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1. 发明专利

JP2010229496A Heat-shielding coating material 审中-公开
标题翻译：热屏蔽涂料
公开(公告)号：JP2010229496A
公开(公告)日：2010-10-14
申请号：JP2009078509
申请日：2009-03-27
申请人： Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社
发明人： NAGANO ICHIRO , TORIGOE TAIJI , MORI KAZUTAKA , OKADA IKUO , TSURU YASUHIKO , SHIDA MASAHITO , NANBA KATSUMI
IPC分类号： C23C4/10 , F01D5/28 , F23R3/42
摘要： PROBLEM TO BE SOLVED: To provide a heat-shielding coating material which is restrained from being peeled during use at a high temperature and has a high heat-shielding effect. SOLUTION: The heat-shielding coating material is formed on a heat resistant alloy base material for high temperature to enhance the heat resistance of the base material and includes a ceramic layer. The ceramic layer is composed of ZrO 2 into which Ta 2 O 5 and M 2 O 3 (M is a rare earth element) are added as stabilizers. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供一种在高温使用期间被抑制剥离并具有高热屏蔽效果的遮光涂层材料。解决方案：隔热涂料形成在用于高温的耐热合金基材上，以提高基材的耐热性，并且包括陶瓷层。陶瓷层由其中Ta 2 O 5和M 2 O 3的ZrO 2 组成。作为稳定剂添加（M为稀土类元素）。版权所有（C）2011，JPO＆INPIT

2. 发明专利

JP2009221587A Method for repairing member 有权
标题翻译：修理会员的方法
公开(公告)号：JP2009221587A
公开(公告)日：2009-10-01
申请号：JP2008070564
申请日：2008-03-19
申请人： Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社
发明人： NANBA KATSUMI , OKADA IKUO , TORIGOE TAIJI , ICHIHASHI ICHIRO , ONO TOMOHIRO , NAKAMURA MOTOYOSHI
IPC分类号： C23C4/06 , F02F1/00
CPC分类号： C23C4/02 , C23C4/01 , C23C4/06 , C23C4/08 , C23C4/131 , Y10T29/49746
摘要： PROBLEM TO BE SOLVED: To provide a method for repairing a member by which a worn member composed of a metallic material for an internal combustion engine or the like can be reused. SOLUTION: A Ni-Al alloy is thermally sprayed on a worn part of a member 10 constituting an internal combustion engine composed of a metallic material such as cast iron by an arc wire spraying process to form a bond layer 11. Then, a Cr-based stainless steel is thermally sprayed on the bond layer 11 by an arc wire spraying process to form a cladding layer 12 having a thickness of 0.1-3 mm. The cladding layer 12 is formed via the bond layer 11, so that the cladding layer can be strongly stuck to the worn part of the member 10 to positively prevent peeling of the cladding layer. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供一种用于修复由内燃机等的金属材料构成的磨损构件可以重复使用的构件的方法。解决方案：通过电弧丝喷涂工艺将Ni-Al合金热喷涂在构成由铸铁等金属材料构成的内燃机的构件10的磨损部分上，形成接合层11.然后，通过电弧丝喷涂工艺将Cr基不锈钢热喷涂在接合层11上，形成厚度为0.1-3mm的包覆层12。通过接合层11形成包覆层12，使得包覆层能够牢固地粘附到构件10的磨损部分，以确保防止包覆层的剥离。版权所有（C）2010，JPO＆INPIT

