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1. 发明授权

US5344971A Process for deodorizing a mercapto acid by extracting malodorous compound therefrom with a supercritical fluid 失效
标题翻译：通过用超临界流体从其中提取恶臭化合物来除臭巯基的方法
公开(公告)号：US5344971A
公开(公告)日：1994-09-06
申请号：US45095
申请日：1993-04-12
申请人： Michel Dedieu , Herve Burgaud , Eric Lapoirie , Veronique Gurfein , Gerard Malle
发明人： Michel Dedieu , Herve Burgaud , Eric Lapoirie , Veronique Gurfein , Gerard Malle
IPC分类号： B01D11/00 , A61K8/00 , A61K8/34 , A61K8/46 , A61Q5/04 , A61Q9/04 , A61Q15/00 , C07B63/00 , C07C319/28 , C07C323/52 , C07C53/00 , C07C55/02
CPC分类号： A61Q15/00 , A61K8/46 , A61Q5/04 , A61Q9/04 , C07C319/28 , Y02P20/544
摘要： A process for deodorizing a mercapto acid includes extracting malodorous compounds present therein by treating the mercapto acid in the presence of a polar solvent with a supercritical extraction fluid having a critical temperature ranging from 0.degree. to 135.degree. C. and a critical pressure ranging from 10.sup.6 to 10.sup.7 Pascals. The mercapto acid has the formula HS--A--COOH wherein A represents ##STR1## wherein n is an integer ranging from 1 to 4 and R is a linear or branched C.sub.1 -C.sub.3 alkyl.
摘要翻译：用于使巯基除臭的方法包括通过在极限溶剂存在下用超临界萃取流体处理巯基酸来提取其中存在的恶臭化合物，所述超临界萃取流体的临界温度为0-135℃，临界压力为106 到107帕斯卡。巯基酸具有式HS-A-COOH，其中A表示其中n是1至4的整数，R是直链或支链的C 1 -C 3烷基。

2. 发明授权

US5329045A Process for deodorising a mercapto acid by extracting malodorous compounds therefrom with carbon dioxide 失效
标题翻译：通过用二氧化碳从其中提取恶臭化合物来除臭巯基的方法
公开(公告)号：US5329045A
公开(公告)日：1994-07-12
申请号：US45140
申请日：1993-04-12
申请人： Michel Dedieu , Herve Burgaud , Eric LaPoirie , Veronique Gurfein , Gerard Malle
发明人： Michel Dedieu , Herve Burgaud , Eric LaPoirie , Veronique Gurfein , Gerard Malle
IPC分类号： B01D53/38 , A61K8/00 , A61K8/34 , A61K8/46 , A61Q5/04 , C07C319/28 , C07C323/52 , C07C51/42
CPC分类号： C07C319/28
摘要： A process for deodorizing a mercapto acid or a polar solvent solution thereof includes extracting malodorous compounds present therein by extraction with carbon dioxide in gaseous, liquid or solid form. The mercapto acid has the formula HS-A-COOH wherein A represents ##STR1## wherein n is an integer ranging from 1-4 and R is linear or branched C.sub.1 -C.sub.3 alkyl.
摘要翻译：用于使巯基酸或其极性溶剂溶液除臭的方法包括通过用气态，液体或固体形式的二氧化碳萃取萃取其中存在的恶臭化合物。巯基酸具有式HS-A-COOH，其中A表示其中n是1-4的整数，R是直链或支链的C 1 -C 3烷基。

