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1. 发明授权

US5389727A Resin compositions and a method of curing the same 失效
标题翻译：树脂组合物及其固化方法
公开(公告)号：US5389727A
公开(公告)日：1995-02-14
申请号：US112311
申请日：1993-08-27
申请人： Noboru Nakai , Osamu Isozaki , Naozumi Iwasawa
发明人： Noboru Nakai , Osamu Isozaki , Naozumi Iwasawa
IPC分类号： C08G59/40 , C07F7/08 , C07F7/18 , C08G59/00 , C08G59/02 , C08G59/04 , C08G59/30 , C08G59/32 , C08G59/70 , C08K5/00 , C08K5/07 , C08K5/1515 , C08K5/5415 , C08L33/06 , C08L43/04 , C08L63/00 , C08L75/04 , C08L101/06 , C09D133/06 , C09D133/14 , C09D143/04 , C09D163/00 , C08F8/00
CPC分类号： C08L63/00 , C07F7/0836 , C07F7/0858 , C07F7/0859 , C07F7/182 , C07F7/1836 , C07F7/1844 , C07F7/1896 , C08G59/02 , C08G59/04 , C08G59/306 , C08G59/3254 , C08G59/70 , C08K5/00 , C08K5/0091 , C08K5/07 , C08K5/1515 , C08K5/5415 , C08L101/06 , C08L75/04 , C09D133/064 , C09D133/068 , C09D143/04 , C09D163/00 , C08L33/068 , C08L43/04
摘要： A resin composition comprising a high molecular weight compound containing an average of 2 or more hydroxyl groups and an average of 1 or more functional groups selected from the class consisting of alkoxysilane, silanol and acyloxysilane groups per molecule and having a number average molecular weight of 3,000 to 200,000; a low molecular weight compound containing an average of 2 or more epoxy groups per molecule and having a number average molecular weight of 240 to 5,000; and, as a curing catalyst, a metal chelate compound, is curable at a relatively low temperature to yield a film having excellent resistance to weathering.
摘要翻译：一种树脂组合物，其包含平均分子量为2以上且平均分子量为1以上的官能团的高分子量化合物，每分子含有烷氧基硅烷，硅烷醇和酰氧基硅烷基，数均分子量为3000 到20万; 每分子平均含有2个以上环氧基且数均分子量为240〜5000的低分子量化合物; 作为固化催化剂，作为固化催化剂，金属螯合物在相对较低的温度下可固化，得到耐候性优异的膜。

2. 发明授权

US5284919A Resin compositions and a method of curing the same 失效
标题翻译：树脂组合物及其固化方法
公开(公告)号：US5284919A
公开(公告)日：1994-02-08
申请号：US672792
申请日：1991-03-21
申请人： Noboru Nakai , Osamu Isozaki , Naozumi Iwasawa
发明人： Noboru Nakai , Osamu Isozaki , Naozumi Iwasawa
IPC分类号： C08G59/40 , C07F7/08 , C07F7/18 , C08G59/00 , C08G59/02 , C08G59/04 , C08G59/30 , C08G59/32 , C08G59/70 , C08K5/00 , C08K5/07 , C08K5/1515 , C08K5/5415 , C08L33/06 , C08L43/04 , C08L63/00 , C08L75/04 , C08L101/06 , C09D133/06 , C09D133/14 , C09D143/04 , C09D163/00 , C08G77/04
CPC分类号： C08L63/00 , C07F7/0836 , C07F7/0858 , C07F7/0859 , C07F7/182 , C07F7/1836 , C07F7/1844 , C07F7/1896 , C08G59/02 , C08G59/04 , C08G59/306 , C08G59/3254 , C08G59/70 , C08K5/00 , C08K5/0091 , C08K5/07 , C08K5/1515 , C08K5/5415 , C08L101/06 , C08L75/04 , C09D133/064 , C09D133/068 , C09D143/04 , C09D163/00 , C08L33/068 , C08L43/04
摘要： A resin composition comprising two different compounds, A and B, with a number average molecular weight of 3,000 to 200,000 and a chelate compound. Compound A has two or more hydroxyl groups. Compound B has two or more epoxy groups and one or more of the following silane groups silanol, alkoxy silane and acyloxy silane.
摘要翻译：包含数均分子量为3,000〜200,000的两种不同化合物A和B的树脂组合物和螯合物。化合物A具有两个或多个羟基。化合物B具有两个或更多个环氧基团和一个或多个以下硅烷基团硅烷醇，烷氧基硅烷和酰氧基硅烷。