3. 发明专利

JP2006193828A Heat-shielding coating material, heat-shielding member, heat-shielding coating member, and method for production of the heat-shielding coating member 有权
标题翻译：热敏涂层材料，热屏蔽部件，加热保护涂层部件及其制造方法
公开(公告)号：JP2006193828A
公开(公告)日：2006-07-27
申请号：JP2005360801
申请日：2005-12-14
申请人： Mitsubishi Heavy Ind Ltd , Qinghua Univ , ツィンファユニバーシティ , 三菱重工業株式会社
发明人： TORIGOE TAIJI , OKADA IKUO , NANBA KATSUMI , MORI KAZUTAKA , PAN WEI , XU QIANG
IPC分类号： C23C4/10 , C23C4/08 , C23C14/08 , F01D5/28 , F02C7/00
CPC分类号： Y02T50/67
摘要： PROBLEM TO BE SOLVED: To provide a heat-shielding coating material which has a peeling resistance in a high-temperature use and has a high heat-shielding effect, to provide a heat-shielding coating member and its production method, to provide a turbine part coated with the heat-shielding coating material, and to provide a gas turbine. SOLUTION: The heat-shielding member is composed of a heat-resistant substrate, a bond coat layer formed on the heat-resistant substrate, and a ceramic layer formed on the bond coat layer, wherein the ceramic layer includes a ceramic represented by the formula: A 2 Zr 2 O 7 (wherein A is a rare earth element) and has (a) a porosity rate of 1 to 30%, and (b) cracks or (c) columnar crystal formed at intervals of 5 to 100% of the thickness of the entire layer except the bond coat layer on the heat-resistant substrate in the thickness direction. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：解决的问题：为了提供一种在高温使用中具有耐剥离性并具有高的热屏蔽效果的遮光涂层材料，以提供一种隔热涂层构件及其制造方法，提供涂覆有热屏蔽涂层材料的涡轮部分，并提供燃气轮机。热屏蔽部件由耐热基板，形成在耐热基板上的接合涂层和形成在接合涂层上的陶瓷层构成，其中陶瓷层包括陶瓷层其中A是稀土元素，并具有（a）孔隙率为1 至（30）％，（b）裂纹或（c）除厚度方向上耐热基材上的粘合涂层以外的整个层的厚度的5〜100％的间隔形成的柱状晶体。版权所有（C）2006，JPO＆NCIPI

4. 发明专利

JP2013197300A Manufacturing method of ultrasonic thickness sensor 审中-公开
标题翻译：超声波传感器的制造方法
公开(公告)号：JP2013197300A
公开(公告)日：2013-09-30
申请号：JP2012062601
申请日：2012-03-19
申请人： Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社
发明人： MORI KAZUTAKA , NANBA KATSUMI , NAGANO ICHIRO , UEMOTO AKIHIRO
IPC分类号： H01L41/22 , C01G29/00 , C04B35/462 , G01B17/02 , H01L41/08 , H01L41/187 , H01L41/257 , H01L41/39
摘要： PROBLEM TO BE SOLVED: To provide a manufacturing method of an ultrasonic thickness sensor that is thin, has flexibility as the ultrasonic thickness sensor, can track a surface of a measuring object even when the surface is curved, can continuously adheres to a measuring object place, eliminates the need of various types of work before and after thickness measurement, greatly reduces time and effort for the thickness measurement, enables the simultaneous thickness measurement of multiple places and the consecutive thickness measurement and can be used at a relatively high temperature not less than 300°C.SOLUTION: A manufacturing method of an ultrasonic thickness sensor comprises the steps of: mixing an alcohol solution of alkoxide of one of Ti and Bi and acetate of the other together to prepare Ti-Bi sol; mixing the Ti-Bi sol and powder that is composed of bismuth titanate (BIT) and has a grain size 1 to 5 μm together; causing a composite to adhere to a surface of a thin plate-like supporting body in which at least the surface has conductivity serving as one electrode; heating and burning the composite to form a BIT sintered body layer; forming the other electrode; and performing polarization treatment of the BIT sintered body layer.
摘要翻译：要解决的问题：为了提供一种薄的超声波厚度传感器的制造方法，具有作为超声波测厚仪传感器的灵活性，即使在表面弯曲的情况下也能追踪被测物体的表面，能够连续地附着在测量对象位置，无需厚度测量前后的各种工作，大大减少了厚度测量的时间和精力，能够同时进行多个位置的厚度测量和连续的厚度测量，可以在不低于 300℃。解决方案：超声波厚度传感器的制造方法包括以下步骤：将Ti和Bi之一的醇盐的醇溶液与另一种的乙酸盐混合，制备Ti-Bi溶胶; 将Ti-Bi溶胶和由钛酸铋（BIT）组成的粉末混合在一起，其粒径为1〜5μm; 导致复合材料附着在至少具有导电性的表面作为一个电极的薄板状支撑体的表面上; 加热和燃烧复合材料以形成BIT烧结体层; 形成另一电极; 并进行BIT烧结体层的极化处理。

