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    • 1. 发明专利
    • 燃料電池単セルおよびその製造方法
    • 燃料电池单电池及其制造方法
    • JP2015056364A
    • 2015-03-23
    • JP2013190817
    • 2013-09-13
    • 株式会社日本自動車部品総合研究所Nippon Soken Inc株式会社デンソーDenso Corp
    • TERANISHI SHINYAKOJIMA KUNIHIRO
    • H01M8/02H01M8/12
    • H01M8/124H01M8/1213H01M2008/1293Y02P70/56
    • 【課題】燃料ガスのガス拡散性を向上させることによって発電特性を向上させることが可能な燃料電池単セルを提供する。【解決手段】燃料電池単セル1は、固体電解質層10と、固体電解質層10の一方面に積層された活性層111と活性層111における固体電解質層10側と反対側の面に積層された拡散層112とを備えるアノード層11と、固体電解質層10の他方面に中間層12を介して積層されたカソード層13とを有しており、アノード層11を支持体とする平板形の単セルである。カソード層13の外形は、固体電解質層10の外形よりも小さく形成されている。拡散層112は、活性層111における固体電解質層10と接する面を除いた残りの面を覆っている。燃料電池単セル1は、活性層111、および、拡散層112の部分であって活性層111の側面を覆う側面被覆部112bを、印刷法により形成する工程を経ることにより、好適に製造することができる。【選択図】図2
    • 要解决的问题:提供一种能够通过改善燃料气体的气体扩散性能来提高其发电特性的燃料电池单电池。解决方案:燃料电池单电池1包括:固体电解质层10; 包括层叠在固体电解质层10的一个表面上的活性层111的阳极层11和层叠在有源层111的表面上的扩散层112,该表面位于与固体电解质层10侧相反的一侧; 以及层叠在固体电解质层10的另一个表面上的中间层12的阴极层13。 燃料电池单电池1是使用阳极层11作为支撑体的板状的单电池。 阴极层13的外形形成为小于固体电解质层10的外形。扩散层112覆盖除了与活性层111中的固体电解质层10接触的表面之外的剩余表面。燃料 可以通过印刷法形成作为扩散层112的一部分并覆盖有源层111的侧面的有源层111和侧面覆盖部112b的工序来适当地制造电池单电池1。
    • 2. 发明专利
    • Method of manufacturing particulate matter detection element, and particulate matter detection sensor
    • 制造颗粒物检测元件和颗粒物检测传感器的方法
    • JP2014032063A
    • 2014-02-20
    • JP2012171820
    • 2012-08-02
    • Nippon Soken Inc株式会社日本自動車部品総合研究所Denso Corp株式会社デンソー
    • MIZUTANI KEIGOTERANISHI SHINYAKIMATA TAKEHITO
    • G01N15/06G01N27/00
    • G01N15/0656
    • PROBLEM TO BE SOLVED: To provide a method of manufacturing a particulate matter detection element having high measurement accuracy while extremely reducing insensible mass, and a particulate matter detection sensor using the particulate matter detection element.SOLUTION: The particulate matter detection sensor includes: a conductive path formed by connecting in series from one ends 103A, 103B to the other ends 104A, 104B of a pair of detection electrodes EL, ELwithout branching; detection electrode bent sections 101A, 101B each having a part bent in a substantially U shape; and breaking detection circuits 301A, 301B using substantially planar detection electrode facing parts 100A, 100B that face each other via an insulating layer 120 with a predetermined thickness, to measure a resistance value from the one ends 103A, 103B to the other ends 104A, 104B, for detecting breaking in the pair of detection electrodes EL, EL.
    • 要解决的问题:提供一种制造具有高测量精度的颗粒物质检测元件的方法,同时极大地减少不可测量的物质,以及使用该颗粒物质检测元件的颗粒物质检测传感器。解决方案:颗粒物检测传感器包括:导电 通过从一端103A,103B串联连接到一对检测电极EL,EL的另一端104A,104B形成的路径,不分支; 每个检测电极弯曲部分101A,101B具有弯曲成大致U形的部分; 以及通过具有预定厚度的绝缘层120相对于彼此面对的基本上平面的检测电极对面部分100A,100B来断开检测电路301A,301B,以测量从一端103A,103B到另一端104A,104B的电阻值 用于检测该对检测电极EL,EL中的断裂。
    • 4. 发明专利
    • Solid electrolyte fuel cell stack
    • 固体电解质燃料电池堆
    • JP2013041673A
    • 2013-02-28
    • JP2011176013
    • 2011-08-11
    • Nippon Soken Inc株式会社日本自動車部品総合研究所Denso Corp株式会社デンソー
    • TERANISHI SHINYAUEHARA MASANORIICHIKAWA SUSUMU
    • H01M4/86H01M8/02H01M8/12
    • Y02E60/525
    • PROBLEM TO BE SOLVED: To provide a solid electrolyte fuel cell stack capable of efficiently generating power while restraining increase of a physical constitution.SOLUTION: A portion of a cathode electrode 13 of each unit cell 10 corresponding to a fuel gas flow downstream side is made of a material with higher electrode reaction activity in an actuation temperature range than a portion corresponding to a fuel gas flow upstream side. Also, at least one of an anode electrode 12 and the cathode electrode 13 of the unit cell positioned on an end side in a lamination direction of a fuel cell stack 1 is made of a material with higher electrode reaction activity in the actuation temperature range than the electrode of the unit cell positioned on a center side in the lamination direction. Furthermore, a solid electrolyte 11 of the unit cell positioned on the end side in the lamination direction of the fuel cell stack 1 is made of a material with higher conductivity in the actuation temperature range than the solid electrolyte 11 of the unit cell positioned on the center side in the lamination direction.
