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1. 发明授权

US5880224A Aliphatic polyester carbonate and process for producing the aliphatic polyester carbonate 失效
标题翻译：脂肪族聚酯碳酸酯及其制造方法
公开(公告)号：US5880224A
公开(公告)日：1999-03-09
申请号：US901468
申请日：1997-07-28
申请人： Mitsuo Miura , Kyohei Takakuwa , Takayasu Fujimori , Maki Ito
发明人： Mitsuo Miura , Kyohei Takakuwa , Takayasu Fujimori , Maki Ito
IPC分类号： C08G63/64 , C08G63/78 , C08G63/88 , C08K3/32 , C08L101/16
CPC分类号： C08G63/64 , C08K3/32
摘要： A process for producing an aliphatic polyester carbonate which comprises reacting (1) an aliphatic dicarboxylic acid compound containing succinic acid as a main component, (2) an aliphatic dihydroxy compound containing 1,4-butanediol as a main component, and (3) (a) a polyhydric alcohol having 3 or more hydroxyl groups in a molecule, (b) a polybasic carboxylic acid compound having 3 or more carboxyl groups in a molecule, or (c) a polybasic carboxylic acid having one or more hydroxyl groups in a molecule to obtain an aliphatic polyester oligomer and reacting the obtained aliphatic polyester oligomer and a carbonate compound, wherein the aliphatic polyester carbonate has a melt tension of 1.5 g or more at 190.degree. C. and at an extrusion rate of 10 mm/minute; a process for producing an aliphatic polyester carbonate which comprises reacting above components (1) and (2) to obtain an aliphatic polyester oligomer and reacting the obtained aliphatic polyester oligomer, above component (3) (a), and a carbonate compound, wherein the aliphatic polyester carbonate has the same properties; and aliphatic polyester carbonates produced by these processes. The aliphatic polyester carbonate is branched and biodegradable, has a high molecular weight, and shows higher melt tension and more excellent molding property in comparison with conventional linear aliphatic polyester carbonates in molding of the polyester carbonate to prepare films, sheets, fibers, and other molded products.
摘要翻译：一种脂肪族聚酯碳酸酯的制造方法，其特征在于，使（1）以琥珀酸为主要成分的脂肪族二羧酸化合物与（2）以1,4-丁二醇为主要成分的脂肪族二羟基化合物和（3）（ a）分子中具有3个以上羟基的多元醇，（b）分子中具有3个以上羧基的多元羧酸化合物，或（c）分子中具有一个以上羟基的多元羧酸得到脂肪族聚酯低聚物，使所得到的脂肪族聚酯低聚物和碳酸酯化合物反应，其中脂族聚酯碳酸酯在190℃，挤出速度为10毫米/分钟时的熔融张力为1.5克以上。一种脂肪族聚酯碳酸酯的制造方法，其特征在于，使上述成分（1）和（2）反应，得到脂肪族聚酯低聚物，使得到的脂肪族聚酯低聚物，上述成分（3）（a）和碳酸酯化合物反应，脂肪族聚酯碳酸酯具有相同的性质; 和通过这些方法生产的脂肪族聚酯碳酸酯。与聚酯碳酸酯成型时的常规直链脂族聚酯碳酸酯相比，脂肪族聚酯碳酸酯是分支和可生物降解的，具有高分子量，并且显示出更高的熔体张力和更优异的成型性能，以制备膜，片，纤维等成型产品。

