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1. 发明专利

JP2014193985A Method for producing polyester and polyurethane 有权
标题翻译：生产聚酯和聚氨酯的方法
公开(公告)号：JP2014193985A
公开(公告)日：2014-10-09
申请号：JP2013117831
申请日：2013-06-04
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社 , Genomatica Inc , ジェノマティカ・インコーポレイテッドGenomatica, Inc.
发明人： UTSUNOMIYA MASARU , IZAWA YUSUKE , KONISHI NORIKAZU , TANAKA KOTA , MATSUZONO SHINICHIRO , SUZUKI TAKAYUKI , MICHAEL JAPS , BURK MARK , CLARK WARREN
IPC分类号： C08G63/78 , C08G18/42 , C08G63/16
CPC分类号： C08G18/4213 , C08G18/42 , C08G18/4238 , C08G18/664 , C08G63/16 , C08G63/183 , C12P7/18
摘要： PROBLEM TO BE SOLVED: To efficiently produce a polyester having good color tone, when producing the polyester using a dicarboxylic acid component and a diol derived from a biomass resource as raw materials.SOLUTION: As a raw material diol derived from a biomass resource, used is one containing a cyclic carbonyl compound having 5 or 6 carbon atoms in an amount of 0.01 to 12 mass ppm. When producing a polyester using the diol derived from biomass resource, color tone of the polyester obtained has a strong correlation with a content of a carbonyl compound, especially the cyclic carbonyl compound having 5 or 6 carbon atoms. By controlling the content of the cyclic carbonyl compound having 5 or 6 carbon atoms in the raw material diol, color tone of the polyester becomes good.
摘要翻译：要解决的问题：为了有效地制造具有良好色调的聚酯，使用二羧酸成分制造聚酯和以生物质资源为原料的二醇。作为原料，使用来自生物质资源的二醇是含有0.01〜12质量ppm的碳原子数为5〜6的环状羰基化合物的化合物。当使用衍生自生物质资源的二醇生产聚酯时，所得聚酯的色调与羰基化合物，特别是具有5或6个碳原子的环状羰基化合物的含量具有很强的相关性。通过控制原料二醇中具有5或6个碳原子的环状羰基化合物的含量，聚酯的色调变好。

2. 发明专利

JP2014193837A Method for producing 1,4-butane diol 有权
标题翻译：生产1,4-丁二醇的方法
公开(公告)号：JP2014193837A
公开(公告)日：2014-10-09
申请号：JP2013117832
申请日：2013-06-04
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社 , Genomatica Inc , ジェノマティカ・インコーポレイテッドGenomatica, Inc.
发明人： UTSUNOMIYA MASARU , IZAWA YUSUKE , KONISHI NORIKAZU , TANAKA KOTA , MATSUZONO SHINICHIRO , SUZUKI TAKAYUKI , MICHAEL JAPS , BURK MARK , CLARK WARREN
IPC分类号： C07C29/80 , C07C29/76 , C07C29/90 , C07C31/20
CPC分类号： C07C29/84 , B01D3/143 , C07C29/80 , C12P7/18 , C07C31/207
摘要： PROBLEM TO BE SOLVED: To produce high quality 1,4BG having good color tone and capable of being used as a raw material of PBT by efficiently removing impurities, which are mixed when 1,4BG derived from a biomass resource is produced in an industrial scale, to purify the 1,4BG derived from a biomass resource.SOLUTION: A method for producing 1,4BG comprises obtaining a crude 1,4BG-containing liquid from a purified raw material 1,4BG-containing liquid, obtained by removing at least a portion of each of fungus bodies, salt content and water from a fermentation medium, through a step for removing high boiling point components and/or low boiling point components by distillation and/or a step for converting unsaturated compounds to hydrides, and further, obtaining purified 1,4BG from a side fraction in a distillation step.
摘要翻译：要解决的问题：为了生产具有良好色调的高质量的1,4BG，并且能够通过有效地去除以工业规模生产来自生物质资源的1,4BG混合的杂质，可以用作PBT的原料纯化来自生物质资源的1,4BG。解决方案：生产1,4BG的方法包括从纯化的含原料1,4BG的液体中获得粗制的含1,4BG的液体，通过除去至少一种通过蒸馏除去高沸点组分和/或低沸点组分的步骤和/或将不饱和化合物转化为氢化物的步骤，进一步获得来自发酵培养基的各种真菌体，盐含量和水的部分，在蒸馏步骤中从副馏分中纯化的1,4BG。

