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1. 发明授权

US06635717B1 Molding material 有权
标题翻译：成型材料
公开(公告)号：US06635717B1
公开(公告)日：2003-10-21
申请号：US09530515
申请日：2000-07-05
申请人： Mitsuru Kishine , Masanori Kitaichi , Tsuyoshi Noguchi , Yoshito Tanaka , Takayuki Araki , Sadashige Irie
发明人： Mitsuru Kishine , Masanori Kitaichi , Tsuyoshi Noguchi , Yoshito Tanaka , Takayuki Araki , Sadashige Irie
IPC分类号： C08F25900
CPC分类号： C08F293/00 , C09K3/1009
摘要： According to the present invention, it is possible to provide a molding material, for example, a sealing material for semiconductor-related production apparatuses which comprises a fluorine-containing multi-segment polymer being excellent in mechanical properties (particularly at high temperature), abrasion resistance and transparency and ensuring reduced contamination and reduced gas permeation while maintaining inherent characteristics of a fluorine-containing elastomer such as flexibility, elasticity, sealing property, chemical resistance and heat resistance. A molding material comprising a fluorine-containing multi-segment polymer having an elastomeric fluorine-containing polymer chain segment and a non-elastomeric fluorine-containing polymer chain segment, in which the elastomeric fluorine-containing polymer chain segment imparts flexibility to the whole polymer and has perhaloolefin units as a recurring unit in an amount of not less than 95% by mole.
摘要翻译：根据本发明，可以提供一种成型材料，例如，用于半导体相关生产设备的密封材料，其包括机械性能（特别是在高温下）具有优异的含氟多段聚合物，耐磨性电阻和透明度，并且确保减少污染和降低气体渗透，同时保持含氟弹性体的固有特性，例如柔性，弹性，密封性，耐化学性和耐热性。一种包含具有弹性体含氟聚合物链段和非弹性含氟聚合物链段的含氟多段聚合物的模塑材料，其中弹性体含氟聚合物链段赋予整个聚合物柔性，具有不低于95摩尔％的重复单元的全卤代烯烃单元。

2. 发明授权

US07455934B1 Fluorocopolymer material with sulfonic acid functional groups as a solid polyelectrolyte for use in fuel cells 有权
标题翻译：具有磺酸官能团的含氟共聚物材料作为用于燃料电池的固体聚电解质
公开(公告)号：US07455934B1
公开(公告)日：2008-11-25
申请号：US09700185
申请日：1999-05-10
申请人： Takayuki Araki , Noritoshi Oka , Yoshito Tanaka , Takayuki Nakamura , Tetsuo Shimizu
发明人： Takayuki Araki , Noritoshi Oka , Yoshito Tanaka , Takayuki Nakamura , Tetsuo Shimizu
IPC分类号： H01M10/08
CPC分类号： H01S5/22 , C08J5/2237 , C08J2327/12 , G02B2006/12097 , G02B2006/12176 , H01B1/122 , H01M8/0289 , H01M8/1025 , H01M8/1039 , H01M8/1067 , H01S5/0655 , H01S5/20 , H01S5/2004 , H01S5/2213 , H01S5/2218 , H01S5/2227
摘要： The invention is a material for a solid polyelectrolyte, comprising a multi-segmented fluoropolymer that comprises a block copolymer and/or a graft copolymer, wherein the copolymer contains one or more blocks essentially consisting of segment A and one or more blocks essentially consisting of segment B, the segment A combines with the segment B, wherein the segment A has a molecular weight of 5,000 to 1,000.000, and the Segment A is a copolymer chain comprising (a) an ethylenicfluoromonomer containing sulfonic acid functional groups each represented by Formula (1) CX2═CX1—(O)n—Rf—SO2Y, wherein X and X1 may be the same or different and are each hydrogen or fluorine; Y is FI, Cl, or OY1 wherein y1 is hydrogen, alkali metal or C1-C5 alkyl; Rf is C1 to C40 divalent fluoroalkylene or C1 to C40 divalent fluoroalkylene having one or more ether bonds; and n is 0 or 1; and (b) at least one type of ethylenic fluoromonomer copolymerizable with the ethylenic fluoromonomer (a) and containing no sulfonic acid functional groups, the segment B is a fluoropolymer containing no sulfonic acid functional groups, has a molecular weight of 3,000 to 1,200,000, and has a crystalline melting point of 100° C. or higher or a glass transition point of 100° C. or higher, wherein the ratio of segment A:segment B in the segmented fluoropolymer is 5:9˜to 98:2 30:70 to 90:10 wt. %.
摘要翻译：本发明是用于固体聚电解质的材料，其包含多段含氟聚合物，其包含嵌段共聚物和/或接枝共聚物，其中所述共聚物含有一个或多个基本上由片段A组成的嵌段和一个或多个基本上由片段 B，段A与段B结合，其中段A的分子量为5,000〜1,000.000，段A为共聚物链，其包含（a）含有各自由式（1）表示的磺酸官能团的烯键式氟单体， CX 2 - - - - - - - - - - - - - - - - - - - - - - - - - - - - （O） SUP> 1可以相同或不同，分别为氢或氟; Y是FI，Cl或OY 1，其中y 1是氢，碱金属或C 1 -C 5 烷基; Rf是C 1至C 40二价氟代亚烷基或C 1至C 40二价氟代亚烷基，其具有一个或多个醚债券并且n为0或1; 和（b）至少一种可与烯属含氟单体（a）共聚并且不含磺酸官能团的烯属含氟单体，段B是不含磺酸官能团的含氟聚合物，分子量为3,000至1,200,000，具有100℃以上的结晶熔点或100℃以上的玻璃化转变温度，其中分段含氟聚合物中A段：B段的比例为5:9〜98:2 30:70 至90:10重量％。