3. 发明申请

US20130039862A1 COMPOUNDS OF DIBENZYLIDENE SORBITOL ESTER TYPE, PROCESS OF PREPARATION, USE, COMPOSITIONS COMPRISING THEM AND COSMETIC TREATMENT METHOD 有权
标题翻译：二苯醚类化合物类型的化合物，制备方法，用途，包含它们的组合物和化妆处理方法
公开(公告)号：US20130039862A1
公开(公告)日：2013-02-14
申请号：US13581915
申请日：2011-02-25
申请人： Gerard Malle , Tiina Luukas
发明人： Gerard Malle , Tiina Luukas
IPC分类号： C07D493/04 , A61K8/49 , A61K8/58 , A61K47/22 , A61K47/24 , A61K8/97 , A61K47/46 , A61K8/98 , A61K8/92 , A61Q19/00 , A61Q1/00 , A61Q3/00 , A61Q5/00 , A61Q17/04 , C07F7/18
CPC分类号： C07D493/04 , C07D519/00
摘要： The invention relates to novel compounds of dibenzylidene sorbitol ester type corresponding to the following formulae (I) and (II): in which: R, R′ and R″ represent a hydrogen atom or a —C(O)Y radical in which Y represents a C2-C25 hydrocarbon radical or an optionally substituted aryl radical; the R1, R2, R3, R4, R5, R′1, R′2, R′3, R′4 and R′5 radicals represent a hydrogen atom; a C1-C18 alkyl radical; a C1-C18 alkoxy radical; a phenoxy radical; an optionally substituted phenyl radical; or a benzyl radical; the divalent radical A represents, in the formula (II), a C1-C52 hydrocarbon radical; an optionally substituted arylene radical; or a silicone radical. The invention also relates to their process of preparation, to their use in structuring lipophilic media, in particular oils, to the cosmetic or pharmaceutical compositions comprising them and to a cosmetic treatment method employing them.
摘要翻译：本发明涉及对应于下式（I）和（II）的二亚苄基山梨醇酯型的新化合物：其中：R，R'和R“表示氢原子或-C（O）Y基团，其中Y 表示C2-C25烃基或任选取代的芳基; R1，R2，R3，R4，R5，R'1，R'2，R'3，R'4和R'5基团代表氢原子; C1-C18烷基; C1-C18烷氧基; 苯氧基; 任选取代的苯基; 或苄基; 二价基团A在式（II）中表示C1-C52烃基; 任选取代的亚芳基; 或硅酮基。本发明还涉及其制备方法，其用于将亲脂性介质，特别是油结构化成包含它们的化妆品或药物组合物以及使用它们的美容治疗方法。

4. 发明申请

US20120085364A1 METHOD FOR MAKING UP EYELASHES 审中-公开
标题翻译：用于制作眼镜的方法
公开(公告)号：US20120085364A1
公开(公告)日：2012-04-12
申请号：US13263381
申请日：2010-04-02
申请人： Gerard Malle , Stephane Arditty , Nathalie Jager Lezer
发明人： Gerard Malle , Stephane Arditty , Nathalie Jager Lezer
IPC分类号： A45D7/04 , A45D44/00 , A61Q1/10 , A45D7/00
CPC分类号： A61Q1/10 , A61K8/8152 , A61K2800/81 , A61K2800/88 , A61K2800/95
摘要： One subject of the invention is a method for making up eyelashes, consisting in: a) coating the eyelashes with a deposit of at least one composition comprising, in a physiologically acceptable medium, at least one compound enabling the composition to attain, in the at least partially dry state, a modulus of rigidity Gp greater than or equal to 1 GPa, b) in the presence of a stimulus to which said compound is sensitive, placing a shaping tool in contact with the thus coated eyelashes so as to modify the curvature of the eyelashes, said contact being maintained until the modulus of rigidity Gp of the composition is at least equal to 1 GPa, the stimulus being chosen so that the modulus of rigidity of at least 1 GPa is obtained in a time t that is less than the time t0 that would be needed to obtain it by leaving the deposit to dry at room temperature.
摘要翻译：本发明的一个主题是一种用于制造睫毛的方法，其包括：a）用至少一种组合物的沉积物涂覆睫毛，所述组合物在生理学上可接受的介质中包含至少一种化合物，使组合物在最小部分干燥状态，刚性模量Gp大于或等于1GPa，b）在存在所述化合物敏感的刺激的情况下，将成形工具与如此涂覆的睫毛接触以改变曲率的睫毛，所述接触保持直到组合物的刚度Gp至少等于1GPa，所述刺激被选择为使得在小于1的时间t获得至少1GPa的刚度模量通过将沉积物在室温下干燥而获得的时间t0。

