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1. 发明授权

US06242662B1 Process for obtaining butene-1 有权
标题翻译：获得丁烯-1的方法
公开(公告)号：US06242662B1
公开(公告)日：2001-06-05
申请号：US09229958
申请日：1999-01-14
申请人： Michel Dorbon , François Hugues , Jean-Charles Viltard , Blaise Didillon , Alain Forestiere
发明人： Michel Dorbon , François Hugues , Jean-Charles Viltard , Blaise Didillon , Alain Forestiere
IPC分类号： C07C525
CPC分类号： C07C11/08 , C07C5/2556 , C07C7/04 , C07C2523/40 , C07C2523/755
摘要： For obtaining butene-1 from butene-2, a charge containing at least one of the isomers of butene-2 is introduced into a distillation zone linked to a hydro-isomerization zone. Part of the effluent from the bottom of the distillation column is removed from the distillation zone, heated in a heat exchanger and passed into an external hydro-isomerization zone. The hydro-isomerization effluent is removed from the hydro-isomerization zone, cooled in a heat exchanger, and then reintroduced into the distillation zone. Effluent containing butene-1 is withdrawn from the top of the column of the distillation zone.
摘要翻译：为了从丁烯-2获得丁烯-1，将含有至少一种丁烯-2异构体的电荷引入连接到加氢异构化区的蒸馏区。将蒸馏塔底部的一部分流出物从蒸馏区除去，在热交换器中加热并进入外部加氢异构化区。将加氢异构化流出物从加氢异构化区域除去，在热交换器中冷却，然后再引入蒸馏区。含有丁烯-1的流出物从蒸馏区的塔顶排出。

2. 发明授权

US06184315B2 Process for polymerization in the presence of alpha olefins 有权
标题翻译：在α-烯烃存在下进行聚合的方法
公开(公告)号：US06184315B2
公开(公告)日：2001-02-06
申请号：US09252869
申请日：1999-02-18
申请人： Alain Forestiere , François Hugues
发明人： Alain Forestiere , François Hugues
IPC分类号： C08F200
CPC分类号： C08F6/003 , C08F6/006 , C08F210/16 , C08L23/08 , C08F210/14
摘要： The polymerization process is carried out starting from a monomer that is introduced via pipe (1) and a comonomer that is introduced via pipe (2); the comonomer that is used, which is an alpha-olefin, is introduced into polymerization reactor P in the form of an approximately pure compound. The polymerization effluent is then separated in separator S1 into two fractions: a heavy fraction that is evacuated via pipe (5) and that contains at least one polymer, and a light fraction that is evacuated via pipe (4) and that comprises the monomer that has not reacted, the comonomer that has not reacted, as well as isomers of this comonomer. At least a portion of the light fraction is then treated during an ethenolysis stage E in the presence of an addition of fresh ethylene that is introduced via line (9). The effluent that is produced in the ethenolysis stage is subjected to at least two separations in separation train S2. After the fraction that contains the light olefins and the fraction that contains the heavy compounds have been separated, the fraction that comprises the comonomer is recycled via pipe (10) toward polymerization zone P.
摘要翻译：从通过管（1）引入的单体和通过管（2）引入的共聚单体开始聚合过程; 将所使用的共聚单体（其为α-烯烃）以近纯化合物的形式引入聚合反应器P中。然后将聚合流出物在分离器S1中分离成两部分：通过管道（5）抽真空并且含有至少一种聚合物的重馏分和通过管道（4）抽空的轻馏分，并且包含单体，没有反应，未反应的共聚单体，以及该共聚单体的异构体。然后在乙烯溶解阶段E中，在加入通过管线（9）引入的新鲜乙烯的存在下，至少部分轻馏分处理。在乙烯分解阶段中产生的流出物在分离系S2中进行至少两次分离。在含有轻质烯烃的馏分和含有重质化合物的馏分已经分离后，包含共聚单体的馏分通过管道（10）再循环到聚合区域P.

3. 发明授权

US06646173B2 Sequence of processes for olefin oligomerisation 有权
公开(公告)号：US06646173B2
公开(公告)日：2003-11-11
申请号：US09984053
申请日：2001-10-26
申请人： Dominique Commereuc , Alain Forestiere , François Hugues , Hélène Olivier-Bourbigou
发明人： Dominique Commereuc , Alain Forestiere , François Hugues , Hélène Olivier-Bourbigou
IPC分类号： C07C202
CPC分类号： C07C2/30 , C07C2/32 , C07C2531/14 , C07C2531/16
摘要： A process is described for carrying out olefin oligomerisation in two catalysis steps of different types, using an organic feed containing at least one olefin. The cut to be treated, containing at least one olefin (Cn), is introduced into a first reaction zone where, in a first step, it undergoes catalytic oligomerisation either of the homogeneous liquid phase type, or of the heterogeneous type with a solid support. The effluent produced is generally sent to a heat exchanger traversed by a cold liquid, the effluent thus being cooled before being sent to a second reaction zone where it undergoes catalytic oligomerisation in a liquid—liquid two-phase medium, the invention being characterized in that at least an ethylenic hydrocarbon containing 3 to 5 carbon atoms per molecule is added to the inlet to the second reaction zone.