5. 发明专利

JP2013114979A Solid oxide fuel cell 有权
标题翻译：固体氧化物燃料电池
公开(公告)号：JP2013114979A
公开(公告)日：2013-06-10
申请号：JP2011261887
申请日：2011-11-30
申请人： Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社
发明人： NANBA KATSUMI , MORI KAZUTAKA , TAKENOBU KOICHI , TOMITA KAZUO , YOSHIDA SHIN , ARAKI KENTA , TSUKUDA HIROSHI , MAEDA KATSUHIKO , MATSUMOTO MINEAKI
IPC分类号： H01M8/02 , H01M8/12 , H01M8/24
CPC分类号： Y02P70/56
摘要： PROBLEM TO BE SOLVED: To provide a solid oxide fuel cell configured by arranging power generation cells on a substrate member in which high power generation performance can be obtained by suppressing decrease in OCV due to a leakage current even if a fuel to be supplied to a fuel electrode passes through the substrate member, and to provide a solid oxide fuel cell cartridge, a solid oxide fuel cell module, and a manufacturing method of a solid oxide fuel cell.SOLUTION: A solid oxide fuel cell 10 includes a porous substrate tube 11, a power generation cell 20 placed on the substrate tube 11 and formed by laminating a fuel electrode 21, a solid electrolyte 22, and an air electrode 23 in this order from the substrate tube 11, and an insulation layer 12 formed between the substrate tube 11 and the power generation cell 20 while containing SrZrOor MgAlOand suppressing a leakage current.
摘要翻译：要解决的问题：提供一种固体氧化物燃料电池，其通过将发电电池配置在能够通过抑制由于泄漏电流引起的OCV的降低而能够获得高发电性能的基板部件上配置发电电池，供给到燃料电极的电极通过基板部件，并且提供固体氧化物燃料电池盒，固体氧化物燃料电池模块和固体氧化物燃料电池的制造方法。解决方案：固体氧化物燃料电池10包括多孔基材管11，放置在基材管11上的发电单元20，并通过层压燃料电极21，固体电解质22和空气电极23形成。在衬底管11和发电单元20之间形成的绝缘层12，同时包含SrZrO 3 或MgAl 2 O 4 并抑制漏电流。版权所有（C）2013，JPO＆INPIT

