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1. 发明申请

WO2017191265A1 SOLAR CELL 审中-公开
标题翻译：太阳能电池
公开(公告)号：WO2017191265A1
公开(公告)日：2017-11-09
申请号：PCT/EP2017/060675
申请日：2017-05-04
申请人： NOVALED GMBH
发明人： RINCON, Maria Cristina Momblona , ESCRIG, Lidon Gil , SESSOLO, Michele , BOLINK, Jan Hendrik , BLOCHWITZ-NIMOTH, Jan , LEDERER, Kay
IPC分类号： H01L51/42 , H01L27/30
CPC分类号： H01L51/4246 , H01L27/302 , Y02E10/549
摘要： The present disclosure refers to a solar cell, having a first electrode, a second electrode, and a stack of layers provided between the first and second electrode. The stack of layers comprises a light absorbing layer comprising an absorber compound provided with a perovskite crystal structure, an organic ρ-type layer provided between the first electrode and the light absorbing layer, and a n-type layer provided between the second electrode and the first light absorbing layer. The organic ρ-type layer comprises at least one of a layer comprising an organic ρ-type dopant, and a layer comprising a mixture of an organic ρ-type dopant and a first organic aromatic matrix compound. The n-type layer comprises at least one of a layer comprising an n-type dopant, and a layer comprising of a mixture of an n-type dopant and a second organic aromatic matrix compound.
摘要翻译：本公开涉及太阳能电池，其具有第一电极，第二电极以及设置在第一电极和第二电极之间的层堆叠。该叠层包括光吸收层，该光吸收层包括具有钙钛矿晶体结构的吸收剂化合物，设置在第一电极和光吸收层之间的有机ρ型层以及设置在第二电极和光吸收层之间的n型层第一光吸收层。有机ρ型层包括含有机ρ型掺杂剂的层和含有有机ρ型掺杂剂和第一有机芳香族基质化合物的混合物的层中的至少一种。 n型层包括含有n型掺杂剂的层和含有n型掺杂剂和第二有机芳香族基质化合物的混合物的层中的至少一种。

2. 发明申请

WO2018178273A1 INK COMPOSITION FOR FORMING AN ORGANIC LAYER OF A SEMICONDUCTOR 审中-公开
公开(公告)号：WO2018178273A1
公开(公告)日：2018-10-04
申请号：PCT/EP2018/058154
申请日：2018-03-29
申请人： NOVALED GMBH
发明人： LEDERER, Kay , RUNGE, Steffen , GARNIER, Jerome , TEICHLER, Anke
IPC分类号： H01L51/54
摘要： The present invention is directed to an ink composition for forming an organic semiconductor layer, wherein the ink composition comprises: - at least one p- type dopant comprising electron withdrawing groups; - at least one first auxiliary compound, wherein the first auxiliary compound is an aromatic nitrile compound, wherein the aromatic nitrile compound has about ≥ 1 to about ≤ 3 nitrile groups and a melting point of about