3. 发明授权

US5026793A Resin compositions and a method of curing the same 失效
标题翻译：树脂组合物及其固化方法
公开(公告)号：US5026793A
公开(公告)日：1991-06-25
申请号：US402408
申请日：1989-09-05
申请人： Noboru Nakai , Osamu Isozaki , Naozumi Iwasawa
发明人： Noboru Nakai , Osamu Isozaki , Naozumi Iwasawa
IPC分类号： C08G59/40 , C07F7/08 , C07F7/18 , C08G59/00 , C08G59/02 , C08G59/04 , C08G59/30 , C08G59/32 , C08G59/70 , C08K5/00 , C08K5/07 , C08K5/1515 , C08K5/5415 , C08L33/06 , C08L43/04 , C08L63/00 , C08L75/04 , C08L101/06 , C09D133/06 , C09D133/14 , C09D143/04 , C09D163/00
CPC分类号： C08L63/00 , C07F7/0836 , C07F7/0858 , C07F7/0859 , C07F7/182 , C07F7/1836 , C07F7/1844 , C07F7/1896 , C08G59/02 , C08G59/04 , C08G59/306 , C08G59/3254 , C08G59/70 , C08K5/00 , C08K5/0091 , C08K5/07 , C08K5/1515 , C08K5/5415 , C08L101/06 , C08L75/04 , C09D133/064 , C09D133/068 , C09D143/04 , C09D163/00 , C08L33/068 , C08L43/04
摘要： A resinous composition containing (A) a high molecular weight hydroxy compound having 2 or more hydroxy groups per molecule and having a number average molecular weight of 3,000 to 200,000, (B) a high molecule weight epoxy compound having 2 or more epoxy groups per molecule and having a number average molecular weight of 120 to 200,000, (C) a silane compound having one or more silicon-containing functional groups per molecule and (D) a chelate of aluminum, titanium or zirconium with a ligand exhibiting ketoenol tautomerism, can be cured at temperatures not exceeding 100.degree. C. and forms a desirable coating when cured.

4. 发明授权

US4927884A Curable composition 失效
标题翻译：可固化组合物
公开(公告)号：US4927884A
公开(公告)日：1990-05-22
申请号：US269084
申请日：1988-11-09
申请人： Naozumi Iwasawa , Osamu Isozaki , Noboru Nakai
发明人： Naozumi Iwasawa , Osamu Isozaki , Noboru Nakai
IPC分类号： C08K5/00 , C08L83/06 , C08L83/07 , C08L83/10 , C09D183/07
CPC分类号： C08L83/06 , C08K5/0091 , C08L83/10
摘要： Disclosed is a curable composition characterized in that the composition comprises:(i) 100 parts by weight of a polymer mixture of(a) about 5 to about 95% by weight of a polymer (X) containing a specific polysiloxane macromonomer as an essential monomer or a polymer (Y) containing a specific alkoxysilane-containing vinyl monomer as an essential monomer, and(b) about 95 to about 5% by weight of a polymer (Z) containing an epoxy-containing vinyl monomer as an essential monomer; and(ii) about 0.01 to about 30 parts by weight of at least one chelate compound selected from the group consisting of aluminum chelate compound, titanium chelate compound and zirconium chelate compound.
摘要翻译：公开了一种可固化组合物，其特征在于所述组合物包含：（i）100重量份的（a）约5至约95重量％的含有特定聚硅氧烷大分子单体作为必需单体的聚合物（X）的聚合物混合物或含有特定烷氧基硅烷的乙烯基单体作为必需单体的聚合物（Y），和（b）含有含环氧基乙烯基单体作为必需单体的聚合物（Z）约95〜约5重量％和（ii）约0.01至约30重量份的选自铝螯合化合物，钛螯合物和锆螯合物的至少一种螯合化合物。