3. 发明授权

US07220809B1 Optical material containing fluorine-containing polymer having functional group 有权
标题翻译：含有具有官能团的含氟聚合物的光学材料
公开(公告)号：US07220809B1
公开(公告)日：2007-05-22
申请号：US10654888
申请日：2003-09-05
申请人： Takayuki Araki , Yoshito Tanaka , Yuzo Komatsu , Yoshito Ando
发明人： Takayuki Araki , Yoshito Tanaka , Yuzo Komatsu , Yoshito Ando
IPC分类号： C08F16/24
CPC分类号： G02B1/04 , C08K3/10 , C08K5/0091 , C08L29/10 , C08L33/16 , H01S3/178
摘要： There is provided an optical material obtained from an organic composition which is suitable for an optical material in optical communication and comprises a fluorine-containing polymer having functional group and a rare earth metal ion, in which the fluorine-containing polymer having functional group has at least one ketone structure in its side chain and a maximum absorption coefficient of not more than 1 cm−1 in each wavelength range of from 1,290 to 1,320 nm, from 1,530 to 1,570 nm and from 600 to 900 nm and the rare earth metal ion is at least one selected from the group consisting of erbium (Er) ion, thulium (Tm) ion, praseodymium (Pr) ion, holmium (Ho) ion, neodymium (Nd) ion, europium (Eu) ion, dysprosium (Dy) ion, samarium (Sm) ion and cerium (Ce) ion.
摘要翻译：提供了一种由有机组合物获得的光学材料，其适用于光学连接的光学材料，并且包括具有官能团的含氟聚合物和稀土金属离子，其中具有官能团的含氟聚合物具有其侧链中的至少一个酮结构和在1,290至1,320nm，1,530至1,570nm和600至900nm的每个波长范围内的最大吸收系数不超过1cm -1 -1 稀土金属离子选自铒（Er）离子，ium（Tm）离子，镨（Pr）离子，钬（Ho）离子，钕（Nd）离子，铕（Eu）离子，镝（Dy）离子，钐（Sm）离子和铈（Ce）离子。