3. 发明申请

WO2017144516A1 CHARGE TRANSPORTING SEMI-CONDUCTING MATERIAL AND ELECTRONIC DEVICE COMPRISING IT 审中-公开
标题翻译：电荷传输半导体材料和包含它的电子器件
公开(公告)号：WO2017144516A1
公开(公告)日：2017-08-31
申请号：PCT/EP2017/054021
申请日：2017-02-22
申请人： NOVALED GMBH , FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E.V.
发明人： LEDERER, Kay , RUNGE, Steffen , BLOCHWITZ-NIMOTH, Jan , LIMBERG, Felix , KRÜGER, Hartmut
IPC分类号： H01L51/54 , C09K11/06
CPC分类号： H01L51/0043 , H01L51/5048
摘要： The present invention relates to a charge transporting semi-conducting material comprising: a) at least one electrical dopant, and b) a branched or cross-linked charge-transporting polymer comprising cyclobutenone cross-linking units of at least one of the general formulae la and/or lb, wherein aa) Pol 1 , Pol 2 , Pol 3 and Pol 4 are independently selected chains of the charge-transporting polymer, bb) X 1 , X 2 , X 3 , and X 4 are independently selected optional spacer units or, independently, represent direct bonding of Pol 1 , Pol 2 , Pol 3 and Pol 4 chains to the cyclobutenone ring, cc) Z 1 , Z 2 , Z 3 , and Z 4 are independently selected from H, halogen or a carbon-containing group; the charge transporting semi-conducting material being obtainable by a process comprising: i) providing a solution containing aaa) at least one precursor charge transporting compound comprising at least one covalently attached alkinyloxy group having generic formula II wherein X is an optional spacer which is further linked to a charge transporting structural moiety of the precursor charge transporting compound, the dashed line represents the bonding to a charge transporting structural moiety of the precursor charge transporting compound and Z 1 , Z 2 , Z 3 , and Z 4 are independently selected from H, halogen or the carbon-containing group, bbb) at least one electrical dopant, ccc) at least one solvent, ii) depositing the solution on a substrate, iii) removing the solvent, and iv) reacting the alkinyloxy groups to effect crosslinking, preferably by heating, wherein the average number of the alkinyloxy groups per one molecule of the precursor charge transporting compound provided in the step i) is equal to or greater than 2, preferably greater than 2.05, and a process for preparing the same.
摘要翻译：本发明涉及电荷输送半导体材料，其包含：a）至少一种电掺杂剂，和b）支链或交联的电荷输送性聚合物，其包含环丁烯酮交联单元通式1a和/或1b中的至少一个，其中aa）是Pol 1，Pol 2，Pol 3和Pol 1， 4是电荷传输聚合物的独立选择的链，bb）X 1，X 2，X 3和X 4是独立选择的可选的间隔基单元，或者独立地表示Pol 1，Pol 2，Pol 3和/或sup 3的直接键合。和Pol 4链连接到环丁烯酮环上，cc）Z 1，Z 2，Z 3和 Z 4独立地选自H，卤素或含碳基团; 所述电荷输送半导体材料可通过包括以下步骤的方法获得：i）提供包含aaa）至少一种前体电荷输送化合物的溶液，所述前体电荷输送化合物包含至少一个具有通式II的共价连接的炔基氧基，其中X是任选的间隔基，与前体电荷输送化合物的电荷输送结构部分连接，虚线代表与前体电荷输送化合物的电荷输送结构部分的键，并且Z 1，Z 2， Z 3和Z 4独立地选自H，卤素或含碳基团，bbb）至少一种电掺杂剂，ccc）至少一种溶剂，ii）将溶液沉积在基材上，iii）除去溶剂，和iv）使所述烷氧基基团反应以实现交联，优选通过加热，其中每个前体装料分子的平均数量的炔基氧基基团在步骤i）中提供的电荷输运化合物等于或大于2，优选大于2.05，以及制备该化合物的方法。

4. 发明申请

WO2014037512A3 CHARGE TRANSPORTING SEMI-CONDUCTING MATERIAL AND SEMI-CONDUCTING DEVICE 审中-公开
公开(公告)号：WO2014037512A3
公开(公告)日：2014-03-13
申请号：PCT/EP2013/068484
申请日：2013-09-06
申请人： NOVALED GMBH
发明人： ZÖLLNER, Mike , LEDERER, Kay , KIRIY, Anton , SENKOVSKYY, Volodymyr , VOIT, Isabelle Brigitte
IPC分类号： H01L51/00 , H01L51/50
摘要： The present invention relates to a charge transporting semi-conducting material comprising: a) optionally at least one electrical dopant, and b) at least one cross-linked charge-transporting polymer comprising 1,2,3-triazole cross-linking units, a method for its preparation and a semiconducting device comprising the charge transporting semi-conducting material.

