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1. 发明申请

US20130085244A1 Use of Temperature and Ethylene Partial Pressure to Introduce Long Chain Branching in High Density Polyethylene 有权
标题翻译：使用温度和乙烯部分压力在高密度聚乙烯中引入长链分支
公开(公告)号：US20130085244A1
公开(公告)日：2013-04-04
申请号：US13252469
申请日：2011-10-04
申请人： Mosha H. ZHAO , Cesar A. Garcia-Franco , Patrick Brant
发明人： Mosha H. ZHAO , Cesar A. Garcia-Franco , Patrick Brant
IPC分类号： C08F110/02 , C08F2/34
CPC分类号： C08F10/02 , C08F4/6592 , C08F110/02 , C08F210/02 , C08F2500/07 , C08F2500/08 , C08F2500/12 , C08F2500/17
摘要： The invention describes the preparation of long chain branching in high density polyethylene by using metallocene catalysts in the presence of ethylene.
摘要翻译：本发明描述了在乙烯存在下使用茂金属催化剂制备高密度聚乙烯中的长支链。

2. 发明授权

US08796409B2 Use of temperature and ethylene partial pressure to introduce long chain branching in high density polyethylene 有权
标题翻译：使用温度和乙烯分压在高密度聚乙烯中引入长链支化
公开(公告)号：US08796409B2
公开(公告)日：2014-08-05
申请号：US13252469
申请日：2011-10-04
申请人： Mosha H. Zhao , Cesar A. Garcia-Franco , Patrick Brant
发明人： Mosha H. Zhao , Cesar A. Garcia-Franco , Patrick Brant
IPC分类号： C08F110/02 , C08F10/02 , C08F4/6592 , C08F210/02
CPC分类号： C08F10/02 , C08F4/6592 , C08F110/02 , C08F210/02 , C08F2500/07 , C08F2500/08 , C08F2500/12 , C08F2500/17
摘要： The invention describes the preparation of long chain branching in high density polyethylene by using metallocene catalysts in the presence of ethylene.
摘要翻译：本发明描述了在乙烯存在下使用茂金属催化剂制备高密度聚乙烯中的长支链。

3. 发明授权

US07427506B2 High throughput property testing of olefin copolymers using rheological determinations 失效
标题翻译：使用流变学测定的烯烃共聚物的高通量性能测试
公开(公告)号：US07427506B2
公开(公告)日：2008-09-23
申请号：US10823460
申请日：2004-04-13
申请人： Cesar A. Garcia-Franco , David J. Lohse , Bruce A. Harrington , Robert Jay Wittenbrink
发明人： Cesar A. Garcia-Franco , David J. Lohse , Bruce A. Harrington , Robert Jay Wittenbrink
IPC分类号： G01N37/00 , G01N1/00 , B01L9/00
CPC分类号： G01N33/445 , Y10T436/13 , Y10T436/25
摘要： A high throughput method to determine an amount of a comonomer in a copolymer sample of a copolymer system comprises the steps of providing a plurality of copolymer samples; creating an array of the copolymer samples; measuring a sample complex modulus of each of the copolymer samples at a comparison phase angle; and determining the amount of a comonomer in the copolymer sample by comparing the sample complex modulus to a calibration curve, wherein the calibration curve relates a concentration of the comonomer in the copolymer sample to a complex moduli of the copolymer sample determined at the comparison phase angle. A method of determining the amount of a comonomer in both a single copolymer sample, and in a high throughput scheme using the crossover modulus is also disclosed.
摘要翻译：用于确定共聚物体系的共聚物样品中共聚单体的量的高通量方法包括提供多个共聚物样品的步骤; 产生共聚物样品阵列; 以比较相位角测量每个共聚物样品的样品复数模量; 并且通过将样品复合物模量与校准曲线进行比较来确定共聚物样品中的共聚单体的量，其中校准曲线将共聚物样品中的共聚单体的浓度与在比较相位角处确定的共聚物样品的复数模量相关。还公开了在单一共聚物样品中以及使用交叉模量的高通量方案中测定共聚单体的量的方法。

