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    • 3. 发明专利
    • Acrylic polyol aqueous dispersion, aqueous two-pack type curing composition, and method for producing them
    • 丙烯酸多元醇水性分散体,水性双组分固化组合物及其制备方法
    • JP2009221244A
    • 2009-10-01
    • JP2008064331
    • 2008-03-13
    • Nippon Paint Co Ltd日本ペイント株式会社
    • MORIOKA CHIYUKIONISHI ISAMUTSUJIOKA HIDEAKIKUSHI YOSHITAKA
    • C08G18/63C09D133/06C09D175/04
    • PROBLEM TO BE SOLVED: To provide an aqueous two-pack type curing composition forming a cured film with excellent appearance even by using a low water-dispersible isocyanate.
      SOLUTION: The aqueous two-pack type curing composition comprises an acrylic polyol aqueous dispersion and a polyisocyanate compound having a sulfonic acid group. The acrylic polyol aqueous dispersion is obtained by dispersing acrylic polyol, which is obtained by polymerization including solution polymerization for producing a core and solution polymerization for producing a shell, in water. A hydroxyl value and an acid value of the whole monomer mixture used in the polymerization are within a predetermined range, a hydroxyl value and an acid value of a monomer mixture (a-2) used in the polymerization of the shell are within a predetermined range, and a ratio of a hydroxyl value of a monomer mixture (a-1) used in the polymerization of the core to the hydroxyl value of the monomer mixture (a-2) is 1.3-3.0. In the polyisocyanate compound, an acid value is 5-12 mgKOH/g, and a content of isocyanate groups is 16-22 mass%.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 待解决的问题:即使使用低水分散性异氰酸酯,也提供形成具有优异外观的固化膜的水性双组分型固化组合物。 解决方案:水性双组分型固化组合物包含丙烯酸多元醇水分散体和具有磺酸基团的多异氰酸酯化合物。 丙烯酸多元醇水性分散体是通过在水中分散通过包括用于制备芯的溶液聚合和用于制备壳的溶液聚合的聚合获得的丙烯酸多元醇而获得的。 聚合中使用的全部单体混合物的羟基值和酸值在预定范围内,壳体聚合中使用的单体混合物(a-2)的羟值和酸值在预定范围内 ,芯体聚合中使用的单体混合物(a-1)的羟值与单体混合物(a-2)的羟基值的比值为1.3〜3.0。 在多异氰酸酯化合物中,酸值为5〜12mgKOH / g,异氰酸酯基的含量为16〜22质量%。 版权所有(C)2010,JPO&INPIT