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1. 发明授权

US5792867A Method of alkylating of triazine derivatives 失效
标题翻译：烷基化三嗪衍生物的方法
公开(公告)号：US5792867A
公开(公告)日：1998-08-11
申请号：US571828
申请日：1996-02-05
申请人： Norio Tanaka , Masataka Hatanaka , Makoto Ishikawa , Yasuo Fukue , Isao Hashiba , Yoshihisa Watanabe
发明人： Norio Tanaka , Masataka Hatanaka , Makoto Ishikawa , Yasuo Fukue , Isao Hashiba , Yoshihisa Watanabe
IPC分类号： C07D251/16 , C07D251/18 , C07D251/52 , C07D251/70 , C07D251/54
CPC分类号： C07D251/70 , C07D251/16 , C07D251/18 , C07D251/52
摘要： A method for alkylation of at least one or more amino groups or mono-substituted amino groups, each on a carbon atom of a triazine ring of 1,3,5-triazine derivatives (melamine, melamine derivatives and various kinds of guanamine derivatives and the like), which includes reacting the 1,3,5-triazine derivatives having at least one or more amino groups or mono-substituted amino groups with alcohols in the presence of a catalyst of a metal of group VII and/or group VIII in the periodic table. The object of the invention is to provide a method for alkylation of 1,3,5-triazine derivatives, which includes alkylating amino groups or mono-substituted amino groups in carbon atoms of a 1,3,5-triazine ring, whereby substituted 1,3,5-triazine derivatives which are a group of useful compounds and which are widely used as intermediates of fine chemicals such as agricultural chemicals, medications, dye-stuffs, paints and the like, as resin materials and as flame-retardant materials can be easily produced in high yields.
摘要翻译： PCT No.PCT / JP94 / 01190 Sec。 371日期：1996年2月5日 102（e）日期1996年2月5日PCT提交1994年7月20日PCT公布。出版物WO95 / 03287 日期1995年2月2日在1,3,5-三嗪衍生物（三聚氰胺，三聚氰胺衍生物等）的三嗪环的碳原子上烷基化至少一个以上的氨基或单取代氨基的方法胍胺衍生物等），其包括使具有至少一个或多个氨基或单取代氨基的1,3,5-三嗪衍生物与醇在VII族金属和/ 或周期表中的VIII族。本发明的目的是提供一种1,3,5-三嗪衍生物的烷基化方法，其包括在1,3,5-三嗪环的碳原子中烷基化氨基或单取代氨基，由此取代1 作为有用化合物的一组的3,5-三嗪衍生物，广泛用作农药，药物，染料，油漆等精细化学品的中间体作为树脂材料和阻燃材料，容易以高产量生产。

2. 发明授权

US6130332A Method of alkylating triazine derivatives 失效
标题翻译：烷基化三嗪衍生物的方法
公开(公告)号：US6130332A
公开(公告)日：2000-10-10
申请号：US737712
申请日：1997-02-07
申请人： Norio Tanaka , Kenichi Mizusawa , Makoto Ishikawa , Yasuo Fukue , Isao Hashiba , Yoshihisa Watanabe
发明人： Norio Tanaka , Kenichi Mizusawa , Makoto Ishikawa , Yasuo Fukue , Isao Hashiba , Yoshihisa Watanabe
IPC分类号： C07D251/70 , C07D251/16 , C07D251/18 , C07D251/42 , C07D251/48
CPC分类号： C07D251/70
摘要： The object of the present invention is to provide a method for producing substituted-1,3,5-triazine derivatives at high yield, in which at least one of carbon atoms in the ring thereof is substituted by a secondary amine group having at leat one of alkyl groups. The method of the present invention is a method for alkylation of 1,3,5-triazine derivatives, characterized by reacting 1,3,5-triazine derivatives (melamines, melamine derivatives, various kinds of guanaminde derivatives, etc.) which has at least one or more amino groups or mono-substituted amino groups on carbon atom of the ring thereof, with aldehydes or ketones alcohols in the presence of a catalyst of a metal of group VII and/or group VIII in the periodic table and a hydrogen-containing gas to alkylate said at least one of amino groups or mono-substituted amino groups. These derivatives are widely used as intermediates of fine chemicals such as agricultural chemicals, medications, dyestuffs, paints and the like and are widely used resin materials and as flame-retardant materials.
摘要翻译： PCT No.PCT / JP95 / 00881 Sec。 371日期1997年2月7日 102（e）日期1997年2月7日PCT提交1995年5月9日PCT公布。 WO95 / 30662 PCT出版物日期：1995年11月16日本发明的目的是提供以高产率制备取代-1,3,5-三嗪衍生物的方法，其中环中的至少一个碳原子被仲胺具有烷基基团的基团。本发明的方法是1,3,5-三嗪衍生物的烷基化方法，其特征在于使1,3,5-三嗪衍生物（三聚氰胺，三聚氰胺衍生物，各种胍胺衍生物等）在环的碳原子上的至少一个或多个氨基或单取代的氨基与醛或酮醇在元素周期表中的第Ⅶ族和/或第Ⅷ族金属的催化剂存在下反应，含有气体以烷基化所述至少一个氨基或单取代的氨基。这些衍生物广泛用作农药，药物，染料，油漆等精细化学品的中间体，是广泛使用的树脂材料和阻燃材料。