5. 发明公开

EP2893576A2 CHARGE TRANSPORTING SEMI-CONDUCTING MATERIAL AND SEMI-CONDUCTING DEVICE 有权
标题翻译：易燃物质不合格物质不合格物质
公开(公告)号：EP2893576A2
公开(公告)日：2015-07-15
申请号：EP13759729.0
申请日：2013-09-06
申请人： Novaled GmbH
发明人： ZÖLLNER, Mike , LEDERER, Kay , KIRIY, Anton , SENKOVSKYY, Volodymyr , VOIT, Isabelle Brigitte
IPC分类号： H01L51/00 , H01L51/50
CPC分类号： H01L51/0043 , C08G61/10 , C08G61/12 , C08G61/123 , C08G61/124 , C08G61/128 , C08G2261/11 , C08G2261/12 , C08G2261/135 , C08G2261/1412 , C08G2261/1414 , C08G2261/1422 , C08G2261/1424 , C08G2261/143 , C08G2261/144 , C08G2261/146 , C08G2261/3142 , C08G2261/3162 , C08G2261/3221 , C08G2261/3241 , C08G2261/51 , C08G2261/76 , C08G2261/95 , C08J3/247 , C08J2365/00 , H01L51/0035 , H01L51/0036 , H01L51/0039 , H01L51/004 , H01L51/0067 , H01L51/506 , H01L51/5076
摘要： The present invention relates to a charge transporting semi-conducting material comprising: a) optionally at least one electrical dopant, and b) at least one cross-linked charge-transporting polymer comprising 1,2,3-triazole cross-linking units, a method for its preparation and a semiconducting device comprising the charge transporting semi-conducting material.
摘要翻译：本发明涉及电荷输送半导体材料，其包括：a）任选的至少一种电掺杂剂，和b）至少一种包含1,2,3-三唑交联单元的交联电荷输送聚合物，其制备方法和包含电荷输送半导体材料的半导体器件。

6. 发明公开

EP3382770A1 INK COMPOSITION FOR FORMING AN ORGANIC LAYER OF A SEMICONDUCTOR 有权转让
公开(公告)号：EP3382770A1
公开(公告)日：2018-10-03
申请号：EP17163956.0
申请日：2017-03-30
申请人： Novaled GmbH
发明人： LEDERER, Kay , RUNGE, Steffen , GANIER, Jerome , TEICHLER, Anke
IPC分类号： H01L51/54
CPC分类号： H01L51/0007 , H01L51/0005 , H01L51/0039 , H01L51/0043 , H01L51/0051 , H01L51/5088 , Y02E10/549
摘要： The present invention is directed to an ink composition for forming an organic semiconductor layer, wherein the ink composition comprises:
- at least one p-type dopant comprising electron withdrawing groups;
- at least one first auxiliary compound, wherein the first auxiliary compound is an aromatic nitrile compound, wherein the aromatic nitrile compound has about ≥ 1 to about ≤ 3 nitrile groups and a melting point of about
wherein the electron withdrawing groups are fluorine, chlorine, bromine and/or nitrile.

7. 发明授权

EP2893576B1 CHARGE TRANSPORTING SEMI-CONDUCTING MATERIAL AND SEMI-CONDUCTING DEVICE 有权
标题翻译：电荷传输半导体材料和半导体器件
公开(公告)号：EP2893576B1
公开(公告)日：2018-04-04
申请号：EP13759729.0
申请日：2013-09-06
申请人： Novaled GmbH
发明人： ZÖLLNER, Mike , LEDERER, Kay , KIRIY, Anton , SENKOVSKYY, Volodymyr , VOIT, Isabelle Brigitte
IPC分类号： H01L51/54
CPC分类号： H01L51/0043 , C08G12/28 , C08G61/10 , C08G61/12 , C08G61/123 , C08G61/124 , C08G61/128 , C08G73/08 , C08G2261/11 , C08G2261/12 , C08G2261/135 , C08G2261/1412 , C08G2261/1414 , C08G2261/142 , C08G2261/1422 , C08G2261/1424 , C08G2261/143 , C08G2261/144 , C08G2261/146 , C08G2261/3142 , C08G2261/3162 , C08G2261/3221 , C08G2261/3241 , C08G2261/51 , C08G2261/76 , C08G2261/79 , C08G2261/95 , C08J3/246 , C08J3/247 , C08J2365/00 , H01B1/12 , H01B1/127 , H01L51/0034 , H01L51/0035 , H01L51/0036 , H01L51/0038 , H01L51/0039 , H01L51/004 , H01L51/0041 , H01L51/005 , H01L51/0051 , H01L51/0052 , H01L51/0059 , H01L51/0067 , H01L51/506 , H01L51/5076
摘要： The present invention relates to a charge transporting semi-conducting material comprising: a) optionally at least one electrical dopant, and b) at least one cross-linked charge-transporting polymer comprising 1,2,3-triazole cross-linking units, a method for its preparation and a semiconducting device comprising the charge transporting semi-conducting material.