5. 发明授权

US5492968A Resin compositions and a method of curing the same 失效
标题翻译：树脂组合物及其固化方法
公开(公告)号：US5492968A
公开(公告)日：1996-02-20
申请号：US335379
申请日：1994-11-03
申请人： Noboru Nakai , Osamu Isozaki , Naozumi Iwasawa
发明人： Noboru Nakai , Osamu Isozaki , Naozumi Iwasawa
IPC分类号： C08G59/40 , C07F7/08 , C07F7/18 , C08G59/00 , C08G59/02 , C08G59/04 , C08G59/30 , C08G59/32 , C08G59/70 , C08K5/00 , C08K5/07 , C08K5/1515 , C08K5/5415 , C08L33/06 , C08L43/04 , C08L63/00 , C08L75/04 , C08L101/06 , C09D133/06 , C09D133/14 , C09D143/04 , C09D163/00 , C08F8/00
CPC分类号： C08L63/00 , C07F7/0836 , C07F7/0858 , C07F7/0859 , C07F7/182 , C07F7/1836 , C07F7/1844 , C07F7/1896 , C08G59/02 , C08G59/04 , C08G59/306 , C08G59/3254 , C08G59/70 , C08K5/00 , C08K5/0091 , C08K5/07 , C08K5/1515 , C08K5/5415 , C08L101/06 , C08L75/04 , C09D133/064 , C09D133/068 , C09D143/04 , C09D163/00 , C08L33/068 , C08L43/04
摘要： A resin composition comprising a) a high molecular weight compound containing an average of 2 or more hydroxyl groups and an average of 2 or more epoxy groups per molecule and having a number average molecular weight of 3,000 to 200,000; b) a silane compound having an average of 1 or more alkoxysilane, silanol and acyloxysilane groups per molecule and having a number average molecular weight of 104 to 200,000; and c) a metal chelate compound, is curable at a relatively low temperature to yield a film having excellent resistance to weathering.
摘要翻译：一种树脂组合物，其包含a）每分子平均含有2个或更多个羟基并且平均具有2个或更多个环氧基并且数均分子量为3,000至200,000的高分子量化合物; b）每分子平均具有1个或更多个烷氧基硅烷，硅烷醇和酰氧基硅烷基团并且数均分子量为104至200,000的硅烷化合物; 和c）金属螯合化合物在相对低的温度下可固化，得到具有优异耐候性的膜。

6. 发明授权

US5216094A Resins with unsaturated carbonyl and hydroxyl groups 失效
标题翻译：具有不饱和羰基和羟基的树脂
公开(公告)号：US5216094A
公开(公告)日：1993-06-01
申请号：US884881
申请日：1992-05-18
申请人： Osamu Isozaki , Naozumi Iwasawa
发明人： Osamu Isozaki , Naozumi Iwasawa
IPC分类号： C08F8/44
CPC分类号： C08F8/44
摘要： The present invention provides a curable resin coating composition consisting essentially of:(i) a resin (A) containing .alpha.,.beta.-unsaturated carbonyl group and primary and/or secondary hydroxyl group, or(ii) a mixture of a resin (B) containing .alpha.,.beta.-unsaturated carbonyl group and a resin (C) containing primary and/or secondary hydroxyl group, and(iii) at least one curing catalyst selected from the group consisting of alkali metal alkoxides, metal hydroxides, organic acid salts of metals, quaternary ammonium hydroxides, quaternary phosphonium hydroxides, tertiary sulfonium hydroxides and organic acid salts of these onium hydroxides.
摘要翻译：本发明提供一种可固化树脂涂料组合物，其基本上由以下组成：（i）含有α，β-不饱和羰基和伯和/或仲羟基的树脂（A），或（ii）树脂（B）含有α，β-不饱和羰基和含有伯和/或仲羟基的树脂（C），和（iii）至少一种选自碱金属醇盐，金属氢氧化物，金属有机酸盐的固化催化剂，季铵氢氧化物，季铵氢氧化物，叔锍氢氧化物和这些氢氧化镧的有机酸盐。

