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    • 1. 发明专利
    • CERAMIC MATERIAL
    • JPS6461356A
    • 1989-03-08
    • JP21854987
    • 1987-09-01
    • NIPPON DENSO CONIPPON SOKEN
    • NUNOGAKI NAOYATOYAMA TETSUOINOKUCHI KAZUHIROITO NOBUE
    • C04B35/581C04B35/58C04B35/584C04B35/599F23Q7/00H05B3/10H05B3/48
    • PURPOSE:To obtain a ceramic material useful as a heater supporting material for glow plug, having excellent electrical insulating properties and variable coefficient of thermal expansion, by packing aggregated parts of a specific additive with a parent material such as Si3N4 and constituting a mutually separated sintered texture. CONSTITUTION:(a) A parent material is obtained from one or more materials selected from Si3N4, AlN and sialon. Then (b) an additive consisting of one or more materials selected from a carbide, silicide, nitride or boride of metal having a higher coefficient of thermal expansion than the parent material a is obtained. Then the component a is blended with the component b in the volume ratio of the component a and the component b of 5-25:95-75 and optionally >=3wt.% sintering auxiliary comprising alumina to give (c) mixed raw material powder. Then the component c is sintered by a hot press to form aggregated parts A having particles of the component b in an island state, to give a sintered texture wherein the aggregated parts are surrounded by the particles of the component a and a ceramic material having >=10 OMEGAcm specific resistance of sintered material is obtained.
    • 8. 发明专利
    • DE3734274C2
    • 1996-07-11
    • DE3734274
    • 1987-10-09
    • NIPPON DENSO CO
    • NUNOGAKI NAOCHIKATOYAMA TETSUOINOGUCHI KAZUHIROITO NOBUEI
    • C04B35/581C04B35/584C04B35/593C04B35/597F23Q7/00C04B35/58
    • An electrically insulating ceramic sintered body suitably used in a ceramic glow plug, for example, is formed by firing a mixed powder of 75 to 95 vol % of a basic material, 25 to 5 vol % of an additive and a sintering aid. The basic material is composed of at least one material selected from the group consisting of silicon nitride, aluminum nitride, and beta -sialon. The additive is composed of at least one material selected from the group consisting of silicide, carbide, nitride, and boride of metal, the additive having a thermal expansion coefficient larger than that of the basic material. And the sintering aid is composed of one of alumina in an amount of 3 to 50 wt % of the total amount of the basic material and the additive, and spinel in an amount of 2 to 15 wt % of the total amount of the basic material and the additive. The sintered body has the structure that particles of the additive cohere and the cohering additive particles are dispersed in particles of the basic material so as to be surrounded by the particles of the basic material and separated from adjacent cohering additive particles by the particles of the basic material. When the sintered body is used as a heater supporting member of the ceramic glow plug, the thermal expansion coefficient thereof can be controlled in accordance with that of the heater, and a high specific resistance of not less than 105 OMEGA cm can be obtained.
    • 9. 发明专利
    • DE3734274A1
    • 1988-04-21
    • DE3734274
    • 1987-10-09
    • NIPPON DENSO CO
    • NUNOGAKI NAOCHIKATOYAMA TETSUOINOGUCHI KAZUHIROITO NOBUEI
    • C04B35/581C04B35/584C04B35/593C04B35/597F23Q7/00C04B35/58C04B35/56
    • An electrically insulating ceramic sintered body suitably used in a ceramic glow plug, for example, is formed by firing a mixed powder of 75 to 95 vol % of a basic material, 25 to 5 vol % of an additive and a sintering aid. The basic material is composed of at least one material selected from the group consisting of silicon nitride, aluminum nitride, and beta -sialon. The additive is composed of at least one material selected from the group consisting of silicide, carbide, nitride, and boride of metal, the additive having a thermal expansion coefficient larger than that of the basic material. And the sintering aid is composed of one of alumina in an amount of 3 to 50 wt % of the total amount of the basic material and the additive, and spinel in an amount of 2 to 15 wt % of the total amount of the basic material and the additive. The sintered body has the structure that particles of the additive cohere and the cohering additive particles are dispersed in particles of the basic material so as to be surrounded by the particles of the basic material and separated from adjacent cohering additive particles by the particles of the basic material. When the sintered body is used as a heater supporting member of the ceramic glow plug, the thermal expansion coefficient thereof can be controlled in accordance with that of the heater, and a high specific resistance of not less than 105 OMEGA cm can be obtained.