8. 发明公开

EP3208862A1 CHARGE TRANSPORTING SEMI-CONDUCTING MATERIAL AND ELECTRONIC DEVICE COMPRISING IT 有权转让
标题翻译：电荷传输半导体材料和包含它的电子器件
公开(公告)号：EP3208862A1
公开(公告)日：2017-08-23
申请号：EP16156693.0
申请日：2016-02-22
申请人： Novaled GmbH , Fraunhofer Gesellschaft zur Förderung der angewandten Forschung e.V.
发明人： LEDERER, Kay , RUNGE, Steffen , LIMBERG, Felix , KRÜGER, Hartmut
IPC分类号： H01L51/54 , C08G61/02
CPC分类号： H01L51/004 , C08F212/14 , C09D5/24 , C09D125/18 , H01L51/0007 , H01L51/0043 , H01L51/0067 , H01L51/0095 , H01L51/506 , H01L2251/533
摘要： The present invention relates to a charge transporting semi-conducting material comprising:
a) optionally at least one electrical dopant, and
b) a branched or cross-linked charge transporting polymer comprising 1,2,3-triazole cross-linking units of at least one of the general formulae Ia and/or Ib,

wherein
aa) Pol 1 - Pol 4 are independently selected chains of the charge-transporting polymer,
bb) X 1 , X 2 , X 3 , and X 4 are independently selected spacer units or, independently, represent direct bonding of pol 1 - Pol 4 to the 1,2,3-triazole ring,
cc) each of R and R' is independently selected from H halogen or a carbon-containing group,
wherein the charge transporting polymer comprises ethylene building units substituted with at least one pending side group comprising a conjugated system of delocalised electrons ,
the charge transporting semi-conducting material being obtainable by a process comprising:
i) providing a solution containing
aaa) a first precursor charge transporting polymer comprising at least one covalently attached azide group and optionally at least one acetylenic group; and/or a second precursor charge transporting polymer comprising at least one covalently attached acetylenic group and optionally at least one azide group; and optionally at least one crosslinking agent comprising at least two functional groups selected from azide and/or acetylenic group,
bbb) optionally at least one electrical dopant,
ccc) at least one solvent,
ii) depositing the solution on a substrate,
iii) removing the solvent, and
iv) reacting the azide and acetylenic groups to effect crosslinking, preferably by heating,
wherein at least one of the first and second precursor charge transporting polymer comprises ethylene building units substituted with at least one pending side group comprising a conjugated system of delocalised electrons,
a first and a second precursor charge transporting polymer used therein, a process for preparing the inventive charge transporting semi-conducting material and an electronic device comprising the same.
摘要翻译：本发明涉及一种电荷输送半导体材料，其包含：a）任选的至少一种电掺杂剂，以及b）包含至少1,2,3-三唑交联单元的支链或交联的电荷输送聚合物，所述交联单元至少为通式Ia和/或Ib之一，其中aa）Pol1-Pol4是电荷输送聚合物的独立选择的链，bb）X1，X2，X3和X4是独立选择的间隔基单元或独立地表示直接键合的pol1-Pol4与1,2,3-三唑环的结合，cc）R和R'各自独立地选自H卤素或含碳基团，其中电荷输送聚合物包含被至少一个其包含离域电子的共轭体系，所述电荷输送半导体材料可通过包括以下的方法获得：i）提供包含aaa）第一前体电荷输送聚合物的溶液，所述第一前体电荷输送聚合物包含至少一个共价连接的叠氮基团和任选的至少一个炔属基团; 和/或第二前体电荷输送聚合物，其包含至少一个共价连接的炔属基团和任选的至少一个叠氮基团; 和任选的至少一种包含至少两个选自叠氮化物和/或炔属基团的官能团的交联剂，bbb）任选地至少一种电掺杂剂，ccc）至少一种溶剂，ii）将溶液沉积在基底上，iii）溶剂，和iv）使叠氮化物和炔属基团进行反应，优选通过加热进行交联，其中第一和第二前体电荷输送聚合物中的至少一个包含被至少一个未决的侧基取代的乙烯构建单元，所述侧基包含离域电子，其中使用的第一和第二前体电荷输送聚合物，制备本发明电荷输送半导体材料的方法以及包含其的电子器件。

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