7. 发明授权

US5015472A Coating compositions and methods for preventing adhesion of organisms 失效
标题翻译：用于防止生物粘附的涂料组合物和方法
公开(公告)号：US5015472A
公开(公告)日：1991-05-14
申请号：US527465
申请日：1990-05-23
申请人： Osamu Isozaki , Naozumi Iwasawa , Toshiro Hirama , Hiroshi Iwai
发明人： Osamu Isozaki , Naozumi Iwasawa , Toshiro Hirama , Hiroshi Iwai
IPC分类号： C09D5/16
CPC分类号： C09D5/1668
摘要： Disclosed are a coating composition (A) for preventing adhesion of organisms which comprises as its vehicle component a homopolymer or a copolymer, the homopolymer being one prepared by homopolymerizing a phenol-modified unsaturated monomer obtained by reacting (a) an unsaturated monomer containing epoxy group and/or hydroxyl group with (b) an addition reaction product of a phenolic compound with a compound having one carboxylic anhydride group per molecule, and the copolymer being one prepared by copolymerizing said phenol-modified unsaturated monomer and a radically polymerizable unsaturated monomer, and also a coating composition (B) for preventing adhesion of organisms which comprises as its vehicle component a phenol-modified resin prepared by reacting (c) a resin containing epoxy group and/or hydroxyl group with (b) and addition reaction product of a phenolic compound with a compound having one carboxylic anhyhdride group per molecule.Also disclosed is a method for preventing adhesion of organisms, characterized by coating a substrate with the coating composition (A) or (B).

8. 发明授权

US4973477A Coating compositions for preventing adhesion of organisms 失效
标题翻译：用于防止生物附着的涂料组合物
公开(公告)号：US4973477A
公开(公告)日：1990-11-27
申请号：US317501
申请日：1989-03-01
申请人： Osamu Isozaki , Naozumi Iwasawa , Toshiro Hirama , Hiroshi Iwai
发明人： Osamu Isozaki , Naozumi Iwasawa , Toshiro Hirama , Hiroshi Iwai
IPC分类号： C09D5/16
CPC分类号： C09D5/1668
摘要： Disclosed are a coating composition (A) for preventing adhesion of organisms which comprises as its vehicle component a homopolymer or a copolymer, the homopolymer being one prepared by homopolymerizing a phenol-modified unsaturated monomer obtained by reacting (a) an unsaturated monomer containing epoxy group and/or hydroxyl group with (b) an addition reaction product of a phenolic compound with a compound having one carboxylic anhydride group per molecule, and the copolymer being one prepared by copolymerizing said phenol-modified unsaturated monomer and a radically polymerizable unsaturated monomer, and also a coating composition (B) for preventing adhesion of organisms which comprises as its vehicle component a phenol-modified resin prepared by reacting (c) a resin containing epoxy group and/or hydroxyl group with (b) an addition reaction product of a phenolic compound with a compound having one carboxylic anhydride group per molecule.Also disclosed is a method for preventing adhesion of organisms, characterized by coating a substrate with the coating composition (A) or (B).

