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1. 发明专利

JP2005162538A Method of manufacturing silicon carbide porous body 有权
标题翻译：制造碳化硅多孔体的方法
公开(公告)号：JP2005162538A
公开(公告)日：2005-06-23
申请号：JP2003404084
申请日：2003-12-03
申请人： Noritake Co Ltd , 株式会社ノリタケカンパニーリミテド
发明人： BARAGOPARU N NAIR , YAMADA SEIJI , YOSHINO YASUSHI
IPC分类号： C04B35/565 , C04B35/626 , C04B38/00
摘要： PROBLEM TO BE SOLVED: To provide a method of manufacturing a high strength and high purity silicon carbide porous body at a relatively low temperature of ≤2,000°C. SOLUTION: Silicon carbide powder having 1μm average particle diameter is formed tubular at 150 MPa pressure based on a cold isotropic pressure process (CIP). The resultant formed body is heated at 1,000°C in the air (a 1st firing process) to be partially oxidized. The temperature rising and cooling rate is 5°C/min. The holding time at a maximum heating temperature is 3 hr. Next, liquid sintering (a 2nd firing process) is carried out at 1,400°C under a nitrogen atmosphere. The temperature rising and cooling rate is 5°C/min and the holding time at the maximum sintering is 3hr. The resultant silicon carbide porous body has 223 nm average fine pore diameter, 43.2% porosity and contains about 6.3 mass% oxygen. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供在≤2,000℃的较低温度下制造高强度和高纯度碳化硅多孔体的方法。解决方案：基于冷各向同性压力工艺（CIP），在150MPa压力下形成具有1μm平均粒径的碳化硅粉末管状。将所得成形体在空气中（1000℃）加热以进行部分氧化。升温速度为5℃/ min。最高加热温度下的保持时间为3小时。接着，在氮气氛下，在1400℃下进行液体烧结（第二烧成工序）。升温和冷却速度为5℃/ min，最大烧结保持时间为3小时。所得碳化硅多孔体的平均细孔直径为223nm，孔隙率为43.2％，氧含量为约6.3质量％。版权所有（C）2005，JPO＆NCIPI

2. 发明专利

JP2004103299A Electrolyte membrane and fuel cell with the same 有权
公开(公告)号：JP2004103299A
公开(公告)日：2004-04-02
申请号：JP2002260485
申请日：2002-09-05
申请人： Noritake Co Ltd , 株式会社ノリタケカンパニーリミテド
发明人： YOSHIKAWA HIROSHI , BARAGOPARU N NAIR
IPC分类号： H01B1/06 , H01M4/86 , H01M8/02 , H01M8/10
CPC分类号： H01M8/106 , H01M4/8605 , H01M8/1004 , H01M8/1011 , Y02E60/523
摘要： PROBLEM TO BE SOLVED: To provide a solid polymer electrolyte membrane excellent in performance for suppressing methanol permeation (a methanol permeation prevention property) and a fuel cell using the same.
SOLUTION: The fuel cell 10 has a configuration in which the electrolyte membrane 13 is sandwiched between a fuel electrode 12 and an air electrode 14. The fuel electrode 12 has a catalyst (a platinum-ruthenium catalyst, etc.) enabled to generate hydrogen from methanol. The electrolyte membrane 13 has a proton conductive polymeric layer 13a mainly composed of a proton conductive polymer (a perfluorocarbon sulfonic acid resin, etc.) and a sheet member 13b mainly composed of an inorganic fiber (a glass fiber, etc.). The methanol permeation prevention property of the electrolyte membrane 13 is improved by suppressing swelling of the polymeric layer 13a even when the methanol is supplied into the fuel electrode 12 because the sheet member 13b is engaged into (buried in) the polymeric layer 13a.
COPYRIGHT: (C)2004,JPO

