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    • 2. 发明授权
    • Method for providing a coating layer of silicon carbide on substrate
surface
    • 在基板表面上提供碳化硅涂层的方法
    • US4560589A
    • 1985-12-24
    • US533649
    • 1983-09-19
    • Morinobu EndouMinoru TakamizawaTatsuhiko HonguTaishi Kobayashi
    • Morinobu EndouMinoru TakamizawaTatsuhiko HonguTaishi Kobayashi
    • C04B41/50C04B41/87C23C16/32D01F11/12D06M11/00
    • C04B41/009C04B41/5059C04B41/87C23C16/325D01F11/126Y10S438/931
    • The invention provides a method for providing a highly protective coating layer of silicon carbide on to the surface of a substrate. The method comprises pyrolyzing the vapor of an organosilicon compound having at least one hydrogen atom directly bonded to the silicon atom in a molecule but having no halogen or oxygen atom directly bonded to the silicon atom at a temperature of 700.degree. to 1400.degree. C. in contact with the substrate surface to deposit silicon carbide thereon. In particular, the method is useful to form a sheath-and-core structure composed of the core of carbon filament and the coating layer of silicon carbide so that the carbon fibers are imparted with greatly improved resistance against oxidation and chemicals including molten metals when the carbon fibers are used as a reinforcing material of a fiber-reinforced metal composite as well as with improved affinity with molten resins and metals which is also an advantageous property as a reinforcing material for such matrix materials.
    • 本发明提供了一种在基材表面上提供碳化硅高保护性涂层的方法。 该方法包括将分子中具有至少一个与硅原子键合的至少一个氢原子的有机硅化合物的蒸气热分解,但在700℃至1400℃的温度下直接与硅原子键合的卤原子或氧原子, 与基底表面接触以在其上沉积碳化硅。 特别地,该方法可用于形成由碳丝芯和碳化硅的涂层组成的皮 - 芯结构,从而使得碳纤维在氧化时具有极大的改善的抗性和包括熔融金属在内的化学物质 碳纤维用作纤维增强金属复合材料的增强材料,并且与熔融树脂和金属具有改进的亲和性,这也是作为这种基体材料的增强材料的有利特性。
    • 3. 发明授权
    • Method for the preparation of silicon carbide fibers
    • 碳化硅纤维的制备方法
    • US4492681A
    • 1985-01-08
    • US505250
    • 1983-06-17
    • Morinobu EndouMinoru TakamizawaTatsuhiko HonguTaishi Kobayashi
    • Morinobu EndouMinoru TakamizawaTatsuhiko HonguTaishi Kobayashi
    • C01B31/36C04B35/571C30B25/00D01F9/10
    • D01F9/10C04B35/571C30B25/005C30B29/36
    • The invention provides a novel method for the preparation of silicon carbide fibers capable of being performed at a relatively low temperature and giving fibers of relatively large lengths by the vapor-phase pyrolysis of an organosilicon compound on a substrate. The method comprises contacting an organosilicon compound, which should have no halogen and oxygen atoms directly bonded to the silicon atoms and have preferably at least one hydrogen atom directly bonded to the silicon atom in a molecule, with a finely divided powder of a metal or a compound of a metal, such as copper, silver, vanadium, niobium, tantalum, iron, cobalt, nickel, palladium and platinum, at a temperature of 700.degree. to 1450.degree. C. so that the powder serves simultaneously as a catalyst and nucleus for the growth of the silicon carbide fibers thereon formed by the pyrolysis of the organosilicon compound. When the organosilicon compound is deficient of the carbon content relative to the silicon so that free silicon may be formed by the pyrolysis, admixing of a hydrocarbon to the feed of the organosilicon compound can solve the problem.
    • 本发明提供了一种制备能够在较低温度下进行的碳化硅纤维的新方法,并且通过基底上的有机硅化合物的气相热解产生相当长的纤维。 该方法包括将不具有卤素和氧原子的有机硅化合物直接键合到硅原子上,并且优选具有至少一个与分子中的硅原子键合的至少一个氢原子,与金属或 金属的化合物,例如铜,银,钒,铌,钽,铁,钴,镍,钯和铂,在700°至1450℃的温度下,使粉末同时作为催化剂和核 通过有机硅化合物的热解形成的碳化硅纤维的生长。 当有机硅化合物相对于硅缺乏碳含量时,可以通过热解形成游离硅,将烃与有机硅化合物的进料混合可以解决问题。