3. 发明专利

JP2014012822A Method for producing polybutylene terephthalate 有权
标题翻译：制备聚苯乙烯聚苯乙烯的方法
公开(公告)号：JP2014012822A
公开(公告)日：2014-01-23
申请号：JP2013117830
申请日：2013-06-04
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社 , Genomatica Inc , ジェノマティカ・インコーポレイテッドGenomatica, Inc.
发明人： UTSUNOMIYA MASARU , IZAWA YUSUKE , KONISHI NORIKAZU , MATSUZONO SHINICHIRO , SUZUKI TAKAYUKI , MICHAEL JAPS , BURK MARK , CLARK WARREN
IPC分类号： C08G63/78 , C08G63/183 , C12N1/19 , C12N1/21 , C12P7/18 , C12P7/62
CPC分类号： C08G63/80 , C08G63/183 , C08G63/78 , C12N9/0006 , C12N9/0008 , C12N9/93 , C12P7/18 , C12Y101/01061 , C12Y102/01024 , C12Y102/04002 , C12Y602/01004 , Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a method for producing polybutylene terephthalate (PBT), having good color tone, using 1,4-butanediol (BG) derived from bioresources.SOLUTION: A method for producing polybutylene terephthalate includes: a process (a) of performing an esterification reaction or ester exchange reaction between a diol component containing a raw material 1,4-butanediol derived from biomass resources and having a nitrogen atom content of 0.01-50 mass ppm and a dicarboxylic acid component containing terephthalic acid or terephthalic acid alkyl ester; and a polycondensation reaction process (b) of performing a polycondensation reaction of the reactant obtained in the process (a) to obtain polybutylene terephthalate. The content of gamma-butyrolactone in the raw material 1,4-butanediol is 1-100 mass ppm.
摘要翻译：要解决的问题：提供一种生产具有良好色调的聚对苯二甲酸丁二醇酯（PBT）的方法，使用衍生自生物资源的1,4-丁二醇（BG）。解决方案：一种生产聚对苯二甲酸丁二醇酯的方法包括：方法（a）在含有源自生物质资源的原料1,4-丁二醇和氮原子含量为0.01〜50质量ppm的二醇成分和含有对苯二甲酸或对苯二甲酸烷基的二羧酸成分之间进行酯化反应或酯交换反应酯; 和进行（a）工序中得到的反应物的缩聚反应的缩聚反应方法（b），得到聚对苯二甲酸丁二醇酯。原料1,4-丁二醇中的γ-丁内酯的含量为1-100质量ppm。