4. 发明授权

US07670640B2 Curable fluorine-containing polymer, curable resin composition prepared from same and antireflection film 有权
标题翻译：可固化的含氟聚合物，由其制备的可固化树脂组合物和抗反射膜
公开(公告)号：US07670640B2
公开(公告)日：2010-03-02
申请号：US11226355
申请日：2005-09-15
申请人： Takayuki Araki , Mihoko Ohashi , Yoshito Tanaka , Tetsuo Shimizu
发明人： Takayuki Araki , Mihoko Ohashi , Yoshito Tanaka , Tetsuo Shimizu
IPC分类号： B05D5/06
CPC分类号： C09D127/12 , C08F8/00 , C08F8/14 , C08F16/32 , C08F214/18 , C08F290/04 , Y10T428/3154 , C08F14/18
摘要： There are provided a curable fluorine-containing polymer which can realize a high hardness by photo-curing while maintaining a low refractive index, an antireflection film possessing improved scratch resistance and abrasion resistance while maintaining a reflection reducing effect, and an antireflection-treated article provided with such an antireflection film. The curable fluorine-containing polymer has a number average molecular weight of from 500 to 1,000,000 and is represented by the formula (1): AM (1) in which the structural unit M is a structural unit derived from a fluorine-containing ethylenic monomer and represented by the formula (M): wherein X1 and X2 are the same or different and each is H or F; X3 is H, F, CH3 or CF3; X4 and X5 are the same or different and each is H, F or CF3; Rf is an organic group in which 1 to 3 of Y1 (Y1 is a monovalent organic group having 2 to 10 carbon atoms and an ethylenic carbon-carbon double bond at its end) are bonded to a fluorine-containing alkyl group having 1 to 40 carbon atoms or a fluorine-containing alkyl group having 2 to 100 carbon atoms and ether bond; a is 0 or an integer of from 1 to 3; b and c are the same or different and each is 0 or 1, the structural unit A is a structural unit derived from a monomer copolymerizable with the fluorine-containing ethylenic monomer represented by the formula (M), and the structural unit M and the structural unit A are contained in amounts of from 0.1 to 100% by mole and from 0 to 99.9% by mole, respectively.
摘要翻译：提供了一种可固化的含氟聚合物，其可以通过光固化同时保持低折射率实现高硬度，在保持反射降低效果的同时具有改善的耐擦伤性和耐磨性的抗反射膜，以及提供的抗反射处理制品具有这样的抗反射膜。可固化含氟聚合物的数均分子量为500〜1,000,000，由式（1）表示：AM（1）其中，结构单元M是来自含氟乙烯性单体的结构单元，由式（M）表示：其中X1和X2相同或不同，各自为H或F; X3是H，F，CH3或CF3; X4和X5相同或不同，分别为H，F或CF 3; Rf为1〜3的Y1（Y1为碳原子数为2〜10的一价有机基团，末端为烯属碳 - 碳双键）的1〜3的有机基团与1〜40的含氟烷基碳原子或碳原子数2〜100的含氟烷基和醚键; a为0或1〜3的整数; b和c相同或不同，分别为0或1，结构单元A是衍生自与式（M）表示的含氟乙烯性单体共聚的单体的结构单元，结构单元M和结构单元A的含量分别为0.1至100摩尔％和0至99.9摩尔％。

5. 再颁专利

USRE41110E1 Heat-resistant material and coating material for OA equipments having flexibility 失效
标题翻译：具有柔性的OA设备的耐热材料和涂料
公开(公告)号：USRE41110E1
公开(公告)日：2010-02-09
申请号：US11512391
申请日：2006-08-30
申请人： Takayuki Araki , Yoshito Tanaka , Masahiro Kumegawa , Norihito Otsuki , Masami Kato , Tetsuo Shimizu
发明人： Takayuki Araki , Yoshito Tanaka , Masahiro Kumegawa , Norihito Otsuki , Masami Kato , Tetsuo Shimizu
IPC分类号： B32B27/00
CPC分类号： C08F214/262 , C08F293/00 , C08L53/00 , C09D153/00 , G03G15/2057 , Y10T428/1352
摘要： It is possible to provide the heat resistant material and coating material for OA equipment which comprise a fluorine-containing multi-segment polymer having heat resistance, abrasion resistance, non-sticking property against toner and oil resistance in addition to flexibility and are used particularly on surfaces of fuser roll and belt. Those materials comprise a fluorine-containing multi-segment polymer having an elastomeric fluorine-containing polymer chain segment A and a non-elastomeric fluorine-containing polymer chain segment B, and the elastomeric fluorine-containing polymer chain segment A comprises not less than 90% by mole of perhaloolefin unit as a recurring unit and imparts flexibility to the whole polymer.
摘要翻译：可以提供包含含氟多层聚合物的OA设备的耐热材料和涂层材料，其具有耐热性，耐磨性，对调色剂的不粘附性和耐油性以及柔性，并且特别用于定影辊和皮带的表面。这些材料包括具有弹性体含氟聚合物链段A和非弹性含氟聚合物链段B的含氟多段聚合物，弹性体含氟聚合物链段A包含不少于90％的全卤代烯烃单元作为重复单元，并赋予整个聚合物柔性。

