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    • 3. 发明授权
    • Washing compositions containing aluminosilicates and nonionics and
method of washing textiles
    • 含有硅铝酸盐和非离子表面活性剂的洗涤组合物和洗涤纺织品的方法
    • US4083793A
    • 1978-04-11
    • US723728
    • 1976-09-16
    • Gunter JakobiPeter KringsMilan Johann SchwugerHeinz Smolka
    • Gunter JakobiPeter KringsMilan Johann SchwugerHeinz Smolka
    • C11D1/83C11D3/08C11D3/12B01J1/04C11D1/825C11D1/831
    • C11D3/08C11D1/8305C11D3/1286
    • A method of washing soiled textiles, wherein the soiled textiles are immersed in an aqueous liquor which contains at least one compound inhibiting alkaline earth metal ion precipitation on said soiled textiles and surface-active compounds comprising using finely-dispersed, water-insoluble silicate compounds having a calcium-binding power of at least 50 mg CaO/gm of anhydrous active substance and having the formula, combined water not shown(M.sub.2/n O).sub.x . Me.sub.2 O.sub.3 . (SiO.sub.2).sub.ywhere M is a cation of the valence n, exchangeable with calcium, x is a number of from 0.7 to 1.5, Me is a member selected from aluminum and boron and y is a number of from 0.8 to 6, as said compound inhibiting alkaline earth metal ion precipitation, together with surface-active compounds including non-ionic surface-active compounds being constituted by a mixture of compounds of different degrees of ethoxylation where one of the ethoxylated compounds has 8 to 20 ethylene oxide units and the other has from 2 to 6 ethylene oxide units; as well as washing compositions containing said silicate compounds and said surface-active compounds.
    • 一种洗涤污染织物的方法,其中将污染的纺织品浸入含有至少一种抑制碱土金属离子沉淀的化合物的水性液体中,所述化合物在所述污染的纺织品和表面活性化合物上包括使用细分散的水不溶性硅酸盐化合物, 具有至少50mg CaO / gm无水活性物质并具有下式的组合水(M2 / nO)x的钙结合力。 Me2O3。 (SiO 2)y其中M是价数为n的阳离子,可与钙交换,x为0.7至1.5的数,Me为选自铝和硼的成员,y为0.8至6的数,如所述 化合物抑制碱土金属离子沉淀,以及包括非离子表面活性化合物在内的表面活性化合物由不同程度乙氧基化的化合物的混合物构成,其中一种乙氧基化合物具有8至20个环氧乙烷单元,另一种 具有2至6个环氧乙烷单元; 以及含有所述硅酸盐化合物和所述表面活性化合物的洗涤组合物。
    • 4. 发明授权
    • Compositions of optical brightness and aluminosilicates and methods of
their production
    • 光学亮度和铝酸盐的组成及其生产方法
    • US3962116A
    • 1976-06-08
    • US541208
    • 1975-01-15
    • Helmut BlochingHeinz SmolkaMilan Johann Schwuger
    • Helmut BlochingHeinz SmolkaMilan Johann Schwuger
    • D06L3/12C09K11/30
    • D06L3/1264
    • Heat dried, finely-divided compositions of optical brighteners and fillers comprising as said fillers at least partly of a finely-divided water-insoluble silicate compound containing at least some combined water and having a calcium binding power of at least 50 mg CaO/gm of anhydrous active substance and the formula on the anhydrous basis(M.sub.2 /.sub.n O).sub.x . Me.sub.2 O.sub.3 . (SiO.sub.2).sub.ywhere M is a cation of the valence n, exchangeable with calcium, x is a member of from 0.7 to 1.5, Me is a member selected from the group consisting of aluminum and boron, and y is a number from 0.8 to 6, preferably from 1.3 to 4, in an amount of at least 5% by weight of the mixture, as well as a process for producing the same comprising the steps of mixing said silicate compound, while at least still moist from its production, with said optical brighteners and converting the entire mixture of components into a pourable product.
    • 1499902荧光增白剂和填充剂DEUTSCHE GOLD - UND SILBER-SCHEIDEAN雪松和HENKEL&CIE GmbH 1975年1月16日[1974年1月17日] 1869/75标题D1P干粉状组合物含有荧光增白剂和细分(最大粒径0.1mm) 具有至少50mg CaO / g无水硅酸盐(= AS)的钙结合能力和通式的水不溶性铝 - 或硼硅酸盐; 其中Cat表示可与钙交换的阳离子和n价的x,x表示0.7至1.5的数,M表示硼或铝,y表示0.8至6的数。可交换阳离子可以是氢,锂,钾,铵或 镁或水溶性有机碱的阳离子,但优选为钠。 增白剂对棉,聚酰胺或聚酯可能是实质的,并且可以是二氨基芪二磺酸,二芳基吡唑啉喹诺酮,1,2-二(2-苯并恶唑基) - 或1,2-二 - (2-苯甲酰亚氨基唑基) - 乙烯,苯并恶唑基噻吩, 香豆素或曲辛二烯二苯基衍生物。 组合物可以通过热干燥形成。 通过单一喷雾或辊子,组分的浆料。 在改性中,形成硅酸盐,例如, 通过将铝酸钠和硅酸钠混合在水性悬浮液中,在光亮剂存在下,其在干燥时由硅酸盐涂覆。 因此可以形成空心珠。 硅酸盐可以是无定形或微晶的。 其他水溶性或细分散的水不溶性惰性物质也可能存在。
    • 6. 发明授权
    • Method of washing textiles
    • 纺织品洗涤方法
    • US4118189A
    • 1978-10-03
    • US700864
    • 1976-06-29
    • Elmar ReinwaldMilan Johann Schwuger
    • Elmar ReinwaldMilan Johann Schwuger
    • C11D11/00D06F35/00D06L1/12B08B3/00
    • C11D3/0094C11D11/0017C11D11/0058D06F35/006D06L1/12
    • An improved method for washing textiles comprising contacting soiled textiles with a foamed detergent solution, said solution containing from 10 to 5o gm per liter of a cleaning composition containing at least some non-ionic surface-active compounds, and being employed in a liquor ratio of 1:1 to 1:5, said detergent solution being foamed by air to a liter weight of 5 to 30 gm before contacting said soiled textiles, agitating said soiled textiles in the presence of said foamed detergent solution for at least 30 seconds, spinning off said foamed detergent solution under sufficient force to break said foam, and to extract said detergent solution, repeating the above steps at least five times, then rinsing said textiles and recovering cleaned textiles.
    • 一种用于洗涤纺织品的改进方法,包括使污染的纺织品与泡沫洗涤剂溶液接触,所述溶液含有10至5gm /升含有至少一些非离子表面活性化合物的清洁组合物,并且以比例 1:1至1:5,所述洗涤剂溶液在接触所述污染的纺织品之前通过空气发泡至5至30gm的升重量,在所述泡沫洗涤剂溶液存在下搅拌所述污染的纺织品至少30秒, 所述泡沫洗涤剂溶液在足够的力下破坏所述泡沫,并提取所述洗涤剂溶液,重复上述步骤至少五次,然后冲洗所述纺织品并回收清洁的纺织品。