
申请日：1994-07-18
申请人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
发明人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
IPC分类号： C08L63/00 , C09D201/04 , C08F4/52 , C08F4/76 , C08F24/00 , C08F30/08
CPC分类号： C08L63/00 , C09D201/04
摘要： Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two-component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.
摘要翻译：公开的是：1）包含含羟基的化合物（A），含环氧基的化合物（B）和含硅烷基的化合物（C）的三组分树脂组合物; 2）包含含羟基的化合物（A）和含硅烷基和含环氧基的化合物（D）的双组分树脂组合物; 3）包含含羟基和含硅烷基的化合物（E）和含环氧基的化合物（B）的双组分树脂组合物; 和4）包含含羟基和含环氧基的化合物（F）和含硅烷基化合物（C）的双组分树脂组合物; 其中，树脂组合物1）〜4）中的至少一种成分为含氟树脂， 5）包含树脂组合物1）至4）之一的可固化组合物和作为固化催化剂的金属螯合物; 和6）包含这种固化组合物和需要时颜料的涂料组合物。

3. 发明授权

US5260376A Resin composition, curable composition and coating composition 失效
标题翻译：树脂组合物，可固化组合物和涂料组合物
公开(公告)号：US5260376A
公开(公告)日：1993-11-09
申请号：US904257
申请日：1992-06-25
申请人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
发明人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
IPC分类号： C08L63/00 , C09D201/04 , C08L27/14 , C08L83/00
CPC分类号： C08L63/00 , C09D201/04
摘要： Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.
摘要翻译：公开的是：1）包含含羟基的化合物（A），含环氧基的化合物（B）和含硅烷基的化合物（C）的三组分树脂组合物; 2）包含含羟基的化合物（A）和含硅烷基和含环氧基的化合物（D）的双组分树脂组合物; 3）包含含羟基和含硅烷基的化合物（E）和含环氧基的化合物（B）的双组分树脂组合物; 和4）包含含羟基和含环氧基的化合物（F）和含硅烷基化合物（C）的双组分树脂组合物; 其中，树脂组合物1）〜4）中的至少一种成分为含氟树脂， 5）包含树脂组合物1）至4）之一的可固化组合物和作为固化催化剂的金属螯合物; 和6）包含这种固化组合物和需要时颜料的涂料组合物。

4. 发明授权

US5418293A Dispersion-type resin composition, curable composition and coating composition 失效
标题翻译：分散型树脂组合物，固化性组合物和涂料组合物
公开(公告)号：US5418293A
公开(公告)日：1995-05-23
申请号：US117321
申请日：1993-09-07
申请人： Nobushige Numa , Akimasa Nakahata , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
发明人： Nobushige Numa , Akimasa Nakahata , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
IPC分类号： C08L27/12 , C08F2/08 , C08F2/14 , C08F2/44 , C09D127/12 , C09D127/16 , C08F259/08 , C08F259/00
CPC分类号： C08F2/08
摘要： The invention provides: 1) a dispersion-type resin composition including polymer particles insoluble in an organic solvent, the resin composition being prepared by polymerizing a radically polymerizable unsaturated monomer in the organic solvent in the presence of a fluorine-type resin containing silane group and epoxy group; 2) a resin composition including polymer particles insoluble in an organic solvent, the resin composition being prepared by polymerizing a radically polymerizable unsaturated monomer in the organic solvent in the presence of a dispersion stabilizer comprising at least one of a component (I) having silane group, and a component (II) having epoxy group, at least one of components (I) and (II) being a fluorine-containing resin; 3) a curable composition including one of the resin compositions 1) and 2) and a metal chelate compound; and 4) a coating composition including one of the curable composition and the resin compositions.
摘要翻译：本发明提供：1）一种分散型树脂组合物，其包含不溶于有机溶剂的聚合物颗粒，该树脂组合物是通过在含有硅烷基团的含氟型树脂和含硅烷基团的存在下使有机溶剂中的可自由基聚合的不饱和单体聚合而制备的，环氧基; 2）包含不溶于有机溶剂的聚合物颗粒的树脂组合物，所述树脂组合物通过在包含具有硅烷基的组分（I）中的至少一种的分散稳定剂的存在下在有机溶剂中聚合自由基聚合性不饱和单体而制备），和具有环氧基的组分（II），组分（I）和（II）中的至少一种是含氟树脂; 3）包含树脂组合物1）和2）和金属螯合物之一的可固化组合物; 和4）包含可固化组合物和树脂组合物之一的涂料组合物。