6. 发明授权

US06901205B2 Fluorine-containing material for optical waveguide 失效
公开(公告)号：US06901205B2
公开(公告)日：2005-05-31
申请号：US10654911
申请日：2003-09-05
申请人： Takayuki Araki , Yoshito Tanaka , Mihoko Ohashi
发明人： Takayuki Araki , Yoshito Tanaka , Mihoko Ohashi
IPC分类号： C08F2/46 , C08F290/00 , C08F299/00 , G02B6/122 , G02B6/10
CPC分类号： C08F299/00 , C08F290/00 , G02B6/1221
摘要： There is provided a material which can give a high elasticity and heat resistance to an optical waveguide member by photo-curing while maintaining transparency in a near infrared region and further makes it possible to use a film forming process by a spin coating method and a process for producing a waveguide by photolithograph, to obtain a waveguide having a large area and to produce an optical waveguide having reduced water absorption, and further there can be provided an optical waveguide member and an optical waveguide device. Namely, there are provided a fluorine-containing optical waveguide material comprising a curable fluorine-containing prepolymer (I) which is a non-crystalline polymer having a fluorine content of not less than 25% by weight and has a carbon-carbon double bond in a polymer side chain and/or at an end of a polymer trunk chain, an optical waveguide member which is a cured article of the optical waveguide material and an optical waveguide device comprising the optical waveguide member.

7. 发明申请

US20050084231A1 Fluorine-containing optical material containing fluorine-containing polymer having functional group capable of forming complex with rare earth metal ion 审中-公开
标题翻译：含有能够与稀土金属离子形成络合物的具有官能团的含氟聚合物的含氟光学材料
公开(公告)号：US20050084231A1
公开(公告)日：2005-04-21
申请号：US10970650
申请日：2004-10-22
申请人： Takayuki Araki , Yoshito Tanaka , Yoshito Ando , Yuzo Komatsu
发明人： Takayuki Araki , Yoshito Tanaka , Yoshito Ando , Yuzo Komatsu
IPC分类号： G02B6/00 , H01S3/17
CPC分类号： H01S3/17 , H01S3/178
摘要： There is provided an optical material which is an organic composition comprising a rare earth metal ion and a fluorine-containing polymer having functional group being capable of forming a complex with the rare earth metal ion and is suitable as an optical material for optical communication, in which the fluorine-containing polymer having functional group being capable of forming a complex with the rare earth metal ion has a side chain having at least two hetero-atoms in its structural unit and has a maximum absorption coefficient of not more than 1 cm−1 in each bandwidth of from 1,290 to 1,320 nm, from 1,530 to 1,570 nm and from 600 to 900 nm, and the rare earth metal ion is at least one selected from the group consisting of erbium (Er) ion, thulium (Tm) ion, praseodymium (Pr) ion, holmium (Ho) ion, neodymium (Nd) ion, europium (Eu) ion, dysprosium (Dy) ion, samarium (Sm) ion, cerium (Ce) ion and terbium (Tb) ion.
摘要翻译：提供了一种光学材料，其是包含稀土金属离子的有机组合物和具有能够与稀土金属离子形成络合物的官能团的含氟聚合物，并且适合作为用于光学通信的光学材料，具有能够与稀土金属离子形成络合物的官能团的含氟聚合物在其结构单元中具有至少两个杂原子的侧链，并且其最大吸收系数不大于1cm

8. 发明授权

US06207236B1 Coating composition, coating film, and method for producing coating film 有权
标题翻译：涂料组合物，涂膜及其制备方法
公开(公告)号：US06207236B1
公开(公告)日：2001-03-27
申请号：US09202592
申请日：1998-12-17
申请人： Takayuki Araki , Yoshito Tanaka , Masahiro Kumegawa , Noritoshi Oka , Tetsuo Shimizu
发明人： Takayuki Araki , Yoshito Tanaka , Masahiro Kumegawa , Noritoshi Oka , Tetsuo Shimizu
IPC分类号： B05D302
CPC分类号： C09D127/12 , C09D127/18 , C08L2666/54
摘要： To provide the water-repellent coating film having excellent transparency, abrasion resistance, weather resistance and water repellency, the method for producing the coating film, the multi-functional composite material provided with the coating film and the coating composition used therefor which has excellent dispersion stability. The coating composition comprises (A) the fluorine-containing ethylenic polymer prepared by copolymerizing a fluorine-containing ethylenic monomer having at least one functional group selected from hydroxyl, carboxyl, a carboxylic salt group, a carboxylic ester group and epoxy, (B-1) the metal oxide sol, and (C) the solvent.
摘要翻译：为了提供具有优异的透明性，耐磨性，耐候性和防水性的防水涂膜，涂膜的制备方法，设置有涂膜的多功能复合材料及其所用的涂料组合物具有优异的分散性稳定性。涂料组合物包含（A）通过共聚含有至少一个选自羟基，羧基，羧酸盐基，羧酸酯基和环氧基的官能团的含氟乙烯性单体制备的含氟乙烯性聚合物（B-1 ）金属氧化物溶胶，和（C）溶剂。

