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    • 2. 发明申请
    • In-situ nitridation of high-k dielectrics
    • 高k电介质的原位氮化
    • US20060273411A1
    • 2006-12-07
    • US11146826
    • 2005-06-07
    • Dina TriyosoOlubunmi AdetutuHsing Tseng
    • Dina TriyosoOlubunmi AdetutuHsing Tseng
    • H01L29/78H01L21/336
    • H01L29/517H01L21/28194H01L21/28202H01L21/28229H01L29/513H01L29/518H01L29/78
    • A semiconductor fabrication process for forming a gate dielectric includes depositing a high-k dielectric stack including incorporating nitrogen into the high-k dielectric stack in-situ. A top high-k dielectric is formed overlying the dielectric stack and the dielectric stack and the top dielectric are annealed. Depositing the dielectric stack may include depositing a plurality of high-k dielectric layers where each layer is formed in a distinct processing step or set of steps. Depositing one of the dielectric layers may include performing a plurality of atomic layer deposition processes to form a plurality of high-k sublayers, wherein each sublayer is a monolayer film. Depositing the plurality of sublayers may include depositing a nitrogen free sublayer and depositing a nitrogen bearing sublayer. Depositing the nitrogen free sublayer may include pulsing an ALD chamber with HfCl4, purging the chamber with an inert, pulsing the chamber with an H2O or D2O, and purging the chamber with an inert.
    • 用于形成栅极电介质的半导体制造工艺包括沉积高k电介质堆叠,其包括将氮掺杂到原位的高k电介质堆叠中。 形成覆盖在电介质堆叠上的顶部高k电介质,并且电介质堆叠和顶部电介质被退火。 沉积介质堆叠可以包括沉积多个高k电介质层,其中每个层以不同的处理步骤或一组步骤形成。 沉积一个电介质层可以包括执行多个原子层沉积工艺以形成多个高k子层,其中每个子层是单层膜。 沉积多个子层可以包括沉积无氮的子层并沉积含氮的子层。 沉积无氮子层可以包括用HfCl 4脉冲发射ALD室,用惰性气体冲洗室,用H 2 O 2或D 2 并且用惰性气体清洗室。
    • 5. 发明申请
    • Transitional dielectric layer to improve reliability and performance of high dielectric constant transistors
    • 过渡介电层提高高介电常数晶体管的可靠性和性能
    • US20060220157A1
    • 2006-10-05
    • US11096515
    • 2005-03-31
    • Sriram KalpatVoon-Yew TheanHsing TsengOlubunmi Adetutu
    • Sriram KalpatVoon-Yew TheanHsing TsengOlubunmi Adetutu
    • H01L29/78H01L21/469
    • H01L21/022H01L21/02175H01L21/0228H01L21/28194H01L21/3141H01L29/513H01L29/517
    • A gate dielectric structure (201) fabrication process includes forming a transitional dielectric film (205) overlying a silicon oxide film (204). A high dielectric constant film (206) is then formed overlying an upper surface of the transitional dielectric film (205). The composition of the transitional dielectric film (205) at the silicon oxide film (204) interface primarily comprises silicon and oxygen. The high K dielectric (206) and the composition of the transitional dielectric film (205) near the upper surface primarily comprise a metal element and oxygen. Forming the transitional dielectric film (205) may include forming a plurality of transitional dielectric layers (207) where the composition of each successive transitional dielectric layer (207) has a higher concentration of the metal element and a lower concentration of silicon. Forming the transitional dielectric layer (205) may include performing multiple cycles of an atomic layer deposition process (500) where a precursor concentration for each cycle differs from the precursor concentration of the preceding cycle.
