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1. 发明申请

WO2012143695A2 POLYMERS FOR CONTACT LENSES 审中-公开
标题翻译：聚合物用于接触镜片
公开(公告)号：WO2012143695A2
公开(公告)日：2012-10-26
申请号：PCT/GB2012/000391
申请日：2012-04-19
申请人： OCUTEC LIMITED , RASHID, Abdul , GRAHAM, Neil , BOWERS, Roderick
发明人： RASHID, Abdul , GRAHAM, Neil , BOWERS, Roderick
CPC分类号： C08G18/283 , C08G18/284 , C08G18/2865 , C08G18/4833 , C08G18/6674 , C08G18/6677 , C08G2101/0091 , C08G2210/00 , G02B1/043 , C08L75/04
摘要： The present invention relates to a polyurethane polymer compositions comprising polyethylene glycol) monoalkyl ether. The compositions may be either crosslinked (suitable for reaction cast moulding) or thermoplastic (suitable for injection and/or compression moulding). Either of the above varieties may contain carbinol terminated polydimethyl siloxane components. There is also provided a process for preparing such a polyurethane polymer composition. The invention also relates to a process for preparing a polyurethane xerogel in the form of a molded article, said process comprising the steps of. i. preparing a mixture of a. at least one poly(ethylene glycol) and/or at least one polyol or macropolyol having a functionality greater than 2, or a mixture of such polyols or macropolyols having a functionality of greater than 2, b. at least one di-or poly-isocyanate, c. optionally at least one OH-terminated chain extender, d. optionally an additional compound comprising at least one hydroxyl group and at least one primary or secondary amine group, and e. at least one poly(ethylene glycol) monoalkyl ether; ii. dispensing the reaction mixture formed in step i) into a mold; iii. allowing the reaction mixture to react and cure; iv. removing the molded article from the mold; and v. hydrating the molded article. Optionally the process may comprise the step of hydrating the molded article to form a hydrated article.
摘要翻译：本发明涉及包含聚乙二醇单烷基醚的聚氨酯聚合物组合物。组合物可以是交联的（适合于反应浇铸成型）或热塑性的（适于注射和/或压塑）。上述品种均可含有甲醇封端的聚二甲基硅氧烷成分。还提供了制备这种聚氨酯聚合物组合物的方法。本发明还涉及一种制备模制品形式的聚氨酯干凝胶的方法，所述方法包括以下步骤。一世。准备一种混合物。 b）具有官能度大于2的至少一种聚（乙二醇）和/或至少一种多元醇或大多元醇，或这些多官能团或大多异氰酸酯的混合物，b。至少一种二异氰酸酯或多异氰酸酯，c。任选地至少一个OH-封端的扩链剂，d。任选的包含至少一个羟基和至少一个伯或仲胺基团的另外的化合物，至少一种聚（乙二醇）单烷基醚; II。将步骤i）中形成的反应混合物分配到模具中; III。使反应混合物反应并固化; IV。将模制品从模具中取出; 和v。水合成型制品。任选地，该方法可以包括使成型制品水合以形成水合制品的步骤。

2. 发明申请

WO2014041323A8 POLYMERS FOR CONTACT LENSES 审中-公开
公开(公告)号：WO2014041323A8
公开(公告)日：2014-03-20
申请号：PCT/GB2013/000379
申请日：2013-09-10
申请人： OCUTEC LIMITED
发明人： RASHID, Abdul , FRASER, John , HONEYMAN, Gordon , MOHAMMED, Mussarrat
IPC分类号： G02B1/04 , C08G18/48 , C08G18/61 , C08G18/66
摘要： There is provided a polyurethane xerogel prepared from a mixture comprising: (a) at least one isocyanate, (b) at least one silicone containing compound of formula J: wherein at least one group represents a hydrocarbyl group and p represents an integer of from 1 to 40, or at least one R 2 group represents a hydrocarbyl group and q represents an integer of from 1 to 40; and at least one R 3 group represents a hydrocarbyl group and w represents an integer of from 1 to 40, or at least one R 4 group represents a hydrocarbyl group and y represents an integer of from 1 to 40; (c) optionally one or more additional components; wherein the isocyanate and silicone containing compound are reacted under substantially anhydrous conditions. There is also provided a contact lens formed from the polyurethane xerogel.