2. 发明授权

US5654380A Aliphatic polyester carbonate and process for producing the same 失效
标题翻译：脂肪族聚酯碳酸酯及其制造方法
公开(公告)号：US5654380A
公开(公告)日：1997-08-05
申请号：US443485
申请日：1995-05-18
申请人： Ryozo Kawai , Mitsuo Miura , Kyohei Takakuwa , Yoshinori Isahaya , Takayasu Fujimori , Jiro Suito , Makoto Nakamura
发明人： Ryozo Kawai , Mitsuo Miura , Kyohei Takakuwa , Yoshinori Isahaya , Takayasu Fujimori , Jiro Suito , Makoto Nakamura
IPC分类号： C08G63/64 , C08F20/00
CPC分类号： C08G63/64 , C08G2230/00
摘要： Provided are an aliphatic polyester carbonate having biodegradability and having a content of carbonate unit of at least 5 mol %, a weight-average molecular weight of at least 100,000, a melt viscosity of 2,000-50,000 poises at 190.degree. C. and under a load of 60 kg and a melting point of 70.degree.-180.degree. C., and a process for producing said aliphatic polyester carbonate which comprises reacting an aliphatic dihydroxy compound with an aliphatic dibasic acid in the presence of an ester exchange catalyst to obtain an oligomer and then reacting the oligomer with a diaryl carbonate in the presence of the ester exchange catalyst. A phosphorus compound may be added to the aliphatic polyester carbonate for the purpose of stabilization.
摘要翻译：本发明提供一种脂肪族聚酯碳酸酯，其具有生物降解性，碳酸酯单元的含量为至少5摩尔％，重均分子量至少为100,000，190℃时的熔融粘度为2,000-50,000泊，负荷 60kg，熔点为70-180℃，以及一种制备所述脂族聚酯碳酸酯的方法，该方法包括在酯交换催化剂存在下使脂族二羟基化合物与脂肪族二元酸反应得到低聚物和然后在酯交换催化剂存在下使低聚物与碳酸二芳基酯反应。为了稳定化，可将磷化合物加入脂族聚酯碳酸酯中。

3. 发明授权

US06359103B1 Aromatic-aliphatic copolycarbonate and process for producing the same 有权
标题翻译：芳香族 - 脂肪族共聚碳酸酯及其制造方法
公开(公告)号：US06359103B1
公开(公告)日：2002-03-19
申请号：US09639985
申请日：2000-08-17
申请人： Satoshi Nagai , Osamu Kondo , Kyohei Takakuwa , Yoshinori Isahaya , Takayasu Fujimori
发明人： Satoshi Nagai , Osamu Kondo , Kyohei Takakuwa , Yoshinori Isahaya , Takayasu Fujimori
IPC分类号： C08G6416
CPC分类号： C08G64/1608 , C08G64/30
摘要： An aromatic-aliphatic copolycarbonate and a process for producing the same which comprises polycondensation of an aromatic dihydroxy compound, such as 1,1-bis(4-hydroxyphenyl)cyclohexane, tricyclo(5.2.1.02,6)decanedimethanol, and a carbonic acid diester in a molten state under heating, wherein the carbonic acid diester has a chlorine content of 20 ppm or lower. The copolycarbonate has improved refractive index, balance of dispersion, and photoelastic constant while retaining high impact resistance, high heat resistance, and excellent hue.
摘要翻译：芳香族 - 脂肪族共聚碳酸酯及其制造方法，其包括芳族二羟基化合物如1,1-双（4-羟基苯基）环己烷，三环（5.2.1.0 2,6）癸烷二甲醇和碳酸二酯的缩聚在加热下处于熔融状态，其中碳酸二酯的氯含量为20ppm以下。共聚碳酸酯具有改善的折射率，平衡分散和光弹性常数，同时保持高耐冲击性，高耐热性和优异的色调。

4. 发明授权

US06376641B2 Aromatic-aliphatic copolycarbonate and process for producing the same 有权
公开(公告)号：US06376641B2
公开(公告)日：2002-04-23
申请号：US09328487
申请日：1999-06-09
申请人： Satoshi Nagai , Osamu Kondo , Kyohei Takakuwa , Yoshinori Isahaya , Takayasu Fujimori
发明人： Satoshi Nagai , Osamu Kondo , Kyohei Takakuwa , Yoshinori Isahaya , Takayasu Fujimori
IPC分类号： C08G6416
CPC分类号： C08G64/1608 , C08G64/30
摘要： An aromatic-aliphatic copolycarbonate and a process for producing the same which comprises polycondensation of an aromatic dihydroxy compound, such as 1,1-bis(4-hydroxyphenyl)cyclohexane, tricyclo(5.2.1.02,6)decanedimethanol, and a carbonic acid diester in a molten state under heating, wherein the carbonic acid diester has a chlorine content of 20 ppm or lower. The copolycarbonate has improved refractive index, balance of dispersion, and photoelastic constant while retaining high impact resistance, high heat resistance, and excellent hue.