    • 要解决的问题:提供一种能够在抑制物理结构的增加的同时有效地发电的固体电解质型燃料电池堆。 解决方案:对应于燃料气体流下游侧的每个单元电池10的阴极电极13的一部分由在与燃料气体流上游相对应的部分的致动温度范围内具有较高电极反应活性的材料制成 侧。 此外,位于燃料电池堆1的层叠方向的端侧的单元电池的阳极电极12和阴极电极13中的至少一个由在驱动温度范围内具有较高的电极反应活性的材料制成, 单元电池的电极位于层叠方向的中心侧。 此外,位于燃料电池堆1的层叠方向的端侧的单元电池的固体电解质11由比驱动温度范围内的高电导率的材料形成,该材料位于位于 中心侧在层叠方向上。 版权所有(C)2013,JPO&INPIT
    • 6. 发明专利
    • Fuel electrode for fuel battery, and method of manufacturing the same
    • 用于燃料电池的燃料电极及其制造方法
    • JP2013051043A
    • 2013-03-14
    • JP2011186886
    • 2011-08-30
    • Nippon Soken Inc株式会社日本自動車部品総合研究所Denso Corp株式会社デンソー
    • TERANISHI SHINYAKOMAGATA KAZUYASUZUKI SOJI
    • H01M4/86H01M4/88H01M8/12
    • Y02P70/56
    • PROBLEM TO BE SOLVED: To provide a fuel electrode for a fuel battery which allows the improvement of the structural reliability against thermal stress, and a manufacturing method and a material which are suitable for the production of the fuel electrode.SOLUTION: The fuel electrode 3 comprises at least a structure 31, and an electron conductor 32. The structure 31 has a core part 311, and a surface layer 312 covering the outer periphery of the core part 311. The core part 311 includes an oxygen ion conductor as its primary component, and the surface layer 312 includes a proton conductor as its primary component. The fuel electrode 3 can be manufactured by baking a mixture of at least a kind of powder formed from the structure 31, and a kind of powder formed from the electron conductor 32, provided that the structure has: the core part 311 including an oxygen ion conductor as its primary component; and the surface layer 312 covering the outer periphery of the core part 311 and including a proton conductor as its primary component.
    • 要解决的问题:提供一种能够提高耐热应力的结构可靠性的燃料电池用燃料电极以及适合于制造燃料电极的制造方法和材料。 解决方案:燃料电极3至少包括结构31和电子导体32.结构31具有芯部311和覆盖芯部311的外周的表面层312。芯部311 包括氧离子导体作为其主要成分,表层312包括作为其主要成分的质子导体。 燃料电极3可以通过烘焙由结构31形成的至少一种粉末的混合物和由电子导体32形成的一种粉末来制造,只要该结构具有:包含氧离子的芯部311 导体作为其主要部件; 并且覆盖芯部311的外周并且包括质子导体作为其主要成分的表面层312。 版权所有(C)2013,JPO&INPIT
    • 7. 发明专利
    • Fuel cell stack and fuel cell
    • 燃料电池堆和燃料电池
    • JP2012190746A
    • 2012-10-04
    • JP2011055319
    • 2011-03-14
    • Denso CorpNippon Soken Inc株式会社デンソー株式会社日本自動車部品総合研究所
    • KOMAGATA KAZUYATERANISHI SHINYA
    • H01M8/02H01M8/12H01M8/24
    • Y02E60/525
    • PROBLEM TO BE SOLVED: To provide a fuel cell stack achieving a small thickness in the stacking direction and a uniform power generation distribution in the cell plane.SOLUTION: The fuel cell stack is made by stacking a plurality of unit cells 2 comprising a solid electrolyte layer 21, a fuel electrode layer 22 on one side of the solid electrolyte layer 21, and an air electrode layer 23 on the other side of the solid electrolyte layer 21, with intervening separators; and has collectors 4a and 4c between the unit cell 2 and the separator. The collectors 4a and 4c comprise a first layer 41 in contact with the separator, and a second layer 42 in contact with the first layer 41 and the unit cell. The first layer 41 comprises a first gas passage 411 for passing a gas led into the unit cell 2 along the plane of the unit cell 2. The second layer 42 comprises a second gas passage 421 for guiding the gas passed through the first gas passage 411 in the direction intersecting the plane of the unit cell 2.