5. 发明授权

US6118008A Diamino pyrazols, their synthesis, keratin fibre dyeing compositions containing them, keratin fibre dyeing methods 失效
标题翻译：二氨基吡唑，它们的合成，含有它们的角蛋白纤维染色组合物，角蛋白纤维染色方法
公开(公告)号：US6118008A
公开(公告)日：2000-09-12
申请号：US180183
申请日：1999-05-07
申请人： Gerard Malle , Laurent Vidal , Agnes Burande , Mireille Maubru
发明人： Gerard Malle , Laurent Vidal , Agnes Burande , Mireille Maubru
IPC分类号： A61K8/00 , A61K8/20 , A61K8/22 , A61K8/23 , A61K8/31 , A61K8/34 , A61K8/36 , A61K8/365 , A61K8/38 , A61K8/41 , A61K8/49 , A61Q5/10 , C07D231/38 , C09B57/00 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/494 , C07D231/38
摘要： The invention discloses new 5-substituted 3,4-diamino pyrazols, their methods of preparation, compositions for keratin fiber oxidation dyeing containing them as an oxidizing base, and the dyeing methods using same.
摘要翻译： PCT No.PCT / FR97 / 00750 Sec。 371日期1999年5月7日 102（e）日期1999年5月7日PCT 1997年4月25日PCT公布。公开号WO97 / 42173 日期1997年11月13日本发明公开了新的5-取代的3,4-二氨基吡唑，它们的制备方法，将它们作为氧化性碱的角蛋白纤维氧化染色的组合物和使用它们的染色方法。

6. 发明授权

US6099592A Composition for dyeing keratin fibers which contain at least one diaminopyrazole, dyeing process, novel diaminopyrazoles and process for their preparation 失效
公开(公告)号：US6099592A
公开(公告)日：2000-08-08
申请号：US642622
申请日：1996-05-03
申请人： Laurent Vidal , Agnes Burande , Gerard Malle , Michel Hocquaux
发明人： Laurent Vidal , Agnes Burande , Gerard Malle , Michel Hocquaux
IPC分类号： A61K8/35 , A61K8/00 , A61K8/19 , A61K8/23 , A61K8/33 , A61K8/34 , A61K8/41 , A61K8/49 , A61Q5/10 , B65D81/32 , C07D231/38 , C09B57/00 , C09B67/42 , D06P3/08 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/494 , C07D231/38
摘要： The invention relates to novel compositions for the oxidation dyeing of keratin fibers, comprising at least one specific diaminopyrazole derivative, to the dyeing process using this composition, to novel diaminopyrazole derivatives and to a process for their preparation.

7. 发明授权

US6063136A Compositions containing pyrrolo-oxazole couplers for dyeing keratin fibers and dyeing methods 失效
标题翻译：含有用于染色角蛋白纤维的吡咯 - 恶唑成色剂和染色方法的组合物
公开(公告)号：US6063136A
公开(公告)日：2000-05-16
申请号：US242932
申请日：1999-02-26
申请人： Laurent Vidal , Gerard Malle
发明人： Laurent Vidal , Gerard Malle
IPC分类号： A61K8/00 , A61K8/20 , A61K8/22 , A61K8/23 , A61K8/34 , A61K8/36 , A61K8/41 , A61K8/46 , A61K8/49 , A61Q5/10 , C09B57/00 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/49
摘要： The present invention relates to a composition and a dyeing process for the dyeing of keratinous fibers, in particular of human hair, having,as coupler, at least one compound of formula: ##STR1## where Z.sub.a and Z.sub.b, which are different from one another, represent an oxygen or nitrogen atom,and at least one oxidation base.
摘要翻译： PCT No.PCT / FR97 / 01522 Sec。 371日期1999年2月26日 102（e）1999年2月26日PCT 1997年8月22日提交PCT公布。公开号WO98 / 08487 日期：1998年3月5日本发明涉及用于染色角质纤维，特别是人发的组合物和染色方法，其具有作为成色剂的至少一种下式的化合物：其中Za和Zb不同于彼此表示氧或氮原子，和至少一个氧化基。