5. 发明授权

US5387646A Fluorine-type resin composition, curable composition and coating composition 失效
标题翻译：氟类树脂组合物，可固化组合物和涂料组合物
公开(公告)号：US5387646A
公开(公告)日：1995-02-07
申请号：US43984
申请日：1993-04-07
申请人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
发明人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
IPC分类号： C08L27/12 , C08G59/30 , C08G59/32 , C08G59/70 , C08L43/04 , C09D127/12 , C09D127/16 , C09D163/00 , C08L27/14 , C08L83/00
CPC分类号： C09D163/00 , C08G59/306 , C08G59/32 , C08G59/70 , C08L43/04
摘要： The invention provides:1) a fluorine-containing resin composition including:a) a fluorine-containing resin having (i) a hydrolyzable group attached directly to a silicon atom and/or a silanol group and (ii) an epoxy group in the molecule, orb) a mixture of a component (I) having a hydrolyzable group attached directly to a silicon atom and/or a silanol group and a component (II) having an epoxy group, such that at least one of the components (I) and (II) is a fluorine-containing resin;2) a curable composition including the resin composition and a metal chelate compound; and3) a coating composition including this resin composition or this curable composition.
摘要翻译：本发明提供：1）一种含氟树脂组合物，其包含：a）含有（i）直接与硅原子和/或硅烷醇基相连的水解基团和（ii）分子中的环氧基的含氟树脂或b）具有直接与硅原子直接连接的可水解基团的组分（I）和/或硅烷醇基的组分和具有环氧基的组分（II）的混合物，使得组分（I）中的至少一种和（II）是含氟树脂; 2）包含该树脂组合物和金属螯合物的可固化组合物; 和3）包含该树脂组合物或该可固化组合物的涂料组合物。

6. 发明授权

US5166265A Resin composition, curable composition and coating composition 失效
标题翻译：树脂组合物，可固化组合物和涂料组合物
公开(公告)号：US5166265A
公开(公告)日：1992-11-24
申请号：US486697
申请日：1990-03-01
申请人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
发明人： Akimasa Nakahata , Nobushige Numa , Masahiro Yamane , Osamu Isozaki , Noboru Nakai
IPC分类号： C08G59/00 , C08G59/18 , C08G59/20 , C08G59/40 , C08G59/62 , C08G59/68 , C08G59/70 , C08L63/00 , C09D163/00 , C09D201/04
CPC分类号： C08L63/00 , C09D201/04
摘要： Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two-component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.
摘要翻译：公开的是：1）包含含羟基的化合物（A），含环氧基的化合物（B）和含硅烷基的化合物（C）的三组分树脂组合物; 2）包含含羟基的化合物（A）和含硅烷基和含环氧基的化合物（D）的双组分树脂组合物; 3）包含含羟基和含硅烷基的化合物（E）和含环氧基的化合物（B）的双组分树脂组合物; 和4）包含含羟基和含环氧基的化合物（F）和含硅烷基化合物（C）的双组分树脂组合物; 其中，树脂组合物1）〜4）中的至少一种成分为含氟树脂， 5）包含树脂组合物1）至4）之一的可固化组合物和作为固化催化剂的金属螯合物; 和6）包含这种固化组合物和需要时颜料的涂料组合物。