4. 发明授权

US08288480B2 In-reactor polymer blends 失效
标题翻译：反应器内聚合物共混物
公开(公告)号：US08288480B2
公开(公告)日：2012-10-16
申请号：US12638895
申请日：2009-12-15
申请人： Peijun Jiang , Kevin R. Squire , Charles J. Ruff , Cesar A. Garcia-Franco
发明人： Peijun Jiang , Kevin R. Squire , Charles J. Ruff , Cesar A. Garcia-Franco
IPC分类号： C08F8/00 , C08L23/00 , C08L23/10
CPC分类号： C08F210/18 , C08L23/145 , C08L2205/02 , C08L2205/025 , C08L2308/00 , C08F2/00 , C08F2/001 , C08L2666/06 , C08F210/06 , C08F232/00 , C08F2500/25 , C08F2500/09 , C08F2500/17 , C08F2500/15 , C08F2500/03 , C08F2500/20
摘要： This invention relates to in-reactor polymer blends comprising at least 60 mole % of propylene and from 0.01 to 10 mole % of at least one diene selected from the group of C6 to C12 α,ω-diene, norbornadiene, vinyl norbornene and mixtures thereof with the balance being ethylene. The blend comprises first and second polymers having different crystallinities and or different Tg's.
摘要翻译：本发明涉及包含至少60摩尔％丙烯和0.01至10摩尔％至少一种选自C6至C12α，ω-二烯，降冰片二烯，乙烯基降冰片烯及其混合物中的至少一种二烯烃的反应器内聚合物共混物其余为乙烯。共混物包含具有不同结晶度和/或不同Tg的第一和第二聚合物。

5. 发明申请

US20100152390A1 Heterogeneous In-Reactor Polymer Blends 有权
标题翻译：非均相反应器聚合物共混物
公开(公告)号：US20100152390A1
公开(公告)日：2010-06-17
申请号：US12638861
申请日：2009-12-15
申请人： Carlos U. De Gracia , Kevin R. Squire , Peijun Jiang , Armenag H. Dekmezian , Beverly J. Poole , Cesar A. Garcia-Franco
发明人： Carlos U. De Gracia , Kevin R. Squire , Peijun Jiang , Armenag H. Dekmezian , Beverly J. Poole , Cesar A. Garcia-Franco
IPC分类号： C08L23/06
CPC分类号： C08L23/16 , C08L23/12 , C08L2314/06 , C08L2666/06
摘要： An in-reactor polymer blend comprises (a) a propylene-containing first polymer; and (b) an ethylene-containing second polymer such that the polymer blend comprises between about 50 wt % and about 80 wt % units derived from ethylene and between about 50 wt % and about 20 wt % units derived from propylene. The blend is substantially free of dienes and the content of ethylene in the second polymer in the form of ethylene-ethylene-ethylene triads is at least 40%. The second polymer contains at least 0.1 branch having 8 or more carbon atoms per 10,000 carbons. In addition, the blend has a strain hardening index of at least 1.8, a shear thinning slope in the plot of log(dynamic viscosity) versus log(frequency) of less than −0.2 and exhibits at least two peaks when subjected to Differential Scanning Calorimetry (first melt) corresponding to a first melting point of at least 150° C. and a second melting point of at least 40° C. such that the difference between the first and second melting temperatures is at least 20° C.
摘要翻译：反应器内聚合物共混物包含（a）含丙烯的第一聚合物; 和（b）含乙烯的第二聚合物，使得聚合物共混物包含衍生自乙烯的约50重量％至约80重量％的单元和衍生自丙烯的约50重量％至约20重量％的单元。共混物基本上不含二烯，乙烯 - 乙烯 - 乙烯三单元组形式的第二聚合物中的乙烯含量至少为40％。第二聚合物含有至少0.1个分支，每10,000个碳原子具有8个或更多个碳原子。此外，共混物的应变硬化指数为至少1.8，对数（动态粘度）对log（频率）的曲线图中的剪切变稀斜率小于-0.2，并且当进行差示扫描量热法时显示出至少两个峰（第一熔体），其对应于至少150℃的第一熔点和至少40℃的第二熔点，使得第一和第二熔融温度之间的差异为至少20℃。

