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    • 3. 发明授权
    • Method and apparatus for producing molecular film
    • 生产分子膜的方法和装置
    • US06183558B2
    • 2001-02-06
    • US09294297
    • 1999-04-19
    • Tadashi OtakeNorihisa MinoTohru NakagawaMamoru SogaKazufumi OgawaTakaiki NomuraYasuo Takebe
    • Tadashi OtakeNorihisa MinoTohru NakagawaMamoru SogaKazufumi OgawaTakaiki NomuraYasuo Takebe
    • B05C108
    • B82Y30/00B05D1/283B05D3/0486B82Y40/00
    • A method for forming a molecular film includes the steps of: coating a surface of a substrate having active hydrogen atoms on its surface with a coating solution containing a silane-based compound having at least one reactive group selected from the group consisting of a chloro group, an alkoxy group and an isocyanate group; and effecting an elimination reaction between the active hydrogen atoms on the surface of the substrate and reactive groups of the silane-based compound, thereby covalently bonding the silane-based compounds to the surface of the substrate. The substrate is supplied to a chamber in which an atmosphere is maintained at a low water vapor density. The surface of the substrate is coated with a coating solution containing the silane-based compound and a solvent by using a transfer element. A dehydrochlorination reaction is effected between the active hydrogen atoms and the chloro groups of the silane-based compounds. Thereafter, any coating solution containing unreacted silane-based compounds after coating is removed inside or outside the chamber.
    • 形成分子膜的方法包括以下步骤:用包含具有至少一个选自氯基团的反应性基团的硅烷基化合物的涂布溶液在其表面上涂覆具有活性氢原子的基材的表面 ,烷氧基和异氰酸酯基; 并且进行基板表面上的活性氢原子与硅烷类化合物的反应性基团之间的消除反应,从而将硅烷类化合物共价键合到基板的表面。 将基板供给到气氛保持在低水蒸汽密度的室中。 通过使用转印元件,将含有硅烷系化合物和溶剂的涂布液涂布在基材的表面上。 在活性氢原子和硅烷基化合物的氯基之间进行脱氯化氢反应。 此后,在室内或室外除去涂布后含有未反应的硅烷类化合物的任何涂布溶液。
    • 4. 发明授权
    • Liquid drop placing apparatus and liquid drop placing method
    • 液滴放置装置和液滴放置方法
    • US07628464B2
    • 2009-12-08
    • US10568059
    • 2005-03-02
    • Tohru NakagawaNorihisa Mino
    • Tohru NakagawaNorihisa Mino
    • B41J29/393
    • B41J2/04586B41J2/01B41J2/04556
    • An ink jet head (1), a substrate (13) receiving a liquid drop (2) discharged from the ink jet head (1), a device for irradiating or reflecting light from a nozzle hole or its vicinity of the ink jet head (1) toward the substrate (13), a position moving device (10) for controlling a relative position between the ink jet head (1) and the substrate (13), and a control device (9) for discharging a liquid from the ink jet head (1) are included. A light-receiving element (6) for recognizing a position of the ink jet head (1) is disposed behind the substrate (13), when seen from the ink jet head (1), the substrate (13) has a transparency at least to a degree that the irradiated light or the light reflected from the nozzle hole or its vicinity toward the substrate (13) enters the light-receiving element (6), and the light-receiving element (6) senses the irradiated light or the light reflected from the nozzle hole or its vicinity toward the substrate (13). Consequently, even if the distance between the ink jet head and the substrate is small, the relative position between the ink jet head and the substrate is adjusted accurately.
