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1. 发明专利

JP2011056494A Water-soluble volatile organic compound adsorbent 审中-公开
标题翻译：水溶性挥发性有机化合物吸附剂
公开(公告)号：JP2011056494A
公开(公告)日：2011-03-24
申请号：JP2009285887
申请日：2009-12-17
申请人： National Institute Of Advanced Industrial Science & Technology , Taikisha Ltd , 株式会社大気社 , 独立行政法人産業技術総合研究所
发明人： SUZUKI MASAYA , MAEDA MASAKI , SUZUKI CHIEKO , SHIOBARA TAKUYA , NAGATA YUJI
IPC分类号： B01J20/16 , B01D53/02
摘要： PROBLEM TO BE SOLVED: To provide a water-soluble volatile organic compound adsorbent consisting of an inorganic compound, adsorbing a water-soluble volatile organic compound and desorbing it at 100-150°C. SOLUTION: The water-soluble volatile organic compound adsorbent has a composite comprising a low crystallizing layered clay mineral and amorphous aluminum silicate and/or a precursor thereof as an effective component. The precursor is turned into the composite by heating at high temperature or by long time heating. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供一种由无机化合物组成的水溶性挥发性有机化合物吸附剂，吸附水溶性挥发性有机化合物并在100-150℃下解吸。解决方案：水溶性挥发性有机化合物吸附剂具有包含低结晶层状粘土矿物和无定形硅酸铝和/或其前体作为有效成分的复合材料。通过在高温或长时间加热下加热将前体变成复合物。版权所有（C）2011，JPO＆INPIT

2. 发明专利

JP2013139029A Porous adsorbent having visible light absorbency, and method for producing the same at low temperature 审中-公开
标题翻译：具有可见光吸收性的多孔吸收体及其在低温下生产相同的方法
公开(公告)号：JP2013139029A
公开(公告)日：2013-07-18
申请号：JP2012263188
申请日：2012-11-30
申请人： National Institute Of Advanced Industrial Science & Technology , 独立行政法人産業技術総合研究所
发明人： NISHIZAWA KAORI , WATANABE EIJI , MAEDA MASAKI , INUKAI KEIICHI , SUZUKI MASAYA
IPC分类号： B01J37/34 , A61L9/00 , A61L9/01 , A61L9/16 , B01J20/12 , B01J20/30 , B01J21/16 , B01J35/02 , E04B1/92
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a functional titania-clay composite with both an excellent substance adsorptive function and a visible light response type photocatalyst function at low temperature of the heat resistant temperature of clay or below.SOLUTION: This method for producing a functional titania-clay composite by imparting a visible light response type photocatalyst function to a clay compound that has an excellent substance adsorptive function includes adding the clay compound in a titania precursor sol solution, prepared with an ethylene glycol monomethyl ether as a solvent, after ultraviolet rays are irradiated thereto, and subjecting the mixture to heating and pressurizing processing as it is using a liquid as a heating medium within a temperature region including the heat resistant temperature of the clay and below.
摘要翻译：要解决的问题：提供一种功能性二氧化钛 - 粘土复合材料的制造方法，其特征在于，在粘土或以下的耐热温度的低温下，具有良好的物质吸附功能和可见光响应型光催化剂功能。通过赋予具有优异的物质吸附功能的粘土化合物赋予可见光响应型光催化剂功能来生产功能性二氧化钛 - 粘土复合材料，包括在用乙二醇单甲醚作为溶剂制备的二氧化钛前体溶胶溶液中加入粘土化合物，在照射紫外线之后，将其作为加热介质的液体进行加热加压处理，该温度范围包括粘土的耐热温度以下。

