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    • 4. 发明申请
    • Method for Alkoxylating Active Hydrogen Containing Compounds and the Alkoxylated Compounds Made Therefrom
    • 含有活性氢的化合物和由其制备的烷氧基化化合物的烷氧基化方法
    • US20080125569A1
    • 2008-05-29
    • US11664463
    • 2005-10-24
    • Richard M. WehmeyerJohn W. WestonMarlin E. Walters
    • Richard M. WehmeyerJohn W. WestonMarlin E. Walters
    • C08G65/26
    • C08G65/26C08G65/2642C08G65/2696
    • A polyether composition comprised of a polyether, a functionalizing catalyst and a metal cyanide catalyst is formed by forming a functionalized initiator compound by reacting a precursor initiator compound with a functionalizing compound and a functionalizing catalyst to form the functionalized initiator compound, forming a mixture of the functionalized initiator compound containing at least a portion of the functionalizing catalyst, an alkylene oxide and a metal cyanide catalyst complex, and subjecting the mixture to conditions sufficient to activate the catalyst complex and to alkoxylate the functionalized initiator compound to form the polyether. The functionalized initiator compound may be of a vegetable oil, animal fat or modified vegetable oil or modified animal fat. The functionalizing catalyst may be a tin, titanium, iodine, rhodium, nickel, acid or enzyme catalyst.
    • 通过使前体引发剂化合物与官能化化合物和官能化催化剂反应形成官能化的引发剂化合物,形成官能化引发剂化合物,形成官能化引发剂化合物,形成由聚醚,官能化催化剂和金属氰化物催化剂组成的聚醚组合物 含有至少一部分官能化催化剂,烯化氧和金属氰化物催化剂络合物的官能化引发剂化合物,并使混合物经受足以活化催化剂配合物的条件,并使官能化的引发剂化合物烷氧基化形成聚醚。 官能化引发剂化合物可以是植物油,动物脂肪或改性植物油或改性动物脂肪。 官能化催化剂可以是锡,钛,碘,铑,镍,酸或酶催化剂。