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1. 发明授权

US5087286A Heat-curable resinous coating composition 失效
标题翻译：可固化树脂涂料组合物
公开(公告)号：US5087286A
公开(公告)日：1992-02-11
申请号：US496201
申请日：1990-03-19
申请人： Mitsuhiro Fukuda , Hirotoshi Inoue , Akira Kasari , Yuzo Miyamoto , Osamu Isozaki , Noboru Nakai
发明人： Mitsuhiro Fukuda , Hirotoshi Inoue , Akira Kasari , Yuzo Miyamoto , Osamu Isozaki , Noboru Nakai
IPC分类号： C09D133/08 , C09D163/00 , C09D167/00 , C09D183/04
CPC分类号： C09D167/00 , C09D133/08 , C09D163/00 , C09D183/04
摘要： A heat-curable resinous coating composition comprising as a binder component(A) 5 to 90% by weight of a hydroxyl-containing resin selected from hydroxyl-containing acrylic resins and hydroxyl-containing polyester resins,(B) 5 to 50% by weight of an amino resin, and(C) 1 to 90% by weight of a crosslinkable resin selected from (C-a) polyfunctional resins having a number average molecular weight of at least 1000 and containing at least two carboxyl groups and at least two epoxy groups on an average per molecule and (C-b) polyorganosiloxanes having a number average molecular weight of at least 500 and containing at least two silanol groups on an average per molecule and if required, further containing an epoxy group.

2. 发明授权

US4933214A Finish coating method 失效
标题翻译：涂饰方法
公开(公告)号：US4933214A
公开(公告)日：1990-06-12
申请号：US272970
申请日：1988-11-18
申请人： Shinji Sugiura , Teiitsu Takagi , Yuzo Miyamoto , Akira Kasari , Sachio Yamaguchi
发明人： Shinji Sugiura , Teiitsu Takagi , Yuzo Miyamoto , Akira Kasari , Sachio Yamaguchi
IPC分类号： B05D5/00 , B05D7/00 , B05D7/14 , B05D7/24 , C08L61/20 , C09D133/06 , C09D167/00
CPC分类号： B05D7/577 , C09D133/066 , C09D167/00 , C08L61/20
摘要： A coating method characterized in that the method comprises the steps of applying a thermosetting coating composition containing a pigment to a substrate to be coated, applying a first clear coating composition to the coat to form a first clear coat, baking the two coats at the same time for curing, applying to the cured coats a second clear coating composition capable of forming a second clear coat having, when cured, a molecular weight between crosslinks of about 200 or less as determined by a xylene-swelling method and baking the second clear coat for curing.
摘要翻译：一种涂布方法，其特征在于该方法包括以下步骤：将含有颜料的热固性涂料组合物涂布于待涂布的基底上，将第一透明涂料组合物涂覆到该涂层上以形成第一透明涂层，同时烘烤两个涂层固化时间，施加到固化涂层上的第二透明涂料组合物，其能够形成第二透明涂层，当固化时，通过二甲苯溶胀法测定的约200或更小的交联键之间的分子量，并烘烤第二透明涂层用于治疗。