    • 栅极电介质结构(201)制造工艺包括形成覆盖氧化硅膜(204)的过渡电介质膜(205)。 然后形成覆盖在过渡介电膜(205)的上表面上的高介电常数膜(206)。 氧化硅膜(204)界面处的过渡电介质膜(205)的组成主要包括硅和氧。 高K电介质(206)和上表面附近的过渡电介质膜(205)的组成主要包括金属元素和氧。 形成过渡电介质膜(205)可以包括形成多个过渡电介质层(207),其中每个连续的过渡介电层(207)的组成具有较高的金属元素浓度和较低的硅浓度。 形成过渡电介质层(205)可以包括执行原子层沉积工艺(500)的多个循环,其中每个循环的前体浓度与先前循环的前体浓度不同。
    • 8. 发明申请
    • Plasma impurification of a metal gate in a semiconductor fabrication process
    • 半导体制造工艺中的金属栅极的等离子体杂质化
    • US20060084217A1
    • 2006-04-20
    • US10969486
    • 2004-10-20
    • Tien LuoOlubunmi AdetutuHsing Tseng
    • Tien LuoOlubunmi AdetutuHsing Tseng
    • H01L21/4763
    • H01L21/76888H01L21/28088H01L21/28176H01L21/823842H01L29/4966H01L29/517H01L29/518H01L29/78
    • A semiconductor fabrication includes forming a gate dielectric overlying a semiconductor substrate and depositing a metal gate film overlying the gate dielectric. Following deposition of the metal gate film, nitrogen, carbon, and/or oxygen is introduced into the metal gate film by exposing the metal gate film to a nitrogen, carbon, and/or oxygen bearing plasma. Thereafter, the nitrogenated/oxygenated/carbonated metal gate film is patterned to form a transistor gate electrode. Depositing the metal gate film is preferably done with a low energy process such as atomic layer deposition (ALD) or metal organic chemical vapor deposition (MOCVD) to reduce damage to the underlying gate dielectric. The metal gate film for NMOS devices is preferably a compound of nitrogen and Ti, W, or Ta. A second metal gate film may be used for PMOS devices. This second metal gate film is preferably a compound of oxygen and Ir, Ru, Mo, or Re.
    • 半导体制造包括形成覆盖在半导体衬底上的栅极电介质并沉积覆盖栅极电介质的金属栅极膜。 在金属栅极膜沉积之后,通过将金属栅极膜暴露于氮,碳和/或含氧等离子体,将氮,碳和/或氧引入金属栅极膜。 此后,对氮化/氧化/碳酸化的金属栅极膜进行构图以形成晶体管栅电极。 优选地,通过诸如原子层沉积(ALD)或金属有机化学气相沉积(MOCVD)的低能量过程来沉积金属栅极膜以减少对下面的栅极电介质的损伤。 用于NMOS器件的金属栅极膜优选为氮和Ti,W或Ta的化合物。 PMOS器件可以使用第二金属栅极膜。 该第二金属栅极膜优选为氧和Ir,Ru,Mo或Re的化合物。
    • 10. 发明申请
    • Semiconductor process for forming stress absorbent shallow trench isolation structures
    • 用于形成应力吸收性浅沟槽隔离结构的半导体工艺
    • US20060110892A1
    • 2006-05-25
    • US10996319
    • 2004-11-22
    • Marius OrlowskiMark FoisyOlubunmi Adetutu
    • Marius OrlowskiMark FoisyOlubunmi Adetutu
    • H01L21/76
    • H01L29/7842H01L21/76224H01L21/76229H01L21/823807H01L21/823878
    • A semiconductor fabrication process includes patterning a hard mask over a semiconductor substrate to expose an isolation region and forming a trench in the isolation region. A flowable dielectric is deposited in the trench to partially fill the trench and a capping dielectric is deposited overlying the first oxide to fill the trench. The substrate may be a silicon on insulator (SOI) substrate including a buried oxide (BOX) layer and the trench may extend partially into the BOX layer. The flowable dielectric may be a spin deposited flowable oxide or a CVD BPSG oxide. The flowable dielectric isolation structure provides a buffer that prevents stress induced on one side of the isolation structure from creating stress on the other side of the structure. Thus, for example, compressive stress created by forming silicon germanium on silicon in PMOS regions does not create compressive stress in NMOS regions.
    • 半导体制造工艺包括在半导体衬底上图案化硬掩模以暴露隔离区域并在隔离区域中形成沟槽。 在沟槽中沉积可流动电介质以部分地填充沟槽,并且覆盖覆盖第一氧化物的覆盖电介质以填充沟槽。 衬底可以是包括掩埋氧化物(BOX)层的绝缘体上硅(SOI)衬底,并且沟槽可以部分地延伸到BOX层中。 可流动电介质可以是自旋沉积的可流动氧化物或CVD BPSG氧化物。 可流动介电隔离结构提供了缓冲器,其防止在隔离结构的一侧上引起的应力在结构的另一侧上产生应力。 因此,例如,通过在PMOS区域中的硅上形成硅锗产生的压缩应力在NMOS区域中不产生压应力。