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1. 发明授权

US5426258A Process for reducing the agglomeration tendency of hydrates in the production effluent 失效
标题翻译：降低生产流出液中水合物聚集倾向的方法
公开(公告)号：US5426258A
公开(公告)日：1995-06-20
申请号：US139666
申请日：1993-10-22
申请人： Michel Thomas , Anne-Sophie Baley , Jean-Pierre Durand
发明人： Michel Thomas , Anne-Sophie Baley , Jean-Pierre Durand
IPC分类号： C10L3/10 , C07C7/20 , C09K8/52 , E21B37/06 , E21B43/22 , C10G33/04
CPC分类号： C09K8/52 , C07C7/20 , C09K2208/22
摘要： A description is given of a process for reducing the agglomeration tendency of hydrates within a fluid incorporating at least water and hydrocarbons, liable to form hydrates, under conditions where said hydrates may form, characterized in that into said fluid is incorporated an alkylene oxide-based hydrosoluble polymer or copolymer containing at least one --(OR)--.sub.n sequence, in which R represents a hydrocarbon group having 2 or 3 carbon atoms and n represents the average degree of polymerization of said sequence, at least one of the --(OR)--.sub.n sequences being an ethylene polyoxide sequence, associated with a thermodynamic inhibitor of the formation of hydrates, e.g. an alcohol or a glycol. This process is particularly appropriate for the case where the fluid to be treated contains a high proportion of water, e.g. more than 30% by weight. The presence of salts in the water can at least partly dispense with the addition of alcohols or glycols.
摘要翻译：给出了在可以形成所述水合物的条件下，降低至少引入水和烃的流体中的水合物的聚集趋势的方法，其特征在于，在所述流体中加入基于环氧烷的含有至少一个（OR）-n序列的水溶性聚合物或共聚物，其中R表示具有2或3个碳原子的烃基，n表示所述序列的平均聚合度， - （OR） -n序列是与形成水合物的热力学抑制剂相关的乙烯多氧化物序列，例如酒精或乙二醇。该方法特别适用于待处理流体含有高比例的水的情况，例如，超过30％重量。水中的盐的存在可以至少部分地不加入醇或二醇。

2. 发明授权

US5877361A Process for recycling a dispersing additive used for the transportation of a condensate gas or of an oil with associated gas in the presence of hydrates 失效
标题翻译：用于在水合物存在下用于运输凝析气体或与相关气体的油相分散的添加剂的方法
公开(公告)号：US5877361A
公开(公告)日：1999-03-02
申请号：US659363
申请日：1996-06-06
申请人： Alexandre Rojey , Michel Thomas , Anne-Sophie Delion , Jean-Pierre Durand
发明人： Alexandre Rojey , Michel Thomas , Anne-Sophie Delion , Jean-Pierre Durand
IPC分类号： E21B43/40 , F17D1/00 , F17D1/05 , C07C7/20
CPC分类号： E21B43/40 , F17D1/005 , F17D1/05 , Y10S585/95
摘要： A process for transporting a fluid in a pipe under conditions where hydrates may form. In the process, the pipe fluid contains at least one of a gaseous hydrocarbon or liquid hydrocarbon and water and the water content is less than the liquid hydrocarbon content. The process includes the steps of 1) adding a dispersive additive in a hydrocarbon solution to the fluid to be transported, so as to form an emulsion, 2) transporting the liquid and gaseous hydrocarbons in the presence of water and the hydrates, 3) separating the gas phase, the hydrocarbon liquid in excess and a liquid hydrocarbon phase comprising the hydrates and the dispersing additive, and 4) separating the liquid hydrocarbon phase comprising the hydrates and the dispersing additives. The liquid hydrocarbon phase comprising the hydrates is separated by dissociating the hydrates to form a water-in-oil emulsion, the additives being solved in the oil or liquid hydrocarbon, and breaking the water-in-oil emulsion so as to obtain an aqueous phase and a liquid hydrocarbon comprising the additives. Finally the liquid hydrocarbon phase containing at least part of the dispersing additive from step 4, is recycled to a point in the pipe.
摘要翻译：在可能形成水合物的条件下在管道中输送流体的方法。在该过程中，管流体含有气态烃或液态烃和水中的至少一种，水含量低于液态烃含量。该方法包括以下步骤：1）将烃溶液中的分散添加剂加入待输送的流体中，以形成乳液; 2）在水和水合物的存在下运输液体和气态烃; 3）分离气相，过量的烃液体和包含水合物和分散添加剂的液体烃相，以及4）分离包含水合物和分散添加剂的液体烃相。通过解离水合物形成包含水合物的液相烃相，形成油包水乳液，将添加剂溶解在油或液态烃中，并将油包水乳液破碎，从而得到水相和包含添加剂的液体烃。最后，将含有来自步骤4的至少一部分分散添加剂的液体烃相再循环到管道中的一个点。