3. 发明专利

JP2012210560A Method for manufacturing volatile organic compound adsorbent 有权
标题翻译：制造挥发性有机化合物吸附剂的方法
公开(公告)号：JP2012210560A
公开(公告)日：2012-11-01
申请号：JP2011076651
申请日：2011-03-30
申请人： Hitachi Chemical Co Ltd , National Institute Of Advanced Industrial Science & Technology , 日立化成工業株式会社 , 独立行政法人産業技術総合研究所
发明人： MIKUNI HIROKI , KAWAI KIYOSHI , INUKAI KEIICHI , SUZUKI MASAYA , OI YUTAKA , MAEDA MASAKI
IPC分类号： B01J20/16 , B01J20/30 , C01B33/26
摘要： PROBLEM TO BE SOLVED: To provide a method for efficiently manufacturing a volatile organic compound adsorbent having a superior gas adsorption capability capable of being detachable without heating the adsorbed VOC.SOLUTION: The method for manufacturing a volatile organic compound adsorbent includes the steps of: obtaining a reaction product by mixing a solution containing a silicate ion and a solution containing an aluminum ion; desalinating and solid separating the reaction product; applying heating treatment of the solid separated reaction product in an aqueous medium in the presence of an acid under concentration condition of silicon atom concentration which is ≥100 mmol/L and aluminum atom concentration which is ≤100 mmol/L; and desalinating and solid separating the obtained reaction product by the heating treatment.
摘要翻译：解决的问题：提供一种有效地制造具有优异的气体吸附能力的挥发性有机化合物吸附剂的方法，其能够在不加热吸附的VOC的情况下分离。解决方案：用于制造挥发性有机化合物吸附剂的方法包括以下步骤：通过混合含有硅酸盐离子的溶液和含有铝离子的溶液获得反应产物; 脱盐和固体分离反应产物; 在硅原子浓度≥100mmol/ L，铝原子浓度≤100mmol/ L的浓度条件下，在酸存在下，在水性介质中进行固体分离反应产物的加热处理; 并通过加热处理使得到的反应产物脱盐并固体分离。版权所有（C）2013，JPO＆INPIT

4. 发明专利

JP2011255331A High performance water vapor adsorbent having alminosilicate compound material as base material 审中-公开
标题翻译：具有ALMINOSILICATE复合材料的高性能水蒸气吸附剂作为基材
公开(公告)号：JP2011255331A
公开(公告)日：2011-12-22
申请号：JP2010132991
申请日：2010-06-10
申请人： Mitsubishi Paper Mills Ltd , National Institute Of Advanced Industrial Science & Technology , 三菱製紙株式会社 , 独立行政法人産業技術総合研究所
发明人： SUZUKI MASAYA , SAKAYORI ERI , SUZUKI CHIEKO , MAEDA MASAKI , KITO MASATOSHI , KOIKE NAOMASA
IPC分类号： B01J20/04 , B01D53/28 , C01B33/46 , F24F3/14
CPC分类号： Y02P20/129
摘要： PROBLEM TO BE SOLVED: To provide an adsorbent not only having high adsorbing performance in a medium humidity region and a high humidity region but also having excellent adsorbing performance in a low humidity region of approximately 10% of a relative humidity in consideration of a support for a particular environment which needs low dew point air such as in a clean room as a dehumidification agent for desiccant air conditioning.SOLUTION: The adsorbent is obtained by impregnating a compound material comprising a low crystallinity laminar clay mineral and amorphous alminosilicate with a magnesium chloride solution, the adsorbent having not less than 40 wt.% of a difference between an adsorbed amount at 60% humidity when adsorbing and an adsorbed amount at 10% humidity when desorbing, and having water vapor adsorbing performance exhibiting an approximately 30 wt.% of an adsorbed amount even in a low humidity region of approximately 10% of a relative humidity. The adsorbent can be used as a dehumidification agent for desiccant air conditioning.
摘要翻译：要解决的问题：考虑到在相对湿度的约10％的低湿度区域中，不仅在中等湿度区域和高湿度区域中具有高吸附性能而且具有优异的吸附性能的吸附剂对于需要低露点空气的特定环境的支持，例如在洁净室中作为用于干燥剂空调的除湿剂。溶液：吸附剂通过用氯化镁溶液浸渍包含低结晶度层状粘土矿物和无定形硅酸铝的复合材料而获得，吸附剂具有不小于40重量％的吸附量的40重量％吸附时的湿度和解吸时的10％湿度的吸附量，即使在相对湿度的约10％的低湿度区域中，也具有表现出吸附量的约30重量％的水蒸气吸附性能。吸附剂可用作干燥剂空调的除湿剂。版权所有（C）2012，JPO＆INPIT