6. 发明专利

JP2014038932A Method for producing oxide-based piezoelectric material powder for ultrasonic thickness sensor, piezoelectric material powder, method for manufacturing ultrasonic thickness sensor, and ultrasonic thickness sensor 有权
标题翻译：用于制造用于超声波厚度传感器的氧化物基压电材料粉末的方法，压电材料粉末，用于制造超声波厚度传感器的方法和超声波厚度传感器
公开(公告)号：JP2014038932A
公开(公告)日：2014-02-27
申请号：JP2012180134
申请日：2012-08-15
申请人： Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社
发明人： MORI KAZUTAKA , NANBA KATSUMI , YAMAMOTO YUKO
IPC分类号： H01L41/39 , C01G33/00 , C04B35/00 , G01B17/02 , G01N29/24 , H01L41/08 , H01L41/187 , H01L41/22 , H01L41/257
摘要： PROBLEM TO BE SOLVED: To provide a method for producing piezoelectric material powder (lithium niobate powder) for an ultrasonic thickness measurement sensor, the piezoelectric material powder being thin and exhibiting flexibility as an ultrasonic thickness sensor, and further being capable of being used even at a high temperature of from 300°C to around 1,000°C, and being obtained by using oxide-base ceramic comprising lithium niobate, and specifically to provide a method for producing piezoelectric material powder, by which piezoelectric characteristics to an extent necessary for an ultrasonic thickness sensor can be obtained.SOLUTION: A method for producing piezoelectric material powder for an ultrasonic thickness sensor includes: a mixing step of mixing powder of lithium carbonate and powder of a niobium oxide or salt; a heat treatment step of heating the mixed powder obtained through the mixing step up to a temperature within the range of 975-1,175°C in an oxidizing atmosphere to synthesize lithium niobate; and a pulverizing step of pulverizing the lithium niobate obtained through the heat treatment step to form powder.
摘要翻译：要解决的问题：为了提供一种用于制造超声波测厚传感器的压电材料粉末（铌酸锂粉末）的制造方法，所述压电材料粉末薄且具有作为超声波厚度传感器的柔性，并且还能够甚至在通过使用包含铌酸锂的氧化物基陶瓷获得，并且具体地提供了一种制造压电材料粉末的方法，其中压电特性达到超声波所需的程度可以获得厚度传感器。解决方案：一种用于制造超声波厚度传感器的压电材料粉末的方法，包括：混合碳酸锂粉末和氧化铌粉末的混合步骤; 在氧化气氛中将通过混合步骤获得的混合粉末加热至975-1175℃的温度以合成铌酸锂的热处理步骤; 以及粉碎通过热处理步骤获得的铌酸锂形成粉末的粉碎步骤。

7. 发明专利

JP2013239636A Method for manufacturing ultrasonic thickness sensor 审中-公开
标题翻译：制造超声波厚度传感器的方法
公开(公告)号：JP2013239636A
公开(公告)日：2013-11-28
申请号：JP2012112547
申请日：2012-05-16
申请人： Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社
发明人： MORI KAZUTAKA , NANBA KATSUMI , NAGANO ICHIRO , UEMOTO AKIHIRO
IPC分类号： H01L41/22 , C04B35/462 , G01B17/02 , H01L41/08 , H01L41/187 , H01L41/257 , H01L41/39
摘要： PROBLEM TO BE SOLVED: To provide a method for manufacturing a thin and flexible ultrasonic thickness measurement sensor which can follow up even a curved surface to be measured, can eliminate various works before and after thickness measurement, while reducing the effort and time required for the thickness measurement, by always pasting a sheet to a part to be measured, can measure the thickness of a large number of parts simultaneously or measure the thickness continuously, and can be used even at a relatively high temperature of 300°C or higher.SOLUTION: The method for manufacturing an ultrasonic thickness sensor comprises: a process including the steps of mixing bismuth titanate powder with low-melting point glass powder of bismuth-based glass or the like, applying paste of the mixture to a surface of a thin-plate-like support member to make one of electrodes with at least its surface having conductivity, and heating and sintering the support member, thereby forming a relatively-porous and flexible thin bismuth titanate sintered compact layer over the surface of the thin-plate-like support member; and a subsequent process including the steps of attaching the other electrode, and performing a polarization process, thereby arranging the sensor to have flexibility generally.
摘要翻译：要解决的问题：为了提供一种能够追随测量的曲面的薄而柔性的超声波厚度测量传感器的制造方法，可以消除厚度测量之前和之后的各种工作，同时减少所需的时间和时间厚度测量通过将片材总是粘贴到待测量的部件上，可以同时测量大量部件的厚度或连续测量厚度，并且即使在相对高的300℃或更高的温度下也可以使用。：超声波厚度传感器的制造方法包括：将钛酸铋粉末与铋基玻璃等的低熔点玻璃粉末混合的工序，将混合物的糊料涂布在薄板的表面形状的支撑构件以使至少具有导电性的电极中的一个电极，并且加热和烧结支撑构件，从而形成相对较小的在薄板状支撑构件的表面上方具有柔软的薄的钛酸铋烧结致密层; 以及随后的处理，其包括附接另一个电极并执行偏振处理的步骤，从而将传感器布置成具有一般的灵活性。

