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1. 发明授权

US08790617B2 Process for producing hydrogen with complete capture of CO2 and recycling unconverted methane 有权
标题翻译：完全捕获二氧化碳并回收未转化甲烷生产氢气的方法
公开(公告)号：US08790617B2
公开(公告)日：2014-07-29
申请号：US12568317
申请日：2009-09-28
申请人： Beatrice Fischer , Fabrice Giroudiere , Jean-Louis Ambrosino , Michel Thomas
发明人： Beatrice Fischer , Fabrice Giroudiere , Jean-Louis Ambrosino , Michel Thomas
IPC分类号： C01B3/26
CPC分类号： C01B3/56 , B01D53/04 , B01D2253/102 , B01D2253/304 , B01D2253/308 , B01D2256/16 , B01D2257/502 , B01D2257/504 , B01D2257/7022 , B01D2259/4009 , C01B3/48 , C01B3/52 , C01B2203/0233 , C01B2203/0283 , C01B2203/0415 , C01B2203/043 , C01B2203/0475 , C01B2203/0822 , C01B2203/0827 , C01B2203/1241 , C01B2203/148 , Y02C10/04 , Y02C10/08 , Y02E60/324 , Y02P20/128 , Y02P20/152 , Y02P30/30
摘要： The present invention concerns a process for producing hydrogen from a hydrocarbon feed and steam, comprising: a step for producing a synthesis gas in a unit for steam reforming the hydrocarbon feed in the presence of steam, with a fuel providing the heat necessary for the reaction; a step for steam converting synthesis gas obtained in the preceding step, producing a stream of hydrogen containing methane and carbon dioxide; a step for capturing carbon dioxide present in the stream obtained from the steam conversion step in order to separate the carbon dioxide from the stream of hydrogen; a step for capturing and recycling the methane and other impurities (CO, CO2) present in the stream of hydrogen to the steam reforming step.
摘要翻译：本发明涉及一种从烃类进料和蒸汽中生产氢气的方法，包括：在蒸汽存在下用于在烃类进料中蒸汽重整的单元中生产合成气的步骤，提供反应所需的热量 ; 在前述步骤中获得的蒸汽转化合成气的步骤，产生含有甲烷和二氧化碳的氢气流; 用于捕获从蒸汽转化步骤获得的物流中存在的二氧化碳以从二氧化碳流中分离二氧化碳的步骤; 将存在于氢气流中的甲烷和其它杂质（CO，CO 2）捕获并再循环到蒸汽重整步骤的步骤。

2. 发明授权

US08784516B2 Process for the production of hydrogen with intermediate-pressure purging 失效
标题翻译：用中压清洗生产氢气的方法
公开(公告)号：US08784516B2
公开(公告)日：2014-07-22
申请号：US13187844
申请日：2011-07-21
申请人： Beatrice Fischer , Fabrice Giroudiere , Jean-Louis Ambrosino , Michel Thomas
发明人： Beatrice Fischer , Fabrice Giroudiere , Jean-Louis Ambrosino , Michel Thomas
IPC分类号： C01B3/24
CPC分类号： C01B3/384 , C01B3/48 , C01B3/52 , C01B3/56 , C01B2203/0227 , C01B2203/0283 , C01B2203/0415 , C01B2203/043 , C01B2203/047 , C01B2203/0475 , C01B2203/048 , C01B2203/0495 , C01B2203/0822 , C01B2203/0827 , C01B2203/148 , C01B2203/84 , C01B2203/86 , Y02P20/128 , Y02P30/30
摘要： This invention relates to a process for the production of hydrogen from a hydrocarbon feedstock and water vapor comprising: A stage for the production of a synthetic gas in a vapor reforming unit of the hydrocarbon feedstock in the presence of water vapor, with a fuel that provides the heat that is necessary to the reaction, A stage for conversion to vapor of the synthetic gas that is obtained in the preceding stage producing a hydrogen stream that contains methane and carbon dioxide, A stage for recovering carbon dioxide that is present in the stream that is obtained in the stage for conversion to vapor, making it possible to separate the carbon dioxide from the hydrogen stream, A stage for recovery and recycling to the vapor reforming stage of impurities that are present in the hydrogen stream, comprising a decompression phase.
摘要翻译：本发明涉及从烃原料和水蒸汽生产氢的方法，包括：在水蒸气存在下在烃原料的气相重整单元中生产合成气体的阶段，其中提供反应所需的热量，在前一阶段获得的合成气体的蒸发阶段，产生含有甲烷和二氧化碳的氢气流的阶段，用于回收存在于流中的二氧化碳的阶段在转化成蒸气的阶段中获得，使得可以将来自氢气流的二氧化碳，用于回收和再循环的阶段分离到存在于氢气流中的包含减压阶段的氢气流中的杂质的气相重整阶段。

