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1. 发明申请

WO2005109549A2 NICKEL METAL HYDRIDE BATTERY DESIGN 审中-公开
标题翻译：镍金属电池电池设计
公开(公告)号：WO2005109549A2
公开(公告)日：2005-11-17
申请号：PCT/US2005009613
申请日：2005-03-22
申请人： OVONIC BATTERY CO , YOUNG KWO
发明人： YOUNG KWO , FIERRO CRISTIAN , REICHMAN BENJAMIN , FETCENKO MICHAEL A , KOCH JOHN , ZALLEN AVRAM
IPC分类号： H01M4/02 , H01M4/04 , H01M4/24 , H01M4/32 , H01M4/36 , H01M4/38 , H01M4/52 , H01M4/58 , H01M4/62 , H01M10/34 , H01M10/42 , H01M10/44 , H01M10/52
CPC分类号： H01M10/345 , H01M4/0438 , H01M4/0445 , H01M4/0492 , H01M4/242 , H01M4/32 , H01M4/366 , H01M4/383 , H01M4/52 , H01M4/62 , H01M4/621 , H01M10/4235 , H01M10/446 , H01M10/52 , H01M2004/027
摘要： The present invention relates to rechargeable nickel metal hydride batteries and methods for making the same. More particularly, the present invention relates to rechargeable nickel metal hydride batteries having a precharge in the negative electrode sufficient for oxidation prevention in the negative electrode. The present invention discloses a nickel metal hydride battery, wherein the precharge of the negative electrode may be supplied by a variety of sources. The positive active material of the positive electrode may have positive active particles, such as nickel hydroxide, having a precursor coating that incorporates cobalt material capable of forming a conductive network. Sources other than cobalt-containing materials in the positive electrode include hydrogen gas provided directly to the negative active material, nickel aluminum mixed with the negative active material, the etching of the negative active material with an alkaline solution and borohydride chemically charging the negative active material. Preferably, a majority of the precharge of the negative electrode is supplied by sources other than cobalt-containing materials in the positive electrode.
摘要翻译：本发明涉及可再充电镍氢电池及其制造方法。更具体地说，本发明涉及在负极中具有足以在负极中进行氧化防止的预充电的可充电镍金属氢化物电池。本发明公开了一种镍金属氢化物电池，其中负极的预充电可以由各种源提供。正极的正极活性材料可以具有正的活性颗粒，例如氢氧化镍，其具有引入可形成导电网络的钴材料的前体涂层。来自正极中的含钴材料以外的源包括直接设置在负极活性物质上的氢气，与负极活性物质混合的镍铝，用碱性溶液腐蚀负极活性物质和化学充电负极活性物质的硼氢化物。优选地，负极的大部分预充电由正极中的含钴材料以外的源供给。

2. 发明专利

JP2007046161A Hydrogen storage alloy having high porosity surface layer 审中-公开
标题翻译：具有高孔隙度表面层的氢储存合金
公开(公告)号：JP2007046161A
公开(公告)日：2007-02-22
申请号：JP2006213523
申请日：2006-08-04
申请人： Ovonic Battery Co Inc , オヴォニックバッテリーカンパニーインコーポレイテッド
发明人： FETCENKO MICHAEL A , OVSHINSKY STANFORD R , YOUNG KWO , REICHMAN BENJAMIN , OUCHI TAIHEI , KOCH JOHN , MAYS WILLIAM
IPC分类号： C22C19/00 , B01J23/755 , B01J23/86 , C01B3/00 , C22C1/00 , C22C1/02 , C22C1/05 , C22C19/03 , C22C30/00 , H01M4/38 , H01M8/04 , H01M10/34
CPC分类号： H01M4/383 , H01M10/345 , Y02E60/324 , Y10S420/90
摘要： PROBLEM TO BE SOLVED: To provide hydrogen storage alloys as well as electrochemical cells, batteries and fuel cells using these alloys, more particularly, to provide hydrogen storage alloys having microstructures that are highly permeable and/or that include high concentrations of catalytically active metal or metal alloy particles. SOLUTION: Electrochemical and thermal hydrogen storage alloy compositions that provide superior performance including an electrochemical hydrogen storage alloy that provides superior low temperature discharge characteristics. The alloy compositions include microstructures in the interface region that are highly porous and that include catalytic metallic particles. The microstructures include a large volume fraction of voids having spherical or channel-like shapes and are sufficiently open structurally to facilitate greater mobility of reactive species within the microstructure and in the vicinity of catalytic metallic particles. Greater accessibility to reactive sites accordingly results. The greater mobility of reactive species and/or the greater density of catalytic particles lead to faster kinetics and improved performance (e.g. higher power), especially at low operating temperatures. The microstructures may be formed through inclusion of a microstructure tuning element in the alloy composition, through control of processing conditions and/or through inclusion of etching steps in the post-formation processing of hydrogen storage alloys. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供使用这些合金的储氢合金以及电化学电池，电池和燃料电池，更具体地说，提供具有高度可渗透性和/或包含高浓度催化剂的微结构的储氢合金活性金属或金属合金颗粒。解决方案：提供优异性能的电化学和热储氢合金组合物，包括提供优异的低温放电特性的电化学储氢合金。合金组合物包括界面区域中的高度多孔的微结构，并且包括催化金属颗粒。微结构包括具有球形或通道状形状的大体积分数的空隙，并且在结构上足够开放以促进反应性物质在微结构内和催化金属颗粒附近的更大迁移率。因此可以更好地获得反应性网站。活性物质的较大迁移率和/或更大密度的催化剂颗粒导致更快的动力学和改进的性能（例如更高的功率），特别是在低的操作温度下。可以通过在合金组合物中包含微结构调谐元件，通过控制加工条件和/或通过在储氢合金的后形成处理中包括蚀刻步骤来形成微观结构。版权所有（C）2007，JPO＆INPIT