5. 发明授权

US06667381B2 Process for producing aliphatic polyester carbonate 失效
公开(公告)号：US06667381B2
公开(公告)日：2003-12-23
申请号：US10257784
申请日：2002-10-17
申请人： Kyohei Takakuwa , Kunitoshi Mimura , Maki Ito , Noriko Dodo
发明人： Kyohei Takakuwa , Kunitoshi Mimura , Maki Ito , Noriko Dodo
IPC分类号： C08G6400
CPC分类号： C08G63/64
摘要： In the process of the present invention for producing an aliphatic poly(ester carbonate), maleic anhydride, a C2-20 glycol and hydrogen are reacted in the presence of a hydrogenating catalyst. By this process, an aliphatic poly(ester carbonate) having practically satisfactory moldability and physical properties is produced in a short period of time by a simplified method as compared to conventional production processes.

6. 发明申请

US20050168690A1 Light control plastic lens, coated sheet-like light control element for the lens production, and a production method for light control plastic lens 有权
标题翻译：光控塑料透镜，用于镜片生产的涂层片状光控元件，以及光控塑料透镜的制造方法
公开(公告)号：US20050168690A1
公开(公告)日：2005-08-04
申请号：US11041337
申请日：2005-01-25
申请人： Ryozo Kawai , Yoshiyuki Aoki , Kyohei Takakuwa , Mitsuhiko Masumoto , Toshizumi Hirota , Motoharu Takeuchi
发明人： Ryozo Kawai , Yoshiyuki Aoki , Kyohei Takakuwa , Mitsuhiko Masumoto , Toshizumi Hirota , Motoharu Takeuchi
IPC分类号： G02C7/02 , B29C39/02 , B29C39/18 , B29C41/20 , B29C45/14 , B29C53/04 , B29C70/70 , B29D11/00 , G02B5/23 , G02B5/30 , G02C7/10 , G02C7/12
CPC分类号： G02C7/12 , B29C39/025 , B29C41/20 , B29C53/04 , B29C70/70 , B29C2791/001 , B29D11/0073 , B29K2105/0002 , G02B5/23 , G02B5/305
摘要： A light control plastic lens, a sheet-like light control element, and a production method for light control plastic lenses are provided. More specifically, a light control plastic lens, such as a high index polarizing property and/or a photochromic plastic lens that is made by cast polymerization is provided. Also provided are a sheet-like light control element for use in the production of the lenses, as well as a production method of such light control plastic lenses. The light control plastic lens has a sheet-like light control element including at least a light control sheet. In particular, the light control plast lens the sheet-like light control element, a curable resin layer laminated on at least one surface of the sheet-like light control element, and a polymerizable lens resin layer laminated at least on the curable resin layer.
摘要翻译：提供了光控塑料透镜，片状光控制元件和用于光控制塑料透镜的制造方法。更具体地，提供了通过浇铸聚合制成的光控塑料透镜，例如高折射率偏振性质和/或光致变色塑料透镜。还提供了用于制造透镜的片状光控制元件以及这种光控塑料透镜的制造方法。光控塑料透镜具有至少包括光控板的片状光控制元件。特别是，光控塑料透镜，片状光控制元件，层压在片状光控制元件的至少一个表面上的可固化树脂层和至少层压在可固化树脂层上的可聚合透镜树脂层。