3. 发明授权

US5077347A Dipsersion of fine particles of a polymer 失效
标题翻译：聚合物精细颗粒的分散
公开(公告)号：US5077347A
公开(公告)日：1991-12-31
申请号：US687619
申请日：1991-04-19
申请人： Motoshi Yabuta , Yasushi Nakao , Shinji Sugiura , Mitsuhiro Fukuda , Yuzo Miyamoto
发明人： Motoshi Yabuta , Yasushi Nakao , Shinji Sugiura , Mitsuhiro Fukuda , Yuzo Miyamoto
IPC分类号： C08F299/00 , C08F290/00 , C08F290/12 , C08F299/04 , C08J3/00 , C08L51/00 , C08L57/00 , C08L101/06 , C09D5/00
CPC分类号： C08F290/12 , C08F299/0485 , C08J3/005 , C08L51/003
摘要： A dispersion of fine particles of a gelled polymer obtainable by copolymerizing and crosslinking a vinyl monomer mixture containing at least 0.5% by weight each of at least two vinyl monomers in the presence of a macromonomer A, which has a molecular chain of poly(12-hydroxystearic acid) and has at least about one polymerizable unsaturated double bond per molecule in average, and a macromonomer B, which is a copolymer of an ethylenic unsaturated monomer and has a solubility parameter value of from 7.5 to 9.2 and about 1.0 to about 1.5 in average of polymerizable unsaturated double bonds, in an organic solvent which is capable of dissolving the macromonomers A and B but is substantially incapable of dissolving a polymer from said vinyl monomer mixture; and a curable resin composition comprising a dispersion of fine particles of the above-described gelled polymer, a base resin which is non-compatible with the macromonomer A but is compatible with the macromonomer B and which forms a continuous phase, and at least one crosslinking agent selected from the group consisting of an amino resin and a polyisocyanate compound.
摘要翻译：通过在大分子单体A的存在下共聚和交联含有至少两种乙烯基单体的至少0.5重量％的乙烯基单体混合物的乙烯基单体混合物，其分子链为聚（12- 羟基硬脂酸），并且平均每分子具有至少约一个可聚合不饱和双键，和作为烯属不饱和单体的共聚物，其溶解度参数值为7.5至9.2和约1.0至约1.5的共聚物的大分子单体B 在可溶解大分子单体A和B但基本上不能从所述乙烯基单体混合物中溶解聚合物的有机溶剂中的可聚合不饱和双键的平均值; 以及包含上述胶凝聚合物的细颗粒分散体的固化性树脂组合物，与大分子单体A不相容但与大分子单体B相容并形成连续相的基础树脂和至少一种交联选自氨基树脂和多异氰酸酯化合物的试剂。

4. 发明授权

US5025060A Dispersion of fine particles of a polymer 失效
标题翻译：聚合物细颗粒的分散
公开(公告)号：US5025060A
公开(公告)日：1991-06-18
申请号：US596327
申请日：1990-10-15
申请人： Motoshi Yabuta , Yasushi Nakao , Shinji Sugiura , Mitsuhiro Fukuda , Yuzo Miyamoto
发明人： Motoshi Yabuta , Yasushi Nakao , Shinji Sugiura , Mitsuhiro Fukuda , Yuzo Miyamoto
IPC分类号： C08F2/16 , C08F290/04 , C08F290/06 , C08F290/12 , C08F290/14 , C08F299/00 , C08F299/02 , C08G18/42 , C08G18/81
CPC分类号： C08G18/4283 , C08F290/04 , C08F290/061 , C08F290/12 , C08F290/141 , C08F299/00 , C08F299/022 , C08G18/8108 , C08G18/8175
摘要： A dispersion of fine particles of a gelled polymer obtainable by copolymerizing and crosslinking a vinyl monomer mixture containing at least 0.5% by weight each of at least two vinyl monomers in the presence of a macromonomer A, which has a molecular chain of poly(12-hydroxystearic acid) and has at least about one polymerizable unsaturated double bond per molecule in average, and a macromonomer B, which is a copolymer of an ethylenic unsaturated monomer and has a solubility parameter value of from 7.5 to 9.2 and about 1.0 to about 1.5 in average of polymerizable unsaturated double bonds, in an organic solvent which is capable of dissolving the macromonomers A and B but is substantially incapable of dissolving a polymer formed from said vinyl monomer mixture; and a curable resin composition comprising a dispersion of fine particles of the above-described gelled polymer, a base resin which is non-compatible with the macromonomer A but is compatible with the macromonomer B and which forms a continuous phase, and at least one crosslinking agent selected from the group consisting of an amino resin and a polyisocyanate compound.
摘要翻译：通过在大分子单体A的存在下共聚和交联含有至少两种乙烯基单体的至少0.5重量％的乙烯基单体混合物的乙烯基单体混合物，其分子链为聚（12- 羟基硬脂酸），并且平均每分子具有至少约一个可聚合不饱和双键，和作为烯属不饱和单体的共聚物，其溶解度参数值为7.5至9.2和约1.0至约1.5的共聚物的大分子单体B 在能够溶解大分子单体A和B但基本上不能溶解由所述乙烯基单体混合物形成的聚合物的有机溶剂中的可聚合不饱和双键的平均值; 以及包含上述胶凝聚合物的细颗粒分散体的固化性树脂组合物，与大分子单体A不相容但与大分子单体B相容并形成连续相的基础树脂和至少一种交联选自氨基树脂和多异氰酸酯化合物的试剂。

