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    • 2. 发明申请
    • ENERGY EFFICIENT SYNTHESIS OF BORANES
    • 能量有效地合成硼
    • WO2007092601A3
    • 2007-11-22
    • PCT/US2007003511
    • 2007-02-08
    • LOS ALAMOS NAT SECURITY LLCTHORN DAVID LTUMAS WILLIAMSCHWARZ DANIEL EBURRELL ANTHONY K
    • THORN DAVID LTUMAS WILLIAMSCHWARZ DANIEL EBURRELL ANTHONY K
    • C08F4/44C08F4/00C08F4/14
    • C01B6/15C01B6/19C01B35/061
    • The reaction of halo-boron compounds (B-X compounds, compounds having one or more boron-halogen bonds) with silanes provides boranes (B-H compounds, compounds having one or more B-H bonds) and halosilanes. Inorganic hydrides, such as surface-bound silane hydrides (Si-H) react with B-X compounds to form B-H compounds and surface-bound halosilanes. The surface bound halosilanes are converted back to surface- bound silanes electrochemically. Halo-boron compounds react with stannanes (tin compounds having a Sn-H bond) to form boranes and halostannanes (tin compounds having a Sn-X bond). The halostannanes are converted back to stannanes electrochemically or by the thermolysis of Sn-formate compounds. When the halo-boron compound is BCI 3 , the B-H compound is B 2 H 6 , and where the reducing potential is provided electrochemically or by the thermolysis of formate.
    • 卤代硼化合物(B-X化合物,具有一个或多个硼 - 卤键的化合物)与硅烷的反应提供硼烷(B-H化合物,具有一个或多个B-H键的化合物)和卤代硅烷。 无机氢化物,例如表面结合的硅烷氢化物(Si-H)与B-X化合物反应以形成B-H化合物和表面结合的卤代硅烷。 表面结合的卤代硅烷通过电化学转化回表面结合的硅烷。 卤代硼化合物与锡烷(具有Sn-H键的锡化合物)反应形成硼烷和卤代烷(具有Sn-X键的锡化合物)。 卤代烷腈通过电化学方法或通过Sn-甲酸酯化合物的热解转化回锡烷。 当卤代硼化合物是BCI 3 N时,BH化合物是B 2 H 6 N,并且其中还原电位是电化学或由 甲酸盐的热解。