3. 发明授权

US5816280A Process for transporting a fluid such as a dry gas likely to form hydrates 失效
标题翻译：用于输送可能形成水合物的干燥气体的流体的方法
公开(公告)号：US5816280A
公开(公告)日：1998-10-06
申请号：US659654
申请日：1996-06-06
申请人： Alexandre Rojey , Michel Thomas , Anne-Sophie Delion , Jean-Pierre Durand
发明人： Alexandre Rojey , Michel Thomas , Anne-Sophie Delion , Jean-Pierre Durand
IPC分类号： E21B43/40 , F17D1/00 , F17D1/05 , E21B43/12
CPC分类号： F17D1/05 , E21B43/40 , F17D1/005 , Y10T137/0391
摘要： Process for transporting gas hydrates formed from a natural gas or from a condensate gas, consisting in using a dispersing additive, possibly coupled with a film-forming additive, in solution in a liquid hydrocarbon fraction, this liquid hydrocarbon fraction participating in the formation of an emulsion and/or of a suspension with the condensation water produced and the hydrates. The dispersing additive is recycled after the transportation of the hydrates in the pipe.
摘要翻译：将由天然气或凝析气体形成的天然气水合物的方法用于在液体烃馏分的溶液中使用可能与成膜添加剂结合的分散添加剂，该液态烃馏分参与形成乳液和/或具有产生的冷凝水和水合物的悬浮液。在管道中输送水合物后，再分散添加剂。

4. 发明授权

US08790617B2 Process for producing hydrogen with complete capture of CO2 and recycling unconverted methane 有权
标题翻译：完全捕获二氧化碳并回收未转化甲烷生产氢气的方法
公开(公告)号：US08790617B2
公开(公告)日：2014-07-29
申请号：US12568317
申请日：2009-09-28
申请人： Beatrice Fischer , Fabrice Giroudiere , Jean-Louis Ambrosino , Michel Thomas
发明人： Beatrice Fischer , Fabrice Giroudiere , Jean-Louis Ambrosino , Michel Thomas
IPC分类号： C01B3/26
CPC分类号： C01B3/56 , B01D53/04 , B01D2253/102 , B01D2253/304 , B01D2253/308 , B01D2256/16 , B01D2257/502 , B01D2257/504 , B01D2257/7022 , B01D2259/4009 , C01B3/48 , C01B3/52 , C01B2203/0233 , C01B2203/0283 , C01B2203/0415 , C01B2203/043 , C01B2203/0475 , C01B2203/0822 , C01B2203/0827 , C01B2203/1241 , C01B2203/148 , Y02C10/04 , Y02C10/08 , Y02E60/324 , Y02P20/128 , Y02P20/152 , Y02P30/30
摘要： The present invention concerns a process for producing hydrogen from a hydrocarbon feed and steam, comprising: a step for producing a synthesis gas in a unit for steam reforming the hydrocarbon feed in the presence of steam, with a fuel providing the heat necessary for the reaction; a step for steam converting synthesis gas obtained in the preceding step, producing a stream of hydrogen containing methane and carbon dioxide; a step for capturing carbon dioxide present in the stream obtained from the steam conversion step in order to separate the carbon dioxide from the stream of hydrogen; a step for capturing and recycling the methane and other impurities (CO, CO2) present in the stream of hydrogen to the steam reforming step.
摘要翻译：本发明涉及一种从烃类进料和蒸汽中生产氢气的方法，包括：在蒸汽存在下用于在烃类进料中蒸汽重整的单元中生产合成气的步骤，提供反应所需的热量 ; 在前述步骤中获得的蒸汽转化合成气的步骤，产生含有甲烷和二氧化碳的氢气流; 用于捕获从蒸汽转化步骤获得的物流中存在的二氧化碳以从二氧化碳流中分离二氧化碳的步骤; 将存在于氢气流中的甲烷和其它杂质（CO，CO 2）捕获并再循环到蒸汽重整步骤的步骤。