5. 发明专利

JP2013074887A Carbon dioxide feeder to horticultural facility utilizing carbon dioxide in flue gas 有权
标题翻译：二氧化碳给二氧化碳生物利用二氧化碳在燃气中的作用
公开(公告)号：JP2013074887A
公开(公告)日：2013-04-25
申请号：JP2012200204
申请日：2012-09-12
申请人： National Institute Of Advanced Industrial Science & Technology , 独立行政法人産業技術総合研究所 , Nara Prefecture , 奈良県 , National Agriculture & Food Research Organization , 独立行政法人農業・食品産業技術総合研究機構 , Osaka Gas Co Ltd , 大阪瓦斯株式会社 , Nippon Light Metal Co Ltd , 日本軽金属株式会社
发明人： SUZUKI MASAYA , TSUKIMURA KATSUHIRO , INUKAI KEIICHI , MAEDA MASAKI , NISHIMOTO TOSHI , NAKA TERUFUMI , HIROOKA KENJI , SANO TARO , INAMOTO KATSUHIKO , YOSHIKAWA MASAAKI , KISHIMOTO AKIRA , KITAMURA KATSUHIRO
IPC分类号： A01G9/18 , B01D53/34 , B01D53/50 , B01D53/56 , B01D53/62 , C01B32/50
CPC分类号： Y02A50/2342 , Y02P20/152 , Y02P60/148 , Y02P60/24
摘要： PROBLEM TO BE SOLVED: To provide a carbon dioxide feeder to a horticultural facility, for supplying carbon dioxide by collecting and storing carbon dioxide from flue gas and discharging the stored carbon dioxide when a carbon dioxide concentration in a greenhouse decreases, using a physical adsorption method requiring no heat source, vacuum pump, or compressor, when collecting the carbon dioxide in the flue gas.SOLUTION: This carbon dioxide feeder to the horticultural facility includes, in this order, a means of bringing the concentration of nitrogen oxides and sulphur oxides in flue gas, generated in a carbon dioxide supply source, to equal to or lower than a concentration affecting no plant growth, and dehumidifying so as not to affect the adsorption performance of carbon dioxide, and a means of collecting and storing the carbon dioxide contained in the flue gas by using a carbon dioxide absorbent for adsorption and desorption by concentration difference of carbon dioxide, and further includes a means of discharging the carbon dioxide stored in the carbon dioxide absorbent to the horticultural facility by sending dehumidified air when needed in the horticultural facility.
摘要翻译：要解决的问题：向园艺设备提供二氧化碳给料器，用于通过从烟道气中收集和储存二氧化碳并在温室中的二氧化碳浓度降低时排出储存的二氧化碳来供应二氧化碳，使用当收集烟道气中的二氧化碳时，不需要热源，真空泵或压缩机的物理吸附方法。解决方案：该园艺设备的二氧化碳给料器按照这个顺序包括使在二氧化碳供应源中产生的烟道气中的氮氧化物和硫氧化物的浓度等于或低于不影响植物生长的浓度，除湿以便不影响二氧化碳的吸附性能，以及通过使用二氧化碳吸收剂通过碳浓度差吸收和解吸来收集和储存烟道气中所含二氧化碳的方法并且还包括通过在园艺设备中需要时发送除湿空气将储存在二氧化碳吸收剂中的二氧化碳排放到园艺设施的方法。版权所有（C）2013，JPO＆INPIT

6. 发明专利

JP2013034910A Method for separating and recovering carbon dioxide from mixed gas 有权
标题翻译：从混合气体分离和回收二氧化碳的方法
公开(公告)号：JP2013034910A
公开(公告)日：2013-02-21
申请号：JP2011170240
申请日：2011-08-03
申请人： Jfe Steel Corp , Jfeスチール株式会社 , National Institute Of Advanced Industrial Science & Technology , 独立行政法人産業技術総合研究所
发明人： MOGI YASUHIRO , SAIMA HITOSHI , HARAOKA TAKASHI , SUZUKI MASAYA , INUKAI KEIICHI , MAEDA MASAKI
IPC分类号： B01D53/04 , B01J20/16 , C01B32/50 , C01B33/26
CPC分类号： Y02A50/2342 , Y02C10/08 , Y02P20/152
摘要： PROBLEM TO BE SOLVED: To provide a method for separating and recovering carbon dioxide from a mixed gas containing carbon dioxide and carbon monoxide by a PSA method, which can efficiently adsorb and separate the carbon dioxide in the mixed gas and also selectively adsorb and separate the carbon dioxide.SOLUTION: A composite of a low crystalline layered clay mineral and amorphous aluminum silicate or the amorphous aluminum silicate which is a precursor thereof is used as an adsorbent. The mixed gas containing carbon dioxide and carbon monoxide is brought into contact with the adsorbent to selectively adsorb the carbon dioxide.
摘要翻译：解决的问题：提供一种通过PSA法从含有二氧化碳和一氧化碳的混合气体中分离回收二氧化碳的方法，其可以有效地吸附和分离混合气体中的二氧化碳，并且还选择性地吸附并分离二氧化碳。解决方案：使用低结晶层状粘土矿物和无定形硅酸铝或作为其前体的无定形硅酸铝的复合材料作为吸附剂。使含有二氧化碳和一氧化碳的混合气体与吸附剂接触以选择性吸附二氧化碳。版权所有（C）2013，JPO＆INPIT

