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    • 6. 发明申请
    • CEMENT ADMIXTURE AND CEMENT COMPOSITION
    • 水泥混合料和水泥组合物
    • WO2002096823A1
    • 2002-12-05
    • PCT/JP2002/005144
    • 2002-05-28
    • NIPPON SHOKUBAI CO., LTD.YAMASHITA, AkihikoTANAKA, HiromichiHIRATA, TsuyoshiUNO, ToruONDA, Yoshiyuki
    • YAMASHITA, AkihikoTANAKA, HiromichiHIRATA, TsuyoshiUNO, ToruONDA, Yoshiyuki
    • C04B24/26
    • C08L51/08C04B24/2647C04B40/0039C04B2103/408C08F283/06C08F290/06C08F290/062C08L71/02C04B24/267C04B24/2694C04B28/02C08L2666/14C08L2666/24C08L2666/02C08L2666/04
    • It is an object of the present invention to provide a cement admixture capable of exhibiting high cement dispersing ability at low addition levels, in particular capable of displaying excellent initial dispersing ability and dispersion retaining ability even in a high water reducing ratio range, and a cement composition in which this admixture is used. A cement admixture comprising two polymers, namely a polymer (A) and a polymer (B), as essential constituents in a ratio of polymer (A) to polymer (B) between 1 to 99/99 to 1% by mass, wherein the polymer (A) is a polymer comprising, as essential constituent units, a constituent unit (I) derived from an unsaturated (poly)alkylene glycol ether monomer (a) and a constituent unit (II) derived from an unsaturated monocarboxylic acid monomer (b) and wherein the constituent units (I) and (II) each ac-counts for not less than 1% by mass relative to all constituent units but the constituent unit (I) accounts for not more than 50 mole percent relative to all constituent units and, wherein the polymer (B) is an oxyalkylene group- or polyoxyalkylene group- and carboxyl group-containing polymer.
    • 本发明的目的是提供一种能够以低添加量表现出高水泥分散能力的水泥混合物,特别是即使在高减水比范围内也能显示优异的初始分散能力和分散保持能力,以及水泥 使用该混合物的组合物。 作为聚合物(A)与聚合物(B)的比例为1〜99/99〜1质量%的必要成分的两种聚合物即聚合物(A)和聚合物(B))的水泥混合物,其中, 聚合物(A)是由不饱和(聚)亚烷基二醇醚单体(a)和不饱和一元羧酸单体(b)的构成单元(II)衍生的构成单元(I)作为必要构成单元的聚合物 ),其中,相对于所有构成单元,构成单元(I)和(II)各自计算不少于1质量%,但构成单元(I)相对于所有构成单元不超过50摩尔% 其中聚合物(B)是氧化烯基或聚氧化烯基和含羧基的聚合物。
    • 7. 发明申请
    • PRODUCTION PROCESSES FOR ALKYLENE OXIDE ADDITION PRODUCT AND ITS DERIVATIVES
    • 烷基氧化物添加剂及其衍生物的生产工艺
    • WO2003097716A1
    • 2003-11-27
    • PCT/JP2003/005602
    • 2003-05-02
    • NIPPON SHOKUBAI CO., LTD.INAOKA, ToruONDA, YoshiyukiTANAKA, HiromichiHIRATA, Tsuyoshi
    • INAOKA, ToruONDA, YoshiyukiTANAKA, HiromichiHIRATA, Tsuyoshi
    • C08G65/28
    • C08G65/2609C08G65/2696C08G65/3322
    • The present invention provides: a production process for an alkylene oxide addition product, by which a high-molecular alkylene oxide addition product can be obtained with ordinary production facilities while the formation of by-products is suppressed; and production processes for derivatives from the alkylene oxide addition product. The present invention production process for an alkylene oxide addition product comprises the step of carrying out an addition reaction of an alkylene oxide to a hydroxyl-group-containing saturated compound in order to obtain the alkylene oxide addition product; with the production process being characterized by further comprising; the initial step of causing the alkylene oxide to add to the hydroxyl-group-containing saturated compound in an amount of not larger than 20 mols on average of the alkylene oxide per 1 mol of the hydroxyl-group-containing saturated compound to thereby obtain an alkylene oxide low-mol-addititon product; and the molar-degree-of-polyaddition-adjusting step of causing the alkylene oxide to further add to the alkylene oxide low-mol-addition product as obtained in the initial step: wherein a portion of the entirety of the alkylene oxide low-mol-addition product as obtained in the initial step is used in the molar-degree-of-polyaddition-adjusting step.