4. 发明专利

JP2013060428A Method for producing gamma-butyrolactone 有权
标题翻译：生产γ-丁内酯的方法
公开(公告)号：JP2013060428A
公开(公告)日：2013-04-04
申请号：JP2012183343
申请日：2012-08-22
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社
发明人： KONISHI NORIKAZU , IZAWA YUSUKE , UTSUNOMIYA MASARU , TANAKA KOTA
IPC分类号： C07D307/33 , C07B61/00
CPC分类号： C07D307/33
摘要： PROBLEM TO BE SOLVED: To restrain a catalyst from deteriorating due to the elapse of time to improve a formation speed of gamma-butyrolactone and prevent a reaction by-product from being formed to efficiently produce gamma-butyrolactone when the gamma-butyrolactone is produced by the dehydrogenation of 1,4-butanediol in the presence of the catalyst.SOLUTION: In a method in which 1,4-butanediol as a raw material, is subjected to dehydrogenation to produce gamma-butyrolactone in the presence of a catalyst which contains a metal belonging to the groups 8-11 of the periodic table, the concentration of a nitrogen-containing compound in the 1,4-butanediol as the raw material is 0.5-15 weight ppm in terms of nitrogen atom. Making the 1,4-butanediol as the raw material contain a nitrogen-containing compound at a prescribed concentration restrains the formation of a by-product and the deterioration of the catalyst due to the elapse of time and improves the formation speed of the gamma-butyrolactone.
摘要翻译：待解决的问题：为了抑制由于时间的推移催化剂劣化，以提高γ-丁内酯的形成速度，并且防止当γ-丁内酯形成时副反应产物有效地产生γ-丁内酯是在催化剂存在下通过1,4-丁二醇的脱氢制备的。解决方案：在作为原料的1,4-丁二醇的方法中，在含有属于周期表第8-11族的金属的催化剂存在下进行脱氢制备γ-丁内酯作为原料的1,4-丁二醇中的含氮化合物的浓度以氮原子计为0.5-15重量ppm。制造1,4-丁二醇为原料含有规定浓度的含氮化合物可抑制副产物的形成和催化剂由于时间的劣化而提高γ射线衍射的形成速度，丁内酯。版权所有（C）2013，JPO＆INPIT

5. 发明专利

JP2014166990A METHOD FOR PRODUCING CARBOXYLIC ACID ANHYDRIDE AND METHOD FOR PRODUCING γ-BUTYROLACTONE 有权
标题翻译：生产羧酸酐的方法及生产γ-丁氧基酮的方法
公开(公告)号：JP2014166990A
公开(公告)日：2014-09-11
申请号：JP2014012507
申请日：2014-01-27
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社
发明人： TANIGUCHI SHOHEI , KONISHI NORIKAZU , IZAWA YUSUKE , UTSUNOMIYA MASARU , IWADE SHINJI
IPC分类号： C07D307/60 , C07B61/00 , C07D307/33
摘要： PROBLEM TO BE SOLVED: To provide an industrially advantageous method for efficiently forming carboxylic acid anhydride by dehydration condensation reaction with a catalyst using carboxylic acid, and to obtain succinic anhydride at yield higher than the conventional case owing to the promoted reaction in accordance with the invention.SOLUTION: Provided is a method for producing carboxylic acid anhydride characterized in that, when carboxylic acid anhydride is formed by bringing dicarboxylic acid as raw material into dehydration condensation reaction, the dehydration condensation reaction is performed in the presence of an organic phosphor compound. It is preferable that the dicarboxylic acid as raw material being succinic acid, the carboxylic acid anhydride being succinic acid anhydride and the organic phosphorous compound being a phosphine compound.
摘要翻译：要解决的问题：为了提供通过使用羧酸与催化剂脱水缩合反应有效形成羧酸酐的工业上有利的方法，并且由于根据本发明的促进反应而获得比常规情况更高的琥珀酸酐解决方案：提供一种制备羧酸酐的方法，其特征在于当通过将二羧酸作为原料进行脱水缩合反应形成羧酸酐时，脱水缩合反应在有机荧光体化合物的存在下进行。作为原料的二羧酸为琥珀酸，羧酸酐为琥珀酸酐，有机磷化合物为膦化合物为佳。