3. 发明申请

WO2011055108A1 POLYMERS FOR CONTACT LENSES 审中-公开
标题翻译：聚合物用于接触镜片
公开(公告)号：WO2011055108A1
公开(公告)日：2011-05-12
申请号：PCT/GB2010/002020
申请日：2010-11-02
申请人： OCUTEC LIMITED , RASHID, Abdul , BOWERS, Roderick, WIlliam, Jonathan , TIPTON, Wade , GRAHAM, Neil, Bonnette
发明人： RASHID, Abdul , BOWERS, Roderick, WIlliam, Jonathan , TIPTON, Wade , GRAHAM, Neil, Bonnette
IPC分类号： C08G18/48 , C08G18/61 , C08G18/66 , G02B1/04
CPC分类号： C08G18/61 , C08G18/4833 , C08G18/6674 , C08G2101/0091 , G02B1/043 , C08L75/04 , C08L83/04
摘要： The present invention relates to a polyurethane prepared from a mixture comprising: (a) at least one polyethylene glycol; (b) at least one di-isocyanate; (c) at least one polydialkyl siloxane diol; and (d) at least one diol of formula (I) wherein n is an integer from 1 to 25; wherein the polyethylene glycol, di-isocyanate, polydialkyl siloxane diol and diol are reacted under substantially anhydrous conditions. Further aspects of the invention relate to a process for preparing a polyurethane. The invention also relates to a process for preparing a polyurethane xerogel in the form of a molded article, said process comprising the steps of: (i) preparing a reaction mixture comprising at least one polyethylene glycol, at least one di-isocyanate, at least one polydialkyl siloxane diol and at least one diol of formula I as described above; (ii) reacting the reaction mixture formed in step (i) under substantially anhydrous conditions to form a polyurethane xerogel; and (iii) injection molding the polyurethane xerogel to form a molded article.
摘要翻译：本发明涉及由以下混合物制备的聚氨酯：（a）至少一种聚乙二醇; （b）至少一种二异氰酸酯; （c）至少一种聚二烷基硅氧烷二醇; 和（d）至少一种式（I）的二醇，其中n是1至25的整数; 其中聚乙二醇，二异氰酸酯，聚二烷基硅氧烷二醇和二醇在基本无水条件下反应。本发明的其它方面涉及一种制备聚氨酯的方法。本发明还涉及一种制备模制品形式的聚氨酯干凝胶的方法，所述方法包括以下步骤：（i）制备包含至少一种聚乙二醇，至少一种二异氰酸酯的反应混合物，至少一种一种聚二烷基硅氧烷二醇和至少一种如上所述的式I的二醇; （ii）在基本上无水条件下使步骤（i）中形成的反应混合物反应形成聚氨酯干凝胶; 和（iii）注射成型聚氨酯干凝胶以形成模塑制品。

4. 发明申请

WO2021156623A1 OPTIMISED CONTACT LENS PACKAGE 审中-公开
公开(公告)号：WO2021156623A1
公开(公告)日：2021-08-12
申请号：PCT/GB2021/050254
申请日：2021-02-05
申请人： OCUTEC LIMITED
发明人： BOWERS, Roderick , HONEYMAN, Gordon , RASHID, Abdul , SWITNCKA, Magdelena
IPC分类号： C11D3/00 , C11D3/37 , C11D17/04
摘要： There is provided a contact lens package including: • a closed housing suitable for the storage of a contact lens, • a contact lens comprising poly(ethylene glycol) in the housing, • a storage formulation in the housing, contacting at least one surface of the lens, • wherein the storage formulation comprises: • a) 0.1 to 7 wt.% of at least one block copolymer of ethylene oxide and propylene oxide; • b) 0.1 to 5 wt.% of at least one polyacrylic acid salt; • c) 0.01 to 3 wt.% of at least one propoxylated ethylenediamine compound. A method of reducing or preventing binding of proteins, lipids or microorganisms to a surface of a contact lens and a method of reducing the contact angle of a surface of contact lens are also provided.