7. 发明授权

US06780902B2 Water-based coating composition 失效
标题翻译：水性涂料组合物
公开(公告)号：US06780902B2
公开(公告)日：2004-08-24
申请号：US10149435
申请日：2002-06-24
申请人： Yuji Hirose , Noboru Nakai , Reiziro Nishida , Nobushige Numa
发明人： Yuji Hirose , Noboru Nakai , Reiziro Nishida , Nobushige Numa
IPC分类号： C08K320
CPC分类号： C09D163/00 , C08G59/12 , C09D167/00 , C08L2666/04 , C08L33/00
摘要： The present invention provides an aqueous coating composition comprising a carboxyl-containing, acrylic-modified polyester resin (B) neutralized and dispersed in an aqueous medium, the polyester resin (B) being obtainable by reacting a carboxyl-containing acrylic resin (c) with an epoxy-modified polyester resin (A) prepared by esterification of a carboxyl-containing polyester resin (a) having a number average molecular weight of 1,000 to 30,000 and an acid value of 5 to 200 mg KOH/g with a 1,2-epoxy-containing low-molecular-weight epoxy compound (b) having a number average molecular weight of 1,200 or less.
摘要翻译：本发明提供一种水性涂料组合物，其包含中和并分散在水性介质中的含羧基的丙烯酸改性聚酯树脂（B），所述聚酯树脂（B）可通过使含羧基的丙烯酸树脂（c）与通过使数均分子量为1,000〜30,000，酸值为5〜200mgKOH / g的含羧基的聚酯树脂（a）与1,2-二羟基苯乙烯酯进行酯化而制备的环氧改性聚酯树脂（A）含环氧基的低分子量环氧化合物（b）的数均分子量为1200以下。

8. 发明授权

US06268429B1 Aqueous coating and method for film formation using the same 失效
标题翻译：水性涂料及其成膜方法
公开(公告)号：US06268429B1
公开(公告)日：2001-07-31
申请号：US09482001
申请日：2000-01-13
申请人： Masaru Mitsuji , Nobushige Numa , Yugen Kawamoto
发明人： Masaru Mitsuji , Nobushige Numa , Yugen Kawamoto
IPC分类号： C08L6702
CPC分类号： C09D133/066 , C08L33/062 , C08L61/20 , C08L61/32 , C09D167/00 , C08L2666/14 , C08L2666/28 , C08L2666/02
摘要： The present invention provides an aqueous coating comprising: (A) a resin having hydroxyl group and carboxyl group in the molecule, (B) an alkyl-etherified methylolmelamine resin, and (C) an oxazoline group-containing compound. This aqueous coating can alleviate the problems of conventional aqueous coatings comprising (a) a resin having hydroxyl group and carboxyl group and (b) an alkyl-etherified methylolmelamine resin.
摘要翻译：本发明提供一种水性涂料，其包含：（A）分子中具有羟基和羧基的树脂，（B）烷基醚化羟甲基三聚氰胺树脂和（C）含有恶唑啉基的化合物。该水性涂料可以缓解常规水性涂料的问题包括（a）具有羟基和羧基的树脂和（b）烷基醚化的羟甲基三聚氰胺树脂。