6. 发明专利

JP2013032341A Method of producing 1,4-butanediol 有权
标题翻译：生产1,4-丁二醇的方法
公开(公告)号：JP2013032341A
公开(公告)日：2013-02-14
申请号：JP2012144393
申请日：2012-06-27
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社
发明人： KONISHI NORIKAZU , IZAWA YUSUKE , UTSUNOMIYA MASARU
IPC分类号： C07C29/94 , C07C29/80 , C07C31/20
摘要： PROBLEM TO BE SOLVED: To provide an industrially advantageous method of producing 1,4-butanediol (1,4-BG) for producing stably the 1,4-BG of high quality excellent as a THF production raw material.SOLUTION: The method of producing the 1,4-butanediol is constituted to bring crude 1,4-butanediol containing 70.0 wt.% or more and less than 99.4 wt.% of 1,4-butanediol, and having 7.01 or more of pH, into contact with an acid, and to obtain refined 1,4-butanediol having 5.5 or more to 6.99 or less of pH, by distilling an obtained crude 1,4-butanediol-containing liquid.
摘要翻译：待解决的问题：提供一种用于生产1,4-丁二醇（1,4-BG）的工业上有利的方法，用于稳定地生产作为THF生产原料的高质量的1,4-BG。解决方案：制备1,4-丁二醇的方法是使含有70.0重量％以上且小于99.4重量％的1,4-丁二醇的粗1,4-丁二醇，并具有7.01或更多的pH与酸接触，通过蒸馏得到的粗1,4-丁二醇的液体，得到pH 5.5以上至6.99以下的精制1,4-丁二醇。版权所有（C）2013，JPO＆INPIT

7. 发明专利

JP2014012663A Method for purifying furfural 有权
标题翻译：净化方法
公开(公告)号：JP2014012663A
公开(公告)日：2014-01-23
申请号：JP2013119856
申请日：2013-06-06
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社
发明人： KONISHI NORIKAZU , YAMASHITA AKIRA , IZAWA YUSUKE , UTSUNOMIYA MASARU , TSUJI HIDETO
IPC分类号： C07D307/48
摘要： PROBLEM TO BE SOLVED: To provide an industrially advantageous method which, when furfural is purified, suppresses the generation of solids to stably and efficiently distill high-purity furfural from raw material furfural, and produces furan by a decarbonylation reaction of the obtained high-purity furfural.SOLUTION: In a method for purifying furfural, when raw material crude furfural is purified by distilling it to obtain furfural, the raw material crude furfural is brought into contact with an anion exchange resin and/or a basic compound beforehand.
摘要翻译：要解决的问题：提供一种工业上有利的方法，当糠醛被纯化时，抑制固体的产生以从糠醛原料中稳定高效地蒸馏出高纯度糠醛，并通过所得到的高纯度的脱羰反应产生呋喃糠醛。方法：在糠醛纯化方法中，将原料粗糠醇通过蒸馏纯化得到糠醛后，将原料粗糠醛与阴离子交换树脂和/或碱性化合物预先接触。

8. 发明专利

JP2013116881A Method for producing tetrahydrofuran 有权
标题翻译：生产四氢呋喃的方法
公开(公告)号：JP2013116881A
公开(公告)日：2013-06-13
申请号：JP2012149684
申请日：2012-07-03
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社
发明人： KONISHI NORIKAZU , IZAWA YUSUKE , UTSUNOMIYA MASARU , TANAKA KOTA
IPC分类号： C07D307/08 , C07B61/00
摘要： PROBLEM TO BE SOLVED: To produce tetrahydrofuran stably at high productivity by preventing a solid material from being deposited during a cyclodehydration reaction when the tetrahydrofuran is produced through the cyclodehydration reaction of 1,4-butanediol by using an acid catalyst having a pKa value of no greater than 4.SOLUTION: The present invention is a method for producing tetrahydrofuran by means of a cyclodehydration reaction of 1,4-butanediol in the presence of an acid catalyst having a pKa value of no greater than 4 in a reaction vessel, wherein a starting material liquid containing 1,4-butanediol made available to the reaction contains 0.01-0.35 wt.% of 2-(4-hydroxybutoxy)-tetrahydrofuran and 1-1,000 wt.ppm inclusive by concentration of nitrogen atoms of at least either of an amine and amide.
摘要翻译：待解决的问题：通过使用具有pKa的酸催化剂通过1,4-丁二醇的环化脱水反应制备四氢呋喃时，通过防止在环化脱水反应期间固体材料沉积来以高生产率稳定地生产四氢呋喃值不大于4.解决方案：本发明是通过1,4-丁二醇在pKa值不大于4的酸催化剂存在下，通过1,4-丁二醇的环化脱水反应生产四氢呋喃的方法反应容器，其中含有可用于该反应的1,4-丁二醇的原料液体含有0.01-0.35重量％的2-（4-羟基丁氧基）四氢呋喃和1-1000重量ppm的含氮浓度的氮原子的胺和酰胺中的至少一种。版权所有（C）2013，JPO＆INPIT