3. 发明授权

US5786479A Process for producing a 6-subsitituted 2(1H)-quinoxalinone 失效
标题翻译：生产6-取代的2（1H） - 喹喔啉酮的方法
公开(公告)号：US5786479A
公开(公告)日：1998-07-28
申请号：US687439
申请日：1996-08-13
申请人： Isao Hashiba , Masataka Hatanaka
发明人： Isao Hashiba , Masataka Hatanaka
IPC分类号： C07D241/44 , C07D241/36
CPC分类号： C07D241/44
摘要： A process for producing a 6-substituted 2(1H)-quinoxalinone of the formula (I): ##STR1## wherein X is a halogen atom, a trihalogeno-substituted C.sub.1-5 alkyl group or a nitro group, which comprises reacting a 6-substituted 2(1H)-quinoxalinone-N-oxide of the formula (II): ##STR2## wherein X is as defined above, with an alkali metal hydrosulfide and/or an alkali metal sulfide in the presence of from 1 to 20 mol times of an alkali.
摘要翻译： PCT No.PCT / JP95 / 00173 Sec。 371日期：1996年8月13日 102（e）日期1996年8月13日PCT提交1995年2月8日PCT公布。公开号WO95 / 22531 日期：1995年8月24日制备式（I）的6-取代的2（1H） - 喹喔啉酮的方法：其中X为卤素原子，三卤代取代的C 1-5烷基或硝基，其包括使式（II）的其中X如上所定义的6-取代的2（1H） - 喹喔啉酮-N-氧化物与碱金属氢硫化物和/或碱金属硫化物在1至20摩尔碱的存在下进行。

4. 发明授权

US06878824B2 Process for preparing N-methylated melamines 失效
标题翻译：制备N-甲基化三聚氰胺的方法
公开(公告)号：US06878824B2
公开(公告)日：2005-04-12
申请号：US10390706
申请日：2003-03-19
申请人： Isao Hashiba , Takayuki Tamura , Hiroyuki Kousaka
发明人： Isao Hashiba , Takayuki Tamura , Hiroyuki Kousaka
IPC分类号： C07D251/56 , C07D251/70
CPC分类号： C07D251/56
摘要： The present invention provides a process for preparing N-methylated melamines in simple steps by using inexpensive raw materials in such a manner that the proportion of mono-type, bis-type and tris-type of the N-methylated melamines as prepared can be controlled. The process comprises reacting by heating melamine with methylamine in the presence of an acidic catalyst under pressure to substitute at least one amino group of the melamine by methylamino group.
摘要翻译：本发明提供了以简单的步骤制备N-甲基化三聚氰胺的方法，其方法是以可以控制所制备的N-甲基化三聚氰胺的单型，双型和三种类型的比例来控制。该方法包括通过在压力下在酸性催化剂存在下加三聚氰胺与甲胺反应，以通过甲基氨基代替至少一个三聚氰胺的氨基。