5. 发明授权

US08216324B2 Process for the production of hydrogen with a thermally-integrated desulfurization unit 有权
标题翻译：用热一体化脱硫装置生产氢气的方法
公开(公告)号：US08216324B2
公开(公告)日：2012-07-10
申请号：US12057576
申请日：2008-03-28
申请人： Alexandre Nicolaos , Michel Thomas , Fabrice Giroudiere , Jijun Xu , Kishore Doshi
发明人： Alexandre Nicolaos , Michel Thomas , Fabrice Giroudiere , Jijun Xu , Kishore Doshi
IPC分类号： B01J7/00 , B01J8/00 , C01B3/36 , C01B6/24 , C01B3/24 , C01B3/26
CPC分类号： C01B3/323 , C01B3/382 , C01B3/48 , C01B2203/0244 , C01B2203/0283 , C01B2203/0405 , C01B2203/043 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/0883 , C01B2203/0888 , C01B2203/0894 , C01B2203/1064 , C01B2203/107 , C01B2203/1229 , C01B2203/1247 , C01B2203/1258 , C01B2203/127 , C01B2203/1294 , Y02P20/129
摘要： The invention relates to a process for the production of thermally-integrated hydrogen from a liquid hydrocarbon feedstock that contains sulfur-containing compounds that comprise at least one stage for heating the liquid hydrocarbon feedstock by indirect heat exchange with a hot stream, a stage for desulfurizing the heated hydrocarbon feedstock, a stage for evaporating the desulfurized hydrocarbon feedstock by indirect heat exchange with the hot stream that exits from the autothermal reformer, a stage for autothermal reforming of the hydrocarbon feedstock, and a stage wherein the carbon monoxide content in the hydrogen-rich gas that is produced is reduced in a reactor for converting carbon monoxide with water. The invention also relates to the hydrogen production installation that corresponds to this process.
摘要翻译：本发明涉及从含有含硫化合物的液体烃原料生产热一体化氢的方法，所述含硫化合物包含至少一个阶段，用于通过与热流的间接热交换来加热液体烃原料，脱硫阶段加热的烃原料，用于通过与从自热重整器出口的热流间接热交换来蒸发脱硫烃原料的阶段，烃原料的自热重整阶段，以及其中氢 - 生成的富氧气体在用于将一氧化碳与水一起转化的反应器中减少。本发明还涉及对应于该方法的氢生产设备。

6. 发明授权

US08137562B2 Use of a colloidal suspension of a cationic polymer to treat a support for medical use 有权
标题翻译：使用阳离子聚合物的胶体悬浮液来治疗用于医疗用途的支持物
公开(公告)号：US08137562B2
公开(公告)日：2012-03-20
申请号：US12305362
申请日：2006-09-06
申请人： Michel Thomas
发明人： Michel Thomas
IPC分类号： B01D11/00 , B01D39/00 , B01D63/06 , B01D63/00 , B01D67/00
CPC分类号： B01D67/0093 , A61L33/06 , B01D69/02 , B01D71/82 , B01D2323/38 , B01D2325/12 , B01D2325/14 , Y10T29/49826
摘要： The invention concerns a composite support comprising a base support for the treatment of a biological fluid, in which: “the base support is essentially-constituted by a first polymer carrying anionic or anionizable groups;” at least a part of the surface of the base support is coated with a second polymer ionically bonded to the first polymer, the second polymer carrying the cationic or cationizable groups which are capable of forming an ionic bond with the anionic or anionizable groups of the first polymer; in which the second polymer is in the colloidal form and in mixture with a polyacid during application to the support, allowing the composite membrane to adsorb at least one entity containing anionic or anionizable groups by bonding with cationic or cationizable groups of the second polymer.
摘要翻译：本发明涉及一种复合载体，其包括用于处理生物流体的基础载体，其中：“基础载体基本上由携带阴离子或阴离子基团的第一聚合物构成”;基底表面的至少一部分支撑体涂覆有离子键合到第一聚合物的第二聚合物，第二聚合物携带能够与第一聚合物的阴离子或阴离子基团形成离子键的阳离子或阳离子基团; 其中所述第二聚合物为胶体形式，并且在施加到所述载体中时与多元酸混合，允许所述复合膜通过与所述第二聚合物的阳离子或阳离子基团结合而吸附至少一个含有阴离子或阴离子基团的实体。