9. 发明授权

US5658988A Resinous composition for coating 失效
标题翻译：用于涂层的树脂组合物
公开(公告)号：US5658988A
公开(公告)日：1997-08-19
申请号：US496481
申请日：1995-06-29
申请人： Shinichi Ogino , Nobushige Numa , Shinji Tomita , Hajime Sukejima
发明人： Shinichi Ogino , Nobushige Numa , Shinji Tomita , Hajime Sukejima
IPC分类号： C08F230/08 , C08G18/62 , C08G18/72 , C09D201/10 , C08L43/04 , C08L83/06
CPC分类号： C08G18/6295 , C08F230/08 , C08G18/728 , C09D201/10 , Y10T428/31547 , Y10T428/31663 , Y10T428/31855
摘要： A one-package resinous coating composition, especially for automobile finishes (A) a resin having a siloxy group, and (B) a catalyst for dissociating the siloxy group. Resinous mixture (A) contains one or more of the following (A-1) through (A-4). (A-1) a mixture of (a) a resin that contains at least one siloxy group and one alkoxysilyl group respectively in the one molecule, and (b) a resin that contains at least one isocyanate group and one alkoxysilyl group respectively in the one molecule; (A-2) a mixture of (a) a resin that contains at least one siloxy group and one alkoxysilyl group respectively in the one molecule, and (c) a compound or a resin that contains at least two isocyanate groups in the one molecule; (A-3) a mixture of (b) a resin that contains at least one isocyanate group and one alkoxysilyl group respectively in the one molecule, and (d) a compound or a resin that contains at least two siloxy groups in the one molecule; and (A-4) (e) a resin that contains at least one siloxy group, one isocyanate group and one alkoxysilyl group respectively in the one molecule.
摘要翻译：一种单组分树脂涂料组合物，特别是用于汽车涂料（A）具有甲硅烷氧基的树脂，和（B）用于解离甲硅烷氧基的催化剂。树脂混合物（A）含有以下（A-1）〜（A-4）中的一种以上。（A-1）分子中分别含有至少一个甲硅烷氧基和一个烷氧基甲硅烷基的树脂的混合物，和（b）分别含有至少一个异氰酸酯基和一个烷氧基甲硅烷基的树脂一分子（A-2）（a）在一个分子中分别含有至少一个甲硅烷氧基和一个烷氧基甲硅烷基的树脂的混合物，和（c）在一个分子中含有至少两个异氰酸酯基团的化合物或树脂 ; （A-3）分子中的（b）分子中含有至少一个异氰酸酯基和一个烷氧基甲硅烷基的树脂的混合物，和（d）在一个分子中含有至少两个甲硅烷氧基的化合物或树脂 ; 和（A-4）（e）分子中含有至少一个甲硅烷氧基，一个异氰酸酯基和一个烷氧基甲硅烷基的树脂。

10. 发明授权

US06706818B2 Curable resin composition 失效
标题翻译：可固化树脂组合物
公开(公告)号：US06706818B2
公开(公告)日：2004-03-16
申请号：US10156793
申请日：2002-05-30
申请人： Yushichi Ishihara , Masami Sugishima , Nobushige Numa , Mitsutaka Hasegawa , Hiroshi Inukai
发明人： Yushichi Ishihara , Masami Sugishima , Nobushige Numa , Mitsutaka Hasegawa , Hiroshi Inukai
IPC分类号： C08G1862
CPC分类号： C09D175/16 , C08F290/067 , C08G18/672 , C08G18/0823
摘要： This invention provides a curable resin composition for one-pack type water-based paint which is readily cured regardless of coating environment, said resin composition comprising copolymer (I) which is produced by the copolymerization of unsaturated group-containing urethane prepolymer (A) which is obtained from a reaction of diisocyanate compound (a), glycol compound (b), carboxyl group-containing glycol compound (c) and hydroxyl group-containing ethylenically unsaturated monomer (d), with maleimide group-containing ethylenically unsaturated monomer (e), carbonyl group-containing ethylenically unsaturated monomer (f) and another ethylenically unsaturated monomer (g), and compound (II) which has, per molecule, two or more same or different functional groups selected from hydrazide group, semicarbazide group and hydrazone group
摘要翻译：本发明提供了一种单组分型水性涂料用固化型树脂组合物，其涂料环境无论易于固化，所述树脂组合物包含通过使含不饱和基团的氨基甲酸酯预聚物（A）的共聚制备的共聚物（I）由二异氰酸酯化合物（a），二醇化合物（b），含羧基的二醇化合物（c）和含羟基的烯属不饱和单体（d）与含有马来酰亚胺基的烯键式不饱和单体（e）的反应得到，，含羰基的烯键式不饱和单体（f）和另一种烯键式不饱和单体（g）和每分子具有两个或多个相同或不同的选自酰肼基，氨基脲基和腙基的官能团的化合物（II）

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