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    • 3. 发明申请
    • Formation of CIGS Absorber Layer by Atomic Layer Deposition
    • 通过原子层沉积形成CIGS吸收层
    • WO2005081789A3
    • 2007-02-08
    • PCT/US2005003748
    • 2005-02-07
    • NANOSOLAR INCSAGER BRIAN MROSCHEISEN MARTIN RLEIDHOLM CRAIG
    • SAGER BRIAN MROSCHEISEN MARTIN RLEIDHOLM CRAIG
    • C23C16/00
    • An absorber layer may be formed on a substrate using atomic layer deposition reactions. An absorber layer containing elements of groups IB, IIIA and VIB may be formed by placing a substrate in a treatment chamber and performing atomic layer deposition of a group IB element and/or one or more group IIIA elements from separate sources onto a substrate to form a film. A group VIA element is then incorporated into the film and annealed to form the absorber layer. The absorber layer may be greater than about 25 nm thick. The substrate may be coiled into one or more coils in such a way that adjacent turns of the coils do not touch one another. The coiled substrate may be placed in a treatment chamber where substantially an entire surface of the one or more coiled substrates may be treated by an atomic layer deposition process. One or more group IB elements and/or one or more group IIIA elements may be deposited onto the substrate in a stoichiometrically controlled ratio by atomic layer deposition using one or more self limiting reactions.
    • 可以使用原子层沉积反应在衬底上形成吸收层。 包含IB,IIIA和VIB族元素的吸收层可以通过将基底放置在处理室中并且将IB族元素和/或一种或多种IIIA族元素从单独的源原子层沉积到基底上形成,以形成 一个电影。 然后将VIA族元素并入膜中并退火以形成吸收层。 吸收层可以大于约25nm厚。 衬底可以被卷绕成一个或多个线圈,使得线圈的相邻匝不彼此接触。 卷绕的基板可以放置在处理室中,其中可以通过原子层沉积工艺来处理一个或多个卷绕的基板的基本上整个表面。 可以通过使用一个或多个自限制反应的原子层沉积以化学计量控制的比例将一个或多个IB族元素和/或一个或多个IIIA族元素沉积到基底上。
    • 9. 发明申请
    • SOLAR CELL ABSORBER LAYER FORMED FROM METAL ION PRECURSORS
    • 从金属离子前驱体形成的太阳能电池吸收层
    • WO2008095146A2
    • 2008-08-07
    • PCT/US2008052730
    • 2008-01-31
    • VAN DUREN JEROEN K JROBINSON MATTHEW RSAGER BRIAN M
    • VAN DUREN JEROEN K JROBINSON MATTHEW RSAGER BRIAN M
    • H01L31/04
    • H01L31/03928H01L31/06H01L31/0749Y02E10/541Y02P70/521
    • Methods and devices are provided for forming an absorber layer. In one embodiment, a method is provided comprising of depositing a solution on a substrate to form a precursor layer. The solution comprises of at least one polar solvent, at least one binder, and at least one Group IB and/or IIIA hydroxide. The precursor layer is processed in one or more steps to form a photovoltaic absorber layer. In one embodiment, the absorber layer may be created by processing the precursor layer into a solid film and then thermally reacting the solid film in an atmosphere containing at least an element of Group VIA of the Periodic Table to form the photovoltaic absorber layer. Optionally, the absorber layer may be processed by thermal reaction of the precursor layer in an atmosphere containing at least an element of Group VIA of the Periodic Table to form the photovoltaic absorber layer.
    • 提供了用于形成吸收层的方法和装置。 在一个实施方案中,提供了一种方法,其包括在基底上沉积溶液以形成前体层。 溶液包含至少一种极性溶剂,至少一种粘合剂和至少一种IB族和/或IIIA型氢氧化物。 在一个或多个步骤中处理前体层以形成光伏吸收层。 在一个实施方案中,吸收层可以通过将前体层加工成固体膜,然后在至少含有元素周期表第VIA族元素的气氛中使固体膜热反应形成光伏吸收层来产生。 任选地,吸收层可以通过前体层在至少含有周期表第VIA族元素的气氛中进行热反应来加工,以形成光伏吸收层。
    • 10. 发明申请
    • THERMOELECTRIC STACK COATING FOR IMPROVES SOLAR PANEL FUNCTION
    • 用于改善太阳能面板功能的热电堆叠涂层
    • WO2012021872A2
    • 2012-02-16
    • PCT/US2011047686
    • 2011-08-12
    • SAGER BRIAN M
    • SAGER BRIAN M
    • H01L31/058H01L35/00
    • H01L35/30H01L31/052H02S10/10H02S40/42Y02E10/50
    • Methods and devices for increase power output from solar devices. In one embodiment, the technique enables the front hot solar panel surface to be cooled by attachment of a thermoelectric multilayer stack to the back solar panel surface. The thermoelectric stack cools the solar panel front surface by drawing heat from the front to the back of the panel. That heat is transformed into mechanical vibrations using an inverse Peltier effect and that mechanical energy then transformed into electrical energy using a piezoelectric effect. Power output is first increased by lower operating temperature on front, resulting in a higher power conversion efficiency for the photovoltaic effect taking place in the CIGS/CdS active layers or other thin films, then from an additional power output from secondary electrical energy created from mechanical arising from the temperature-gradient driven occurrence of the thermoelectric effect.
    • 用于增加太阳能设备功率输出的方法和装置。 在一个实施例中,该技术使得能够通过将热电多层堆叠附接到后太阳能电池板表面来冷却前部热太阳能电池板表面。 热电叠层通过从面板的前面到后面的热量来冷却太阳能电池板前表面。 使用反珀珀尔效应将热转化为机械振动,然后使用压电效应将机械能转化为电能。 功率输出首先由前面的较低工作温度升高,导致在CIGS / CdS有源层或其他薄膜中发生的光电效应的更高的功率转换效率,然后来自从机械产生的次级电能的附加功率输出 由温度梯度驱动发生的热电效应引起。