7. 发明授权

US06454998B1 Blood circulation apparatus coupling device which improves biocompatibility of inner surfaces with treated blood 失效
标题翻译：血液循环装置联合装置，其改善内表面与处理过的血液的生物相容性
公开(公告)号：US06454998B1
公开(公告)日：2002-09-24
申请号：US09364052
申请日：1999-07-30
申请人： Michel Thomas , Pierre Valette
发明人： Michel Thomas , Pierre Valette
IPC分类号： A61M3700
CPC分类号： A61M1/16 , A61L33/068 , A61M1/3672 , A61M1/3673 , B01D61/28 , B01D63/021 , B01D65/022 , B01D67/0088 , B01D67/0093 , B01D71/42 , B01D2313/13 , B01D2321/34 , B01D2321/346 , C08L79/02
摘要： A coupling is connectable to an access of a blood compartment. The compartment has at least one inner surface intended to be coated with at least one molecular layer of a substance soluble in an aqueous solution and capable of increasing biocompatibility. A determined quantity of the substance is deposited inside the coupling in a form such that the substance is capable of undergoing, substantially without deterioration, an irradiation capable of sterilizing the coupling.
摘要翻译：联接器可连接到血液隔室的通路。隔室具有至少一个内表面，其旨在涂覆有至少一种可溶于水溶液的物质的分子层并且能够增加生物相容性。确定量的物质以耦合器内部的形式沉积，使得物质能够基本上不损坏能够消除联接器的照射。

8. 发明授权

US06290751B1 Method and plant for processing a natural gas with high N2 contents and recycling 失效
标题翻译：用于处理高氮含量和回收利用的天然气的方法和装置
公开(公告)号：US06290751B1
公开(公告)日：2001-09-18
申请号：US09362724
申请日：1999-07-29
申请人： Karine Ragil , Michel Thomas , Sophie Jullian
发明人： Karine Ragil , Michel Thomas , Sophie Jullian
IPC分类号： B01D53047
CPC分类号： C10L3/10 , B01D53/047 , B01D53/0476 , B01D2253/102 , B01D2253/108 , B01D2253/308 , B01D2256/10 , B01D2256/24 , B01D2256/245 , B01D2257/102 , B01D2257/504 , B01D2257/702 , B01D2257/7025 , B01D2259/40052 , B01D2259/402 , B01D2259/404 , Y02C10/08 , Y02C20/20
摘要： A method and plant to process a fluid comprising one or more compounds G2 having a kinetic diameter less than or equal to that of nitrogen and one or more compounds G1 having a kinetic diameter greater than or equal to that of methane. The method and plant use in combination, several adsorption and desorption stages during which a first stream F1 mainly comprising compounds G1, a second stream F2 enriched in compounds G2, a third stream F3 mainly comprising compounds G2 and a fourth stream F4 mainly comprising compounds G1 are produced. At least a fraction of stream F3 is used to flush adsorption section A1.
摘要翻译：一种处理含有一种或多种动力学直径小于或等于氮的化合物G2和一种或多种动力学直径大于或等于甲烷的化合物G1的化合物G2的流体的方法和装置。方法和植物组合使用，其中主要包含化合物G1的第一流F1，富含化合物G2的第二流F2，主要包含化合物G2的第三流F3和主要包含化合物G1的第四流F4的几个吸附和解吸阶段被生产。使用流F3的至少一部分冲洗吸附段A1。

9. 发明授权

US6010475A Apparatus for the treatment of blood by extracorporeal circulation and process of manufacture 失效
标题翻译：用于通过体外循环和制造过程处理血液的装置
公开(公告)号：US6010475A
公开(公告)日：2000-01-04
申请号：US933032
申请日：1997-09-18
申请人： Michel Thomas , Pierre Valette
发明人： Michel Thomas , Pierre Valette
IPC分类号： A61L33/06 , A61M1/16 , A61M1/18 , A61M1/36 , B01D63/02 , B01D67/00 , A61M37/00 , A61M1/14 , A61L13/00
CPC分类号： A61M1/16 , A61L33/068 , A61M1/3672 , B01D61/28 , B01D63/021 , B01D65/022 , B01D67/0088 , B01D67/0093 , B01D71/42 , B01D2313/13 , B01D2321/34 , B01D2321/346
摘要： An apparatus for the treatment of blood or plasma by extracorporeal circulation includes a compartment for the circulation of blood. The compartment is provided with two accesses and has at least one inner surface intended to be coated, after sterilization, with at least one molecular layer of a substance soluble in an aqueous solution. The aqueous solution is capable of increasing the bicompatibility of the inner surface of the compartment. A determined quantity of the substance is deposited inside the blood compartment, at one of the accesses, in a form such that the substance is capable of undergoing, substantially without deterioration, an irradiation capable of sterilizing the apparatus. The quantity of substance is determined such that the circulation of a determined volume of aqueous solution through the blood compartment, starting from the access where the substance has been deposited, should result in the formation, by durable bonding, of at least one molecular layer of the substance on the inner surface of the blood compartment to be treated.
摘要翻译：用于通过体外循环治疗血液或血浆的装置包括用于血液循环的隔室。隔室设置有两个通道，并且具有至少一个内表面，其在灭菌后具有可溶于水溶液的物质的至少一个分子层。水溶液能够增加隔室内表面的双相容性。确定量的物质沉积在血液隔室内，在一个通路中，以使得物质能够基本上不会劣化能够对该装置进行灭菌的照射的形式进行。确定物质的量，使得从沉积物质的入口开始，确定体积的水溶液通过血液隔室的循环将导致通过耐久结合形成至少一个分子层待处理血液室内表面上的物质。