5. 发明授权

US5962740A Processes for producing 4,6-bis (substituted)phenylazoresorcinols 失效
标题翻译：生产4,6-双（取代）苯基次氮杂环戊烯的方法
公开(公告)号：US5962740A
公开(公告)日：1999-10-05
申请号：US66335
申请日：1998-04-28
申请人： Kazuhiko Akimoto , Kenichi Tokunaga , Isao Hashiba , Hideo Suzuki , Yasuo Katsumura , Kazuo Osaki , Hideo Kawashita , Satoshi Yamazaki
发明人： Kazuhiko Akimoto , Kenichi Tokunaga , Isao Hashiba , Hideo Suzuki , Yasuo Katsumura , Kazuo Osaki , Hideo Kawashita , Satoshi Yamazaki
IPC分类号： C07C245/08 , C07C213/02
CPC分类号： C07C245/08
摘要： A process for producing 4,6-bisphenylazoresorcinol of formula �2! wherein R represents halogen atom, C.sub.1-5 alkyl group, hydroxycarbonyl or C.sub.1-5 alkoxy group, n represents 0 or an integer of 1 to 5, and two or more Rs are the same or different from each other, which comprises reacting resorcinol with a benzenediazonium salt of formula �1! wherein R and n are the same as defined in the above formula �1!, and X represents Cl, Br, OSO.sub.3 H or OPO.sub.3 H.sub.2, in an alkaline solvent, characterized in that (a) a solution of the compound of the formula �1! is mixed with a solution or suspension of an alkali metal or alkaline earth metal hydroxide to obtain an alkaline mixture, and this alkaline mixture is mixed to be reacted with a solution or suspension containing resorcinol and/or its alkali metal salt or alkaline earth metal salt, or (b) a solution of the compound of formula �1! is mixed to be reacted with a solution or suspension of a mixture of resorcinol with its alkali metal hydroxide or alkaline earth metal hydroxide 15 to 40 times by mol as much as the resorcinol. By the above-described method, the reaction volume can be reduced as compared with the conventional processes, and 4,6-bisphenylazoresorcinol can be obtained in high yield.
摘要翻译： PCT No.PCT / JP96 / 03199 Sec。 371日期：1998年4月28日 102（e）1998年4月28日PCT PCT 1996年10月31日PCT公布。第WO97 / 16411号公报日期1997年5月9日制备式[2]的4,6-双苯并苯并氮杂酚的方法，其中R表示卤素原子，C 1-5烷基，羟基羰基或C 1-5烷氧基，n表示0或1〜5的整数，两个或多个Rs相同或不同，其包括使间苯二酚与式[1]的苯二氮鎓盐反应，其中R和n与上式[1]中定义相同，X表示Cl，Br， OSO 3 H或OPO 3 H 2，在碱性溶剂中，其特征在于：（a）式[1]化合物的溶液与碱金属或碱土金属氢氧化物的溶液或悬浮液混合，得到碱性混合物，将碱性混合物与含有间苯二酚和/或其碱金属盐或碱土金属盐的溶液或悬浮液混合，或（b）将式[1]化合物的溶液与溶液或溶液反应，或间苯二酚与其碱金属氢氧化物的混合物悬浮 de或碱土金属氢氧化物为间苯二酚的15〜40倍摩尔。通过上述方法，与常规方法相比可以降低反应体积，可以高产率获得4,6-双苯并氮杂间苯二酚。

6. 发明授权

US5153329A Process for producing N-alkylpyrazoles 失效
标题翻译：生产N-烷基吡唑的方法
公开(公告)号：US5153329A
公开(公告)日：1992-10-06
申请号：US678241
申请日：1991-04-01
申请人： Hiroshi Murakami , Susumu Yamamoto , Yoshihiro Iwasawa , Fumio Suzuki , Isao Hashiba
发明人： Hiroshi Murakami , Susumu Yamamoto , Yoshihiro Iwasawa , Fumio Suzuki , Isao Hashiba
IPC分类号： C07D231/12 , C07D521/00
CPC分类号： C07D231/12 , C07D233/56 , C07D249/08
摘要： Disclosed herein is a process for producing N-alkylpyrazoles represented by the formula (1), which comprises reacting an alkali metal or an alkali metal-containing base with N- unsubstituted pyrazoles represented by the formula (2), to form an alkali metal salt thereof and, subsequently, reacting the obtained alkali metal salt with an alkylating agent. ##STR1## R.sup.1 : H, C.sub.1 -C.sub.4 alkyl; R.sup.2 : C.sub.1 -C.sub.4 alkyl;n: an integer of 1-3.

7. 发明授权

US4970336A Method of purifying .alpha.-substituted acetic acids 失效
标题翻译： α-取代乙酸的纯化方法
公开(公告)号：US4970336A
公开(公告)日：1990-11-13
申请号：US359682
申请日：1989-05-31
申请人： Yoshikazu Yoshioka , Isao Hashiba , Suketoshi Tsukamoto
发明人： Yoshikazu Yoshioka , Isao Hashiba , Suketoshi Tsukamoto
IPC分类号： C07C51/00 , C07C51/08 , C07C51/42 , C07C51/47 , C07C51/487 , C07C57/30 , C07C57/58 , C07C59/64 , C07C59/84 , C07C59/88 , C07C59/90 , C07C67/00 , C07C313/00 , C07C319/28 , C07C323/22 , C07C323/56 , C07C323/62
CPC分类号： C07C319/28 , C07C51/42 , C07C51/487
摘要： This invention relates to methods of preparing and purifying .alpha.-substituted acetic acids, which comprise treating an .alpha.aromatic-substituted acetic acid represented by a specific general formula with a weak alkali while shielding light, or subjecting an .alpha.-aromatic-substituted acetonitrile represented by a specific general formula to acid hydrolysis, followed by treatment with a weak alkali while shielding light; and treating the alkali salt of .alpha.-substituted acetic acid thus formed with a decolorizing agent.