3. 发明专利

JP2005319383A Hydrogen separating material and its manufacturing method 有权
标题翻译：氢分离材料及其制造方法
公开(公告)号：JP2005319383A
公开(公告)日：2005-11-17
申请号：JP2004138799
申请日：2004-05-07
申请人： Noritake Co Ltd , 株式会社ノリタケカンパニーリミテド
发明人： YOSHINO YASUSHI , BARAGOPARU N NAIR
IPC分类号： B01D71/82 , B01D71/02 , C04B41/85
摘要： PROBLEM TO BE SOLVED: To provide a hydrogen separating material with an enhancement in hydrogen separating capacity at a high temperature, that is, hydrogen permselectivity and/or hydrogen permeation speed, and its manufacturing method.
SOLUTION: The hydrogen separating material is equipped with a porous body (preferably comprising a baked ceramic material) having a hydrogen separating layer (preferably an average pore size is 0.3-0.5 nm and thickness is 5-200 nm), of which the pore size has a size capable of permeating hydrogen selectively, provided at least to a part thereof, and keeps the hydrogen separating layer modified with a silazane compound. The manufacturing method of the hydrogen separating material includes a process for preparing the porous body and a process for modifying (preferably impregnating) the hydrogen separating layer (preferably after surface homogenizing treatment, for example, plasma treatment) with the silazane compound (preferably especially hexamethylsilazane with a molecular weight of 200 or below).
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：解决的问题：提供一种在高温下氢分选能力和/或氢渗透速度提高氢分离能力的氢分离材料及其制造方法。解决方案：氢气分离材料配备有具有氢分离层（优选平均孔径为0.3-0.5nm，厚度为5-200nm）的多孔体（优选包括焙烧陶瓷材料），其中选择性地使孔径具有能够选择性地渗透氢的尺寸，至少提供一部分，并且保持用硅氮烷化合物改性的氢分离层。氢分离材料的制造方法包括制备多孔体的方法和用硅氮烷化合物（优选特别是六甲基硅氮烷）（优选浸渍）氢分离层（优选在表面均化处理，例如等离子体处理之后）分子量为200以下）。版权所有（C）2006，JPO＆NCIPI

4. 发明专利

JP2005171269A Method for manufacturing composite material 有权
标题翻译：制造复合材料的方法
公开(公告)号：JP2005171269A
公开(公告)日：2005-06-30
申请号：JP2003408261
申请日：2003-12-05
申请人： Noritake Co Ltd , 株式会社ノリタケカンパニーリミテド
发明人： BARAGOPARU N NAIR , YOSHINO YASUSHI , YOSHIKAWA HIROSHI , TAGUCHI HISATOMI
IPC分类号： C04B41/85 , B01J23/42 , B01J23/44 , B01J23/58 , B01J37/02 , C04B41/87 , C04B41/89 , C23C14/06 , C23C14/18 , C23C14/28
摘要： PROBLEM TO BE SOLVED: To provide a method for manufacturing a composite material having a complex layer in which a plurality of materials (typically, a base metal, a catalyst and the second material) are uniformly dispersed on the surface of a porous substrate. SOLUTION: This manufacturing method comprises employing a target having a catalytic material (palladium) and an inorganic material (zirconia) concentrically placed, in a pulsed laser ablation deposition method (PLD); and irradiating the target with a pulsed laser while vibrating the target in a predetermined direction (approximately in a Z direction), to sequentially vaporize the catalytic material and the inorganic material, and to deposit the catalytic material and the inorganic material on a porous substrate while mixing them approximately uniformly. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供一种复合材料的制造方法，所述复合材料具有复合层，其中多个材料（通常为贱金属，催化剂和第二材料）均匀地分散在多孔基质。解决方案：该制造方法包括在脉冲激光烧蚀沉积法（PLD）中使用具有同心放置的催化材料（钯）和无机材料（氧化锆）的靶; 并且在预定方向（大致Z方向）上振动目标物时，用脉冲激光照射目标物，以使催化材料和无机材料顺序蒸发，并将催化材料和无机材料沉积在多孔基材上，同时将其大致均匀混合。版权所有（C）2005，JPO＆NCIPI

5. 发明专利

JP2013147377A Inorganic porous body of alkaline resistance and method for manufacturing the same 有权
标题翻译：无机碱性碱性电阻体及其制造方法
公开(公告)号：JP2013147377A
公开(公告)日：2013-08-01
申请号：JP2012009102
申请日：2012-01-19
申请人： Noritake Co Ltd , 株式会社ノリタケカンパニーリミテド
发明人： BARAGOPARU N NAIR , WATANABE HIROKAZU , HORI KENJIRO
IPC分类号： C04B41/85 , B01D69/10 , C04B38/00
摘要： PROBLEM TO BE SOLVED: To provide a method for manufacturing an inorganic porous body enhanced in chemical stability and hydrophobicity compared with the past.SOLUTION: In this invention, a method for manufacturing an inorganic porous body is provided. This manufacturing method includes providing an organic silicon compound containing at least a fluorine atom at a surface of the inorganic porous material, and heating the inorganic porous material containing the organic silicon compound in such a manner that fluorine atoms originating from the organic silicon compound remains at least at a part of the surface of the inorganic porous material at a temperature equal to or higher than the boiling point of the organic silicon compound.
摘要翻译：要解决的问题：提供一种与过去相比提高化学稳定性和疏水性的无机多孔体的制造方法。解决方案：在本发明中，提供了一种无机多孔体的制造方法。这种制造方法包括在无机多孔材料的表面提供至少含有氟原子的有机硅化合物，并且以含有有机硅化合物的氟原子的方式加热含有有机硅化合物的无机多孔质，至少在无机多孔材料的表面的一部分处于等于或高于有机硅化合物的沸点的温度。