9. 发明专利

JP2012153667A Method for producing polyalkylene ether glycol and method for purifying acetic anhydride 审中-公开
标题翻译：用于生产聚亚甲基醚的方法和用于纯化乙酸酐的方法
公开(公告)号：JP2012153667A
公开(公告)日：2012-08-16
申请号：JP2011015323
申请日：2011-01-27
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社
发明人： YANO KAORI , KONISHI NORIKAZU , UTSUNOMIYA MASARU , NISHIMURA SEIJIRO
IPC分类号： C07C51/573 , C07C53/12 , C08G65/20
摘要： PROBLEM TO BE SOLVED: To provide a method for purifying acetic anhydride, which can obtain high-quality acetic anhydride and a method for producing a polyalkylene ether glycol, which can obtain a high-quality polyalkylene ether glycol having little discoloration using purified acetic anhydride obtained by the purification method.SOLUTION: The method for purifying acetic anhydride includes adjusting absorbance of crude acetic anhydride to ≥0.12 by UV spectrum at a measurement wavelength in a region of 300-330 nm, distilling the crude acetic anhydride and separating and recovering purified acetic anhydride.

10. 发明专利

JP2013060429A Method of purifying 1,4-butanediol and method of manufacturing tetrahydrofuran 审中-公开
标题翻译：纯化1,4-丁二醇的方法及制备四氢呋喃的方法
公开(公告)号：JP2013060429A
公开(公告)日：2013-04-04
申请号：JP2012183344
申请日：2012-08-22
申请人： Mitsubishi Chemicals Corp , 三菱化学株式会社
发明人： KONISHI NORIKAZU , IZAWA YUSUKE , UTSUNOMIYA MASARU , TANAKA KOTA
IPC分类号： C07C29/80 , C07C31/20 , C07D307/08
摘要： PROBLEM TO BE SOLVED: To provide an industrially useful method of purifying 1,4-butanediol in which purification is performed by separating and removing impurities that become the cause of staining during manufacture of tetrahydrofuran stably and efficiently from crude 1,4-butanediol at a low cost.SOLUTION: Crude 1,4-butanediol containing 100 ppm by weight to 1.2 wt.% chain aliphatic diol having 4 or 5 carbon atoms expressed by general formula (I) (aliphatic diol (I)) is distilled in a distillation tower. When the distilled 1,4-butanediol is removed from the bottom of the distillation tower, the concentration of aliphatic diol (I) within the bottom liquid is controlled to 1.0 ppm by weight to 99 ppm by weight. (In the formula, R, R, and Reach represent a hydrogen atom, a hydroxyl group, or a methyl group, and one among Rto Ris a hydroxyl group).
摘要翻译：待解决的问题：提供一种工业上有用的纯化1,4-丁二醇的方法，其中通过在粗制1,4-二醇的稳定和有效地分离和除去成为四氢呋喃的四氢呋喃的四氢呋喃的四氢呋喃的四氢呋喃的制备中，丁二醇成本低。解决方案：在蒸馏塔中蒸馏含有100重量ppm至1.2重量％的由通式（I）表示的具有4或5个碳原子的链脂肪族二醇（脂族二醇（I））的粗1,4-丁二醇。当从蒸馏塔的底部除去蒸馏的1,4-丁二醇时，底部液体中的脂肪族二醇（I）的浓度被控制在1.0重量ppm至99重量ppm。（在公式中，R 1 ，R 2 ，R 3 各自表示氢原子，羟基或甲基，R“中的一个表示羟基，R”表示氢原子，羟基或甲基，R“ 组）。版权所有（C）2013，JPO＆INPIT

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