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1. 发明授权

US6077626A Alkaline storage battery and method for charging battery 有权
标题翻译：碱性蓄电池及蓄电池充电方法
公开(公告)号：US6077626A
公开(公告)日：2000-06-20
申请号：US284860
申请日：1999-04-22
申请人： Mitsuzou Nogami , Mutsumi Yano , Mitsunori Tokuda , Syuichi Suzuki , Shin Fujitani , Reizo Maeda , Ikuo Yonezu , Koji Nishio
发明人： Mitsuzou Nogami , Mutsumi Yano , Mitsunori Tokuda , Syuichi Suzuki , Shin Fujitani , Reizo Maeda , Ikuo Yonezu , Koji Nishio
IPC分类号： H01M4/52 , H01M10/24 , H01M10/44 , H01M4/32
CPC分类号： H01M10/44 , H01M10/24 , H01M4/52 , Y02E60/124
摘要： In an alkali storage battery comprising a positive electrode, a negative electrode and an alkali electrolyte in a battery can, .alpha.-nickel hydroxide containing manganese is used as a cathode active material for the positive electrode, and the difference between a charging potential and an oxygen gas evolution potential at the positive electrode is increased, to suppress oxygen gas evolution during the charging, and the volume percentage of the cathode active material and an anode active material is set to not less than 75% in the battery can, to obtain a large battery capacity.
摘要翻译： PCT No.PCT / JP97 / 04774 Sec。 371日期1999年4月22日 102（e）1999年4月22日PCT 1997年12月22日PCT公布。第WO98 / 31063号公报日期：1998年7月16日在包含电池罐中的正极，负极和碱性电解质的碱性蓄电池中，使用含有锰的氢氧化镍含量作为正极的正极活性物质，充电电位和正极的氧气放出电位增加，以抑制充电期间的氧气放出，并且阴极活性物质和负极活性物质的体积百分比在电池罐中设定为不小于75％，以获得较大的电池容量。

2. 发明授权

US06235428B1 Enclosed alkali storage battery 有权
标题翻译：封闭式碱性蓄电池
公开(公告)号：US06235428B1
公开(公告)日：2001-05-22
申请号：US09331969
申请日：1999-06-30
申请人： Mutsumi Yano , Syuichi Suzuki , Mitsunori Tokuda , Mitsuzou Nogami , Mamoru Kimoto , Shin Fujitani , Koji Nishio
发明人： Mutsumi Yano , Syuichi Suzuki , Mitsunori Tokuda , Mitsuzou Nogami , Mamoru Kimoto , Shin Fujitani , Koji Nishio
IPC分类号： H01M432
CPC分类号： H01M4/362 , H01M4/366 , H01M4/50 , H01M4/52 , H01M10/34 , H01M2006/5094
摘要： A sealed alkaline storage battery using, as a positive electrode active material, nickel oxyhydroxide including Mn as a solid-solution element and having a &ggr; ratio of 65 through 100%; a sealed alkaline storage battery using, as a positive electrode active material, nickel oxyhydroxide including as an additive or coated with a rare earth element and/or a rare earth compound in a ratio measured based on the rare earth element of 0.05 through 5 wt %; and a sealed alkaline storage battery including, as a positive electrode active material, nickel oxyhydroxide having a half-width of a peak in a lattice plane (003) in an X-ray diffraction pattern of 0.8° or more. The pressure within the battery is not largely increased for a long period of charge-discharge cycles, and hence, the electrolyte hardly leaks.
摘要翻译：使用包含Mn作为固溶体元素并具有65至100％的γ比的正极活性材料的氢氧化正镍的密封碱性蓄电池; 使用包含作为添加剂的氢氧化镍或以稀土元素和/或稀土类化合物为基础的以0.05〜5重量％的稀土元素测定的比例包含稀土元素和/或稀土类化合物作为正极活性物质的密封型碱性蓄电池， ; 以及密封的碱性蓄电池，其包括在0.8°以上的X射线衍射图案中，作为正极活性物质，具有晶格面（003）中的峰的半值宽度的氢氧化正镍。电池中的压力在长时间的充放电循环中不会大幅度增加，因此电解质几乎不泄漏。