4. 发明授权

US06203712B1 Process for separation by settling in a plurality of distinct zones 有权
标题翻译：通过沉降多个不同区域进行分离的方法
公开(公告)号：US06203712B1
公开(公告)日：2001-03-20
申请号：US09229578
申请日：1999-01-13
申请人： Charles Bronner , Alain Forestiere , François Hugues
发明人： Charles Bronner , Alain Forestiere , François Hugues
IPC分类号： B01D2130
CPC分类号： B01D17/0208 , B01D17/0214
摘要： A process for separating at least two liquid phases which are at least partially non miscible is characterized in that after reacting, a polyphase effluent is settled in at least two distinct settling zones arranged in parallel, each of these settling zones containing at least one settler. The feed to be treated is sent to reactor R via a means for circulating fluids P via line 1. The effluent leaves the reactor via line 2 and is separated into two fractions. One fraction is sent to a settling zone a) via line 3; the other fraction is sent to a settling zone b) via line 4. The heavy phase from settling zone a) is sent to the reactor via line 7 and the heavy phase of the settling zone b) is sent to the reactor via line 6. The light phase from settling zone a) is sent to line 8, and rejoins fresh feed supply line 1. The light phase from settling zone b) is evacuated from the circuit via line 5.
摘要翻译：分离至少部分不混溶的至少两个液相的方法的特征在于，在反应之后，多相流出物沉降在平行布置的至少两个不同的沉降区中，每个这些沉降区含有至少一个沉降器。待处理的进料经由管线1循环流体P的装置送至反应器R.流出物通过管线2离开反应器并分离成两部分。一部分经由管线3送至沉降区a）另一部分通过管线4送至沉降区b）。来自沉降区a）的重相通过管线7送至反应器，沉降区b）的重相通过管线6送至反应器。来自沉降区a）的光相被送到管线8，并重新加入新鲜的进料供应管线1.来自沉降区域b）的光相通过管线5从回路排出。

5. 发明授权

US07696397B2 Catalytic composition and its application to olefin oligomerization 有权
标题翻译：催化组合物及其在烯烃低聚反应中的应用
公开(公告)号：US07696397B2
公开(公告)日：2010-04-13
申请号：US11767164
申请日：2007-06-22
申请人： Dominique Commereuc , Alain Forestiere , François Hugues , Hélène Olivier
发明人： Dominique Commereuc , Alain Forestiere , François Hugues , Hélène Olivier
IPC分类号： C07C2/02 , B01J31/00
CPC分类号： B01J31/04 , B01J29/06 , B01J31/143 , B01J31/2208 , B01J2231/20 , B01J2531/847 , C07C2/30 , C07C2531/04 , C07C2531/14
摘要： An improved catalytic composition for oligomerization, in particular dimerization, of monoolefins comprises the product resulting from bringing the following three constituents into contact in any order: a) at least one divalent nickel compound; b) at least one hydrocarbylaluminium dihalide, optionally enriched with an aluminum trihalide; and c) at least one organic Bronsted acid; the catalytic composition being pre-conditioned in a solvent before using it for oligomerization.
摘要翻译：用于低聚，特别是二烯化的单烯烃的改进的催化组合物包括由以下三种组分以任何顺序接触而得到的产物：a）至少一种二价镍化合物; b）至少一种烃基二卤化物，任选地富含三卤化铝; 和c）至少一种有机布朗斯台德酸; 催化组合物在使用其进行低聚反应之前在溶剂中预调节。

