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1. 发明授权

US09441054B2 Vinylidene fluoride copolymers 有权
标题翻译：偏二氟乙烯共聚物
公开(公告)号：US09441054B2
公开(公告)日：2016-09-13
申请号：US13995275
申请日：2011-12-13
申请人： Milena Stanga , Bradley Lane Kent , Alessio Marrani , Giulio Brinati
发明人： Milena Stanga , Bradley Lane Kent , Alessio Marrani , Giulio Brinati
IPC分类号： H01M4/00 , C08F14/22 , C08F214/22 , C08J5/22 , C08L27/16 , H01M4/02 , H01M4/86 , H01M8/02 , H01M8/10 , H01M10/0565 , C08K5/06 , C08L33/02
CPC分类号： C08F14/22 , C08F214/22 , C08F214/225 , C08J5/2237 , C08J2327/16 , C08K5/06 , C08L27/16 , C08L33/02 , C08L2205/02 , C08L2205/025 , H01M4/02 , H01M4/8605 , H01M8/0289 , H01M8/1023 , H01M10/0565 , Y02E60/521 , Y02P70/56 , C08F2/16 , C08F220/06 , C08F214/182 , C08F214/24
摘要： The present invention pertains to a fluoropolymer [polymer (F)] comprising: recurring units derived from vinylidene fluoride (VDF), and from 0.01% to 5% by moles of recurring units derived from at least one (meth)acrylic monomer [monomer (MA)] having formula (I) here below: wherein: R1, R2 and R3, equal to or different from each other, are independently selected from a hydrogen atom and a C1-C3 hydrocarbon group, and ROH represents a hydrogen atom or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group, said polymer (F) comprising end groups having formula —CF2H and/or —CF2CH3 in an amount of at least 30 mmoles per Kg of vinylidene fluoride (VDF) recurring units. The invention also pertains to a process for the manufacture of said polymer (F) and to use of said polymer (F) as binders for the manufacture of electrodes or for the manufacture of membranes.
摘要翻译：本发明还涉及制备所述聚合物（F）的方法和所述聚合物（F）用作制备电极或制造膜的粘合剂。

2. 发明申请

US20130264522A1 Vinylidene fluoride copolymers 有权
标题翻译：偏二氟乙烯共聚物
公开(公告)号：US20130264522A1
公开(公告)日：2013-10-10
申请号：US13995275
申请日：2011-12-13
申请人： Milena Stanga , Bradley Lane Kent , Alessio Marrani , Giulio Brinati
发明人： Milena Stanga , Bradley Lane Kent , Alessio Marrani , Giulio Brinati
IPC分类号： C08F14/22 , C08L33/02 , C08K5/06
CPC分类号： C08F14/22 , C08F214/22 , C08F214/225 , C08J5/2237 , C08J2327/16 , C08K5/06 , C08L27/16 , C08L33/02 , C08L2205/02 , C08L2205/025 , H01M4/02 , H01M4/8605 , H01M8/0289 , H01M8/1023 , H01M10/0565 , Y02E60/521 , Y02P70/56 , C08F2/16 , C08F220/06 , C08F214/182 , C08F214/24
摘要： The present invention pertains to a fluoropolymer [polymer (F)] comprising: recurring units derived from vinylidene fluoride (VDF), and from 0.01% to 5% by moles of recurring units derived from at least one (meth)acrylic monomer [monomer (MA)] having formula (I) here below: wherein: R1, R2 and R3, equal to or different from each other, are independently selected from a hydrogen atom and a C1-C3 hydrocarbon group, and ROH represents a hydrogen atom or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group, said polymer (F) comprising end groups having formula —CF2H and/or —CF2CH3 in an amount of at least 30 mmoles per Kg of vinylidene fluoride (VDF) recurring units. The invention also pertains to a process for the manufacture of said polymer (F) and to use of said polymer (F) as binders for the manufacture of electrodes or for the manufacture of membranes.
摘要翻译：本发明涉及含氟聚合物[聚合物（F）]，其包含：衍生自偏二氟乙烯（VDF）的重复单元和0.01％至5％（摩尔）来源于至少一种（甲基）丙烯酸单体的重复单元[单体（ MA）]，其中：R 1，R 2和R 3彼此相同或不同，独立地选自氢原子和C1-C3烃基，ROH表示氢原子或包含至少一个羟基的C 1 -C 5烃部分，所述聚合物（F）包含具有式-CF 2 H和/或-CF 2 CH 3的端基，其量为至少30mmol / Kg偏二氟乙烯（VDF）重复单元。本发明还涉及制备所述聚合物（F）的方法和所述聚合物（F）用作制备电极或制造膜的粘合剂。

