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    • 9. 发明申请
    • PROCESS FRO THE PRODUCTION OF HYDROGEN
    • 过程生产氢气
    • WO2011151792A1
    • 2011-12-08
    • PCT/IB2011/052403
    • 2011-05-31
    • NOVAUCDPHILLIPS, AndrewSCHREIBER, Dominique
    • PHILLIPS, AndrewSCHREIBER, Dominique
    • C01B3/04B01J31/18B01J31/22C07F15/00
    • C01B3/06B01J31/1805B01J31/2295B01J2231/76B01J2531/821B01J2531/825B01J2531/842C01B3/04C07F15/0046C07F17/02C09B57/10H01M8/0606Y02E60/364
    • The present invention relates to a process for the production of hydrogen comprising contacting at least one complex of formula (I), wherein: X - is an anion; Y is N or CR 6 ; M is selected from Ru, Os and Fe; each of A and B is independently a saturated, unsaturated or partially unsaturated carbocyclic ring; R 5 , R 6 and R 7 are each independently selected from H, NR24R25, C 1-6 -alkyl and C 1-6 - haloalkyl, or two or more of R 5 , R 6 and R 7 are linked, together with the carbons to which they are attached, to form a saturated or unsaturated carbocyclic group; R 8 -R 25 are each independently selected from H, C 1-6 -alkyl, C 1-6 -haloalkyl and a linker group optionally attached to a solid support; with at least one substrate of formula (II), R 1 R 2 -NH-BH-R 3 R 4 (II), wherein R 1 , R 2 , R 3 and R 4 are each independently selected from H, C 1-20 -alkyl, fluoro- substituted-C 1-20 -alkyl and C 6-14 -aryl, or any two of R 1 , R 2 , R 3 and R 4 are linked to form a C 2-10 -alkylene group, which together with the nitrogen and/or boron atoms to which they are attached, forms a cyclic group. Further aspects of the invention relate to a hydrogen generation system comprising a complex of formula (I), a substrate of formula (II) and a solvent, and to the use of complexes of formula (I) in fuel cells. Another aspect of the invention relates to novel complexes of formula (I).
    • 本发明涉及一种生产氢气的方法,包括使至少一种式(I)配合物与式I化合物接触,其中:X-是阴离子; Y为N或CR6; M选自Ru,Os,Fe; A和B各自独立地为饱和的,不饱和的或部分不饱和的碳环; R 5,R 6和R 7各自独立地选自H,NR 24 R 25,C 1-6 - 烷基和C 1-6 - 卤代烷基,或者R 5,R 6和R 7中的两个或多个与它们所连接的碳一起连接到 形成饱和或不饱和碳环基团; R8-R25各自独立地选自H,C 1-6 - 烷基,C 1-6 - 卤代烷基和任选地连接到固体载体上的连接基团; 与式(II)的至少一个底物,R1R2-NH-BH-R3R4(II),其中R1,R2,R3和R4各自独立地选自H,C1-20烷基,氟取代的C1-20 - 烷基和C 6-14 - 芳基,或R 1,R 2,R 3和R 4中的任何两个连接形成C 2-10 - 亚烷基,它们与它们所连接的氮原子和/或硼原子一起形成 循环组。 本发明的另外方面涉及包含式(I)的配合物,式(II)的底物和溶剂的氢生成系统,以及在燃料电池中使用式(I)的络合物。 本发明的另一方面涉及式(I)的新型配合物。