3. 发明申请

US20120017511A1 PROCESS FOR THE PRODUCTION OF HYDROGEN WITH INTERMEDIATE-PRESSURE PURGING 失效
标题翻译：用中间压力生产氢气的方法
公开(公告)号：US20120017511A1
公开(公告)日：2012-01-26
申请号：US13187844
申请日：2011-07-21
申请人： Beatrice Fischer , Fabrice Giroudiere , Jean-Louis Ambrosino , Michel Thomas
发明人： Beatrice Fischer , Fabrice Giroudiere , Jean-Louis Ambrosino , Michel Thomas
IPC分类号： C01B3/34
CPC分类号： C01B3/384 , C01B3/48 , C01B3/52 , C01B3/56 , C01B2203/0227 , C01B2203/0283 , C01B2203/0415 , C01B2203/043 , C01B2203/047 , C01B2203/0475 , C01B2203/048 , C01B2203/0495 , C01B2203/0822 , C01B2203/0827 , C01B2203/148 , C01B2203/84 , C01B2203/86 , Y02P20/128 , Y02P30/30
摘要： This invention relates to a process for the production of hydrogen from a hydrocarbon feedstock and water vapor comprising: A stage for the production of a synthetic gas in a vapor reforming unit of the hydrocarbon feedstock in the presence of water vapor, with a fuel that provides the heat that is necessary to the reaction, A stage for conversion to vapor of the synthetic gas that is obtained in the preceding stage producing a hydrogen stream that contains methane and carbon dioxide, A stage for recovering carbon dioxide that is present in the stream that is obtained in the stage for conversion to vapor, making it possible to separate the carbon dioxide from the hydrogen stream, A stage for recovery and recycling to the vapor reforming stage of impurities that are present in the hydrogen stream, comprising a decompression phase.
摘要翻译：本发明涉及从烃原料和水蒸汽生产氢的方法，包括：在水蒸气存在下在烃原料的气相重整单元中生产合成气体的阶段，其中提供反应所需的热量，在前一阶段获得的合成气体的蒸发阶段，产生含有甲烷和二氧化碳的氢气流的阶段，用于回收存在于流中的二氧化碳的阶段在转化成蒸气的阶段中获得，使得可以将来自氢气流的二氧化碳，用于回收和再循环的阶段分离到存在于氢气流中的包含减压阶段的氢气流中的杂质的气相重整阶段。

4. 发明授权

US07449049B2 Method of purifying a natural gas by mercaptan adsorption 失效
标题翻译：通过硫醇吸附法净化天然气的方法
公开(公告)号：US07449049B2
公开(公告)日：2008-11-11
申请号：US11366581
申请日：2006-03-03
申请人： Michel Thomas , Eszter Toth , Fabrice Lecomte , Peter Meyer , Jean-Louis Ambrosino
发明人： Michel Thomas , Eszter Toth , Fabrice Lecomte , Peter Meyer , Jean-Louis Ambrosino
IPC分类号： B01D53/04 , B01D53/48 , C07C7/13
CPC分类号： C10L3/10 , B01D53/0462 , B01D2253/102 , B01D2253/104 , B01D2253/108 , B01D2253/306 , B01D2253/308 , B01D2256/24 , B01D2256/245 , B01D2257/304 , B01D2257/306 , B01D2257/504 , B01D2257/702 , B01D2257/80 , B01D2259/40001 , B01D2259/40045 , B01D2259/40052 , B01D2259/40056 , B01D2259/40064 , B01D2259/4009 , B01D2259/403 , Y02C10/08
摘要： The raw natural gas is deacidized and dehydrated in units DA and DH. The treated gas is then purified by adsorption of the mercaptans in first enclosure A1. Part of the purified gas is heated in E1, then fed into second enclosure A2 so as to discharge the water adsorbed by the adsorbent material contained in this second enclosure. A steam-rich stream is fed into third enclosure A3 containing a mercaptan-laden adsorbent material. In A3, the mercaptans are desorbed and replaced by the steam.
摘要翻译：原始天然气在DA和DH单位脱酸脱水。然后经处理的气体通过吸附第一外壳A 1中的硫醇来纯化。净化气体的一部分在E 1中被加热，然后进料到第二外壳A 2中，以排出由第二外壳中包含的吸附材料吸附的水。富含蒸汽的料流进料到含有载有硫醇的吸附剂材料的第三壳体A 3中。在A 3中，硫醇解吸并用蒸汽代替。