3. 发明申请

US20140154573A1 AQUEOUS VINYLIDENE FLUORIDE POLYMER LATEX 审中-公开
标题翻译：水性乙烯基氟化物聚合物
公开(公告)号：US20140154573A1
公开(公告)日：2014-06-05
申请号：US14232894
申请日：2012-07-13
申请人： Milena Stanga , Riccardo Pieri , Anna Maria Bertasa , Bradley Lane Kent , Giulio Brinati
发明人： Milena Stanga , Riccardo Pieri , Anna Maria Bertasa , Bradley Lane Kent , Giulio Brinati
IPC分类号： H01M4/62 , H01M4/04
CPC分类号： H01M4/623 , C08L27/16 , C09D127/16 , H01M4/0402 , H01M4/0404 , H01M4/133 , H01M4/1393 , H01M4/622 , H01M10/0525
摘要： The present invention pertains to an aqueous composition comprising: (A) an aqueous latex comprising at least one vinylidene fluoride (VDF) polymer [polymer (F)] comprising recurring units derived from vinylidene fluoride (VDF) and at least one (meth)acrylic monomer (MA) having formula (I) here below: wherein: —R1, R2 and R3, equal to or different from each other, are independently selected from a hydrogen atom and a C1-C3 hydrocarbon group, and —ROH is a hydrogen atom or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group, (B) at least one powdery electrode material, and (C) optionally, less than 10% by weight, based on the total weight of the aqueous composition, of at least one organic solvent (S), wherein the polymer (F) in the N aqueous latex is under the form of primary particles having an average primary particle size of less than 1 μm, as measured according to ISO 13321. The present invention also pertains to a process for manufacturing an electrode using said aqueous composition, to an electrode comprising a metal substrate coated on at least one surface with said aqueous composition and to use of said electrode for manufacturing a non-aqueous-type electrochemical device.
摘要翻译：本发明涉及一种水性组合物，其包含：（A）包含至少一种含偏二氯乙烯（VDF）的重复单元和至少一种（甲基）丙烯酸酯的偏二氟乙烯（VDF）聚合物[聚合物（F）具有式（I）的单体（MA）如下：其中：-R1，R2和R3彼此相同或不同，独立地选自氢原子和C1-C3烃基，-ROH是氢原子或包含至少一个羟基的C 1 -C 5烃部分，（B）至少一种粉末状电极材料，和（C）任选地，基于水性组合物的总重量，小于10重量％的至少一种有机溶剂（S），其中根据ISO 13321测量，N水性胶乳中的聚合物（F）的平均初级粒径小于1μm的初级粒子的形式。本发明还涉及涉及使用sai制造电极的方法 d含量的组合物涂覆到包含涂覆在至少一个表面上的金属基材与所述含水组合物并且使用所述电极制造非水型电化学装置的电极。

4. 发明授权

US10079388B2 Aqueous vinylidene fluoride-(meth)acrylic co-polymer latex, electrode and lithium ion secondary battery using the same 有权
公开(公告)号：US10079388B2
公开(公告)日：2018-09-18
申请号：US14232894
申请日：2012-07-13
申请人： Milena Stanga , Riccardo Pieri , Anna Maria Bertasa , Bradley Lane Kent , Giulio Brinati
发明人： Milena Stanga , Riccardo Pieri , Anna Maria Bertasa , Bradley Lane Kent , Giulio Brinati
IPC分类号： H01M4/04 , H01M4/1393 , H01M4/62 , H01M10/0525 , C08L27/16 , C09D127/16 , H01M4/133
CPC分类号： H01M4/623 , C08L27/16 , C09D127/16 , H01M4/0402 , H01M4/0404 , H01M4/133 , H01M4/1393 , H01M4/622 , H01M10/0525
摘要： The present invention pertains to an aqueous composition comprising: (A) an aqueous latex comprising at least one vinylidene fluoride (VDF) polymer [polymer (F)] comprising recurring units derived from vinylidene fluoride (VDF) and at least one (meth)acrylic monomer (MA) having formula (I) here below: wherein: —R1, R2 and R3, equal to or different from each other, are independently selected from a hydrogen atom and a C1-C3 hydrocarbon group, and —ROH is a hydrogen atom or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group, (B) at least one powdery electrode material, and (C) optionally, less than 10% by weight, based on the total weight of the aqueous composition, of at least one organic solvent (S), wherein the polymer (F) in the aqueous latex is under the form of primary particles having an average primary particle size of less than 1 μm, as measured according to ISO 13321. The present invention also pertains to a process for manufacturing an electrode using said aqueous composition, to an electrode comprising a metal substrate coated on at least one surface with said aqueous composition and to use of said electrode for manufacturing a non-aqueous-type electrochemical device.