3. 发明专利

JP2006183148A Modified electrochemical hydrogen storage alloy having increased capacity, rate capability and catalytic activity 有权
标题翻译：改进的电化学储氢合金具有增加的能力，速率能力和催化活性
公开(公告)号：JP2006183148A
公开(公告)日：2006-07-13
申请号：JP2005365347
申请日：2005-12-19
申请人： Ovonic Battery Co Inc , オヴォニックバッテリーカンパニーインコーポレイテッド
发明人： FETCENKO MICHAEL A , YOUNG KWO , OVSHINSKY STANFORD R , REICHMAN BENJAMIN , KOCH JOHN , MAYS WILLIAM
IPC分类号： B22F1/00 , C22C19/00 , B22F1/02 , B22F5/00 , C01B3/00 , C22C1/00 , C22C1/02 , C22C14/00 , C22C16/00 , C22C27/02 , C22C27/06 , C22C30/04 , H01M4/38 , H01M10/30
CPC分类号： C01B3/0031 , C22C14/00 , C22C16/00 , C22C27/025 , C22C27/06 , H01M4/383 , Y02E60/327 , Y10S420/90 , Y10T428/12104
摘要： PROBLEM TO BE SOLVED: To provide a modified electrochemical hydrogen storage alloy having increased capacity, rate capability and catalytic activity, and used as negative electrode materials for secondary batteries. SOLUTION: The modified Ti-V-Zr-Ni-Mn-Cr electrochemical hydrogen storage alloy comprises a base alloy consisting of, by atom, 0.1 to 60% Ti, 0.1 to 40% Zr, 0 to 60% V, 0.1 to 57% Ni, 5 to 22% Mn and 0 to 56% Cr and modifying elements comprising 0.1 to 10.0% Al, 0.1 to 10.0% Co, 0 to 3.5% Fe and 0.1 to 3.0% Sn. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供具有增加的容量，速率能力和催化活性的改进的电化学储氢合金，并且用作二次电池的负极材料。解决方案：改性Ti-V-Zr-Ni-Mn-Cr电化学储氢合金包括由原子组成的基体合金，0.1至60％Ti，0.1至40％Zr，0至60％V， 0.1〜57％的Ni，5〜22％的Mn和0〜56％的Cr，以及包含0.1〜10.0％的Al，0.1〜10.0％的Co，0〜3.5％的Fe和0.1〜3.0％的Sn的改性元素。版权所有（C）2006，JPO＆NCIPI

4. 发明专利

MX290707B NICKEL METAL HYDRIDE BATTERY DESIGN. 未知
公开(公告)号：MX290707B
公开(公告)日：2011-10-04
申请号：MXPA06012210
申请日：2005-03-22
申请人： OVONIC BATTERY CO
发明人： FETCENKO MICHAEL A , REICHMAN BENJAMIN , KOCH JOHN , FIERRO CRISTIAN , ZALLEN AVRAM
IPC分类号： H01M4/02 , H01M4/04 , H01M4/24 , H01M4/32 , H01M4/36 , H01M4/38 , H01M4/52 , H01M4/58 , H01M4/62 , H01M10/34 , H01M10/42 , H01M10/44 , H01M10/52