3. 发明授权

US06566008B2 Sealed alkaline storage battery 有权
标题翻译：密封碱性蓄电池
公开(公告)号：US06566008B2
公开(公告)日：2003-05-20
申请号：US09794326
申请日：2001-02-28
申请人： Mutsumi Yano , Syuichi Suzuki , Mitsunori Tokuda , Mitsuzou Nogami , Mamoru Kimoto , Shin Fujitani , Koji Nishio
发明人： Mutsumi Yano , Syuichi Suzuki , Mitsunori Tokuda , Mitsuzou Nogami , Mamoru Kimoto , Shin Fujitani , Koji Nishio
IPC分类号： H01M432
CPC分类号： H01M4/362 , H01M4/366 , H01M4/50 , H01M4/52 , H01M10/34 , H01M2006/5094
摘要： A sealed alkaline storage battery using, as a positive electrode active material, nickel oxyhydroxide including Mn as a solid-solution element and having a &ggr; ratio of 65 through 100%; a sealed alkaline storage battery using, as a positive electrode active material, nickel oxyhydroxide including as an additive or coated with a rare earth element and/or a rare earth compound in a ratio measured based on the rare earth element of 0.05 through 5 wt %; and a sealed alkaline storage battery including, as a positive electrode active material, nickel oxyhydroxide having a half-width of a peak in a lattice plane (003) in an X-ray diffraction pattern of 0.8° or more. The pressure within the battery is not largely increased for a long period of charge-discharge cycles, and hence, the electrolyte hardly leaks.
摘要翻译：使用包含Mn作为固溶体元素并具有65至100％的γ比的正极活性材料的氢氧化正镍的密封碱性蓄电池; 使用包含作为添加剂的氢氧化镍或以稀土元素和/或稀土类化合物为基础的以0.05〜5重量％的稀土元素测定的比例包含稀土元素和/或稀土类化合物作为正极活性物质的密封型碱性蓄电池， ; 以及密封的碱性蓄电池，其包括在0.8°以上的X射线衍射图案中，作为正极活性物质，具有晶格面（003）中的峰的半值宽度的氢氧化正镍。电池中的压力在长时间的充放电循环中不会大幅度增加，因此电解质几乎不泄漏。

4. 发明授权

US06174624B1 Positive-electrode active material for alkaline secondary battery and an alkaline secondary battery 有权
标题翻译：碱性二次电池用正极活性物质和碱性二次电池
公开(公告)号：US06174624B1
公开(公告)日：2001-01-16
申请号：US09267399
申请日：1999-03-15
申请人： Mutsumi Yano , Mitsunori Tokuda , Mitsuzou Nogami , Shin Fujitani , Koji Nishio
发明人： Mutsumi Yano , Mitsunori Tokuda , Mitsuzou Nogami , Shin Fujitani , Koji Nishio
IPC分类号： H01M458
CPC分类号： H01M6/085 , H01M4/364 , H01M4/48 , H01M4/50 , H01M4/52 , H01M10/283
摘要： A positive-electrode active material for alkaline secondary battery according to the invention has an &agr;-Ni(OH)2 crystal structure which incorporates therein manganese and a trivalent metal other than manganese.
摘要翻译：根据本发明的碱性二次电池用正极活性物质具有含有锰和锰以外的三价金属的α-Ni（OH）2结晶结构。