5. 发明申请

WO2011051689A2 POLYMERS FOR CONTACT LENSES 审中-公开
标题翻译：用于接触镜片的聚合物
公开(公告)号：WO2011051689A2
公开(公告)日：2011-05-05
申请号：PCT/GB2010/002018
申请日：2010-11-02
申请人： OCUTEC LIMITED , RASHID, Abdul , BOWERS, Roderick, William, Jonathan , TIPTON, Wade , GRAHAM, Neil, Bonnette
发明人： RASHID, Abdul , BOWERS, Roderick, William, Jonathan , TIPTON, Wade , GRAHAM, Neil, Bonnette
IPC分类号： C08G18/48 , C08G18/61 , C08K5/00 , G02B1/04
CPC分类号： C08G71/04 , C08G18/4825 , C08G18/4829 , C08G18/4833 , C08G18/61 , C08G2101/0091 , C08G2210/00 , G02B1/043 , C08L69/00
摘要： The present invention relates to a polyurethane polymer composition comprising polyethyleneglycol dialkyl ether. There is also provided a process for preparing a polyurethane. The invention also relates to a process for preparing a polyurethane xerogel in the form of a molded article, said process comprising the steps of: i. preparing a mixture of a. at least one polyethylene glycol or at least one polyol of formula (I), wherein at least three Of X 1 , X 2 , X 3 , X 4 and X 5 are each independently an OH-terminated group, and the remainder of X 1 , X 2 , X 3 , X 4 and X 5 are each independently H or absent, and Z is a central linking unit, a. at least one di- or poly-isocyanate, b. optionally at least one OH-terminated chain extender, and c. at least one polyethyleneglycol dialkyl ether; ii. dispensing the reaction mixture formed in step i) into a mold; iii. allowing the reaction mixture to react and cure; iv. removing the molded article from the mold; and v. hydrating the molded article.
摘要翻译：本发明涉及包含聚乙二醇二烷基醚的聚氨酯聚合物组合物。还提供了制备聚氨酯的方法。本发明还涉及一种制备模制品形式的聚氨酯干凝胶的方法，所述方法包括以下步骤：准备一种混合物。至少一种聚乙二醇或至少一种式（I）的多元醇，其中X 1，X 2，X 3，X 4和X 5中的至少三个各自独立地是OH-封端的基团，其余的X 1，X 2，X 3，X 4 和X 5各自独立地为H或不存在，Z为中心连接单元，a。至少一种二异氰酸酯或多异氰酸酯，b。任选地至少一个OH-封端的扩链剂，和c。至少一种聚乙二醇二烷基醚; II。将步骤i）中形成的反应混合物分配到模具中; III。使反应混合物反应并固化; IV。将模制品从模具中取出; 和v。水合成型制品。

6. 发明申请

WO2007104966A1 METHOD OF FORMING 审中-公开
标题翻译：成形方法
公开(公告)号：WO2007104966A1
公开(公告)日：2007-09-20
申请号：PCT/GB2007/000870
申请日：2007-03-12
申请人： OCUTEC LIMITED , BOWERS, Roderick, William, Jonathan , HRANHAM, Neil, Bonnette , RASHID, Abdul
发明人： BOWERS, Roderick, William, Jonathan , HRANHAM, Neil, Bonnette , RASHID, Abdul
IPC分类号： C08J5/00
CPC分类号： G02B1/043 , A61L27/18 , C08L71/02
摘要： The present invention relates to a method of using non-macrogelled polymer-solvent combinations to form devices, in particular medical devices and / or cosmetic devices, more specifically contact lenses. The method of using polymer solvent combinations is suitable for forming useful 3D dimensionally stable structures which may include curved surfaces, which may be significantly different to those curved surfaces achieved by using simple meniscus effects.
摘要翻译：本发明涉及使用非微胶凝聚合物 - 溶剂组合来形成装置，特别是医疗装置和/或美容装置，更具体地为隐形眼镜的方法。使用聚合物溶剂组合的方法适用于形成有用的3D尺寸稳定的结构，其可以包括曲面，其可能与通过使用简单的弯月面效应实现的那些曲面显着不同。

7. 发明公开

EP1994082A1 METHOD OF FORMING 审中-公开
标题翻译：教育过程
公开(公告)号：EP1994082A1
公开(公告)日：2008-11-26
申请号：EP07732012.5
申请日：2007-03-12
申请人： Ocutec Limited
发明人： BOWERS, Roderick, William, Jonathan , GRAHAM, Neil, Bonnette , RASHID, Abdul
IPC分类号： C08J5/00
CPC分类号： G02B1/043 , A61L27/18 , C08L71/02
摘要： The present invention relates to a method of using non-macrogelled polymer-solvent combinations to form devices, in particular medical devices and / or cosmetic devices, more specifically contact lenses. The method of using polymer solvent combinations is suitable for forming useful 3D dimensionally stable structures which may include curved surfaces, which may be significantly different to those curved surfaces achieved by using simple meniscus effects.