6. 发明申请

US20100152388A1 In-Reactor Polymer Blends 失效
标题翻译：反应器聚合物共混物
公开(公告)号：US20100152388A1
公开(公告)日：2010-06-17
申请号：US12638895
申请日：2009-12-15
申请人： Peijun Jiang , Kevin R. Squire , Charles J. Ruff , Cesar A. Garcia-Franco
发明人： Peijun Jiang , Kevin R. Squire , Charles J. Ruff , Cesar A. Garcia-Franco
IPC分类号： C08L45/00 , C08L9/00
CPC分类号： C08F210/18 , C08L23/145 , C08L2205/02 , C08L2205/025 , C08L2308/00 , C08F2/00 , C08F2/001 , C08L2666/06 , C08F210/06 , C08F232/00 , C08F2500/25 , C08F2500/09 , C08F2500/17 , C08F2500/15 , C08F2500/03 , C08F2500/20
摘要： This invention relates to in-reactor polymer blends comprising at least 60 mole % of propylene and from 0.01 to 10 mole % of at least one diene selected from the group of C6 to C12 α,ω-diene, norbornadiene, vinyl norbornene and mixtures thereof with the balance being ethylene. The blend comprises first and second polymers having different crystallinities and or different Tg's.
摘要翻译：本发明涉及包含至少60摩尔％丙烯和0.01至10摩尔％至少一种选自C6至C12α，ω-二烯，降冰片二烯，乙烯基降冰片烯及其混合物中的至少一种二烯烃的反应器内聚合物共混物其余为乙烯。共混物包含具有不同结晶度和/或不同Tg的第一和第二聚合物。

7. 发明授权

US06355757B2 Processing olefin copolymers 失效
公开(公告)号：US06355757B2
公开(公告)日：2002-03-12
申请号：US09020270
申请日：1998-02-06
申请人： Cesar A. Garcia-Franco , David J. Lohse , Robert A. Mendelson , Lewis J. Fetters , Scott T. Milner , Nikos Hadjichristidis , David W. Mead
发明人： Cesar A. Garcia-Franco , David J. Lohse , Robert A. Mendelson , Lewis J. Fetters , Scott T. Milner , Nikos Hadjichristidis , David W. Mead
IPC分类号： C08F21000
CPC分类号： C08L23/0815 , C08F110/02 , C08F255/00 , C08F255/02 , C08F257/02 , C08F279/02 , C08F290/042 , C08F290/044 , C08F290/06 , C08F297/08 , C08L23/02 , C08L51/06 , C08L55/00 , C08L55/005 , C08L2666/02 , C08L2666/24 , C08L2666/04 , C08F2500/03 , C08F2500/09 , C08F2500/12
摘要： The invention is directed to essentially saturated hydrocarbon polymer composition comprising essentially saturated hydrocarbon polymers having A) a backbone chain, B) a plurality of essentially hydrocarbyl sidechains connected to A), said sidechains each having a number-average molecular weight of from 2500 Daltons to 125,000 Daltons and a MWD by SEC of 1.0-3.5; and having A) a Newtonian limiting viscosity (&eegr;0) at 190° C. at least 50% greater than that of a linear olefinic polymer of the same chemical composition and weight average molecular weight, preferably at least twice as great as that of said linear polymer, B) a ratio of the rubbery plateau modulus at 190° C. to that of a linear polymer of the same chemical composition less than 0.5, preferably

8. 发明授权

US09068034B2 In-reactor polymer blends 有权
标题翻译：反应器内聚合物共混物
公开(公告)号：US09068034B2
公开(公告)日：2015-06-30
申请号：US13609593
申请日：2012-09-11
申请人： Kevin R. Squire , Charles J. Ruff , Cesar A. Garcia-Franco , Peijun Jiang
发明人： Kevin R. Squire , Charles J. Ruff , Cesar A. Garcia-Franco , Peijun Jiang
IPC分类号： C08F8/00 , C08L23/04 , C08L23/10 , C08F210/18 , C08L23/14
CPC分类号： C08F210/18 , C08L23/145 , C08L2205/02 , C08L2205/025 , C08L2308/00 , C08F2/00 , C08F2/001 , C08L2666/06 , C08F210/06 , C08F232/00 , C08F2500/25 , C08F2500/09 , C08F2500/17 , C08F2500/15 , C08F2500/03 , C08F2500/20
摘要： This invention relates to in-reactor polymer blends comprising at least 60 mole % of propylene and from 0.01 to 10 mole % of at least one diene selected from the group of C6 to C12 α,ω-diene, norbornadiene, vinyl norbornene and mixtures thereof with the balance being ethylene. The blend comprises first and second polymers having different crystallinities and or different Tg's.
摘要翻译：本发明涉及包含至少60摩尔％丙烯和0.01至10摩尔％至少一种选自C6至C12α，ω-二烯，降冰片二烯，乙烯基降冰片烯及其混合物中的至少一种二烯烃的反应器内聚合物共混物其余为乙烯。共混物包含具有不同结晶度和/或不同Tg的第一和第二聚合物。