5. 发明授权

US06200700B1 Alkaline secondary battery 失效
标题翻译：碱性二次电池
公开(公告)号：US06200700B1
公开(公告)日：2001-03-13
申请号：US09272399
申请日：1999-03-19
申请人： Mutsumi Yano , Mitsunori Tokuda , Mitsuzou Nogami , Shin Fujitani , Koji Nishio
发明人： Mutsumi Yano , Mitsunori Tokuda , Mitsuzou Nogami , Shin Fujitani , Koji Nishio
IPC分类号： H01M202
CPC分类号： H01M6/085 , H01M4/42 , H01M4/50 , H01M4/52 , H01M4/661 , H01M10/283 , H01M10/30
摘要： The present invention is directed to an alkaline secondary battery comprising a positive electrode, a zinc based negative electrode, and an alkaline electrolyte solution, wherein the positive electrode includes a central cavity for receiving the zinc based negative electrode, and the negative electrode includes a central cavity for holding the alkaline electrolyte solution. The battery is arranged such that the positive electrode presents a smaller capacity than the negative electrode at least in an initial charge/discharge period.
摘要翻译：本发明涉及一种包括正极，锌基负极和碱性电解质溶液的碱性二次电池，其中所述正极包括用于接收所述锌基负极的中心腔，所述负极包括中心保持碱性电解液的腔体。电池被布置成使得正电极至少在初始充电/放电时段中具有比负极更小的容量。

6. 发明授权

US06190801B1 Sealed alkaline-zinc storage battery 有权
标题翻译：密封碱性锌蓄电池
公开(公告)号：US06190801B1
公开(公告)日：2001-02-20
申请号：US09274808
申请日：1999-03-23
申请人： Mitsunori Tokuda , Mutsumi Yano , Mitsuzou Nogami , Shin Fujitani , Koji Nishio
发明人： Mitsunori Tokuda , Mutsumi Yano , Mitsuzou Nogami , Shin Fujitani , Koji Nishio
IPC分类号： H01M442
CPC分类号： H01M4/244 , H01M4/0497 , H01M4/26 , H01M4/32 , H01M4/48 , H01M4/52 , H01M10/24 , H01M10/283 , H01M10/30 , H01M2010/4292 , Y02E60/124
摘要： The invention provides a sealed alkaline-zinc storage battery including a tubular positive electrode containing, as an active material, a material having reversibility in a charge-discharge reaction; a separator; a negative electrode disposed within the tubular positive electrode with the separator sandwiched therebetween; and an alkaline electrolyte, in which the positive electrode has a capacity smaller than a capacity of the negative electrode at least in initial charge-discharge cycles, and the amounts of an uncharged active material and zinc to be packed in the negative electrode in manufacture of the sealed alkaline-zinc storage battery are set so that a theoretical capacity P of the uncharged active material existing in the negative electrode can be 0.3 through 1.8 times as large as a battery capacity in a completely charged state in the initial charge-discharge cycles, and that a theoretical capacity Q of zinc existing in the negative electrode can be 0.6 through 2.5 times as large as the battery capacity in a completely discharged state in the initial charge-discharge cycles. Thus, a sealed alkaline-zinc storage battery with high charge-discharge cycle performance is obtained.
摘要翻译：本发明提供一种密封的碱锌蓄电池，其包括管状正电极，其包含作为活性材料的充电 - 放电反应具有可逆性的材料; 分隔符设置在管状正极内的负极，分隔件夹在其间; 和碱性电解质，其中至少在初始充放电循环中，正极具有小于负极容量的容量，以及在制造中要包装在负极中的不带电的活性材料和锌的量密封的碱性锌蓄电池被设定为使得存在于负极中的不带电活性物质的理论容量P在初始充放电循环中可以是完全充电状态下的电池容量的0.3〜1.8倍，在初始充放电循环中，存在于负极中的锌的理论容量Q可以是完全放电状态下的电池容量的0.6〜2.5倍。因此，获得具有高充放电循环性能的密封的碱锌蓄电池。