5. 发明专利

DE602004010083T2 未知
公开(公告)号：DE602004010083T2
公开(公告)日：2008-08-28
申请号：DE602004010083
申请日：2004-03-23
申请人： OVONIC BATTERY CO INC
发明人： FETCENKO MICHAEL A , OVSHINSKY STANFORD R , YOUNG KWO , REICHMAN BENJAMIN , OUCHI TAIHEI , KOCH JOHN , MAYS WILLIAM
IPC分类号： C22C30/00 , B01J23/755 , C22C1/05 , C22C19/03 , H01M4/38 , H01M10/34
摘要： Electrochemical and gas phase hydrogen storage alloy compositions that provide superior performance, especially at low temperature, and excellent cycle life characteristics. The alloys of this invention are AB 5 type alloys that include a cycle life enhancement element and a low Co concentration. The preferred cycle life enhancement elements include Zr and Si. The cycle life enhancement elements increase the cycle life of the instant alloys by reducing the pulverization of alloy particles upon repeated cycles of charging-discharging or hydriding-dehydriding. The alloys are characterized by low hysteresis on cycling, where hysteresis is measured in terms of mass concentration difference, a parameter related to the activation energy associated with the incorporation of hydrogen into the alloy. The instant alloys are designed to have a low activation energy for hydrogen incorporation and as a result, provide low hysteresis and a more uniform concentration of absorbed hydrogen within the material. As a result, differential lattice expansion effects associated with the absorption of hydrogen are minimized and the tendency for particle pulverization on cycling is minimized. Alloys having a low Co concentration and long cycle life are thus provided for.

6. 发明专利

MXPA06012210A DISENO DE BATERIA DE NIQUEL HIDRURO DE METAL. 未知
公开(公告)号：MXPA06012210A
公开(公告)日：2007-01-17
申请号：MXPA06012210
申请日：2005-03-22
申请人： OVONIC BATTERY CO
发明人： FETCENKO MICHAEL A , REICHMAN BENJAMIN , KOCH JOHN , FIERRO CRISTIAN , ZALLEN AVRAM
IPC分类号： H01M4/52 , H01M4/02 , H01M4/04 , H01M4/24 , H01M4/32 , H01M4/36 , H01M4/38 , H01M4/58 , H01M4/62 , H01M10/34 , H01M10/42 , H01M10/44 , H01M10/52
摘要： La presente invencion se relaciona a baterias de niquel hidruro de metal recargables y metodos para hacer las mismas. Mas particularmente, la presente invencion se relaciona a baterias de niquel hidruro de metal recargables que tienen una precarga en el electrodo negativo suficiente para prevenir la oxidacion en el electrodo negativo. La presente invencion divulga una bateria de niquel hidruro de metal, en donde la precarga del electrodo negativo se puede suministrar mediante una variedad de fuentes. El material activo positivo del electrodo positivo puede tener particulas activas positivas, tal como hidroxido de niquel, que tiene un recubrimiento precursor que se incorpora al material de cobalto capaz de formar una pared conductora. Las fuentes diferentes a los materiales que contienen cobalto en el electrodo positivo incluyen gas de hidrogeno proporcionado directamente al material activo negativo, niquel aluminio mezclado con el material activo negativo, el grabado del material activo negativo con una solucion alcalina y borohidruro que carga quimicamente el material activo negativo. Preferiblemente, una mayoria de la precarga del electrodo negativo se suministra mediante fuentes diferentes a los materiales que contienen cobalto en el electrodo positivo.

7. 发明专利

AU775748B2 Modified electrochemical hydrogen storage alloy having increased capacity, rate capability and catalytic activity 未知
公开(公告)号：AU775748B2
公开(公告)日：2004-08-12
申请号：AU4338900
申请日：2000-04-11
申请人： OVONIC BATTERY CO
发明人： FETCENKO MICHAEL A , YOUNG KWO , OVSHINSKY STANFORD R , REICHMAN BENJAMIN , KOCH JOHN , MAYS WILLIAM
IPC分类号： B22F1/00 , B22F1/02 , B22F5/00 , C01B3/00 , C22C14/00 , C22C16/00 , C22C19/00 , C22C27/02 , C22C27/06 , H01M4/38
摘要： An electrochemical hydrogen storage alloy including an oxide surface having metallic catalytic particles distributed throughout, wherein said metallic catalytic particles have an average particle size of 10-40 Angstroms in size.