8. 发明专利

JP2013239635A Method for manufacturing ultrasonic thickness sensor 审中-公开
标题翻译：制造超声波厚度传感器的方法
公开(公告)号：JP2013239635A
公开(公告)日：2013-11-28
申请号：JP2012112546
申请日：2012-05-16
申请人： Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社
发明人： MORI KAZUTAKA , NANBA KATSUMI , NAGANO ICHIRO , UEMOTO AKIHIRO
IPC分类号： H01L41/22 , B28B1/30 , C04B35/462 , G01B17/02 , H01L41/08 , H01L41/09 , H01L41/187 , H01L41/257
摘要： PROBLEM TO BE SOLVED: To provide a method for manufacturing a thin and flexible ultrasonic thickness measurement sensor which can follow up even a curved surface to be measured, can eliminate various works before and after thickness measurement, while reducing the effort and time required for the thickness measurement, by always pasting a sheet to a part to be measured, can measure the thickness of a large number of parts simultaneously or measure the thickness continuously, and can be used even at a relatively high temperature of 300°C or higher.SOLUTION: The method for manufacturing an ultrasonic thickness sensor comprises: a process including the steps of preparing bismuth titanate powder to become ultra-fine powder having an average particle diameter 0.15-0.25 μm, applying paste of the ultra-fine powder to a surface of a thin-plate-like support member to make one of electrodes with at least its surface having conductivity, and heating and sintering the support member, thereby forming a relatively-porous and flexible thin bismuth titanate sintered compact layer over the surface of the thin-plate-like support member; and a subsequent process including the steps of forming the other electrode, and performing a polarization process, thereby arranging the sensor to have flexibility generally.
摘要翻译：要解决的问题：为了提供一种能够追随测量的曲面的薄而柔性的超声波测厚传感器的制造方法，能够消除厚度测量之前和之后的各种工作，同时减少所需的时间和时间厚度测量通过将片材总是粘贴到待测量的部件上，可以同时测量大量部件的厚度或连续测量厚度，并且即使在相对高的300℃或更高的温度下也可以使用。超声波厚度传感器的制造方法，其特征在于，包括以下工序：将钛酸铋粉末制成平均粒径为0.15〜0.25μm的超细粉末，将超细粉末的糊料涂布在薄板状支撑构件，使至少具有导电性的电极中的一个电极，以及加热和烧结支撑构件，从而为在薄板状支撑构件的表面上形成相对多孔且柔性薄的钛酸铋烧结致密层; 以及随后的处理，包括形成另一个电极的步骤，并执行偏振处理，从而将传感器布置成具有一般的灵活性。