7. 发明授权

US06265105B1 Sealed, alkaline-zinc storage battery 有权
标题翻译：密封，碱锌蓄电池
公开(公告)号：US06265105B1
公开(公告)日：2001-07-24
申请号：US09329603
申请日：1999-06-10
申请人： Mitsunori Tokuda , Mutsumi Yano , Mitsuzou Nogami , Shin Fujitani , Koji Nishio
发明人： Mitsunori Tokuda , Mutsumi Yano , Mitsuzou Nogami , Shin Fujitani , Koji Nishio
IPC分类号： H01M604
CPC分类号： H01M10/26 , H01M4/244 , H01M4/32 , H01M10/34 , H01M2004/023 , Y02E60/124
摘要： A sealed alkaline-zinc storage battery includes a battery can, a hollow positive electrode disposed within the battery can in electrical contact therewith and containing a positive active material including nickle hydroxide, a negative electrode disposed inwardly of the positive electrode and containing a negative active material including zinc, a separator disposed between the positive and negative electrodes, a negative current collector inserted into the negative electrode, and an alkaline electrolyte filled in the battery can and impregnated into the positive electrode, negative electrode and separator. The positive electrode, negative electrode, separator, negative current collector and electrolyte together account for at least 75% of an internal volume of the battery can. The alkaline electrolyte is in the 30 to 45 mass % concentration range and has a total water content in the range of 0.5 to 0.9 g for each theoretical capacity of the negative electrode expressed as 1 Ah (ampere-hour).
摘要翻译：密封的碱性锌蓄电池包括电池罐，设置在与其接触的电池壳内的中空正电极，并且包含含有氢氧化镍的正极活性物质，设置在正极内侧的负极并含有负极活性物质包括锌，设置在正极和负极之间的隔膜，插入负极的负极集电体和填充在电池壳中的碱性电解质，并浸渍在正极，负极和隔板中。正极，负极，隔膜，负极集电器和电解质一起占电池罐内部体积的至少75％。碱性电解质的浓度范围为30〜45质量％，对于负极的理论容量为1 Ah（安培小时），总含水量为0.5〜0.9g。

8. 发明授权

US6007946A Non-sintered nickel electrode for alkaline storage battery, alkaline storage battery including the same, and method for production of non-sintered nickel electrode for alkaline storage battery 失效
标题翻译：碱性蓄电池用非烧结镍电极，含碱蓄电池的碱性蓄电池及碱性蓄电池用非烧结镍电极的制造方法
公开(公告)号：US6007946A
公开(公告)日：1999-12-28
申请号：US881146
申请日：1997-06-24
申请人： Mutsumi Yano , Mitsuzo Nogami , Katsuhiko Shinyama , Kousuke Satoguchi , Mitsunori Tokuda , Ikuo Yonezu , Koji Nishio , Masao Inoue , Shin Fujitani
发明人： Mutsumi Yano , Mitsuzo Nogami , Katsuhiko Shinyama , Kousuke Satoguchi , Mitsunori Tokuda , Ikuo Yonezu , Koji Nishio , Masao Inoue , Shin Fujitani
IPC分类号： H01M4/32 , H01M4/52 , H01M4/24 , H01M4/26
CPC分类号： H01M4/32 , H01M4/52 , Y02P70/54
摘要： In the non-sintered nickel electrode for an alkaline storage battery according to the invention, a yttrium metal powder and/or a yttrium compound powder has been added to a particulate active material comprising composite particles each consisting of a nickel hydroxide core and a sodium-doped cobalt compound shell. Because the yttrium metal powder and/or yttrium compound powder inhibits the diffusion of cobalt into the nickel hydroxide core, the non-sintered nickel electrode of the invention exhibits a high utilization efficiency not only in an initial phase of charge-discharge cycling but over a long time of use. Moreover, because the yttrium metal powder and/or yttrium compound powder enhances the oxygen overpotential, the non-sintered nickel electrode for an alkaline storage battery according to the invention shows very satisfactory charge characteristics particularly at high temperatures.
摘要翻译：在根据本发明的碱性蓄电池的非烧结镍电极中，将钇金属粉末和/或钇化合物粉末添加到包含复合颗粒的颗粒活性材料中，每个复合颗粒由氢氧化镍芯和钠 - 掺钴复合壳。由于钇金属粉末和/或钇化合物粉末抑制钴扩散到氢氧化镍芯中，本发明的非烧结镍电极不仅在充放电循环的初始阶段中显示出高的利用效率，使用时间长此外，由于钇金属粉末和/或钇化合物粉末提高氧超电势，所以根据本发明的碱性蓄电池的非烧结镍电极显示出非常令人满意的充电特性，特别是在高温下。

