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    • 2. 发明授权
    • Thermal ink-jet inks having reduced black to color and color to color
bleed
    • 热喷墨油墨具有减少的黑色到颜色和颜色到颜色的流失
    • US5536306A
    • 1996-07-16
    • US501262
    • 1995-07-11
    • Loren E. JohnsonHiang P. LauwNorman E. PawlowskiJames P. ShieldsJohn M. Skene
    • Loren E. JohnsonHiang P. LauwNorman E. PawlowskiJames P. ShieldsJohn M. Skene
    • C09D11/00C09D11/02
    • C09D11/38C09D11/40
    • A set of thermal ink-jet inks and method for formulating the same are provided in which the cyan, magenta, and yellow inks contain a combination of surfactants and inorganic salts designed to reduce both color to color bleed as well as black to color bleed. In general, the present cyan, magenta, and yellow inks each comprise about 0.1 to 4 wt. % of at least one dye; about 3 to 20 wt. % of at least one diol; 0 to about 5 wt. % of at least one glycol ether; about 3 to 9 wt. % of 2-pyrrolidone; up to about 4 wt. % of at least one component selected from the group consisting of biocides and buffers; and water. To achieve a reduction in color to color and black to color bleed, the cyan, magenta, and yellow inks are formulated to further comprise the following combination of surfactants and inorganic salts: (a) a surfactant component comprising about 1 to 4 wt. % of a first surfactant consisting essentially of at least one secondary alcohol ethoxylate surfactant predominantly having 4 to 8 ethoxylated units and an aliphatic chain having about 12 to 18 carbon atoms; and (b) about 3 to 6 wt. % of at least one inorganic salt component.
    • 提供一组热喷墨油墨及其配制方法,其中青色,洋红色和黄色油墨含有表面活性剂和无机盐的组合,其设计用于减少颜色到颜色渗色以及黑色到颜色渗色。 通常,本发明的青色,品红色和黄色油墨各自包含约0.1至4wt。 至少一种染料的%; 约3至20wt。 %的至少一种二醇; 0至约5wt。 %至少一种二醇醚; 约3〜9重量% %的2-吡咯烷酮; 高达约4wt。 %的至少一种选自杀生物剂和缓冲剂的组分; 和水。 为了实现颜色降低到颜色和黑色到颜色渗色,配制青色,品红色和黄色油墨以进一步包含以下表面活性剂和无机盐的组合:(a)包含约1至4wt。 基本上由至少一种仲醇乙氧基化物表面活性剂主要具有4至8个乙氧基化单元和具有约12至18个碳原子的脂族链组成的第一表面活性剂的% 和(b)约3至6wt。 %的至少一种无机盐组分。
    • 8. 发明授权
    • Addition of alcohol to prewet solutions to enhance and accelerate
wetting to hydrophobic foams for application to ink-jet pens
    • 加入醇以预湿溶液以增强和加速润湿疏水泡沫以适用于喷墨笔
    • US5467117A
    • 1995-11-14
    • US200794
    • 1994-02-23
    • Roger F. EvansCharles L. Thierheimer, Jr.Norman E. Pawlowski
    • Roger F. EvansCharles L. Thierheimer, Jr.Norman E. Pawlowski
    • B41J2/175G01D15/18
    • B41J2/17553B41J2/17513
    • A method is provided for enhancing and accelerating wetting of hydrophobic foams for use as ink reservoirs in ink-jet printer pens. First, the foam is placed in a prewet bath, having already been compressed to expel air. The prewet bath contains an aqueous solution with a low molecular weight alcohol additive, such as n-propanol, ranging in concentration from about 3 to 10 wt. %. Second, the foam is repeatedly compressed and allowed to expand while in the prewet bath, thereby promoting the foam's absorbance of prewetting solution and further improving foam wettability. Finally, the foam is removed from the prewet bath and is compressed to expel excess prewetting solution. The foam retains residual alcohol from the prewet bath that subsequently becomes a constituent of the ink stored in the foam. In addition to improving the wetting process for hydrophobic foam, the alcohol additive prevents orifice plugging within ink-jet pens by becoming a residual constituent of the ink and wetting pen parts through ink usage.
    • 提供了一种用于增强和加速用于喷墨打印机笔中的墨水储存器的疏水泡沫的润湿的方法。 首先,将泡沫放置在已经被压缩以排出空气的预湿浴中。 预湿浴包含含有浓度为约3至10重量%的低分子量醇添加剂如正丙醇的水溶液。 %。 第二,泡沫在预湿浴中反复压缩并允许膨胀,从而促进泡沫的预润湿溶液的吸光度并进一步提高泡沫润湿性。 最后,将泡沫从预湿浴中取出并被压缩以排出过量的预润湿溶液。 泡沫保留来自预湿浴的剩余的醇,其随后成为存储在泡沫中的油墨的成分。 除了改善疏水泡沫的润湿过程之外,醇添加剂通过成为油墨的残留成分并通过油墨使用润湿笔部件来防止喷墨笔中的孔堵塞。
    • 9. 发明授权
    • Polyamines complexed to anionic dyes, thereby forming water-soluble
cationic dyes
    • 多胺与阴离子染料络合,从而形成水溶性阳离子染料
    • US5788753A
    • 1998-08-04
    • US738532
    • 1996-10-28
    • Norman E. PawlowskiDavid J. HalkoJoseph W. TsangKimberly L. Hockaday Dahm
    • Norman E. PawlowskiDavid J. HalkoJoseph W. TsangKimberly L. Hockaday Dahm
    • C09B69/04C09D11/00C09D11/02
    • C09D11/328C09B69/04
    • An ink-jet ink for ink-jet printers is provided, comprising: (a) an aqueous-based vehicle; and (b) an anionic dye complexed with a polyamine in an amount sufficient to form a pH-insensitive, water-soluble, dye:polyamine complex that acts like a cationic dye. Further, a method of converting the anionic dye to the cationic dye for formulating the ink-jet ink having a desired pH is provided. The method comprises adding a sufficient amount of the polyamine to form the dye:polyamine complex. The dye:polyamine complex is a complex of the dye and the polyamine polymer, which is cationic. Consequently, this complex behaves as a cationic dye. These ink-jet inks show remarkable waterfastness on a variety of common office papers and are pH-insensitive and even in some cases, completely pH-independent. These inks are thus stable over a wide pH range. In addition, the ink-jet inks exhibit superior ink-to-ink bleed when printed next to a drop of another color ink which contains an anionic polymer or carboxylated colorant and resist crusting or drying in ink-jet nozzles.
    • 提供一种用于喷墨打印机的喷墨油墨,包括:(a)水性载体; 和(b)与多胺络合的阴离子染料,其量足以形成像阳离子染料一样起作用的pH不敏感的水溶性染料:多胺络合物。 此外,提供了将阴离子染料转化为阳离子染料以配制具有所需pH的喷墨油墨的方法。 该方法包括加入足量的多胺以形成染料:多胺络合物。 染料:多胺络合物是染料和聚胺聚合物的复合物,其是阳离子的。 因此,这种复合物表现为阳离子染料。 这些喷墨墨水在各种常见的办公用纸上显示出显着的耐水性,并且pH不敏感,甚至在某些情况下,完全不依赖于pH。 因此,这些油墨在宽的pH范围内是稳定的。 此外,喷墨墨水在印刷在一滴含有阴离子聚合物或羧化着色剂的另一种彩色墨水上并且在喷墨喷嘴中抵抗结皮或干燥时表现出优异的墨到墨渗色。