9. 发明授权

US5093223A Method of forming a cured coating film 失效
标题翻译：形成固化涂膜的方法
公开(公告)号：US5093223A
公开(公告)日：1992-03-03
申请号：US278505
申请日：1988-12-01
申请人： Naozumi Iwasawa , Osamu Isozaki
发明人： Naozumi Iwasawa , Osamu Isozaki
IPC分类号： B05D3/06 , C08G59/14 , C08J3/28 , G03F7/038
CPC分类号： G03F7/038 , B05D3/068 , C08G59/1433 , C08J3/28 , G03F7/0388 , Y10S522/904
摘要： The invention provides a method of forming a cured coating film which comprises exposing a coating composition consisting of, or containing as a main component, a resin containing polymerizable unsaturated group and aprotic onium-containing group of the formula ##STR1## wherein R.sub.1 means a hydrogen atom or a hydrocarbon group of 1 to 8 carbon atoms which may optionally be substituted by a hydroxyl, alkoxy or ester group or a halogen atom; ##STR2## where Z means a nitrogen atom or phosphorus atom and Y means a sulfur atom; R.sub.2, R.sub.3 and R.sub.4 are the same or different and respectively mean an organic group of 1 to 14 carbon atoms, provided that R.sub.2 and R.sub.3, or R.sub.2, R.sub.3 and R.sub.4 may jointly form a heterocyclic group taken together with the adjacent nitrogen, phosphorus or sulfur atom, to actinic radiation or electron beams to thereby induce a crosslinking reaction and, then, subjecting the composition to heat treatment at a temperature not less than 80.degree. C.
摘要翻译：本发明提供一种形成固化涂膜的方法，该方法包括使包含可聚合不饱和基团的树脂和式（Ⅰ）所示的非质子含鎓基团组成或包含作为主要成分的涂料组合物，其中R 1 是指氢原子或可任选被羟基，烷氧基或酯基或卤素原子取代的1至8个碳原子的烃基; 其中Z表示氮原子或磷原子，Y表示硫原子; R 2，R 3和R 4相同或不同，分别表示1至14个碳原子的有机基团，条件是R 2和R 3或R 2，R 3和R 4可以与相邻的氮，磷或磷一起形成杂环基硫原子，光化辐射或电子束，从而引起交联反应，然后使组合物在不低于80℃的温度下进行热处理。

10. 发明授权

US3974303A Method for forming coating films 失效
标题翻译：涂膜形成方法
公开(公告)号：US3974303A
公开(公告)日：1976-08-10
申请号：US490753
申请日：1974-07-22
申请人： Seigo Iwase , Osamu Isozaki , Naozumi Iwasawa , Tadashi Watanabe
发明人： Seigo Iwase , Osamu Isozaki , Naozumi Iwasawa , Tadashi Watanabe
IPC分类号： C09D5/00 , B05D3/06 , C08G18/32 , C08G18/67 , C08J3/28 , C09D4/00 , C09D5/03 , C09D175/16 , B05B5/02
CPC分类号： C08G18/3206 , B05D3/067 , B05D3/068 , C08G18/672 , C08J3/28 , C09D175/16 , B05D2401/32 , C08G2150/20
摘要： A method for forming coating films which can provide coating films having good surface appearance and being excellent in such properties as impact resistance, adhesion to the substrate article, flexibility and chemical resistance, said method comprising coating a powdery composition of a thermoplastic resin having 0.5 to 3.5 polymerizable unsaturated bonds per 1000 of the molecular weight on an article to be coated, heat-melting the powdery resinous composition, and curing the molten film under application of ionizing radiation or ultraviolet radiation.
摘要翻译：一种形成涂膜的方法，其可以提供具有良好的表面外观并且具有优异的耐冲击性，对基材制品的粘附性，柔韧性和耐化学性的性能的涂膜，所述方法包括将具有0.5的热塑性树脂的粉末组合物涂覆至 3.5可聚合的不饱和键，每1000个待涂覆的物品上的分子量，对粉末状树脂组合物进行加热熔融，并在施加电离辐射或紫外线辐射下固化熔融膜。

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