6. 发明专利

JP2005281024A Method for producing hydrogen, and membrane reactor used therefor 审中-公开
标题翻译：生产氢的方法及其使用的膜反应器
公开(公告)号：JP2005281024A
公开(公告)日：2005-10-13
申请号：JP2004094489
申请日：2004-03-29
申请人： Noritake Co Ltd , 株式会社ノリタケカンパニーリミテド
发明人： BARAGOPARU N NAIR , SUZUKI TAKEHIRO , ITO NAOJI , OMORI TAKAO , TSURU TOSHIAKI
IPC分类号： C01B3/38
摘要： PROBLEM TO BE SOLVED: To provide a method for producing hydrogen with high reaction efficiency and to provide a membrane reactor capable of carrying out the method.
SOLUTION: The method for producing hydrogen includes a step of supplying source gas containing a source material for hydrogen reformation and H
2 O to the hydrogen generating side separated by a hydrogen separation membrane in a membrane type reactor which essentially comprises a reformation catalyst and a ceramic porous material having the hydrogen separation membrane, and a step of supplying sweep gas substantially comprising H
2 O to the hydrogen permeating and recovering side separated by the hydrogen separation membrane. The sweep gas is supplied to the reactor while the H
2 O partial pressure in the sweep gas is controlled to maintain the relation of 0.3 2 O partial pressure in the hydrogen generating side and P2 is the H
2 O partial pressure in the hydrogen permeating and recovering side.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：待解决的问题：提供一种生产具有高反应效率的氢的方法，并提供能够实施该方法的膜反应器。解决方案：氢气的制造方法包括将由氢气分离膜分离的氢气发生侧的源气体供给到氢气重整用的源气体和H SB 2 O的步骤，反应器，其基本上包括重整催化剂和具有氢分离膜的陶瓷多孔材料，以及向由氢分离膜分离的氢透过和回收侧供给基本上包含H 2 S 2 O的吹扫气体的步骤。将吹扫气体供给到反应器中，同时控制吹扫气体中的H SB 2 O分压，以保持0.3 2 O分压和P2是氢渗透和回收侧的H SB 2 O分压。版权所有（C）2006，JPO＆NCIPI

7. 发明专利

JP2005145776A Porous ceramic material, method of manufacturing the same and gas separation module provided with the same 有权
标题翻译：多孔陶瓷材料及其制造方法及其分离模块
公开(公告)号：JP2005145776A
公开(公告)日：2005-06-09
申请号：JP2003387633
申请日：2003-11-18
申请人： Chubu Electric Power Co Inc , Noritake Co Ltd , 中部電力株式会社 , 株式会社ノリタケカンパニーリミテド
发明人： BARAGOPARU N NAIR , ANDO TAISUKE , NAGAYA SHIGEO , FURUMURA SEIJI , WATANABE AKIZO
IPC分类号： B01D71/02 , C04B38/00
摘要： PROBLEM TO BE SOLVED: To provide a porous ceramic material stable at a high temperature particularly exceeding 600°C.
SOLUTION: The porous ceramic material is obtained by thermally decomposing a ceramic precursor polymer having a number average molecular weight of ≥80 and 2 /g, particularly 150 m
2 /g surface area. It is preferable that a film of the porous ceramic material is formed particularly on at least a part of a surface of a supporting body.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供在特别高于600℃的高温下稳定的多孔陶瓷材料。解决方案：通过将数均分子量为≥80且<1,000，特别是≥500和<1,000的陶瓷前体聚合物热分解并基本上由惰性气体气氛中的Si和C组成而获得多孔陶瓷材料。多孔陶瓷材料基本上由Si和C组成，并且即使在700℃的高温和至少100m 2 SP SP 2下，也具有至少4，特别是至少10的小的氢/氮分离因子。 / g，特别是150m 2 / SP / g表面积。优选地，多孔陶瓷材料的膜特别地形成在支撑体的表面的至少一部分上。版权所有（C）2005，JPO＆NCIPI