10. 发明授权

US5192460A Safe acidic hard surface cleaner 失效
标题翻译：安全酸性硬面清洁剂
公开(公告)号：US5192460A
公开(公告)日：1993-03-09
申请号：US388731
申请日：1989-07-31
申请人： Michel Thomas , Genevieve Blandiaux , Baudouin Valange
发明人： Michel Thomas , Genevieve Blandiaux , Baudouin Valange
IPC分类号： C11D3/02 , C11D3/20 , C11D3/36 , C11D17/00
CPC分类号： C11D3/046 , C11D17/0021 , C11D3/2079 , C11D3/2082 , C11D3/2086 , C11D3/364
摘要： An acidic aqueous cleaner, preferably in emulsion or microemulsion form, which is of a pH in the range of one to four and is useful for cleaning hard surfaced items, such as bathtubs, sinks, tiles and porcelains, and even some such items which are not acid resistant, such as those of a European enamel known as zirconium white enamel, comprises synthetic organic detergent, such as a mixture of anionic and nonionic detergents, e.g., sodium paraffin sulfonate, higher fatty alcohol ethoxylate sulfate and higher fatty alcohol or phenol ethoxylate, organic acid, e.g., mixture of succinic, glutaric and adipic acids, phosphonic acid, e.g., aminotris-(methylenephosphonic acid) and phosphoric acid in an aqueous medium.The acidic cleaner is useful to remove soap scum, lime scale and grease from surfaces of the mentioned items without adversely affecting such surfaces, and removals of the scum, scale and grease are easy, being effected by applying the microemulsion to the surface to be cleaned, followed by wiping it off. Although the cleaned surfaces may be rinsed that is often not necessary and the surfaces will be left clean and shiny after wiping, even without rinsing, or with minimal rinsing.In the described emulsions the organic acid components effectively remove soap scum and lime scale, the detergents remove greasy soils and promote effective contact between the acid and the surfaces to be treated, and the combination of phosphoric and phosphonic acids prevents acidic attack by the organic acid(s) on the European enamel surface being cleaned.
摘要翻译：酸性含水清洁剂，优选乳液或微乳液形式，其pH为1-4，适用于清洁硬表面物品如浴缸，水槽，瓷砖和瓷器，甚至一些这样的物品不耐酸的，例如被称为锆白色搪瓷的欧洲珐琅质的那些，包括合成有机洗涤剂，例如阴离子和非离子洗涤剂的混合物，例如烷基磺酸钠，高级脂肪醇乙氧基化物硫酸盐和高级脂肪醇或酚乙氧基化物，有机酸，例如琥珀酸，戊二酸和己二酸的混合物，膦酸，例如氨基三（亚甲基膦酸）和磷酸在水性介质中。酸性清洁剂可用于从所述物品的表面去除皂浮渣，石灰垢和油脂，而不会对这些表面产生不利影响，并且通过将微乳液施加到要清洁的表面上来实现浮渣，垢垢和油脂的清除容易，然后擦掉它。尽管经过清洗的表面可能经常不需要冲洗，擦拭后即使没有冲洗，也可以在最小程度的冲洗下，表面将保持清洁和有光泽。在所述的乳液中，有机酸组分有效地去除了皂垢和石灰垢，洗涤剂除去油腻的污垢并促进了酸和待处理表面之间的有效接触，磷酸和膦酸的组合可防止有机酸的酸性侵蚀在欧洲牙釉质表面上被清洁。

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