5. 发明申请

US20060204419A1 Method of purifying a natural gas by mercaptan adsorption 失效
标题翻译：通过硫醇吸附法净化天然气的方法
公开(公告)号：US20060204419A1
公开(公告)日：2006-09-14
申请号：US11366581
申请日：2006-03-03
申请人： Michel Thomas , Eszter Toth , Fabrice Lecomte , Peter Meyer , Jean-Louis Ambrosino
发明人： Michel Thomas , Eszter Toth , Fabrice Lecomte , Peter Meyer , Jean-Louis Ambrosino
IPC分类号： B01D53/46
CPC分类号： C10L3/10 , B01D53/0462 , B01D2253/102 , B01D2253/104 , B01D2253/108 , B01D2253/306 , B01D2253/308 , B01D2256/24 , B01D2256/245 , B01D2257/304 , B01D2257/306 , B01D2257/504 , B01D2257/702 , B01D2257/80 , B01D2259/40001 , B01D2259/40045 , B01D2259/40052 , B01D2259/40056 , B01D2259/40064 , B01D2259/4009 , B01D2259/403 , Y02C10/08
摘要： The raw natural gas is deacidized and dehydrated in units DA and DH. The treated gas is then purified by adsorption of the mercaptans in first enclosure A1. Part of the purified gas is heated in E1, then fed into second enclosure A2 so as to discharge the water adsorbed by the adsorbent material contained in this second enclosure. A steam-rich stream is fed into third enclosure A3 containing a mercaptan-laden adsorbent material. In A3, the mercaptans are desorbed and replaced by the steam.
摘要翻译：原始天然气在DA和DH单位脱酸脱水。然后经处理的气体通过吸附第一外壳A 1中的硫醇来纯化。净化气体的一部分在E 1中被加热，然后进料到第二外壳A 2中，以排出由第二外壳中包含的吸附材料吸附的水。富含蒸汽的料流进料到含有载有硫醇的吸附剂材料的第三壳体A 3中。在A 3中，硫醇解吸并用蒸汽代替。

6. 发明授权

US08216324B2 Process for the production of hydrogen with a thermally-integrated desulfurization unit 有权
标题翻译：用热一体化脱硫装置生产氢气的方法
公开(公告)号：US08216324B2
公开(公告)日：2012-07-10
申请号：US12057576
申请日：2008-03-28
申请人： Alexandre Nicolaos , Michel Thomas , Fabrice Giroudiere , Jijun Xu , Kishore Doshi
发明人： Alexandre Nicolaos , Michel Thomas , Fabrice Giroudiere , Jijun Xu , Kishore Doshi
IPC分类号： B01J7/00 , B01J8/00 , C01B3/36 , C01B6/24 , C01B3/24 , C01B3/26
CPC分类号： C01B3/323 , C01B3/382 , C01B3/48 , C01B2203/0244 , C01B2203/0283 , C01B2203/0405 , C01B2203/043 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/0883 , C01B2203/0888 , C01B2203/0894 , C01B2203/1064 , C01B2203/107 , C01B2203/1229 , C01B2203/1247 , C01B2203/1258 , C01B2203/127 , C01B2203/1294 , Y02P20/129
摘要： The invention relates to a process for the production of thermally-integrated hydrogen from a liquid hydrocarbon feedstock that contains sulfur-containing compounds that comprise at least one stage for heating the liquid hydrocarbon feedstock by indirect heat exchange with a hot stream, a stage for desulfurizing the heated hydrocarbon feedstock, a stage for evaporating the desulfurized hydrocarbon feedstock by indirect heat exchange with the hot stream that exits from the autothermal reformer, a stage for autothermal reforming of the hydrocarbon feedstock, and a stage wherein the carbon monoxide content in the hydrogen-rich gas that is produced is reduced in a reactor for converting carbon monoxide with water. The invention also relates to the hydrogen production installation that corresponds to this process.
摘要翻译：本发明涉及从含有含硫化合物的液体烃原料生产热一体化氢的方法，所述含硫化合物包含至少一个阶段，用于通过与热流的间接热交换来加热液体烃原料，脱硫阶段加热的烃原料，用于通过与从自热重整器出口的热流间接热交换来蒸发脱硫烃原料的阶段，烃原料的自热重整阶段，以及其中氢 - 生成的富氧气体在用于将一氧化碳与水一起转化的反应器中减少。本发明还涉及对应于该方法的氢生产设备。