7. 发明专利

JP2012148241A Manufacturing method of volatile organic compound adsorbent and volatile organic compound adsorbent manufactured by the method 有权
标题翻译：挥发性有机化合物吸附剂和挥发性有机化合物吸附剂的制造方法
公开(公告)号：JP2012148241A
公开(公告)日：2012-08-09
申请号：JP2011009188
申请日：2011-01-19
申请人： Hitachi Chemical Co Ltd , National Institute Of Advanced Industrial Science & Technology , 日立化成工業株式会社 , 独立行政法人産業技術総合研究所
发明人： MIKUNI HIROKI , KAWAI KIYOSHI , INUKAI KEIICHI , SUZUKI MASAYA , OI YUTAKA , MAEDA MASAKI
IPC分类号： B01J20/16 , B01D53/02 , B01J20/28 , B01J20/30 , C01B33/26 , C01B33/36
CPC分类号： Y02A50/235
摘要： PROBLEM TO BE SOLVED: To provide a manufacturing method of a reproducible volatile organic compound (VOC) adsorbent with less energy consumption having gas adsorption capability which is equal to or more than activated carbon and zeolite while adsorption temperature of the VOC adsorbed once is 150 °C or less.SOLUTION: The manufacturing method of the volatile organic compound adsorbent includes steps for: (a) obtaining a precursor of cylindrical aluminum silicate by mixing a solution containing silicic acid source and a solution containing aluminum source; (b) washing the precursor; (c) obtaining the cylindrical aluminum silicate by heating the precursor after washing in the step (b) in the presence of an acid; and (d) washing the cylindrical aluminum silicate.
摘要翻译：要解决的问题：为了提供具有等于或大于活性炭和沸石的气体吸附能力的具有较少能量消耗的可再现的挥发性有机化合物（VOC）吸附剂的制造方法，同时吸附一次VOC的吸附温度为150℃以下。挥发性有机化合物吸附剂的制造方法包括以下步骤：（a）通过混合含有硅酸源的溶液和含有铝源的溶液来获得圆柱形硅酸铝的前体; （b）洗涤前体; （c）通过在酸的存在下在步骤（b）中洗涤之后加热前体获得圆筒形硅酸铝; 和（d）洗涤圆柱形硅酸铝。版权所有（C）2012，JPO＆INPIT

8. 发明专利

JP2012012267A Method for producing aluminum silicate complex 有权
标题翻译：生产硅酸铝复合物的方法
公开(公告)号：JP2012012267A
公开(公告)日：2012-01-19
申请号：JP2010152580
申请日：2010-07-05
申请人： National Institute Of Advanced Industrial Science & Technology , 独立行政法人産業技術総合研究所
发明人： NAKANISHI RYOSUKE , MAEDA MASAKI , TAJIRI KOJI , INUKAI KEIICHI , KOZUKA NATSUKO , SUZUKI CHIEKO , SUZUKI MASAYA , TSUKIMURA KATSUHIRO , SAKAYORI ERI
IPC分类号： C01B33/26 , B01D53/28 , B01J20/16 , B01J20/30
CPC分类号： Y02C10/08
摘要： PROBLEM TO BE SOLVED: To provide an adsorbent having excellent adsorption performance of not less than 30 wt.% in the humidity range of 10-60 wt.% using a low cost reagent as its raw material.SOLUTION: This complex comprising a low-crystalline layered clay mineral and an amorphous aluminum silicate is synthesized using water glass as the Si source and aluminum sulfate as the aluminum source, mixing each aqueous solutions so that the Si/Al ratio of the mixed solution will be 0.80-1.6, regulating its pH to be 6-10 using an acid or an alkali, heating at 95-200°C and finally desalting. The resultant complex comprising a low-crystalline layered clay mineral and an amorphous aluminum silicate has excellent water vapor adsorption performance of not less than 30 wt.% at the difference of relative humidity at adsorption of 60% and relative humidity at desorption of 10% and can be used as an adsorbent such as an adsorbent for desiccant air-conditioning.
摘要翻译：要解决的问题：使用低成本试剂作为其原料，在10-60重量％的湿度范围内提供吸附性能优异的吸附性能不小于30重量％的吸附剂。解决方案：使用水玻璃作为Si源和硫酸铝作为铝源合成包含低结晶层状粘土矿物和无定形硅酸铝的复合物，混合各水溶液，使得Si / Al比率混合溶液为0.80-1.6，用酸或碱将其pH调节至6-10，加热至95-200℃，最后脱盐。所得到的包含低结晶层状粘土矿物和无定形硅酸铝的配合物在吸附60％相对湿度和解吸附近的相对湿度差为10％时具有优异的水汽吸附性能，不低于30重量％，可以用作吸附剂，例如用于干燥剂空调的吸附剂。版权所有（C）2012，JPO＆INPIT