5. 发明授权

US09751967B2 Vinylidene fluoride and trifluoroethylene polymers 有权
公开(公告)号：US09751967B2
公开(公告)日：2017-09-05
申请号：US13996018
申请日：2011-12-13
申请人： Alessio Marrani , Giulio Brinati
发明人： Alessio Marrani , Giulio Brinati
IPC分类号： C08F214/22
CPC分类号： C08F214/225 , C08F214/22
摘要： The present invention pertains to a fluoropolymer [polymer (F)] comprising: recurring units derived from vinylidene fluoride (VDF); from 10% to 50% by moles of recurring units derived from trifluoroethylene (TrFE); and from 0.01% to 10% by moles of recurring units derived from at least one (meth)acrylic monomer [monomer (MA)] having formula (I) here below: wherein: R1, R2 and R3, equal to or different from each other, are independently selected from a hydrogen atom and a C1-C3 hydrocarbon group, and ROH represents a hydrogen atom or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group. The invention also pertains to a process for the manufacture of said polymer (F) and to use of said polymer (F) as ferroelectric, piezoelectric, pyroelectric or dielectric material in electrical and electronic devices.

6. 发明授权

US08575286B2 Vinylidene fluoride and trifluoroethylene containing polymers 有权
标题翻译：偏二氟乙烯和含三氟乙烯的聚合物
公开(公告)号：US08575286B2
公开(公告)日：2013-11-05
申请号：US12995214
申请日：2009-05-26
申请人： Giulio Brinati , Alessio Marrani , Bernard Goffaux
发明人： Giulio Brinati , Alessio Marrani , Bernard Goffaux
IPC分类号： C08F114/22
CPC分类号： H01L41/193 , C08F214/182 , C08F214/22 , H01L37/025 , C08F2/26 , C08F2/20
摘要： A polymer comprising recurring units derived from vinylidene fluoride (VDF) and trifluoroethylene (TrFE), such polymer comprising end groups of formula —CF2H and/or —CF2CH3 in an amount of at least 60 mmoles per kg of VDF recurring units [polymer (F)], a process for its manufacture and the use thereof as ferroelectric, piezoelectric, dielectric or pyroelectric material in electric/electronic devices.
摘要翻译：包含衍生自偏氟乙烯（VDF）和三氟乙烯（TrFE）的重复单元的聚合物，包含至少60mmol / kg VDF重复单元的量的式-CF 2 H和/或-CF 2 CH 3的端基的聚合物[聚合物（F ）]，其制造方法及其在电气/电子设备中的铁电，压电，电介质或热电材料的使用。

7. 发明申请

US20130296512A1 Vinylidene fluoride and trifluoroethylene polymers 有权
标题翻译：偏二氟乙烯和三氟乙烯聚合物
公开(公告)号：US20130296512A1
公开(公告)日：2013-11-07
申请号：US13996018
申请日：2011-12-13
申请人： Alessio Marrani , Giulio Brinati
发明人： Alessio Marrani , Giulio Brinati
IPC分类号： C08F214/22
CPC分类号： C08F214/225 , C08F214/22
摘要： The present invention pertains to a fluoropolymer [polymer (F)] comprising: recurring units derived from vinylidene fluoride (VDF); from 10% to 50% by moles of recurring units derived from trifluoroethylene (TrFE); and from 0.01% to 10% by moles of recurring units derived from at least one (meth)acrylic monomer [monomer (MA)] having formula (I) here below: wherein: R1, R2 and R3, equal to or different from each other, are independently selected from a hydrogen atom and a C1-C3 hydrocarbon group, and ROH represents a hydrogen atom or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group. The invention also pertains to a process for the manufacture of said polymer (F) and to use of said polymer (F) as ferroelectric, piezoelectric, pyroelectric or dielectric material in electrical and electronic devices.
摘要翻译：本发明涉及含氟聚合物[聚合物（F）]，其包含：衍生自偏二氟乙烯（VDF）的重复单元; 来自三氟乙烯（TrFE）的10％至50％摩尔的重复单元; 和0.01％至10％摩尔的衍生自具有式（I）的至少一种（甲基）丙烯酸单体[单体（MA）]的重复单元：其中：R1，R2和R3等于或不同于另一个独立地选自氢原子和C 1 -C 3烃基，ROH表示氢原子或包含至少一个羟基的C 1 -C 5烃部分。本发明还涉及制造所述聚合物（F）的方法以及所述聚合物（F）在电气和电子设备中用作铁电，压电，热电或介电材料的方法。