7. 发明申请

US20090246119A1 PROCESS FOR THE PRODUCTION OF HYDROGEN WITH A THERMALLY-INTEGRATED DESULFURIZATION UNIT 有权
标题翻译：用热合成脱硫装置生产氢的方法
公开(公告)号：US20090246119A1
公开(公告)日：2009-10-01
申请号：US12057576
申请日：2008-03-28
申请人： Alexandre NICOLAOS , Michel Thomas , Fabrice Giroudiere , Jijun Xu , Kishore Doshi
发明人： Alexandre NICOLAOS , Michel Thomas , Fabrice Giroudiere , Jijun Xu , Kishore Doshi
IPC分类号： C01B3/12
CPC分类号： C01B3/323 , C01B3/382 , C01B3/48 , C01B2203/0244 , C01B2203/0283 , C01B2203/0405 , C01B2203/043 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/0883 , C01B2203/0888 , C01B2203/0894 , C01B2203/1064 , C01B2203/107 , C01B2203/1229 , C01B2203/1247 , C01B2203/1258 , C01B2203/127 , C01B2203/1294 , Y02P20/129
摘要： The invention relates to a process for the production of thermally-integrated hydrogen from a liquid hydrocarbon feedstock that contains sulfur-containing compounds that comprise at least one stage for heating the liquid hydrocarbon feedstock by indirect heat exchange with a hot stream, a stage for desulfurizing the heated hydrocarbon feedstock, a stage for evaporating the desulfurized hydrocarbon feedstock by indirect heat exchange with the hot stream that exits from the autothermal reformer, a stage for autothermal reforming of the hydrocarbon feedstock, and a stage wherein the carbon monoxide content in the hydrogen-rich gas that is produced is reduced in a reactor for converting carbon monoxide with water. The invention also relates to the hydrogen production installation that corresponds to this process.
摘要翻译：本发明涉及从含有含硫化合物的液体烃原料生产热一体化氢的方法，所述含硫化合物包含至少一个阶段，用于通过与热流的间接热交换来加热液体烃原料，脱硫阶段加热的烃原料，用于通过与从自热重整器出口的热流间接热交换来蒸发脱硫烃原料的阶段，烃原料的自热重整阶段，以及其中氢 - 生成的富氧气体在用于将一氧化碳与水一起转化的反应器中减少。本发明还涉及对应于该方法的氢生产设备。

8. 发明授权

US08273153B2 Dry natural gas liquefaction method 有权
标题翻译：干燥天然气液化方法
公开(公告)号：US08273153B2
公开(公告)日：2012-09-25
申请号：US12679796
申请日：2008-09-23
申请人： Michel Thomas , Beatrice Fischer , Gilles Ferschneider
发明人： Michel Thomas , Beatrice Fischer , Gilles Ferschneider
IPC分类号： B01D53/02
CPC分类号： B01D53/04 , B01D2253/108 , B01D2257/702 , B01D2257/80 , B01D2258/06 , B01D2259/4061 , B01D2259/4146 , B01D2259/416 , C10G5/02 , C10G2300/1025 , C10L3/10 , F25J1/0022 , F25J2205/66 , F25J2210/04 , F25J2220/60 , F25J2220/62 , F25J2220/64 , F25J2220/68 , F25J2230/08 , F25J2230/60 , F25J2245/02 , F25J2245/90 , Y02C20/20
摘要： The method allows liquefaction of a dry natural gas comprising water and heavy hydrocarbons containing more than five carbon atoms. The following stages are carried out: a) passing the dry natural gas through a water-adsorbent solid so as to obtain a water-depleted natural gas and a water-laden adsorbent solid, b) passing the water-depleted natural gas through a solid adsorbing heavy hydrocarbons comprising at least five carbon atoms so as to obtain a heavy hydrocarbon-depleted natural gas and a heavy hydrocarbon-laden adsorbent solid, c) liquefying the heavy hydrocarbon-depleted natural gas at a pressure above 40 bar abs so as to obtain a liquid natural gas under pressure, d) expanding the liquid natural gas under pressure obtained in stage c) to atmospheric pressure so as to obtain a liquid natural gas and a gas fraction.
摘要翻译：该方法允许液化包含含有多于5个碳原子的水和重质烃的干燥天然气。进行以下阶段：a）将干燥的天然气通过吸水剂固体，以获得无水的天然气和含水的吸附剂固体，b）使无水的天然气通过固体吸附含有至少五个碳原子的重烃，以获得重质贫烃天然气和重质烃负载吸附剂固体，c）在高于40巴abs的压力下液化重质贫烃天然气，以获得在压力下的液态天然气，d）将在阶段c）中得到的压力下的液态天然气膨胀至大气压，以获得液态天然气和气体馏分。