8. 发明专利

CA2334363A1 MODIFIED ELECTROCHEMICAL HYDROGEN STORAGE ALLOY HAVING INCREASED CAPACITY, RATE CAPABILITY AND CATALYTIC ACTIVITY 未知
公开(公告)号：CA2334363A1
公开(公告)日：2000-10-19
申请号：CA2334363
申请日：2000-04-11
申请人： OVONIC BATTERY CO
发明人： YOUNG KWO , FETCENKO MICHAEL A , KOCH JOHN , MAYS WILLIAM , REICHMAN BENJAMIN , OVSHINSKY STANFORD R
IPC分类号： B22F1/00 , B22F1/02 , B22F5/00 , C01B3/00 , C22C14/00 , C22C16/00 , C22C19/00 , C22C27/02 , C22C27/06 , H01M4/38
摘要： A modified Ti-V-Zr-Ni-Mn-Cr electrochemical hydrogen storage alloy which has at least one of the following characteristics: 1) an increased charge/discharge rate capability over that the base Ti-V-Zr-Ni-Mn-Cr electrochemical hydrogen storage alloy; 2) a formation cycling requirement which is reduced to one tenth that of the base Ti-V-Zr-Ni-Mn-Cr electrochemical hydrogen storage alloy; 3) no chemical/thermal activation of the modified alloy is required to attain full operating capacity as is required by the base Ti-V-Zr-Ni-Mn-Cr electrochemical hydrogen storage alloy : and 4) an oxide surface layer having a higher electrochemical hydrogen stora ge catalytic activity than the base Ti-V-Zr-Ni-Mn-Cr electrochemical hydrogen storage alloy.

9. 发明专利

AU2004233114B2 Hydrogen storage alloys having a high porosity surface layer 未知
公开(公告)号：AU2004233114B2
公开(公告)日：2010-03-04
申请号：AU2004233114
申请日：2004-03-23
申请人： OVONIC BATTERY CO
发明人： KOCH JOHN , REICHMAN BENJAMIN , OVSHINSKY STANFORD R , FETCENKO MICHAEL A , OUCHI TAIHEI , MAYS WILLIAM , YOUNG KWO
IPC分类号： C22C30/00 , B01J23/755 , C22C1/05 , C22C19/03 , H01M4/38 , H01M4/58 , H01M10/34
摘要： Electrochemical and gas phase hydrogen storage alloy compositions that provide superior performance, especially at low temperature, and excellent cycle life characteristics. The alloys of this invention are AB 5 type alloys that include a cycle life enhancement element and a low Co concentration. The preferred cycle life enhancement elements include Zr and Si. The cycle life enhancement elements increase the cycle life of the instant alloys by reducing the pulverization of alloy particles upon repeated cycles of charging-discharging or hydriding-dehydriding. The alloys are characterized by low hysteresis on cycling, where hysteresis is measured in terms of mass concentration difference, a parameter related to the activation energy associated with the incorporation of hydrogen into the alloy. The instant alloys are designed to have a low activation energy for hydrogen incorporation and as a result, provide low hysteresis and a more uniform concentration of absorbed hydrogen within the material. As a result, differential lattice expansion effects associated with the absorption of hydrogen are minimized and the tendency for particle pulverization on cycling is minimized. Alloys having a low Co concentration and long cycle life are thus provided for.

10. 发明专利

DE60026502D1 未知
公开(公告)号：DE60026502D1
公开(公告)日：2006-05-04
申请号：DE60026502
申请日：2000-04-11
申请人： OVONIC BATTERY CO
发明人： FETCENKO A , YOUNG KWO , OVSHINSKY R , REICHMAN BENJAMIN , KOCH JOHN , MAYS WILLIAM
IPC分类号： B22F1/00 , C22C14/00 , B22F1/02 , B22F5/00 , C01B3/00 , C22C16/00 , C22C19/00 , C22C19/05 , C22C22/00 , C22C27/02 , C22C27/06 , H01M4/38
摘要： An electrochemical hydrogen storage alloy including an oxide surface having metallic catalytic particles distributed throughout, wherein said metallic catalytic particles have an average particle size of 10-40 Angstroms in size.

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