8. 发明申请

US20110082271A1 Vinylidene fluoride and trifluoroethylene containing polymers 有权
标题翻译：偏二氟乙烯和含三氟乙烯的聚合物
公开(公告)号：US20110082271A1
公开(公告)日：2011-04-07
申请号：US12995214
申请日：2009-05-26
申请人： Giulio Brinati , Alessio Marrani , Bernard Goffaux
发明人： Giulio Brinati , Alessio Marrani , Bernard Goffaux
IPC分类号： C08F214/22 , C08F214/18 , C08F2/00 , C08F4/32
CPC分类号： H01L41/193 , C08F214/182 , C08F214/22 , H01L37/025 , C08F2/26 , C08F2/20
摘要： A polymer comprising recurring units derived from vinylidene fluoride (VDF) and trifluoroethylene (TrFE), such polymer comprising end groups of formula —CF2H and/or —CF2CH3 in an amount of at least 60 mmoles per kg of VDF recurring units [polymer (F)], a process for its manufacture and the use thereof as ferroelectric, piezoelectric, dielectric or pyroelectric material in electric/electronic devices.
摘要翻译：包含衍生自偏氟乙烯（VDF）和三氟乙烯（TrFE）的重复单元的聚合物，包含至少60mmol / kg VDF重复单元的量的式-CF 2 H和/或-CF 2 CH 3的端基的聚合物[聚合物（F ）]，其制造方法及其在电气/电子设备中的铁电，压电，电介质或热电材料的使用。

9. 发明授权

US09534106B2 Method for polymerizng vinylidene fluoride 有权
标题翻译：聚偏氟乙烯的方法
公开(公告)号：US09534106B2
公开(公告)日：2017-01-03
申请号：US14125940
申请日：2012-06-15
申请人： Bradley Lane Kent , Valeriy Kapelyushko , Giulio Brinati , Alessandro Veneroni
发明人： Bradley Lane Kent , Valeriy Kapelyushko , Giulio Brinati , Alessandro Veneroni
IPC分类号： C08K5/42 , C08F14/22 , C08F214/22
CPC分类号： C08K5/42 , C08F14/22 , C08F214/22 , C08F2/16
摘要： A process for manufacturing a dispersion of a vinylidene fluoride (VDF) thermoplastic polymer [polymer (F)], said process comprising polymerizing VDF in an aqueous phase comprising from 0.5 to 1.5 g/l of at least one surfactant of formula F—(CF2CF2)3—CH2CH2—SO3Xa, wherein Xa is H, a alkali metal or a NRH4 group, with RH being H or a C1-C6 hydrocarbon group [surfactant (T)] and an organic oxidizing agent [agent (O)] as polymerization initiator.
摘要翻译：一种制备偏二氟乙烯（VDF）热塑性聚合物[聚合物（F）]的分散体的方法，所述方法包括在包含0.5至1.5g / l的至少一种式F-（CF 2 CF 2）的表面活性剂的水相中聚合VDF ）3-CH 2 CH 2 -SO 3 Xa，其中Xa为H，碱金属或NRH4基，RH为H或C1-C6烃基[表面活性剂（T）]和有机氧化剂[试剂（O）]为聚合发起人

10. 发明申请

US20140121321A1 METHOD FOR POLYMERIZNG VINYLIDENE FLUORIDE 有权
标题翻译：聚乙烯酰氟的方法
公开(公告)号：US20140121321A1
公开(公告)日：2014-05-01
申请号：US14125940
申请日：2012-06-15
申请人： Bradley Lane Kent , Valeriy Kapelyushko , Giulio Brinati , Alessandro Veneroni
发明人： Bradley Lane Kent , Valeriy Kapelyushko , Giulio Brinati , Alessandro Veneroni
IPC分类号： C08K5/42
CPC分类号： C08K5/42 , C08F14/22 , C08F214/22 , C08F2/16
摘要： A process for manufacturing a dispersion of a vinylidene fluoride (VDF) thermoplastic polymer [polymer (F)], said process comprising polymerizing VDF in an aqueous phase comprising from 0.5 to 1.5 g/l of at least one surfactant of formula F—(CF2CF2)3—CH2CH2—SO3Xa, wherein Xa is H, a alkali metal or a NRH4 group, with RH being H or a C1-C6 hydrocarbon group [surfactant (T)] and an organic oxidizing agent [agent (O)] as polymerization initiator.
摘要翻译：一种制备偏二氟乙烯（VDF）热塑性聚合物[聚合物（F）]的分散体的方法，所述方法包括在包含0.5至1.5g / l的至少一种式F-（CF 2 CF 2）的表面活性剂的水相中聚合VDF ）3-CH 2 CH 2 -SO 3 Xa，其中Xa为H，碱金属或NRH4基，RH为H或C1-C6烃基[表面活性剂（T）]和有机氧化剂[试剂（O）]为聚合发起人

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