8. 发明授权

US5531987A Method for extracting malodorous compounds present in a formulation containing at least one compound carrying a thiol group and deodorized compositions thus obtained 失效
标题翻译：用于提取含有至少一种带有硫醇基的化合物的制剂中存在的恶臭化合物的方法和由此获得的除臭组合物
公开(公告)号：US5531987A
公开(公告)日：1996-07-02
申请号：US285541
申请日：1994-08-02
申请人： Daniel Bauer , Francoise Richard , Muriel Hassoun , Gerard Malle , Henri Samain
发明人： Daniel Bauer , Francoise Richard , Muriel Hassoun , Gerard Malle , Henri Samain
IPC分类号： A61K8/00 , A61K8/46 , A61K8/97 , A61L9/01 , A61Q5/00 , A61Q5/04 , A61Q15/00 , B01D15/00 , C07C319/28 , C07C323/24 , C07C323/25 , C07C323/52 , C07C323/58 , A61K7/11
CPC分类号： A61Q5/04 , A61K8/46 , A61K8/97 , A61Q15/00 , C07C319/28
摘要： Method for extracting malodorous compounds present in a liquid formulation containing at least one compound bearing a thiol functional group of formula:HS--A--Y--B (I)in which said formulation is placed in contact with a pulverulent absorbing agent, in order to obtain a deodorized composition, intended for a subsequent use, said absorbing agent being such that, when it is suspended in an aqueous solution containing 92 g/l of thioglycolic acid, said aqueous solution also contains at least 30% by weight of the initial thioglycolic acid after contact for 15 minutes.
摘要翻译：用于提取含有至少一种含有式HS-AYB（I）的硫醇官能团的化合物的液体制剂中存在的恶臭化合物的方法，其中所述制剂与粉状吸收剂接触，以获得除臭组合物用于随后的使用，所述吸收剂使得当其悬浮在含有92g / l巯基乙酸的水溶液中时，所述水溶液还含有至少30重量％的接触后的初始巯基乙酸， 15分钟。

