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    • 2. 发明专利
    • DE60212047T2
    • 2006-12-21
    • DE60212047
    • 2002-07-19
    • NIPPON POLYURETHANE KOGYO KK
    • KITA MOTOMUIKEMOTO MITSUSHIGESASAHARA TOSHIAKI
    • C08G18/28C08G18/32C08G18/22C08G18/70C08G18/78C08G18/79
    • A self-emulsifiable polyisocyanate with high functionality, having the average number of functional groups in 4.3 or more and a viscosity of 8,000 mPa . s (at 25 DEG C) or less, which is obtained by subjecting a modified polyisocyanate containing allophanate bonds and a poly(oxyalkylene)glycol monoalkyl ether (e) having oxyethylene bonds in a total amount of 30 mole % or more in its molecule to a urethanization reaction, said modified polyisocyanate being obtained by reacting a polyol (a) having the average number of functional groups in an amount of 2 or more with an organic polyisocyanate (b) in the presence of an allophanate-forming catalyst (c) comprising a zirconium carboxylate; and a process for producing the same. As compared with a conventional self-emulsifiable polyisocyanate, a self-emulsifiable polyisocyanate with high functionality of the present invention is equivalent or similar in water-dispersibility, lower in viscosity, more excellent in performance such as stain resistance, whereby it can be used as a base material or a curing agent for: a water-based paint, an aqueous adhesive, a sealing material, ink, an agent for treating fibers or glass fibers, a sizing agent, a stopping material, a primer, a consolidating agent, an anchor coating agent, various binders, or the like.
    • 5. 发明专利
    • NON-AQUEOUS LAMINATE ADHESIVE
    • MY136492A
    • 2008-10-31
    • MYPI20012649
    • 2001-06-06
    • NIPPON POLYURETHANE KOGYO KK
    • MORIKAWA YUKIHIROHIGASHIKUBO ICHIROYOSHIDA KOUJISASAHARA TOSHIAKI
    • A NON AQUEOUS LAMINATE ADHESIVE COMPRISING A TERTIARY AMINO GROUP-CONTANINING POLYURATE RESIN (A) OR A TERTIARY AMINO GROUP- AND CARBOXYL GROUP-CONTAINING POLYURETHANE RESIN (A) OR A TERTIARY AMINO GROUP- AND CARBOXYL GROUP-CONTAINING POLYURETHANE RESIN (B) AND A POLYISOCYANATE CURING AGENT. THE REISN (A) IS OBTAINED FROM (1) AN ACTIVE HYDROGEN GROUP-CONTAINING COMPOUND COMPRISING AT LEAST A TERTIARY AMINO GROUP- AND HYDROXYL GROUP-CONTAINING COMPOUND AND (3) AN ORGANIC POLYISOCYANATE, AND THE RESIN (B) IS OBTAINED FROM (2) AN ACTIVE HYDROGEN GROUP-CONTAINING COMPOUND COMPRISING AT LEAST A TERTIARY AMINO GROUP- AND HYDROXYL GROUP-CONTAINING COMPOUND AND A CARBOXYL GROUP- AND HYDROXYL GROUP-CONTAINING COMPOUND AND (3) AN ORGANIC POLYISOCYANATE. THE CONTENT OF THE TERTIARY AMINO GROUP IN THE RESIN (A), THE CONTENT OF THE TERTIARY AMINO GROUP IN THE RESIN (B), AND THE CARBOXYL GROUP IN THE RESIN (B) ARE EACH 0.001 TO 1 MMOL/G. THE NON-AQUEOUS LAMINATE ADHESIVE HAS A SHORT AGING TIME, A LONG POT LIFE AND GOOD STORAGE STABILITY, ALL OF WHICH HAVE BEEN UNACHIEVEABLE WITH CONVENTIONAL LAMINATE ADHESIVES.
    • 7. 发明专利
    • DE60212047D1
    • 2006-07-20
    • DE60212047
    • 2002-07-19
    • NIPPON POLYURETHANE KOGYO KK
    • KITA MOTOMUIKEMOTO MITSUSHIGESASAHARA TOSHIAKI
    • C08G18/28C08G18/32C08G18/22C08G18/70C08G18/78C08G18/79
    • A self-emulsifiable polyisocyanate with high functionality, having the average number of functional groups in 4.3 or more and a viscosity of 8,000 mPa . s (at 25 DEG C) or less, which is obtained by subjecting a modified polyisocyanate containing allophanate bonds and a poly(oxyalkylene)glycol monoalkyl ether (e) having oxyethylene bonds in a total amount of 30 mole % or more in its molecule to a urethanization reaction, said modified polyisocyanate being obtained by reacting a polyol (a) having the average number of functional groups in an amount of 2 or more with an organic polyisocyanate (b) in the presence of an allophanate-forming catalyst (c) comprising a zirconium carboxylate; and a process for producing the same. As compared with a conventional self-emulsifiable polyisocyanate, a self-emulsifiable polyisocyanate with high functionality of the present invention is equivalent or similar in water-dispersibility, lower in viscosity, more excellent in performance such as stain resistance, whereby it can be used as a base material or a curing agent for: a water-based paint, an aqueous adhesive, a sealing material, ink, an agent for treating fibers or glass fibers, a sizing agent, a stopping material, a primer, a consolidating agent, an anchor coating agent, various binders, or the like.