9. 发明申请

US20100263532A1 DRY NATURAL GAS LIQUEFACTION METHOD 有权
标题翻译：干天然气液化方法
公开(公告)号：US20100263532A1
公开(公告)日：2010-10-21
申请号：US12679796
申请日：2008-09-23
申请人： Michel Thomas , Beatrice Fischer , Gilles Ferschneider
发明人： Michel Thomas , Beatrice Fischer , Gilles Ferschneider
IPC分类号： B01D53/02
CPC分类号： B01D53/04 , B01D2253/108 , B01D2257/702 , B01D2257/80 , B01D2258/06 , B01D2259/4061 , B01D2259/4146 , B01D2259/416 , C10G5/02 , C10G2300/1025 , C10L3/10 , F25J1/0022 , F25J2205/66 , F25J2210/04 , F25J2220/60 , F25J2220/62 , F25J2220/64 , F25J2220/68 , F25J2230/08 , F25J2230/60 , F25J2245/02 , F25J2245/90 , Y02C20/20
摘要： The method allows liquefaction of a dry natural gas comprising water and heavy hydrocarbons containing more than five carbon atoms. The following stages are carried out: a) passing the dry natural gas through a water-adsorbent solid so as to obtain a water-depleted natural gas and a water-laden adsorbent solid, b) passing the water-depleted natural gas through a solid adsorbing heavy hydrocarbons comprising at least five carbon atoms so as to obtain a heavy hydrocarbon-depleted natural gas and a heavy hydrocarbon-laden adsorbent solid, c) liquefying the heavy hydrocarbon-depleted natural gas at a pressure above 40 bar abs so as to obtain a liquid natural gas under pressure, d) expanding the liquid natural gas under pressure obtained in stage c) to atmospheric pressure so as to obtain a liquid natural gas and a gas fraction.
摘要翻译：该方法允许液化包含含有多于5个碳原子的水和重质烃的干燥天然气。进行以下阶段：a）将干燥的天然气通过吸水剂固体，以获得无水的天然气和含水的吸附剂固体，b）使无水的天然气通过固体吸附含有至少五个碳原子的重烃，以获得重质贫烃天然气和重质烃负载吸附剂固体，c）在高于40巴abs的压力下液化重质贫烃天然气，以获得在压力下的液态天然气，d）将在阶段c）中得到的压力下的液态天然气膨胀至大气压，以获得液态天然气和气体馏分。

10. 发明授权

US08137562B2 Use of a colloidal suspension of a cationic polymer to treat a support for medical use 有权
标题翻译：使用阳离子聚合物的胶体悬浮液来治疗用于医疗用途的支持物
公开(公告)号：US08137562B2
公开(公告)日：2012-03-20
申请号：US12305362
申请日：2006-09-06
申请人： Michel Thomas
发明人： Michel Thomas
IPC分类号： B01D11/00 , B01D39/00 , B01D63/06 , B01D63/00 , B01D67/00
CPC分类号： B01D67/0093 , A61L33/06 , B01D69/02 , B01D71/82 , B01D2323/38 , B01D2325/12 , B01D2325/14 , Y10T29/49826
摘要： The invention concerns a composite support comprising a base support for the treatment of a biological fluid, in which: “the base support is essentially-constituted by a first polymer carrying anionic or anionizable groups;” at least a part of the surface of the base support is coated with a second polymer ionically bonded to the first polymer, the second polymer carrying the cationic or cationizable groups which are capable of forming an ionic bond with the anionic or anionizable groups of the first polymer; in which the second polymer is in the colloidal form and in mixture with a polyacid during application to the support, allowing the composite membrane to adsorb at least one entity containing anionic or anionizable groups by bonding with cationic or cationizable groups of the second polymer.
摘要翻译：本发明涉及一种复合载体，其包括用于处理生物流体的基础载体，其中：“基础载体基本上由携带阴离子或阴离子基团的第一聚合物构成”;基底表面的至少一部分支撑体涂覆有离子键合到第一聚合物的第二聚合物，第二聚合物携带能够与第一聚合物的阴离子或阴离子基团形成离子键的阳离子或阳离子基团; 其中所述第二聚合物为胶体形式，并且在施加到所述载体中时与多元酸混合，允许所述复合膜通过与所述第二聚合物的阳离子或阳离子基团结合而吸附至少一个含有阴离子或阴离子基团的实体。

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