8. 发明申请

WO2020035681A1 FORMULATION 审中-公开
公开(公告)号：WO2020035681A1
公开(公告)日：2020-02-20
申请号：PCT/GB2019/052280
申请日：2019-08-13
申请人： OCUTEC LIMITED
发明人： BOWERS, Roderick , SWITNICKA, Magdalena , GRAHAM, Neil , CARNEGIE, James , HONEYMAN, Gordon , RASHID, Abdul
IPC分类号： A61L27/34 , A61L27/50 , A61L29/08 , A61L29/14 , A61L31/10 , A61L31/14
摘要： There is disclosed a formulation suitable for the reduction or prevention of contamination of articles by microorganisms. The formulation includes at least one block copolymer of ethylene oxide and propylene oxide, at least one polyacrylic acid salt, and at least one propoxylated ethylenediamine compound.

9. 发明申请

WO2016005733A1 POLYURETHANES FOR CONTACT LENSES 审中-公开
标题翻译：用于接触镜片的聚氨酯
公开(公告)号：WO2016005733A1
公开(公告)日：2016-01-14
申请号：PCT/GB2015/051960
申请日：2015-07-07
申请人： OCUTEC LIMITED
发明人： RASHID, Abdul , HONEYMAN, Gordon , FRASER, John
IPC分类号： C08G18/75 , C08G18/48 , C08G18/66 , C08G18/61 , C08G18/65 , G02B1/04
CPC分类号： C08G18/6674 , C08G18/4808 , C08G18/4833 , C08G18/4837 , C08G18/61 , C08G18/6517 , C08G18/6677 , C08G18/758 , C08G2210/00 , C08J3/075 , C08J2375/08 , C08K5/13 , G02B1/043 , C08L75/04 , C08L83/04 , C08L101/14
摘要： The present invention provides a poly(ethylene) glycol based polyurethane polymer composition, particularly useful in the production of contact lenses. Generally the reactant mixture used to form the polymer includes a branched chain extender. There is also provided a method of manufacturing a contact lens formed from such a polymer.
摘要翻译：本发明提供聚（乙烯）二醇类聚氨酯聚合物组合物，特别可用于制造隐形眼镜。通常用于形成聚合物的反应物混合物包括支链增链剂。还提供了一种制造由这种聚合物形成的隐形眼镜的方法。

10. 发明申请

WO2011055110A1 POLYMERS FOR CONTACT LENSES 审中-公开
标题翻译：聚合物用于接触镜片
公开(公告)号：WO2011055110A1
公开(公告)日：2011-05-12
申请号：PCT/GB2010/002026
申请日：2010-11-02
申请人： OCUTEC LIMITED , RASHID, Abdul , BOWERS, Roderick, Willaim, Jonathan , TIPTON, Wade , GRAHAM, Neil, Bonnette
发明人： RASHID, Abdul , BOWERS, Roderick, Willaim, Jonathan , TIPTON, Wade , GRAHAM, Neil, Bonnette
IPC分类号： C08G18/48 , C08G18/66 , G02B1/04
CPC分类号： C08G18/4833 , C08G18/6674 , C08G2220/00 , G02B1/043 , C08L75/08
摘要： The present invention relates to a thermoplastic polyurethane contact lens prepared from a mixture comprising: (a) at least one polyethylene glycol; (b) at least one di-isocyanate; and (c) at least one diol of formula (I): wherein n is an integer from 1 to 25; wherein the polyethylene glycol, di-isocyanate and diol are reacted under substantially anhydrous conditions. Further aspects of the invention relate to a process for preparing a contact lens. The invention also relates to a process for preparing a polyurethane xerogel in the form of a molded article, said process comprising the steps of: (i) preparing a reaction mixture comprising at least one polyethylene glycol, at least one di-isocyanate and at least one diol of formula I as described above; (ii) reacting the reaction mixture formed in step (i) under substantially anhydrous conditions to form a polyurethane xerogel; (iii) injection molding the polyurethane xerogel to form a molded article, (iv) hydrating the xerogel molded article to form a contact lens.
摘要翻译：本发明涉及由以下混合物制备的热塑性聚氨酯隐形眼镜：（a）至少一种聚乙二醇; （b）至少一种二异氰酸酯; 和（c）至少一种式（I）的二醇：其中n是1至25的整数; 其中聚乙二醇，二异氰酸酯和二醇在基本无水条件下反应。本发明的其它方面涉及一种制备隐形眼镜的方法。本发明还涉及一种制备模制品形式的聚氨酯干凝胶的方法，所述方法包括以下步骤：（i）制备包含至少一种聚乙二醇，至少一种二异氰酸酯和至少一种二异氰酸酯的反应混合物如上所述的一种式I的二醇; （ii）在基本上无水条件下使步骤（i）中形成的反应混合物反应形成聚氨酯干凝胶; （iii）注射成型聚氨酯干凝胶以形成模塑制品，（iv）将干凝胶模塑制品保湿以形成隐形眼镜。

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