会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 4. 发明授权
    • Solid gel membrane separator in rechargeable electrochemical cells
    • 固体凝胶膜分离器在可充电电化学电池中
    • US06358651B1
    • 2002-03-19
    • US09482126
    • 2000-01-11
    • Muguo ChenLin-Feng LiTsepin Tsai
    • Muguo ChenLin-Feng LiTsepin Tsai
    • H01M216
    • B01D67/0006B01D69/10B01D69/141B01D2323/16B01D2323/34B01D2323/385B01D2325/26C08F257/02C08F283/00G02F1/1525H01B1/121H01B1/122H01M6/22H01M12/06H01M12/08Y02E60/128Y10T29/49108C08F220/54
    • Rechargeable electrochemical cells that employ a highly conductive polymer-based solid gel membrane separator disposed between the anode and charging electrode are disclosed. The separator comprises a support or substrate and a polymeric gel composition having an ionic species contained in a solution phase thereof. In preparing the separator, the ionic species is added to a monomer solution prior to polymerization and remains embedded in the resulting polymer gel after polymerization. The ionic species behaves like a liquid electrolyte, while at the same time, the polymer-based solid gel membrane provides a smooth impenetrable surface that allows the exchange of ions for both discharging and charging of the cell. Advantageously, the separator reduces dendrite penetration and prevents the diffusion of reaction products such as metal oxide to remaining parts of the cell. Furthermore, the measured ionic conductivity of the separator is much higher than those of prior art solid electrolytes or electroyte-polymer films. The disclosed rechargeable electrochemical cells include, for example, metal/air, Zn/Ni, Zn/MnO2, Zn/AgO, Fe/Ni, and lead-acid systems.
    • 公开了使用设置在阳极和充电电极之间的高导电性聚合物固体凝胶膜分离器的可充电电化学电池。 分离器包括载体或底物和在其溶液相中具有离子种类的聚合物凝胶组合物。 在制备隔膜时,在聚合之前将离子物质加入到单体溶液中,并在聚合后保持嵌入所得的聚合物凝胶中。 离子物质表现为液体电解质,而同时基于聚合物的固体凝胶膜提供了光滑的不透明表面,其允许用于电池的放电和充电的离子交换。 有利地,分离器减少枝晶渗透并防止反应产物如金属氧化物扩散到电池的剩余部分。 此外,分离器的测量离子电导率远高于现有技术的固体电解质或电解质聚合物膜。 所公开的可充电电化学电池包括例如金属/空气,Zn / Ni,Zn / MnO 2,Zn / AgO,Fe / Ni和铅酸体系。
    • 8. 发明申请
    • POLYMER MEMBRANE UTILIZED AS A SEPARATOR IN RECHARGEABLE ZINC CELLS
    • 聚合物膜可用作可再充电的锌电池中的分离器
    • US20100062342A1
    • 2010-03-11
    • US12207354
    • 2008-09-09
    • Lin-Feng Li
    • Lin-Feng Li
    • H01M2/16
    • H01M10/24H01M2/162H01M2/1653H01M2/166H01M2/1686H01M10/30H01M12/08Y02E60/128
    • A separator for zinc electrode-based cells that is effective in preventing dendrite growth in a zinc rechargeable cell is prepared as A standalone membrane, or as a composite membrane by impregnating the membrane into a nonwoven fabric. Interpenetrating polymer networks are employed by combining two different polymers. The two polymers penetrate each other on a molecular scale so that mechanical strength, water content and conductivity of the membranes can be effectively optimized. Since the water content of membrane can be optimized by introducing high water content polymers other than polyvinyl alcohol, wherein the diffusion of water from the separator membrane when the membrane contacts alkaline electrolyte solution can be largely reduced. Such membranes demonstrate excellent dendrite blocking capability in a practical zinc rechargeable cell.
    • 通过将膜浸入非织造布中,可以制备有效防止可再充电电池中的枝晶生长的锌电极基电池的隔膜作为独立膜,或作为复合膜。 通过组合两种不同的聚合物来使用互穿聚合物网络。 两种聚合物以分子尺度相互渗透,从而可以有效地优化膜的机械强度,水含量和导电性。 由于可以通过引入除聚乙烯醇以外的高含水量聚合物来优化膜的含水量,其中当膜接触碱性电解质溶液时,从隔离膜扩散水可以大大降低。 这种膜在实际的锌可充电电池中表现出优异的树枝状阻挡能力。