7. 发明申请

US20090317616A1 PROCESS FOR PRODUCING MELANIN, MELANIN PRODUCED BY THE PROCESS, FUNCTIONAL FILM CONTAINING THE MELANIN, AND PROCESS FOR PRODUCING THE SAME 审中-公开
标题翻译：生产MELANIN的方法，由该方法生产的MELANIN，含有MELANIN的功能膜及其生产方法
公开(公告)号：US20090317616A1
公开(公告)日：2009-12-24
申请号：US11995621
申请日：2006-07-14
申请人： Ryozo Kawai , Yoshiyuki Aoki , Eiko Aoki , Kyohei Takakuwa , Masahiko Namiki
发明人： Ryozo Kawai , Yoshiyuki Aoki , Eiko Aoki , Kyohei Takakuwa , Masahiko Namiki
IPC分类号： C08L29/04 , C04B14/00
CPC分类号： C09B59/00 , C09B67/0097 , C09B69/104 , G02B5/208 , G02B5/3033
摘要： The present invention provides a melanin that is excellent in coloring a functional film, and in reproducibility and stability during storage, and a method for its production. Also, the invention provides a functional film containing a melanin and its method for production. Specifically, it provides a functional film containing a melanin of which the alteration is improved and which is excellent in the property for protecting eyes from ultraviolet rays, and in its method for production.The method for producing a melanin of the present invention, comprises, at least, under controlled conditions, a step for an oxidative reaction wherein a melanin precursor is continuously oxidized while the mole ratio of the melanin precursor relative to the oxidative agent is maintained at a constant ratio, and a step for precipitation wherein a melanin is precipitated by acidifying a reaction solution after the step for an oxidative reaction.
摘要翻译：本发明提供了对功能性膜着色，保存时的再现性和稳定性优异的黑色素及其制造方法。另外，本发明提供含有黑色素的功能性膜及其制造方法。具体地说，提供了含有黑色素的功能性膜，其变化得到改善，并且在保护眼睛免受紫外线的性质方面优异，并且在其生产方法中。本发明的黑色素的制备方法至少在受控条件下，包括氧化反应的步骤，其中黑色素前体被连续氧化，而黑色素前体相对于氧化剂的摩尔比保持在恒定比例和沉淀步骤，其中通过在氧化反应步骤之后使反应溶液酸化而使黑色素沉淀。

8. 发明申请

US20080252972A1 MULTI-LAYERED POLARIZING SHEET, AND A NON-GLARING PRODUCT AND A POLARIZING SHEET FOR A LIQUID-CRYSTAL DISPLAY COMPRISING THE POLARIZING SHEET 审中-公开
标题翻译：多层偏振片，以及非液晶产品和用于包含偏光片的液晶显示器的偏光片
公开(公告)号：US20080252972A1
公开(公告)日：2008-10-16
申请号：US12102217
申请日：2008-04-14
申请人： Hiroyuki CHIDA , Kazutoshi Tanoho , Kyohei Takakuwa , Kenichi Kurata , Masahiko Namiki , Masukazu Hirata
发明人： Hiroyuki CHIDA , Kazutoshi Tanoho , Kyohei Takakuwa , Kenichi Kurata , Masahiko Namiki , Masukazu Hirata
IPC分类号： G02B1/08 , G02B5/30
CPC分类号： G02B5/3033 , B32B27/08 , G02C7/12 , Y10T428/1041
摘要： [Problem to be Solved] The present inventions provide a polarizing film and a polarizing sheet of which the resistance for the response in the vertical direction against the direction for the extension.[Means to Solve the Problem] In a multi-layered polarizing sheet comprising a laminated body in which a polarizing layer consisting of a polarizing film is held between two transparent plastic materials and is adhered to them, the polarizing layer is produced by dyeing a film made of poly(vinyl alcohol) and the like having a weight average molecular weight of 150,000-500,000 and by extending it. The non-glaring product and polarizing sheet for a liquid crystal display are produced by using the multi-layered polarizing sheet.
摘要翻译： [待解决的问题]本发明提供一种偏振膜和偏振片，其具有相对于延伸方向的垂直方向响应的电阻。解决问题的手段在包含层叠体的多层偏振片中，其中由偏振膜组成的偏振层保持在两个透明塑料材料之间并粘附到它们上，偏振层通过将膜由聚（乙烯醇）等制成，其重均分子量为150,000-500,000，并延伸。通过使用多层偏光片制造液晶显示器的非眩光产品和偏振片。