9. 发明专利

JP2008179534A Amorphous aluminum silicate having excellent adsorption characteristic in high humidity range, and its manufacture method 有权
标题翻译：在高湿度范围内具有优异吸附特性的非晶铝硅酸铝及其制造方法
公开(公告)号：JP2008179534A
公开(公告)日：2008-08-07
申请号：JP2007334188
申请日：2007-12-26
申请人： National Institute Of Advanced Industrial & Technology , 独立行政法人産業技術総合研究所
发明人： SUZUKI MASAYA , IKEDA CHIEKO , INUKAI KEIICHI , MAEDA MASAKI
IPC分类号： C01B33/26 , B01D53/28 , B01J20/16
CPC分类号： C01B33/46 , B01J20/16 , C01B33/26
摘要： PROBLEM TO BE SOLVED: To provide an adsorbent having excellent adsorption performance in a high humidity range, by using an amorphous aluminum silicate.
SOLUTION: An amorphous aluminum silicate having a peak around -93 ppm in a
29 Si solid NMR spectrum is synthesized by mixing a monosilicate water solution and an aluminum solution so as to have a Si/Al ratio of 1.0-3.0, and performing desalting and heating after adjusting the pH to 6-8 with an acid or an alkali. The obtained amorphous aluminum silicate has a water vapor adsorption amount of 30 wt.% or less in the relative humidity of 0-80% and a moisture adsorption amount of 70 wt.% or more in the relative humidity of 80-98% or higher.
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：通过使用无定形硅酸铝提供在高湿度范围内具有优异吸附性能的吸附剂。解决方案：通过将单硅酸盐水溶液和铝溶液混合以使Si / Al合成，可以合成在 29 Si固体NMR光谱中具有约-93ppm峰值的无定形硅酸铝比例为1.0-3.0，并在用酸或碱调节pH至6-8之后进行脱盐和加热。得到的无定形硅酸铝在相对湿度为0〜80％的水蒸汽吸附量为30重量％以下，相对湿度为80-98％以上的水分吸附量为70重量％以上。版权所有（C）2008，JPO＆INPIT

10. 发明专利

JP2006076836A Novel aluminum silicate and method for synthesizing the same 有权
标题翻译：新型硅酸铝及其合成方法
公开(公告)号：JP2006076836A
公开(公告)日：2006-03-23
申请号：JP2004263269
申请日：2004-09-10
申请人： National Institute Of Advanced Industrial & Technology , 独立行政法人産業技術総合研究所
发明人： SUZUKI MASAYA , IKEDA CHIEKO , SATO HISAYO , SUZUKI MAKIKO , INUKAI KEIICHI , MAEDA MASAKI
IPC分类号： C01B33/26 , B01J20/16
摘要： PROBLEM TO BE SOLVED: To inexpensively provide a novel excellent aluminum silicate which can quickly adsorb and desorb various substances over a wide humidity range.
SOLUTION: The aluminum silicate has the composition expressed in terms of a molar ratio among oxides: SiO
2 xAl
2 O
3 yH
2 O (wherein x=0.5 to 2.0; and y=0 to 15) and gives a powder X-ray diffraction spectrum having relatively large broad peaks at Bragg angles (2θ±0.5°) of 3.5°, 8.5°, 26°, and 40°. This silicate is a novel porous material having numerous micropores, and by virtue of its excellent properties such as adsorptivity, it can be used in material recovery and storage, dehumidification, moisture removal, detoxification, combustibles storage and deodorization, etc., and especially as a humidity self-conditioning material which maintains humidity in a living environment at an optimal level.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：为了廉价地提供可以在宽的湿度范围内快速吸附和解吸各种物质的新型优异的硅酸铝。解决方案：硅酸铝具有根据氧化物之间的摩尔比表示的组成：SiO 2 xAl 2 3 SB> 2 O（其中x = 0.5〜2.0; y = 0〜15），得到在布拉格角（2θ±0.5°）为3.5°时具有较大宽峰的粉末X射线衍射光谱， 8.5°，26°和40°。该硅酸盐是具有多个微孔的新颖的多孔材料，由于其优异的吸附性能，可用于材料回收和储存，除湿，除湿，解毒，可燃物储存和除臭等，特别是作为一种将生活环境中的湿度保持在最佳水平的湿度自调节材料。版权所有（C）2006，JPO＆NCIPI

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