9. 发明授权

US4980509A Aromatic polycyclic derivatives, their process of preparation and their use in human and veterinary medicine and in cosmetics 失效
标题翻译：芳香族多环衍生物，其制备方法及其在人兽药和化妆品中的应用
公开(公告)号：US4980509A
公开(公告)日：1990-12-25
申请号：US214225
申请日：1988-07-01
申请人： Jean Maignan , Gerard Lang , Gerard Malle , Serge Restle
发明人： Jean Maignan , Gerard Lang , Gerard Malle , Serge Restle
IPC分类号： A61K8/30 , A61K8/00 , A61K8/46 , A61K31/10 , A61K31/12 , A61K31/135 , A61K31/15 , A61K31/165 , A61K31/18 , A61K31/19 , A61P17/00 , A61P27/02 , A61P27/14 , A61P29/00 , A61P35/00 , A61P37/00 , A61P37/08 , A61Q5/00 , A61Q7/00 , A61Q19/00 , A61Q90/00 , C07C67/00 , C07C301/00 , C07C309/28 , C07C309/29 , C07C309/33 , C07C309/72 , C07C311/15 , C07C311/16 , C07C311/17 , C07C311/18 , C07C311/19 , C07C311/29 , C07C313/00 , C07C315/00 , C07C317/00 , C07C317/14 , C07C317/18 , C07C317/22 , C07C317/28 , C07C317/32 , C07C317/44 , C07C321/28 , C07C323/00 , C07C323/12 , C07C323/18 , C07C323/19 , C07C323/22 , C07C323/24 , C07C323/25 , C07C323/32 , C07C323/47 , C07C323/52 , C07C323/58 , C07C323/60
CPC分类号： A61Q5/008 , A61K8/466 , A61Q19/00 , A61Q5/00 , C07C317/00 , C07C323/00 , A61Q19/008 , A61Q7/00
摘要： An aromatic polycyclic compound has the formula ##STR1## wherein R represents --SO.sub.3 H, SO.sub.2 NHR.sub.3, ##STR2## --SO.sub.2 R.sub.3, --SOR.sub.3 or --SR.sub.3, R.sub.3 represents lower alkyl, monohydroxyalkyl, polyhydroxyalkyl, aminoalkyl, carboxyalkyl, aminocarboxyalkyl or alkoxyalkyl,R' represents hydrogen, lower alkyl, lower alkoxy, hydroxy, C.sub.1 -C.sub.4 acyloxy or amino,R" represents hydrogen, lower alkyl or lower alkoxy, orR' and R", taken together, form an oxo, methano or hydroxyimino radical,R.sub.1 represents hydrogen or lower alkyl,n is 0 or 1,when n=1, R.sub.2 represents hydrogen or lower alkyl, or R.sub.1 and R.sub.2, taken together form a vinylene radical, andAr represents an aromatic radical selected from ##STR3## wherein R.sub.4, R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.9, R.sub.10 and R.sub.11 represent hydrogen or lower alkyl, at least one of R.sub.4 and/or R.sub.5 being other than hydrogen, and at least two of R.sub.8 -R.sub.11 being other than hydrogen,A represents methylene or dimethylene substituted or not by lower alkyl; when A represents dimethylene, R.sub.8 and R.sub.10 together can form a methylene or dimethylene radical,and the salts of the compound of formula I as well as their geometric and optical isomers.These compounds are useful in human and veterinary medicines and in cosmetic compositions.
摘要翻译：芳族多环化合物具有下式（I）其中R表示-SO 3 H，SO 2 NHR 3，-SO 2 R 3，-SOR 3或-SR 3，R 3表示低级烷基，单羟基烷基，多羟基烷基，氨基烷基，羧基烷基，氨基羧基烷基或烷氧基烷基， R“表示氢，低级烷基，低级烷氧基，羟基，C 1 -C 4酰氧基或氨基，R”表示氢，低级烷基或低级烷氧基，或R'和R“一起形成氧代，甲氧基或羟基亚氨基基团，R 1表示氢或低级烷基，n为0或1，当n = 1时，R 2表示氢或低级烷基，或者R 1和R 2一起形成亚乙烯基，Ar表示选自< （ⅰ）其中R 4，R 5，R 6，R 7，R 8，R 9，R 10和R 11表示氢或低级烷基，R 4和/或R 5中的至少一个不同于氢，并且R 8 -R 11中的至少两个不是氢，A表示亚甲基或被亚低级烷基取代的二亚甲基; 当A表示二亚甲基时，R 8和R 10一起可以形成亚甲基或二亚甲基，以及式I化合物的盐以及它们的几何和旋光异构体。这些化合物可用于人和兽用药物和化妆品组合物中。