5. 发明授权

US4981759A Coating method 失效
标题翻译：涂布方法
公开(公告)号：US4981759A
公开(公告)日：1991-01-01
申请号：US189167
申请日：1988-05-02
申请人： Eisaku Nakatani , Masaru Mitsuji , Yasuhiro Fujii , Katsuya Sera , Yuzo Miyamoto , Masafumi Kume , Tadayoshi Tatsuno , Akimasa Nakahata
发明人： Eisaku Nakatani , Masaru Mitsuji , Yasuhiro Fujii , Katsuya Sera , Yuzo Miyamoto , Masafumi Kume , Tadayoshi Tatsuno , Akimasa Nakahata
IPC分类号： C09D5/44 , C09D5/46
CPC分类号： C09D5/4473 , Y10T428/12569 , Y10T428/31522
摘要： A coating method, which comprises(i) applying to a substrate a multilayer film-forming cationic electrodeposition paint composed of(A) a cationic electrodepositable epoxy resin having a surface tension of 40 to 60 dynes/cm and being able to form a cathodically electrodepositable aqueous bath by neutralization with an acid, and(B) a nonionic film-forming resin having a surface tension of 25 to 45 dynes/cm, the weight ratio of resin (A) to resin (B) being from 60:40 to 98:2 and the surface tension of resin (A) being greater than that of resin (B), and curing the coated film by heating,(ii) applying a water-base or organic solvent-base colored paint as a first top coat, and(iii) applying as a second top coat a powder paint capable of forming a transparent film which may be colored.
摘要翻译：一种涂布方法，其包括（i）向基材施加多层成膜阳离子电沉积涂料，其由（A）表面张力为40至60达因/厘米的阳离子可电沉积环氧树脂组成，并且能够形成阴极电沉积（B）表面张力为25〜45达因/厘米的树脂（A）与树脂（B）的重量比为60:40〜98的非离子性成膜树脂：2，树脂（A）的表面张力大于树脂（B）的表面张力，并且通过加热固化涂膜，（ii）施加水基或有机溶剂基着色涂料作为第一面漆，和（iii）作为第二面漆施加能够形成可以着色的透明膜的粉末涂料。

6. 发明授权

US5346958A Curable coating compositions containing polystyrene microparticles 失效
标题翻译：含有聚苯乙烯微粒的可固化涂料组合物
公开(公告)号：US5346958A
公开(公告)日：1994-09-13
申请号：US46987
申请日：1993-04-16
申请人： Yoshiyuki Yukawa , Motoshi Yabuta , Akimasa Nakahata , Yuzo Miyamoto , Masaaki Kobayashi , Naruhito Ueno
发明人： Yoshiyuki Yukawa , Motoshi Yabuta , Akimasa Nakahata , Yuzo Miyamoto , Masaaki Kobayashi , Naruhito Ueno
IPC分类号： B05D1/36 , C08L25/14 , C08L61/20 , C09D125/00 , C09D125/08 , C09D133/04 , C09D133/06 , C09D161/20 , C09D175/04 , C08F8/30 , C08F8/32 , C08L75/04
CPC分类号： C09D125/08 , C08L2205/18 , C08L25/14 , C08L61/20 , Y10T428/29 , Y10T428/31855 , Y10T428/31862
摘要： A curable top coating composition essentially including(A) a hydroxyl-containing vinyl type resin containing 45 to 55% by weight of styrene monomer as a copolymerized unit of the resin,(B) at least one member selected from among amino resins and (blocked) polyisocyanate compounds, and(C) a microparticulate polymer having an average particle diameter within the range of 0.01 to 1 .mu.m and containing 40 to 60% by weight of styrene monomer as a copolymerized component of each particle,wherein the cured film from the coating composition contains the styrene-derived benzene ring in a proportion of 13 to 40% by weight of the total resin solids;a coating method using the above coating composition, anda coated article obtainable by using the above coating composition.
摘要翻译：一种可固化顶涂层组合物，其基本上包括（A）含有45至55重量％的作为树脂的共聚单元的苯乙烯单体的含羟基的乙烯基型树脂，（B）选自氨基树脂和（封端的）中的至少一种）多异氰酸酯化合物，（C）平均粒径为0.01〜1μm的微粒聚合物，含有40〜60重量％的作为各粒子的共聚成分的苯乙烯单体，其中，来自涂料组合物含有苯乙烯衍生的苯环的比例为总树脂固体重量的13-40％使用上述涂料组合物的涂布方法和使用上述涂料组合物可获得的涂布制品。

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