    • 喷墨头(1),接收从喷墨头(1)排出的液滴(2)的基板(13),用于照射或反射来自喷墨头的喷嘴孔或其附近的光的装置 1)朝向基板(13),用于控制喷墨头(1)和基板(13)之间的相对位置的位置移动装置(10)和用于从墨水排出液体的控制装置(9) 喷头(1)。 用于识别喷墨头(1)的位置的光接收元件(6)设置在基板(13)后面,当从喷墨头(1)看时,基板(13)至少具有透明度 使照射光或从喷嘴孔或其附近朝向基板(13)反射的光进入受光元件(6),受光元件(6)感测照射的光或光 从喷嘴孔或其附近朝向基板(13)反射。 因此,即使喷墨头和基板之间的距离小,喷墨头和基板之间的相对位置被精确地调整。
    • 5. 发明授权
    • Latent image, preparation and development thereof and articles with the
image
    • 潜在的形象,准备和发展以及形象的文章
    • US5906871A
    • 1999-05-25
    • US645773
    • 1996-05-14
    • Yasuo TakebeKoichi KugimiyaNorihisa MinoTohru Nakagawa
    • Yasuo TakebeKoichi KugimiyaNorihisa MinoTohru Nakagawa
    • B41M3/00B44F1/02
    • B41M3/005Y10T428/24802Y10T428/24835Y10T428/24942
    • A latent image comprising a first substance formed on a substrate of a second substance having a surface tension different from a surface tension of the first substance, the first substance and the substrate having a difference of 0.1 to 100 nm in height from each other. The latent image is formed by a method comprising the-step of subjecting a substrate of a first substance to a chemical treatment or a physical treatment to form a surface of a second substance which has a surface tension different from a surface tension of the first substance and has a difference of 0.1 to 100 nm in height from the substrate on part of the substrate. The latent image is developed by a method comprising the steps of contacting a latent image comprising a first substance formed on a substrate of a second substance having a surface tension different from a surface tension of the first substance with a third substance different from the first substance and the second substance, and applying a developing ray to the latent image.
    • 一种潜像,其包括形成在第二物质的基底上的第一物质,所述第二物质的表面张力不同于所述第一物质的表面张力,所述第一物质和所述基底的高度彼此的差异为0.1〜100nm。 该潜像通过包括以下步骤的方法形成:将第一物质的基材进行化学处理或物理处理以形成具有与第一物质的表面张力不同的表面张力的第二物质的表面的方法 并且在基板的一部分上与基板的高度差为0.1〜100nm。 通过包括以下步骤的方法显影潜像:将形成在第一物质的表面张力不同于第一物质的第二物质的基板上形成的第一物质的潜像与不同于第一物质的第三物质 和第二物质,并将显影射线施加到潜像上。
    • 6. 发明授权
    • Method and apparatus for producing molecular film
    • 生产分子膜的方法和装置
    • US5948476A
    • 1999-09-07
    • US964471
    • 1997-11-04
    • Tadashi OtakeNorihisa MinoTohru NakagawaMamoru SogaKazufumi OgawaTakaiki NomuraYasuo Takebe
    • Tadashi OtakeNorihisa MinoTohru NakagawaMamoru SogaKazufumi OgawaTakaiki NomuraYasuo Takebe
    • B05D1/28B05D3/04
    • B82Y30/00B05D1/283B05D3/0486B82Y40/00
    • A method for forming a molecular film includes the steps of: coating a surface of a substrate having active hydrogen atoms on its surface with a coating solution containing a silane-based compound having at least one reactive group selected from the group consisting of a chloro group, an alkoxy group and an isocyanate group; and effecting an elimination reaction between the active hydrogen atoms on the surface of the substrate and reactive groups of the silane-based compound, thereby covalently bonding the silane-based compounds to the surface of the substrate. The substrate is supplied to a chamber in which an atmosphere is maintained at a low water vapor density. The surface of the substrate is coated with a coating solution containing the silane-based compound and a solvent by using a transfer element. A dehydrochlorination reaction is effected between the active hydrogen atoms and the chloro groups of the silane-based compounds. Thereafter, any coating solution containing unreacted silane-based compounds after coating is removed inside or outside the chamber.