9. 发明授权

US6077625A Non-sintered nickel electrode for alkaline storage battery 失效
标题翻译：碱性蓄电池用非烧结镍电极
公开(公告)号：US6077625A
公开(公告)日：2000-06-20
申请号：US97679
申请日：1998-06-16
申请人： Mutsumi Yano , Mitsunori Tokuda , Kousuke Satoguchi , Shin Fujitani , Koji Nishio
发明人： Mutsumi Yano , Mitsunori Tokuda , Kousuke Satoguchi , Shin Fujitani , Koji Nishio
IPC分类号： H01M4/52 , H01M4/32
CPC分类号： H01M4/52
摘要： Non-sintered nickel electrodes for alkaline storage batteries which can express high active material utilization efficiency not only at the time of charging at ordinary temperature but also at the time of charging in a high-temperature atmosphere are provided by using an active material powder composed of composite particles each comprising a substrate particle containing nickel hydroxide, an inner coat layer covering the substrate particle and comprising yttrium, scandium or a lanthanoid, or an yttrium, scandium or lanthanoid compound, and an outer coat layer covering the inner coat layer and comprising cobalt or a cobalt compound, or composed of composite particles each comprising a substrate particle containing nickel hydroxide, an inner coat layer covering the substrate particle and comprising cobalt or a cobalt compound, and an outer coat layer covering the inner coat layer and comprising yttrium, scandium or a lanthanoid, or an yttrium, scandium or lanthanoid compound.
摘要翻译：通过使用由以下组成的活性物质粉末，可以提供不仅在常温充电时也能在高温气氛中充电的情况下表现出高活性物质利用效率的碱性蓄电池用非烧结镍电极每个复合颗粒包含含有氢氧化镍的底物颗粒，覆盖基质颗粒并包含钇，钪或镧系元素的内涂层，或钇，钪或镧系元素化合物的外涂层和覆盖内涂层的外涂层，或钴化合物，或由包含含有氢氧化镍的基底颗粒的复合颗粒或覆盖基材颗粒并包含钴或钴化合物的内涂层以及覆盖内涂层并包含钇，钪的外涂层的复合颗粒组成或镧系元素，或钇，钪或镧系元素化合物。

10. 发明授权

US6110304A Hydrogen-absorbing alloy electrode for alkaline storage batteries 失效
标题翻译：碱性蓄电池用吸氢合金电极
公开(公告)号：US6110304A
公开(公告)日：2000-08-29
申请号：US749531
申请日：1996-11-15
申请人： Mitsuzo Nogami , Yoshinori Matsuura , Mamoru Kimoto , Nobuyuki Higashiyama , Mitsunori Tokuda , Takahiro Isono , Ikuo Yonezu , Koji Nishio
发明人： Mitsuzo Nogami , Yoshinori Matsuura , Mamoru Kimoto , Nobuyuki Higashiyama , Mitsunori Tokuda , Takahiro Isono , Ikuo Yonezu , Koji Nishio
IPC分类号： B22F9/04 , H01M4/38 , C22C19/03
CPC分类号： H01M4/383 , B22F9/04 , B22F2009/041 , Y10S420/90
摘要： The hydrogen-absorbing alloy electrode for alkaline storage batteries according to the invention comprises a hydrogen absorbing alloy powder prepared by grinding a strip of hydrogen absorbing alloy produced by solidifying a molten alloy by a roll method and satisfying the following relations:r/t.ltoreq.0.5 (1)60.ltoreq.t.ltoreq.180 (2)30.ltoreq.r.ltoreq.90 (3)wherein r represents the mean particle size (.mu.m) of the hydrogen absorbing alloy powder and t represents the mean thickness (.mu.m) of the strip absorbing alloy. The hydrogen absorbing alloy electrode of this invention features an improved high-rate discharge characteristic at low temperature.
摘要翻译：根据本发明的碱性蓄电池的吸氢合金电极包括通过研磨通过辊法固化熔融合金而制备的吸氢合金条而制备的吸氢合金粉末，并且满足以下关系：r / t < = 0.5（1）60

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