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    • 1. 发明授权
    • Absorbent composite, method for production thereof, and absorbent article
    • 吸收性复合材料,其制造方法和吸收性物品
    • US5853867A
    • 1998-12-29
    • US713866
    • 1996-09-13
    • Nobuyuki HaradaYoshihiro MotonoShigeru SakamotoToshimasa Kitayama
    • Nobuyuki HaradaYoshihiro MotonoShigeru SakamotoToshimasa Kitayama
    • A61L15/60A61F13/15
    • A61L15/60Y10S428/913Y10T428/249986Y10T442/277Y10T442/2885Y10T442/2893Y10T442/2918
    • This invention concerns an absorbent composite a supporting member and a cationic absorbent polymer and anionic absorbent polymer particles fixed to the supporting member. This absorbent composite excels in absorbing capacity under pressure, vertical aspiration power, and flexibility and suffers only sparing exfoliation of an absorbent polymer. This invention further concerns an absorbent composite which contains an absorbent polymer in an amount of at least 30% by weight based on the total weight of the absorbent composite and, after absorbing a liquid, shows a value of not less than 3 for the expansion anisotropy specified by the following formula. Expansion anisotropy=(Ez/Ex+Ez/Ey)/2 (wherein Ex, Ey, and Ez respectively represent coefficient of liner expansion in the directions of X axis, Y axis, and Z axis) and an absorbent article using the absorbent composite. This invention permits production of a novel absorbent composite which suffers no leakage and excels in water absorbing power, water retaining power, and flexibility and an absorbent article using the absorbent composite.
    • 本发明涉及一种吸收性复合材料,其是支撑构件和阳离子吸收聚合物以及固定在支撑构件上的阴离子吸收性聚合物颗粒。 这种吸收性复合材料在压力,垂直抽吸力和柔韧性下的吸收能力优异,并且仅仅吸收聚合物的剥落。 本发明还涉及一种吸收性复合材料,其含有吸收性聚合物,该吸收性聚合物的量相对于吸收性复合材料的总重量为至少30重量%,并且在吸收液体之后,对于膨胀各向异性显示不小于3的值 由以下公式指定。 膨胀各向异性=(Ez / Ex + Ez / Ey)/ 2(其中,Ex,Ey和Ez分别表示在X轴,Y轴和Z轴方向上的衬垫膨胀系数)和使用吸收性复合材料 。 本发明允许生产不会发生泄漏并且吸水力,保水力和柔软性优异的吸收性复合材料,以及使用吸收性复合体的吸收性物品。
    • 2. 发明授权
    • Method of producing a hydrophilic resin
    • 亲水性树脂的制造方法
    • US6150469A
    • 2000-11-21
    • US930272
    • 1997-09-29
    • Nobuyuki HaradaShigeru SakamotoYoshihiro MotonoTadao Shimomura
    • Nobuyuki HaradaShigeru SakamotoYoshihiro MotonoTadao Shimomura
    • C08J3/20C08J3/24C08F8/00
    • C08J3/24C08J3/20C08J2300/14
    • A hydrophilic polymer is denatured with a gaseous denaturant or a powdery denaturant substance made from a liquid denaturant substance. The liquid denaturant substance is made into powders by, for example, a method of mixing the liquid denaturant substance with a water-insoluble compound, a method of cooling the liquid denaturant substance to or below its melting point to turn the same into a solid state. Consequently, the hydrophilic polymer can be denatured uniformly. In case that the hydrophilic polymer is denatured with a gaseous denaturant, the hydrophilic polymer and denaturant react with each other efficiently in a safe manner regardless of the size or shape of the hydrophilic polymer. In case that the hydrophilic polymer is denatured with the powdery denaturant substance, not only the liquid denaturant substance which is substantially in the solid state can be mixed with the hydrophilic polymer, but also the denaturation timing can be readily controlled.