8. 发明授权

US5880309A Phenylphosphonic acid derivative and production process therefor 失效
标题翻译：苯基膦酸衍生物及其制备方法
公开(公告)号：US5880309A
公开(公告)日：1999-03-09
申请号：US8244
申请日：1998-01-15
申请人： Hideo Suzuki , Masafumi Nomura , Kenichi Tokunaga , Isao Hashiba
发明人： Hideo Suzuki , Masafumi Nomura , Kenichi Tokunaga , Isao Hashiba
IPC分类号： C07F9/38 , C07F9/40
CPC分类号： C07F9/3834 , C07F9/4021
摘要： A dialkyl dialkoxycarbonylphenylphosphonate which is useful as a resin modifier, a process for producing the same in high yield at a low cost, and a process for producing a dicarboxyphenylphosphonic acid in high yield at a low cost are described.The process for producing a dialkyl dialkoxycarbonylphenylphosphonate comprises heating and reacting a dialkoxycarbonylphenyl halide with a trialkyl phosphate in the presence of a catalyst comprising an element of group VIII of the periodic table (such as an alumina supported palladium catalyst) and hydrolyzing the obtained dialkyl dialkoxycarbonylphenylphosphonate in the presence of an acid or base to produce a dicarboxyphenylphosphonic acid.
摘要翻译：描述了可用作树脂改性剂的二烷基二烷氧基羰基苯基膦酸酯，以低成本高产率地制备其的方法和以低成本高产率生产二羧基苯基膦酸的方法。制备二烷基二烷氧基羰基苯基膦酸二烷基酯的方法包括在包含元素周期表第Ⅷ族元素（如氧化铝负载的钯催化剂）的催化剂存在下，加热和反应二烷氧基羰基苯基卤化物与磷酸三烷基酯，并将得到的二烷基二烷氧基羰基苯基膦酸酯水解存在酸或碱以产生二羧基苯基膦酸。

9. 发明授权

US5847199A Derivative of phosphonic acid and process for the preparation thereof 失效
标题翻译：膦酸衍生物及其制备方法
公开(公告)号：US5847199A
公开(公告)日：1998-12-08
申请号：US957026
申请日：1997-10-24
申请人： Isao Hashiba , Kenichi Tokunaga
发明人： Isao Hashiba , Kenichi Tokunaga
IPC分类号： C07F9/38 , C08K5/5317 , C07F9/40
CPC分类号： C08K5/5317 , C07F9/3834
摘要： To provide 2,5-dicarboxyphenyl phosphonic acid and a process for the preparation thereof, comprising the steps of: forming a reaction liquid phase by supplying a 2,5-dialkylphenyl phosphonic acid, a solvent, a cobalt salt, a manganese salt and/or a cerium salt, and bromine or a bromine compound into a reaction zone; and supplying oxygen into the reaction liquid phase by bringing an oxygen-containing gas into contact with the reaction liquid phase by supplying an oxygen-containing gas into the above-mentioned reaction zone.
摘要翻译：为了提供2,5-二羧基苯基膦酸及其制备方法，包括以下步骤：通过将2,5-二烷基苯基膦酸，溶剂，钴盐，锰盐和/ 或铈盐，溴或溴化合物转化成反应区; 并通过使含氧气体通过向上述反应区域供给含氧气体使含氧气体与反应液相接触而将氧气供给到反应液相中。

10. 发明授权

US4537984A Process for producing 2-(4-hydroxyphenoxy) propionate derivatives 失效
标题翻译： 2-（4-羟基苯氧基）丙酸酯衍生物的制备方法
公开(公告)号：US4537984A
公开(公告)日：1985-08-27
申请号：US604156
申请日：1984-04-26
申请人： Isao Hashiba , Tadashi Nishikimi , Shuji Tsuchiya
发明人： Isao Hashiba , Tadashi Nishikimi , Shuji Tsuchiya
IPC分类号： C07C69/712 , C07C69/76
CPC分类号： C07C69/712
摘要： A process for producing a 2-(4-hydroxyphenoxy) propionate derivative represented by the formula: ##STR1## where Alk is a C.sub.1 -C.sub.5 alkyl group, which comprises reacting a phenoxy propionate derivative represented by the formula: ##STR2## where Alk is as defined above, with a peroxide to obtain a formate derivative represented by the formula: ##STR3## where Alk is as defined above, and hydrolyzing the formate of the formula III.
摘要翻译：一种制备式（Ⅰ）所示的2-（4-羟基苯氧基）丙酸酯衍生物的方法，其中Alk是C1-C5烷基，其中包括使由下式表示的苯氧基丙酸酯衍生物：（II）其中Alk如上所定义，与过氧化物反应，得到式（III）表示的甲酸酯衍生物，其中Alk如上所定义，并水解式III的甲酸酯。

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