    • 形成分子膜的方法包括以下步骤:用包含具有至少一个选自氯基团的反应性基团的硅烷基化合物的涂布溶液在其表面上涂覆具有活性氢原子的基材的表面 ,烷氧基和异氰酸酯基; 并且进行基板表面上的活性氢原子与硅烷类化合物的反应性基团之间的消除反应,从而将硅烷类化合物共价键合到基板的表面。 将基板供给到气氛保持在低水蒸汽密度的室中。 通过使用转印元件,将含有硅烷系化合物和溶剂的涂布液涂布在基材的表面上。 在活性氢原子和硅烷基化合物的氯基之间进行脱氯化氢反应。 此后,在室内或室外除去涂布后含有未反应的硅烷类化合物的任何涂布溶液。
    • 7. 发明申请
    • Liquid Drop Placing Apparatus and Liquid Drop Placing Method
    • 液滴放置装置和液滴放置方法
    • US20080158300A1
    • 2008-07-03
    • US10568059
    • 2005-03-02
    • Tohru NakagawaNorihisa Mino
    • Tohru NakagawaNorihisa Mino
    • B41J2/14
    • B41J2/04586B41J2/01B41J2/04556
    • An ink jet head (1), a substrate (13) receiving a liquid drop (2) discharged from the ink jet head (1), a device for irradiating or reflecting light from a nozzle hole or its vicinity of the ink jet head (1) toward the substrate (13), a position moving device (10) for controlling a relative position between the ink jet head (1) and the substrate (13), and a control device (9) for discharging a liquid from the ink jet head (1) are included. A light-receiving element (6) for recognizing a position of the ink jet head (1) is disposed behind the substrate (13), when seen from the ink jet head (1), the substrate (13) has a transparency at least to a degree that the irradiated light or the light reflected from the nozzle hole or its vicinity toward the substrate (13) enters the light-receiving element (6), and the light-receiving element (6) senses the irradiated light or the light reflected from the nozzle hole or its vicinity toward the substrate (13). Consequently, even if the distance between the ink jet head and the substrate is small, the relative position between the ink jet head and the substrate is adjusted accurately.
    • 喷墨头(1),接收从喷墨头(1)排出的液滴(2)的基板(13),用于照射或反射来自喷墨头的喷嘴孔或其附近的光的装置 1)朝向基板(13),用于控制喷墨头(1)和基板(13)之间的相对位置的位置移动装置(10)和用于从墨水排出液体的控制装置(9) 喷头(1)。 用于识别喷墨头(1)的位置的光接收元件(6)设置在基板(13)后面,当从喷墨头(1)看时,基板(13)至少具有透明度 使照射光或从喷嘴孔或其附近朝向基板(13)反射的光进入受光元件(6),受光元件(6)感测照射的光或光 从喷嘴孔或其附近朝向基板(13)反射。 因此,即使喷墨头和基板之间的距离小,喷墨头和基板之间的相对位置被精确地调整。
    • 8. 发明授权
    • Electrically chargeable substrate
    • 可充电的基板
    • US06210793B1
    • 2001-04-03
    • US08976302
    • 1997-11-21
    • Tohru NakagawaYasuo TakebeNorihisa Mino
    • Tohru NakagawaYasuo TakebeNorihisa Mino
    • B32B1700
    • C03C17/30Y10S29/90Y10T29/49998Y10T428/261Y10T428/265Y10T428/31612Y10T428/31663Y10T428/31667
    • A thin film composed of a silane-based compound comprising an alkyl group or a fluoroalkyl group is bonded to the surface of an electrically insulating substrate through a covalent bond, thus obtaining an electrically chargeable substrate maintaining a charged state for a long time regardless of relative humidity of an atmosphere. A glass plate for placing a sheet in an overhead projector is dipped into a solution comprising CF3(CF)7(CH2)2SiCl3. As a result, a molecular composed of CF3(CF2)7(CH2)2Si(O)3—is chemically bonded to the glass surface. A high charged state, a water-repelling property having a static contact angle of pure water on the thin film formed on the glass surface of 110 degrees and a volume electric resistivity in the range of 1×1011−1×1019&OHgr;·cm are provided.