    • PCT No.PCT / JP97 / 00229 Sec。 371日期:1997年9月29日 102(e)1997年9月29日PCT PCT 1997年1月31日PCT公布。 公开号WO97 / 28209 日期1997年8月7日亲水性聚合物由气态变性剂或由液体变性剂物质制成的粉末状变性剂变性。 液体变性剂物质通过例如将液体变性剂物质与水不溶性化合物混合的方法制成粉末,将液体变性剂物质冷却至其熔点以下以使其变为固态的方法 。 因此,亲水性聚合物可以均匀地变性。 亲水性聚合物在气态变性剂变性的情况下,无论亲水性聚合物的尺寸或形状如何,亲水性聚合物和变性剂以安全的方式有效地彼此反应。 亲水性聚合物与粉末状变性剂变性的情况下,不仅可以将基本上处于固体状态的液体变性剂与亲水性聚合物混合,而且可以容易地控制变性定时。
    • 3. 发明授权
    • Method of production of water-absorbing resin
    • 吸水树脂的生产方法
    • US6100305A
    • 2000-08-08
    • US91462
    • 1998-06-18
    • Koji MiyakeYoshihiro MotonoNobuyuki HaradaAkito YanoTeruyuki KantoShigeru Sakamoto
    • Koji MiyakeYoshihiro MotonoNobuyuki HaradaAkito YanoTeruyuki KantoShigeru Sakamoto
    • B01J20/26C08J9/36
    • B01J20/26
    • A water-absorbent resin is produced by crushing a mass of crosslinked hydrogel polymer having high adhesion and elastic properties without kneading it, and drying the crushed crosslinked hydrogel polymer. In the case when the crosslinked hydrogel polymer includes cells therein, the crosslinked hydrogel polymer is crushed so as to restrain reduction in the number of cells contained in the crosslinked hydrogel polymer. The crosslinked hydrogel polymer is crushed by any of crushing methods including: shearing the crosslinked hydrogel polymer with a fixed blade and a rotary blade; cutting the crosslinked hydrogel polymer with a cutter having a pair of rotary blades that are mounted on different shafts and rotate while at least partly overlapping each other; cutting the crosslinked hydrogel polymer with a cutter having a rotary blade using a lubricant; and crushing the crosslinked hydrogel polymer after freezing. With the use of the above methods, it is possible to industrially and easily mass-produce porous water-absorbent resins with excellent absorption properties while restraining reduction in the number of cells contained in the crosslinked hydrogel polymer.
    • PCT No.PCT / JP97 / 03753 Sec。 371日期1998年6月18日 102(e)1998年6月18日PCT 1997年10月16日PCT PCT。 第WO98 / 17453号公报 日期:1998年04月30日吸水性树脂通过粉碎具有高粘合性和弹性的交联水凝胶聚合物的质量而不进行捏合而制造,并干燥破碎的交联水凝胶聚合物。 当交联的水凝胶聚合物包括其中的细胞时,交联的水凝胶聚合物被粉碎,以便抑制交联的水凝胶聚合物中所含的细胞数量的减少。 交联的水凝胶聚合物通过任何破碎方法粉碎,包括:用固定刀片和旋转刀片剪切交联的水凝胶聚合物; 用具有一对旋转叶片的切割器切割交联的水凝胶聚合物,所述一对旋转叶片安装在不同的轴上并在彼此至少部分重叠的同时旋转; 用具有旋转叶片的切割机使用润滑剂切割交联的水凝胶聚合物; 并在冷冻后破碎交联的水凝胶聚合物。 通过使用上述方法,可以在抑制交联水凝胶聚合物中所含的细胞数量的抑制的情况下,工业上容易地大量生产具有优异吸收性能的多孔吸水性树脂。
    • 4. 发明授权
    • Water-swellable crosslinked polymer composition and production
    • 水溶胀性交联聚合物组合物和生产
    • US06333109B1
    • 2001-12-25
    • US09371956
    • 1999-08-11
    • Nobuyuki HaradaShigeru SakamotoYoshifumi AdachiToshimasa Kitayama
    • Nobuyuki HaradaShigeru SakamotoYoshifumi AdachiToshimasa Kitayama
    • B32B1502
    • B01J20/26A61L15/60C08L101/14Y10T428/2982Y10T428/31855C08L79/00C08L33/02C08L2666/02
    • The present invention has an object to provide a novel water-swellable crosslinked polymer composition which exhibits excellent saltwater absorption speed and capacity under a load. This object can be achieved in the case where, in a water-swellable crosslinked polymer composition comprising a blend of water-swellable crosslinked polymer particles of basicity in water and water-swellable crosslinked polymer particles of acidity in water, the water-swellable crosslinked polymer particles of basicity in water are unified with the water-swellable crosslinked polymer particles of acidity in water through ionic bondings in a state where water is present between the particles, wherein the ionic bondings are formed in a state where water is present between the particles by neutralization of at least part of acid groups of the water-swellable crosslinked polymer particles of acidity in water with the water-swellable crosslinked polymer particles of basicity in water.