9. 发明授权

US08754140B2 Material for solid polyelectrolyte suitable for use in fuel cell 失效
标题翻译：适用于燃料电池的固体聚电解质材料
公开(公告)号：US08754140B2
公开(公告)日：2014-06-17
申请号：US12272226
申请日：2008-11-17
申请人： Takayuki Araki , Noritoshi Oka , Yoshito Tanaka , Takayuki Nakamura , Tetsuo Shimizu
发明人： Takayuki Araki , Noritoshi Oka , Yoshito Tanaka , Takayuki Nakamura , Tetsuo Shimizu
IPC分类号： H01M6/18
CPC分类号： H01S5/22 , C08J5/2237 , C08J2327/12 , G02B2006/12097 , G02B2006/12176 , H01B1/122 , H01M8/0289 , H01M8/1025 , H01M8/1039 , H01M8/1067 , H01S5/0655 , H01S5/20 , H01S5/2004 , H01S5/2213 , H01S5/2218 , H01S5/2227
摘要： A material for solid polyelectrolytes which comprises a polymer comprising two or more fluoropolymer segments differing in monomer composition, wherein at least one of the fluoropolymer segments has sulfonic acid type functional groups.
摘要翻译：一种用于固体聚电解质的材料，其包含包含两个或更多个单体组成不同的含氟聚合物链段的聚合物，其中至少一个含氟聚合物链段具有磺酸型官能团。

10. 发明申请

US20060189788A1 Cyclic ether copolymer, coating resin composition, optical devices, and process for production of the devices 审中-公开
标题翻译：环状醚共聚物，涂料树脂组合物，光学元件以及器件生产工艺
公开(公告)号：US20060189788A1
公开(公告)日：2006-08-24
申请号：US10552684
申请日：2004-03-31
申请人： Takayuki Araki , Yoshito Tanaka , Yuzo Komatsu
发明人： Takayuki Araki , Yoshito Tanaka , Yuzo Komatsu
IPC分类号： C08G65/34
CPC分类号： G02B6/1221 , C08F234/02 , C08G65/14 , C08G65/16 , C08L71/02 , C08L2205/05 , C09D145/00 , C08L2666/04
摘要： This invention provides a cyclic ether copolymer such as a cyclic ether copolymer excellent in solubility in solvents and easy to form uniform thin films therefrom. The present invention relates to a cyclic ether copolymer obtained from a 1,3-dioxole ring structure-containing compound represented by the following general formula (I) and an ethylenically unsaturated monomer: (wherein R1 and R2 are the same or different and each represents F, H, Cl or a perfluoroalkyl group containing 1 to 5 carbon atoms and X1 and X2 are the same or different and each represents F, H, Cl or —OR3, and R3 represents a perfluoroalkyl group containing 1 to 5 carbon atoms, provided that at least one of R1 and R2 is F or a perfluoroalkyl group containing 1 to 5 carbon atoms), which compolymer has a glass transition point of 100 to 135° C. and an intrinsic viscosity of 0.01 to 0.4 dl/g as determined at 35° C. in perfluoro-2-butyltetrahydrofuran.
摘要翻译：本发明提供了一种环状醚共聚物，例如在溶剂中溶解性优异的环状醚共聚物，并且易于形成均匀的薄膜。本发明涉及由以下通式（I）表示的含1,3-二氧杂环环结构的化合物和烯属不饱和单体（其中R 1和R 2）和R 2个相同或不同，各自表示F，H，Cl或含有1至5个碳原子的全氟烷基，X 1和X 2 2 >相同或不同，各自表示F，H，Cl或-OR 3，并且R 3表示含有1至5个碳原子的全氟烷基，条件是在 R 1和R 2中的至少一个为F或含有1至5个碳原子的全氟烷基），该共聚物的玻璃化转变点为100至135℃。并且在35℃下在全氟-2-丁基四氢呋喃中测定的特性粘度为0.01至0.4dl / g。

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