9. 发明专利

JP2013187382A Ultrasonic thickness sensor and method of manufacturing the same 审中-公开
标题翻译：超声波厚度传感器及其制造方法
公开(公告)号：JP2013187382A
公开(公告)日：2013-09-19
申请号：JP2012051680
申请日：2012-03-08
申请人： Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社
发明人： NANBA KATSUMI , MORI KAZUTAKA , UEMOTO AKIHIRO
IPC分类号： H01L41/08 , C04B35/00 , C04B35/462 , C04B35/491 , G01B17/02 , H01L41/187 , H01L41/22 , H01L41/39
摘要： PROBLEM TO BE SOLVED: To provide: an ultrasonic thickness sensor which is slim and flexible, and is capable of following even a curved target face to be measured; and a method of manufacturing the ultrasonic thickness sensor.SOLUTION: An ultrasonic thickness sensor comprises: a substrate made of a zirconia-based ceramic, e.g. yttria partially stabilized zirconia and having an average thickness of 30-100 μm; a metallization layer formed as a first electrode on a surface of the substrate, made of a high-temperature oxidation resistant metal with good conductivity, and having an average thickness of 5-20 μm; a sintered compact layer formed on the metallization layer, made of an oxide-based piezoelectric material, and having a density of 70-80% and an average thickness of 30-150 μm; and a second electrode formed on the sintered compact layer, and having an average thickness of 10-100 μm. A method of manufacturing the ultrasonic thickness sensor comprises the steps of: metallizing the surface of the substrate (i.e. forming the first electrode); and coating the resultant substrate with a viscous liquid material including the oxide-based piezoelectric material; sintering the substrate; forming the second electrode; and performing polarization treatment.
摘要翻译：要解决的问题：提供一种超薄且柔软的超声波厚度传感器，能够追随待测量的弯曲目标面; 以及超声波厚度传感器的制造方法。解决方案：超声波测厚仪包括：由氧化锆系陶瓷制成的基板，氧化钇部分稳定的氧化锆，平均厚度为30-100μm; 金属化层，其形成为在由具有良好导电性的高温抗氧化金属制成的基板的表面上的平均厚度为5-20μm的第一电极; 形成在金属化层上的由氧化物基压电材料制成的密度为70-80％，平均厚度为30-150μm的烧结致密层; 以及形成在烧结致密层上的第二电极，其平均厚度为10〜100μm。一种制造超声波厚度传感器的方法包括以下步骤：金属化基片的表面（即形成第一电极）; 并用包含氧化物基压电材料的粘性液体材料涂覆所得基板; 烧结基材; 形成第二电极; 并进行极化处理。

10. 发明专利

JP2011195895A Heat shielding coating material, turbine member with the same, and gas turbine 审中-公开
标题翻译：热风涂层材料，具有相同功能的涡轮机构和气体涡轮机
公开(公告)号：JP2011195895A
公开(公告)日：2011-10-06
申请号：JP2010063880
申请日：2010-03-19
申请人： Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社
发明人： NANBA KATSUMI , TORIGOE TAIJI , NAGANO ICHIRO , SHIDA MASAHITO , OKADA IKUO , MORI KAZUTAKA , TSURU YASUHIKO , ITO EISAKU , OKAJIMA YOSHIFUMI
IPC分类号： C23C24/08 , C01G25/00 , C23C4/10 , F01D5/28 , F01D25/00 , F02C7/00
摘要： PROBLEM TO BE SOLVED: To provide a heat shielding coating material having excellent durability and manufactured more inexpensively, to provide a turbine member including the same and to provide a gas turbine.SOLUTION: In the heat shielding coating material including a bond coat 12 and a top coat 13 made of high temperature oxide alloy on a heat resistant alloy base material 11, the top coat 13 is constituted of, in order from the bond coat 12 side: a zirconia-containing layer 14 mainly made of zirconia and a radiation layer 15 mainly made of a material represented by general formula AZrO(A denotes a rare earth element) or A'BZrO(A' and B each denote any one of La, Nd, Sm, Gd, Dy, Ce and Yb and A' and B denote elements different from each other). The film thickness of the radiation layer 15 is thinner than 10% of the film thickness of the top coat 13.
摘要翻译：要解决的问题：提供一种耐久性优异且制造成本低廉的隔热涂层材料，以提供一种包括该隔热涂层的涡轮机构件，并提供一种燃气轮机。解决方案：在包括粘合涂层12和由耐高温氧化物合金制成的顶涂层13在耐热合金基材11上，顶涂层13由从粘合涂层12侧起依次构成：主要由氧化锆构成的含氧化锆的层14和辐射层15 主要由通式AZrO（A表示稀土元素）或A'BZrO（A'和B各自表示La，Nd，Sm，Gd，Dy，Ce和Yb以及A'和B中的任一种表示的材料）表示彼此不同的元素）。辐射层15的膜厚度比顶涂层13的膜厚的10％薄。

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