9. 发明授权

US08835577B2 Catalyst systems having a tailored hydrogen response 有权
标题翻译：具有定制氢气响应的催化剂体系
公开(公告)号：US08835577B2
公开(公告)日：2014-09-16
申请号：US13321736
申请日：2010-05-14
申请人： Francis C. Rix , Sun-Chueh Kao , Rainer Kolb , Dongming Li , Cesar A. Garcia-Franco
发明人： Francis C. Rix , Sun-Chueh Kao , Rainer Kolb , Dongming Li , Cesar A. Garcia-Franco
IPC分类号： C08F4/653 , C08F4/642 , C08F4/6592 , C08F10/00 , C08L23/00 , C08F210/16 , C08F4/659
CPC分类号： C08F4/65904 , C08F4/659 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F210/16 , Y10S526/943 , C08F2/38 , C08F210/14 , C08F2500/05 , C08F4/64193 , C08F4/64148 , C08L23/00
摘要： A polymerization catalyst system and polymerization processes using the catalyst systems are disclosed. The polymerization catalyst systems may include a) a first catalyst compound, and b) a second catalyst compound, wherein the first catalyst compound comprises a biphenyl phenol compound having essentially no hydrogen response.
摘要翻译：公开了使用催化剂体系的聚合催化剂体系和聚合方法。聚合催化剂体系可以包括a）第一催化剂化合物和b）第二催化剂化合物，其中第一催化剂化合物包含基本上没有氢响应的联苯酚化合物。

10. 发明授权

US08586497B2 Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom 有权
标题翻译：聚合催化剂，制造方法，使用方法和由其制成的聚烯烃产品
公开(公告)号：US08586497B2
公开(公告)日：2013-11-19
申请号：US12741137
申请日：2008-11-12
申请人： Rainer Kolb , Dongming Li , Francis C. Rix , Cesar A. Garcia-Franco
发明人： Rainer Kolb , Dongming Li , Francis C. Rix , Cesar A. Garcia-Franco
IPC分类号： C08F4/64 , C08F4/642 , C08F4/653 , C08F4/655 , C08F210/02
CPC分类号： C08F10/00 , C07F7/003 , C07F17/00 , C08F4/65912 , C08F4/65916 , C08F210/16 , C08F2420/02 , Y10S526/943 , C08F4/65925 , C08F2500/18 , C08F2500/12 , C08F2500/24 , C08F4/64058 , C08F4/64193 , C08F4/65904 , C08F4/64148 , C08F4/64144 , C08F4/64048 , C08F4/6592
摘要： Olefin polymerization catalyst systems including a high molecular weight catalyst compound and a low molecular weight catalyst compound, and methods of making same are provided. High molecular weight catalysts include metallocene catalysts and low molecular weight catalysts include non-metallocene compounds including biphenyl phenol compounds. Generally catalyst systems may include less than about 5.0 mol % of the high molecular weight catalyst compound relative to said low molecular weight catalyst. Methods for olefin polymerization including the aforementioned catalyst systems, and polyolefins and products made therefrom.
摘要翻译：提供了包含高分子量催化剂化合物和低分子量催化剂化合物的烯烃聚合催化剂体系及其制备方法。高分子量催化剂包括金属茂催化剂，低分子量催化剂包括非茂金属化合物，包括联苯酚化合物。通常催化剂体系可以包括相对于所述低分子量催化剂的小于约5.0摩尔％的高分子量催化剂化合物。包括上述催化剂体系的烯烃聚合方法以及由其制备的聚烯烃和产物。

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