    • 由包含烷基或氟烷基的硅烷类化合物构成的薄膜通过共价键与电绝缘性基板的表面接合,从而获得长时间保持充电状态的可充电基板,而不管相关 气氛湿度 将用于将片材放置在高架投影仪中的玻璃板浸入包含CF 3(CF)7(CH 2)2 SiCl 3的溶液中。 结果,由CF 3(CF 2)7(CH 2)2 Si(O)3组成的分子化学键合到玻璃表面。 提供高充电状态,在110度的玻璃表面上形成的薄膜上具有纯水的静态接触角以及1×10 11〜1×10 19Ω·cm范围内的体积电阻率的防水性。
    • 9. 发明授权
    • Substrate for use in crystallization and method for producing the same
    • 用于结晶的基板及其制造方法
    • US07579086B2
    • 2009-08-25
    • US11020063
    • 2004-12-23
    • Norihisa MinoYuusuke Takada
    • Norihisa MinoYuusuke Takada
    • B32B9/04
    • C30B29/58C30B7/00Y10T428/31663
    • A substrate for use in crystallization has a base member, and an organic molecular film on a surface of the base member. The organic molecular film has non-affinity to a liquid, and the surface of the base member and the organic molecular film are covalently bound to each other. The substrate formed with the organic molecular film having non-affinity to the liquid on the surface of the base member is produced by contacting the surface of the base member having an active hydrogen atom or the surface of the base member to which the active hydrogen atom is introduced, with an organic molecule including a terminal-bonding functional group capable of covalently bonding to the surface of the base member at one end thereof, and a functional group showing non-affinity to the liquid at the other end thereof so as to covalently bond the terminal-bonding functional group of the organic molecule to the active hydrogen atom on the surface of the base member by reaction of the terminal-bonding functional group with the active hydrogen atom. The substrate enables to efficiently crystallize polymeric compounds including biomolecules such as proteins, nucleic acids, and sugars; and resins, as well as other organic compounds, and inorganic compounds.
    • 用于结晶的基材具有基材,在基材的表面上具有有机分子膜。 有机分子膜对液体具有非亲和性,并且基材和有机分子膜的表面共价键合。 通过使具有活性氢原子的基材的表面或基体的表面与活性氢原子的表面接触,形成有与基材的表面上的液体不亲和的有机分子膜的基材 引入有机分子,其包括能够在其一端与基材的表面共价结合的末端键合官能团和在其另一端显示与液体非亲和性的官能团,以共价方式 通过末端键合官能团与活性氢原子的反应,将有机分子的末端键合官能团与基体的表面上的活性氢原子键合。 底物使得能够有效地结晶包括生物分子如蛋白质,核酸和糖的聚合物; 和树脂,以及其它有机化合物和无机化合物。
    • 10. 发明授权
    • Organic electronic device and method for manufacturing the same
    • 有机电子器件及其制造方法
    • US07560731B2
    • 2009-07-14
    • US11633924
    • 2006-12-05
    • Shinichi YamamotoNorihisa MinoKazufumi Ogawa
    • Shinichi YamamotoNorihisa MinoKazufumi Ogawa
    • H01L35/24
    • G02F1/13439C08G61/122G02F1/1343G02F2001/136295G02F2202/022H01L51/0021H01L51/0035
    • An organic electronic device of the present invention includes a substrate, at least two electrodes formed on the substrate, a conductive organic thin film that is formed on the substrate and electrically connects the electrodes, and a coating film for coating at least a portion of the electrodes. The conductive organic thin film is a polymer of organic molecules containing a conjugated-bondable group, and one end of each of the organic molecules is chemically bonded to the surface of the substrate and the conjugated-bondable groups in the organic molecules are polymerized with other conjugated-bondable groups to form a conjugated bond chain. The coating film electrically connects the electrodes to the conductive organic thin film and achieves a smaller connection resistance than that in the case where the electrodes and the conductive organic thin film are connected directly. As the coating film, a film made of metal selected from gold, platinum, and silver, a conductive polymeric film, or a monomolecular film that is chemically bonded to the electrodes can be used.
    • 本发明的有机电子器件包括基板,形成在基板上的至少两个电极,形成在基板上并电连接电极的导电有机薄膜,以及用于涂覆至少一部分 电极。 导电有机薄膜是含有共轭键合基团的有机分子的聚合物,并且每个有机分子的一端化学键合到基底表面,并且有机分子中的共轭键基团与其它分子聚合 共轭键合基团以形成共轭键链。 涂膜将电极与导电性有机薄膜电连接,与直接连接电极和导电性有机薄膜的情况相比,能够实现较小的连接电阻。 作为涂膜,可以使用由金,铂,银等金属制成的膜,导电性聚合物膜,或与电极化学键合的单分子膜。