8. 发明专利

JP2004238243A Porous ceramic material and its production method 有权
公开(公告)号：JP2004238243A
公开(公告)日：2004-08-26
申请号：JP2003028591
申请日：2003-02-05
申请人： Chubu Electric Power Co Inc , Noritake Co Ltd , 中部電力株式会社 , 株式会社ノリタケカンパニーリミテド
发明人： BARAGOPARU N NAIR , TAGUCHI HISATOMI , NAGAYA SHIGEO , FURUMURA SEIJI , WATANABE AKIZO
IPC分类号： C04B38/00
摘要： PROBLEM TO BE SOLVED: To provide a non-oxide-base porous ceramic material rich in micropores and improved in durability under oxidative conditions.
SOLUTION: This porous ceramic material has a porous part substantially comprising a noncrystalline part which is composed of a non-oxide ceramic mainly consisting of silicon and a crystalline part which is composed of a non-oxide ceramic mainly consisting of silicon and is scattered in the noncrystalline part. The peak value of the micropore diameter distribution of the porous part is 2 nm or less.
COPYRIGHT: (C)2004,JPO&NCIPI

9. 发明专利

JP2004123415A Porous ceramic material and method of manufacturing the same 有权
公开(公告)号：JP2004123415A
公开(公告)日：2004-04-22
申请号：JP2002286829
申请日：2002-09-30
申请人： Chubu Electric Power Co Inc , Noritake Co Ltd , 中部電力株式会社 , 株式会社ノリタケカンパニーリミテド
发明人： BARAGOPARU N NAIR , TAGUCHI HISATOMI , MIYAJIMA KEITA , NAGAYA SHIGEO , FURUMURA SEIJI
IPC分类号： B01D53/22 , B01D69/10 , B01D71/02 , C04B38/00 , C04B41/87
摘要： PROBLEM TO BE SOLVED: To provide a method of manufacturing a porous ceramic material having a surface ceramic layer rich in micropores and capable of being used even in a high temperature condition, and a method of manufacturing the porous ceramic material.
SOLUTION: The method of manufacturing the porous ceramic material is performed by preparing a porous ceramic supporting body (120) having a precursor polymer of a non-oxide ceramic consisting essentially of silicon at least on a part of the surface part, applying the thermal decomposition pretreatment to the supporting body and thermally decomposing the precursor polymer to form the porous non-oxide ceramic layer rich in the micropores on the surface part of the supporting body. In the thermal decomposition pretreatment, the supporting body is held for ≥1 hr at about ≥40°C being a temperature at which the precursor polymer is substantially not thermally decomposed or the supporting body is arranged in a pressure vessel (101) and is held at a temperature that the precursor polymer is substantially not thermally decomposed while pressurizing the inside of the vessel to ≥0.12 MPa.
COPYRIGHT: (C)2004,JPO

10. 发明专利

JP2006008435A Inorganic porous body and method for manufacturing the same 有权
标题翻译：无机多孔体及其制造方法
公开(公告)号：JP2006008435A
公开(公告)日：2006-01-12
申请号：JP2004185809
申请日：2004-06-24
申请人： Noritake Co Ltd , 株式会社ノリタケカンパニーリミテド
发明人： BARAGOPARU N NAIR
IPC分类号： C04B41/85 , B01D67/00 , B01J20/30 , C23C14/28 , C23C30/00
摘要： PROBLEM TO BE SOLVED: To provide an inorganic porous body having an inorganic porous film through which molecules or particles contained in a fluidity to be treated is efficiently permeated and a method for manufacturing the porous body.
SOLUTION: The inorganic porous body is provided with the inorganic porous film having a plurality of pores oriented almost in the film thickness direction on the surface of the porous base material. The average pore diameter is preferably 2-200 nm. The method of obtaining the porous body includes a process for preparing a target containing an inorganic material and the porous base material and a process for forming the porous film by arranging the target and the porous base material under 1-200 Pa atmospheric pressure, irradiating the target with pulse laser having 5-500 Hz frequency to produce the vapor of the inorganic material, and depositing the vapor on the surface of the porous base material. The porous film forming process is preferably carried out under a fixed temperature condition in which the base material temperature is set to ≤1,000°C. The number of irradiation times with the pulse laser is preferably ≤200,000 times.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供一种具有无机多孔膜的无机多孔体，通过该无机多孔膜有效地渗透待处理的流动性中所含的分子或颗粒，以及制造多孔体的方法。解决方案：无机多孔体设置有多孔基材的表面上具有多个在膜厚度方向取向的多孔的无机多孔膜。平均孔径优选为2〜200nm。获得多孔体的方法包括制备包含无机材料的靶和多孔基材的方法，以及通过将靶和多孔基材设置在1-200Pa大气压下形成多孔膜的方法，照射目标是具有5-500Hz频率的脉冲激光，以产生无机材料的蒸气，并将蒸气沉积在多孔基材的表面上。多孔膜形成方法优选在将基材温度设定为≤1000℃的固定温度条件下进行。脉冲激光器的照射次数优选为≤200,000次。版权所有（C）2006，JPO＆NCIPI

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