6. 发明授权

US07235703B2 Catalytic composition and its application to olefin oligomerization 有权
标题翻译：催化组合物及其在烯烃低聚反应中的应用
公开(公告)号：US07235703B2
公开(公告)日：2007-06-26
申请号：US11107794
申请日：2005-04-18
申请人： Dominique Commereuc , Alain Forestiere , François Hugues , Hélène Olivier
发明人： Dominique Commereuc , Alain Forestiere , François Hugues , Hélène Olivier
IPC分类号： C07C2/02 , B01J31/00
CPC分类号： B01J31/04 , B01J29/06 , B01J31/143 , B01J31/2208 , B01J2231/20 , B01J2531/847 , C07C2/30 , C07C2531/04 , C07C2531/14
摘要： An improved catalytic composition for oligomerization, in particular dimerization, of monoolefins comprises the product resulting from bringing the following three constituents into contact in any order: a) at least one divalent nickel compound; b) at least one hydrocarbylaluminium dihalide, optionally enriched with an aluminium trihalide; and c) at least one organic Bronsted acid; the catalytic composition being pre-conditioned in a solvent before using it for oligomerization.
摘要翻译：用于低聚，特别是二烯化的单烯烃的改进的催化组合物包括由以下三种组分以任何顺序接触而得到的产物：a）至少一种二价镍化合物; b）至少一种烃基二卤化物，任选地富含三卤化铝; 和c）至少一种有机布朗斯台德酸; 催化组合物在使用其进行低聚反应之前在溶剂中预调节。

7. 发明授权

US06281402B1 Alternated process for olefin metathesis 有权
标题翻译：烯烃复分解的交替过程
公开(公告)号：US06281402B1
公开(公告)日：2001-08-28
申请号：US09208585
申请日：1998-12-10
申请人： Vincent Coupard , François Hugues , Dominique Commereuc , Béatrice Fischer , Pierre Boucot , Alain Forestiere
发明人： Vincent Coupard , François Hugues , Dominique Commereuc , Béatrice Fischer , Pierre Boucot , Alain Forestiere
IPC分类号： C07C604
CPC分类号： C07C6/04 , C07C2521/04 , C07C2523/36 , Y02P20/584
摘要： The present invention relates to a process for continuous metathesis or disproportionation of olefins, comprising at least 2 phases, a reaction phase a) carried out in a zone comprising at least one reactor containing at least one fixed bed of catalyst and a regeneration phase b) carried out in a zone comprising at least one reactor containing at least one fixed bed of catalyst, characterized in that at least one reactor passes from one phase to the other in alternation. In FIG. 1, the feed containing olefins traverses reactor R1 in riser mode. The feed to be treated containing olefins is introduced into reactor R1 via line 1a. In this reactor, the olefins contained in the feed undergo metathesis or disproportionation, then the effluent leaves the circuit via line 11. Simultaneously, reactor R2 is placed in catalyst regeneration phase, the different regeneration gases are introduced into reactor R2 via line 2b and leave this reactor via line 2c. Passage from the operating phase of a reactor to the catalyst regeneration phase thereof is carried out as follows: the reactor for which the catalyst is to be regenerated is isolated from the remainder of the apparatus, the hydrocarbons contained in the reactor are evacuated, then the reactor is purged. Said reactor is then connected to a regeneration loop and undergoes regeneration of its catalyst, and at the end of the regeneration phase, the reactor and the regeneration loop are purged.
摘要翻译：本发明涉及一种烯烃的连续复分解或歧化方法，包括至少两相，在包含至少一个含有至少一个催化剂固定床和再生阶段的反应器的区域中进行的反应相a）在包含至少一个包含至少一个催化剂固定床的反应器的区域中进行，其特征在于至少一个反应器交替地从一个相转移到另一个相。在图如图1所示，含有烯烃的进料以提升管方式穿过反应器R1。待处理含烯烃的进料通过管线1a引入反应器R1。在该反应器中，进料中所含的烯烃经过复分解或歧化，然后流出物通过管线11离开回路。同时，将反应器R2置于催化剂再生阶段，不同的再生气体通过管线2b引入反应器R2，并留下该反应器经由管线2c。从反应器的操作阶段到催化剂再生阶段的通过如下进行：将待再生催化剂的反应器与装置的其余部分分离，将反应器中包含的烃抽真空，然后反应器被清除。然后将所述反应器连接到再生回路并经历其催化剂的再生，并且在再生阶段结束时，将反应器和再生回路清除。

8. 发明授权

US06235956B1 Acetals, their preparation and their use 有权
标题翻译：缩醛，它们的制备和使用
公开(公告)号：US06235956B1
公开(公告)日：2001-05-22
申请号：US09217584
申请日：1998-12-22
申请人： François Hugues , Alain Forestiere , Lucien Saussine , Dominique Commereuc
发明人： François Hugues , Alain Forestiere , Lucien Saussine , Dominique Commereuc
IPC分类号： C07C232
CPC分类号： C07C43/303 , C07D307/12 , C07F7/003
摘要： An acetal, wherein the acetal is 2,2-di(tetrahydrofurfuryloxy)propane as well as processed for producing the acetal and methods of using the acetal.
摘要翻译：缩醛，其中缩醛是2,2-二（四氢呋喃氧基）丙烷，以及用于制备缩醛的方法和使用缩醛的方法。