10. 发明授权

US4892940A Aromatic naphthyl compounds, a process for their preparation and their use in human and veterinary medicine and in cosmetic compositions 失效
标题翻译：芳香族萘基化合物，其制备方法及其在人和兽医学和化妆品组合物中的应用
公开(公告)号：US4892940A
公开(公告)日：1990-01-09
申请号：US52930
申请日：1987-05-22
申请人： Jean Maignan , Gerard Lang , Gerard Malle , Serge Restle , Braham Shroot
发明人： Jean Maignan , Gerard Lang , Gerard Malle , Serge Restle , Braham Shroot
IPC分类号： C07C41/00 , A61K8/00 , A61K8/30 , A61K8/34 , A61K8/35 , A61K8/36 , A61K8/368 , A61K8/37 , A61K8/41 , A61K8/42 , A61K8/49 , A61K31/045 , A61K31/085 , A61K31/12 , A61K31/16 , A61K31/165 , A61K31/19 , A61K31/215 , A61P17/00 , A61P29/00 , A61P37/08 , C07C29/143 , C07C33/18 , C07C33/26 , C07C33/28 , C07C33/32 , C07C33/46 , C07C41/18 , C07C43/14 , C07C43/164 , C07C43/20 , C07C43/23 , C07C45/30 , C07C45/46 , C07C47/546 , C07C49/215 , C07C49/76 , C07C49/86 , C07C51/347 , C07C57/44 , C07C59/48 , C07C59/64 , C07C59/84 , C07C59/90 , C07C63/36 , C07C65/24 , C07C65/34 , C07C65/40 , C07C67/00 , C07C69/618 , C07C69/738 , C07C69/76 , C07C231/00 , C07C231/02 , C07C233/11 , C07C233/65 , C07C235/34 , C07C235/66 , C07C235/84 , C07C239/00
CPC分类号： C07C65/40 , C07C43/23 , C07C45/305 , C07C49/86 , C07C59/90 , C07C65/24 , C07C65/34 , Y10S514/844 , Y10S514/859 , Y10S514/88
摘要： An aromatic naphthyl compound of the formula ##STR1## wherein n is 0 or 1,R' is hydrogen, OH, acyloxy, alkoxy or NH.sub.2,R" is hydrogen or lower alkoxy, or R' and R" taken together form an oxo, methano or hydroxy-imino radical,R is --CH.sub.2 OH or --COR.sub.8,R.sub.8 is hydrogen, --OR.sub.9 or ##STR2## R.sub.9 is hydrogen, alkyl having 1-20 carbon atoms, mono or polyhydroxyalkyl, aryl, aralkyl, the residue of a sugar or ##STR3##is 1, 2 or 3,r' and r" each independently represent hydrogen, alkyl, monohydroxyalkyl, polyhydroxyalkyl, aryl, benzyl, the residue of amino acid or the residue of aminated sugar, or r' and r" together form a heterocycle,R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represent hydrogen, lower alkyl, alkoxy having 1-4 carbon atoms, fluoroalkoxy, CF.sub.3, cycloalkyl, lower acyl, halogen, OH, amino, acylamino or alkoxy carbonyl,R.sub.5, R.sub.6 and R.sub.7 represent hydrogen or methyl or when n=1, R.sub.5 and R.sub.7 taken together can form with the benzene ring a naphthalene ring, and the salts of the compound of formula I or their geometric or optical isomers.These compounds are useful in human and veterinary medicine and in cosmetic compositions.
摘要翻译：式（I）的芳香族萘基化合物，其中n为0或1，R'为氢，OH，酰氧基，烷氧基或NH 2，R“为氢或低级烷氧基，或R'和R”为一起形成氧代，甲醇或羟基亚氨基，R为-CH 2 OH或-COR 8，R 8为氢，-OR 9或R 9为氢，具有1-20个碳原子的烷基，单或多羟基烷基，芳基，芳烷基，糖或“IMAGE”的残基为1,2或3，r'和r“各自独立地表示氢，烷基，单羟基烷基，多羟基烷基，芳基，苄基，氨基酸的残基或胺化糖的残基，或 r'和r“一起形成杂环，R 1，R 2，R 3和R 4表示氢，低级烷基，具有1-4个碳原子的烷氧基，氟烷氧基，CF 3，环烷基，低级酰基，卤素，OH，氨基，酰氨基或烷氧基羰基，R 5，R 6和R 7表示氢或甲基，或当n = 1时，R 5和R 7一起可以与苯环形成萘环，式I化合物或其几何形式的盐 c或光学异构体。这些化合物可用于人和兽医学和化妆品组合物。

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