    • 要解决的问题:提供在堆叠方向上实现小厚度的燃料电池堆和在电池平面中均匀的发电分布。 解决方案:燃料电池堆是通过将固体电解质层21,固体电解质层21的一侧上的燃料电极层22和另一方的空气极层23堆叠的多个单电池2堆叠而制成的 固体电解质层21的一侧,具有中间隔板; 并且在单元电池2和分离器之间具有集电体4a和4c。 集电体4a和4c包括与分离器接触的第一层41和与第一层41和单元电池接触的第二层42。 第一层41包括用于沿着单元电池2的平面通过引入单元电池2的气体的第一气体通道411.第二层42包括用于引导通过第一气体通道411的气体的第二气体通道421 在与单位电池2的平面相交的方向上。版权所有(C)2013,JPO&INPIT
    • 8. 发明专利
    • Particulate matter detection sensor
    • 颗粒物检测传感器
    • JP2012127907A
    • 2012-07-05
    • JP2010281629
    • 2010-12-17
    • Denso CorpNippon Soken Inc株式会社デンソー株式会社日本自動車部品総合研究所
    • HARADA TOSHIHIKONAKAMURA SATOSHITERANISHI SHINYAMAEDA ERIKO
    • G01N27/04F01N3/02G01N15/06
    • G01N15/0656
    • PROBLEM TO BE SOLVED: To prevent measurement difference by coarse particles by improving classification performance and quickly detecting failures or the like of a DPF (diesel particulate filter) with high detection precision at low costs in a particulate matter detection sensor of an electrical resistance system used for PM detection in exhaust gases of an internal-combustion engine.SOLUTION: A sensing element part 1 of a PM sensor S installed in an exhaust tube EX of an engine E/G places two pairs of detection electrodes 3, 4 with insides of two slits 20a, 20b provided for an insulating base 10 as measurement spaces 2a, 2b, and embeds a pair of electric field application electrodes 52, 53 on both sides of the slit 20a and a pair of electric field application electrodes 52, 53 on both sides of the slit 20b. Thus, there are provided two pairs of electric field application electrodes having a common electric field application electrode 53 between the slits 20a and 20b. A unique electric field is generated in the measurement spaces 2a, 2b by the electric field application electrodes 51, 52, PM detection results of the two pairs of detection electrodes 3, 4 are averaged, and made to be sensor output, so that output variation becomes small.
    • 要解决的问题:为了防止粗粒子的测量差异,通过在电气的颗粒物质检测传感器中以低成本提高分级性能并快速检测具有高检测精度的DPF(柴油微粒过滤器)的故障等, 用于内燃机排气中PM检测的电阻系统。 解决方案:安装在发动机E / G的排气管EX中的PM传感器S的感测元件部分1将两对检测电极3,4与设置在绝缘基座10上的两个狭缝20a,20b的内侧 作为测量空间2a,2b,在狭缝20a的两侧嵌入一对电场施加电极52,53,在狭缝20b的两侧嵌入一对电场施加电极52,53。 因此,提供两对电场施加电极,其在狭缝20a和20b之间具有公共电场施加电极53。 通过电场施加电极51,52在测量空间2a,2b中产生独特的电场,将两对检测电极3,4的PM检测结果平均化,并将其作为传感器输出,使得输出变化 变小 版权所有(C)2012,JPO&INPIT
    • 10. 发明专利
    • Particulate detection element
    • 颗粒检测元件
    • JP2011080780A
    • 2011-04-21
    • JP2009231182
    • 2009-10-05
    • Denso CorpNippon Soken Inc株式会社デンソー株式会社日本自動車部品総合研究所
    • SAWADA TAKASHIARAKI TAKASHIITO HIDEAKITERANISHI SHINYAMATSUOKA HIROSHIGE
    • G01N27/04G01N15/06
    • PROBLEM TO BE SOLVED: To provide a particulate detection element simply constituted so as to detect PM contained in gas to be measured, having no insensitive period and enhanced in reliability.
      SOLUTION: The particulate detection element 10 is equipped with: a detection part 100 exposed to the gas to be measured and constituted by providing a pair of detection electrodes 11 and 12, which are opposed to each other at a predetermined interval, on the surface of an electric insulating heat-resistant substrate 13; and a detection means 21 for detecting electric resistor R
      X changed corresponding to the amount of the conductive fine particles deposited between the detection electrodes 11 and 12 of the detection part 100, and detects PM in the gas to be measured. A resistor 20 having a predetermined resistance value R
      FIX is provided in parallel to the electric resistor R
      X formed on the detection part 100 as a resistor for eliminating the insensitive period.
      COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:提供一种微粒检测元件,其简单地构成为检测包含在待测气体中的PM,其不具有不敏感期并提高可靠性。 解决方案:颗粒物检测元件10配备有:被检测气体暴露的检测部件100,并且通过以预定间隔彼此相对地设置一对检测电极11和12来构成 电绝缘耐热基板13的表面; 以及用于检测电阻R X SB SB的检测电极R< SB>相对于检测部100的检测电极11,12之间的导电性微粒的量而变化的检测单元21,检测气体中的PM 测量。 与形成在检测部件100上的电阻R SB SBS并联设置具有预定电阻值R FIX 的电阻器20作为消除不敏感期间的电阻器。 版权所有(C)2011,JPO&INPIT