    • 本发明提供:一种环氧烷加成物的制造方法,通过该方法可以获得具有普通生产设备的高分子量烯化氧加成产物,同时抑制副产物的形成; 以及来自烯化氧加成产物的衍生物的制备方法。 本发明的烯化氧加成产物的制备方法包括进行烯化氧与含羟基的饱和化合物的加成反应以获得环氧烷烃加成产物的步骤; 其制造方法的特征在于还包括: 相对于每1摩尔含羟基的饱和化合物,环氧烷平均加入到含羟基的饱和化合物的平均值不大于20摩尔的初始步骤,从而得到 环氧烷低摩尔加成产物; 和加成摩尔加聚度调整步骤,使得氧化烯进一步添加到在初始步骤中得到的环氧烷低摩尔加成产物:其中一部分环氧烷低摩尔 在初始步骤中获得的加成产物用于加聚度加聚步骤。
    • 10. 发明公开
    • REACTION DISTILLATION APPARATUS AND REACTION DISTILLATION METHOD
    • 装置在VERFAHREN ZUR REAKTIONSDESTILLATION
    • EP0842685A1
    • 1998-05-20
    • EP97922103.3
    • 1997-05-20
    • NIPPON SHOKUBAI CO., LTD.
    • TSUNEKI, HideakiMORIYA, AtusiYOSHIDA, HiroshiWAKAYAMA, HirokiWATANABE, KenichiONDA, Yoshiyuki
    • B01D3/00C07C67/03C07C67/02B01J8/02
    • C07C68/06B01D3/009B01J8/02B01J2208/00247B01J2208/00539B01J2208/00557C07C67/03Y02P20/127C07C69/24C07C69/96
    • Reactive distillation equipment applicable to a relatively complicated reaction composed of at least two steps of equilibrium reactions, and a reactive distillation method capable of performing the reaction efficiently. Raw material feeding pipes 5, 6 and 7 are connected to a reactive distillation column 1. The raw material feeding pipes 5, 6 and 7 are disposed on different stages of the reactive distillation column 1 in this order from the top of the column downward. It is preferred that the reactive distillation column 1 includes a stage to which no raw material feeding pipe is connected between a first stage connected to the raw material feeding pipe 5 and a second stage connected to the raw material feeding pipe 6, and between the second stage and a third stage connected to the raw material feeding pipe 7. By feeding raw material (A), raw material (B) and raw material (E) from the raw material feeding pipes 5, 6 and 7, respectively, vapor-liquid contacting of raw materials (A) and (B), and vapor-liquid contacting of product (C) and raw material (E) are carried out.
    • 适用于由至少两个平衡反应步骤组成的相对复杂的反应的反应蒸馏设备和能够有效地进行反应的反应蒸馏方法。 原料供给管5,6和7连接到反应性蒸馏塔1.原料供给管5,6和7从塔顶向下依次设置在反应蒸馏塔1的不同阶段。 优选的是,反应蒸馏塔1包括在与原料供给管5连接的第一阶段和与原料供给管6连接的第二阶段之间以及第二阶段之间没有原料供给管连接的阶段 分别与原料供给管7连接的原料(A),原料(B)和原料(E)分别从原料供给管5,6和7供给气液 原料(A)和(B)的接触,以及产品(C)和原料(E)的气液接触进行。