9. 发明授权

US08071655B2 Cobalt-based catalyst for fischer-tropsch synthesis 有权
标题翻译：用于费托合成的钴基催化剂
公开(公告)号：US08071655B2
公开(公告)日：2011-12-06
申请号：US11721923
申请日：2005-11-17
申请人： Fabrice Diehl , François Hugues , Marie-Claire Marion , Denis Uzio
发明人： Fabrice Diehl , François Hugues , Marie-Claire Marion , Denis Uzio
IPC分类号： C07C27/00 , B01J23/00 , B01J21/00 , B01J20/00
CPC分类号： B01J21/12 , B01J23/005 , B01J23/462 , B01J23/745 , B01J23/75 , B01J23/755 , B01J23/8913 , B01J29/405 , B01J29/7049 , B01J29/7088 , B01J29/7092 , B01J29/90 , B01J37/08 , C10G2/332 , Y10S502/524
摘要： A catalyst applicable to the synthesis gas conversions especially E-T slurry processes, said catalyst comprising: a) a support containing at least a first aluminate element of mixed spinel structure of formula MxM′(1−x)Al2O4/Al2O3.SiO2, x ranging between and excluding 0 and 1, or of simple spinel structure of formula MAl2O4/Al2O3.SiO2, said support being calcined in an at least partly oxidizing atmosphere, at a temperature ranging between 850° C. and 900° C., and b) an active phase deposited on said support, which contains one or more group VIII metals, selected from among cobalt, nickel, ruthenium or iron. Said catalyst is used in a fixed bed or suspended in a three-phase reactor for hydrocarbon synthesis from a CO, H2 mixture.
摘要翻译：一种适用于合成气转化尤其是ET淤浆法的催化剂，所述催化剂包括：a）至少含有式M x M'（1-x）Al 2 O 4 / Al 2 O 3 -SiO 2的混合尖晶石结构的第一铝酸盐元素的载体，并且不包括0和1，或者简单的尖晶石结构式为MA1204 / Al2O3.SiO2，所述载体在至少部分氧化的气氛中在850℃和900℃之间的温度下煅烧，和b）活性相沉积在所述载体上，其含有一种或多种选自钴，镍，钌或铁的第VIII族金属。所述催化剂用于固定床或悬浮在三相反应器中，用于从CO，H 2混合物合成碳氢化合物。

10. 发明授权

US06277781B1 Process for preparing a rhenium and cesium based metathesis catalyst 失效
标题翻译：制备铼和铯基复分解催化剂的方法
公开(公告)号：US06277781B1
公开(公告)日：2001-08-21
申请号：US09413192
申请日：1999-10-05
申请人： Dominique Commereuc , François Hugues , Lucien Saussine
发明人： Dominique Commereuc , François Hugues , Lucien Saussine
IPC分类号： B01J2304
CPC分类号： C07C6/04 , B01J23/36 , C07C2521/04 , C07C2523/04 , C07C2523/36 , Y02P20/52
摘要： The present invention provides a catalyst and a process for metathesis of olefinic C4 cuts. The catalyst contains rhenium, cesium and delta alumina. The preferred catalyst contains at least one rhenium compound deposited on a support principally composed of alumina, treated at a temperature of more than 750° C., and modified by at least one cesium compound. With the use of the catalyst, the duration of the cycle between two regeneration operations can be substantially increased. The catalyst is suitable for use in a process for production of propylene from an olefinic C4 cut in three steps: (1) selective hydrogenation of butadiene with isomerisation of 1-butene to 2-butene, (2) separation by distillation of the major portion of the isobutene, and (3) metathesis of the cut rich in 2-butene with ethylene.
摘要翻译：本发明提供催化剂和烯烃C4馏分的复分解方法。催化剂含有铼，铯和δ氧化铝。优选的催化剂含有沉积在主要由氧化铝组成的载体上的至少一种铼化合物，其在大于750℃的温度下处理并被至少一种铯化合物修饰。通过使用催化剂，可以显着增加两次再生操作之间的循环持续时间。该催化剂适用于以下三个步骤从烯烃C4馏分生产丙烯的方法：（1）丁烯与1-丁烯异构化至2-丁烯的选择性氢化，（2）通过主蒸馏分离的异丁烯，（3）富含2-丁烯的馏分与乙烯的复分解。

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