    • 本发明的目的是提供一种在负荷下表现出优异的盐水吸收速度和容量的新的水溶胀性交联聚合物组合物。 该水溶胀性交联聚合物组合物包含在水中具有碱性的水溶胀性交联聚合物粒子和水中的酸溶性水溶胀性交联聚合物粒子的共混物的水溶胀性交联聚合物组合物的情况下,可以实现该目的, 在水中存在水的状态下,通过离子键合,在水中呈酸性的水溶胀性交联聚合物颗粒与水中的碱度一致,其中在颗粒之间存在水的状态下形成离子键, 在水中具有碱性的水溶胀性交联聚合物颗粒在水中中和酸溶性的水溶胀性交联聚合物颗粒的至少一部分酸基团。
    • 10. 发明授权
    • Method for producing water absorbent resin particle
    • 吸水性树脂颗粒的制造方法
    • US09593212B2
    • 2017-03-14
    • US12296808
    • 2007-09-28
    • Shigeru SakamotoYoshio IrieHiroyuki IkeuchiMakoto NagasawaKunihiko IshizakiSayaka Machida
    • Shigeru SakamotoYoshio IrieHiroyuki IkeuchiMakoto NagasawaKunihiko IshizakiSayaka Machida
    • C08J3/12B29B17/00
    • C08J3/12B29B9/06B29B17/00C08J2300/14Y02W30/62
    • The present invention provides a method for producing a water absorbent resin particle, in high productivity, not only in a controlled manner of particle size but also enhancing fundamental property (absorption capacity or absorption capacity against pressure) of a water absorbent resin. A method for producing a water absorbent resin particle having the cross-linking polymerization step for an aqueous solution of an unsaturated monomer; the grain refining step for water-swellable, water-containing gel-like cross-linked polymer (a) obtained in the cross-linking polymerization step; the drying step for grain refined gel; and the crushing step for a dried substance, wherein, in the grain refining step for the water-swellable, water-containing gel-like cross-linked polymer (a), water-swellable, water-containing gel-like cross-linked polymer (b), having solid content or centrifuge retention capacity different from solid content or centrifuge retention capacity of the cross-linked polymer (a) by equal to or larger than 1%, is subjected to coexistence.
    • 本发明提供了一种生产吸水性树脂颗粒的方法,不仅以受控的粒度控制,而且提高了吸水性树脂的基本性能(吸收能力或抗吸收能力)。 一种制备具有用于不饱和单体的水溶液的交联聚合步骤的吸水性树脂颗粒的方法; 在交联聚合步骤中获得的水溶胀性含水凝胶状交联聚合物(a)的晶粒细化步骤; 颗粒精制凝胶的干燥步骤; 和干物质的破碎步骤,其中在水溶胀性含水凝胶状交联聚合物(a)的晶粒细化工序中,水溶胀性含水凝胶状交联聚合物 (b)具有不同于交联聚合物(a)的固体含量或离心保留能力等于或大于1%的固体含量或离心保留能力共存。