9. 发明授权

US07350917B2 Light control plastic lens, coated sheet-like light control element for the lens production, and a production method for light control plastic lens 有权
标题翻译：光控塑料透镜，用于镜片生产的涂层片状光控元件，以及光控塑料透镜的制造方法
公开(公告)号：US07350917B2
公开(公告)日：2008-04-01
申请号：US11041337
申请日：2005-01-25
申请人： Ryozo Kawai , Yoshiyuki Aoki , Kyohei Takakuwa , Mitsuhiko Masumoto , Toshizumi Hirota , Motoharu Takeuchi
发明人： Ryozo Kawai , Yoshiyuki Aoki , Kyohei Takakuwa , Mitsuhiko Masumoto , Toshizumi Hirota , Motoharu Takeuchi
IPC分类号： G02C7/10
CPC分类号： G02C7/12 , B29C39/025 , B29C41/20 , B29C53/04 , B29C70/70 , B29C2791/001 , B29D11/0073 , B29K2105/0002 , G02B5/23 , G02B5/305
摘要： A light control plastic lens, a sheet-like light control element, and a production method for light control plastic lenses are provided. More specifically, a light control plastic lens, such as a high index polarizing property and/or a photochromic plastic lens that is made by cast polymerization is provided. Also provided is a sheet-like light control element for use in the production of the lenses, as well as a production method of such light control plastic lenses. The light control plastic lens has a sheet-like light control element including at least a light control sheet. In particular, the light control plastic lens has a sheet-like light control element, a curable resin layer laminated on at least one surface of the sheet-like light control element, and a polymerizable lens resin layer laminated at least on the curable resin layer.
摘要翻译：提供了光控塑料透镜，片状光控制元件和用于光控制塑料透镜的制造方法。更具体地，提供了通过浇铸聚合制成的光控塑料透镜，例如高折射率偏振性质和/或光致变色塑料透镜。还提供了用于制造透镜的片状光控制元件以及这种光控塑料透镜的制造方法。光控塑料透镜具有至少包括光控板的片状光控制元件。特别地，光控塑料透镜具有片状光控制元件，层叠在片状光控制元件的至少一个表面上的固化树脂层和至少层叠在固化树脂层上的聚合透镜树脂层。

10. 发明授权

US06262184B1 Resin composition and molded article 失效
标题翻译：树脂组合物和模制品
公开(公告)号：US06262184B1
公开(公告)日：2001-07-17
申请号：US09409443
申请日：1999-09-30
申请人： Takeshi Kanamori , Hiroshi Urayama , Kyohei Takakuwa , Makoto Nakamura , Yasuo Teraya , Sakae Shimotsuma
发明人： Takeshi Kanamori , Hiroshi Urayama , Kyohei Takakuwa , Makoto Nakamura , Yasuo Teraya , Sakae Shimotsuma
IPC分类号： C08L6702
CPC分类号： C08L67/04 , A42B3/06 , C08L69/005 , C08L2666/18
摘要： The present invention provides a resin composition comprising polylactic acid and aliphatic polyester carbonate, which has practically adequate heat-resistance temperature, moldability, thermostability, solvent resistance and high mechanical strength, as well as a molded article thereof. In the resin composition, the Vicat softening point is 60° C. or more, the tensile modulus of elasticity is 0.9 GPa or more, the modulus in flexure is 0.6 GPa or more, and the mixing ratio of polylactic acid (A) and aliphatic polyester carbonate (B), in terms of the ratio of (A)/(B) by weight, is 95/5 to 5/95. Further, the present invention provides a biodegradable injection-molded article having improvements in mechanical characteristics and impact resistance and superior disposal properties, particularly having strength enough to make it usable as a headgear material for use in helmets. The biodegradable injection-molded article is excellent in impact resistance, comprising mainly polylactic acid (A) and aliphatic polyester (E) and/or aliphatic polyester carbonate (B). This injection-molded article has a flexural strength of 30 MPa or more and an Izod impact strength of 3 kJ/m2 or more, and it is used as helmet headgear.
摘要翻译：本发明提供了具有实际上足够的耐热温度，成型性，耐热性，耐溶剂性和高机械强度的聚乳酸和脂肪族聚酯碳酸酯的树脂组合物及其成型品。在树脂组合物中，维卡软化点为60℃以上，拉伸弹性模量为0.9GPa以上，挠曲模量为0.6GPa以上，聚乳酸（A）和脂肪族聚酯碳酸酯（B）按重量比（A）/（B）计为95/5〜5/95。此外，本发明提供了具有机械特性和耐冲击性改善以及优异的处置性能的生物降解性注射成型制品，特别是具有足以使其可用作头盔用头盔材料的强度。生物降解性注射成型品的耐冲击性优异，主要包括聚乳酸（A）和脂肪族聚酯（E）和/或脂肪族聚酯碳酸酯（B）。该注射成型品的弯曲强度为30MPa以上，Izod冲击强度为3kJ / m 2以上，用作头盔头饰。

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