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1. 发明授权

US6118008A Diamino pyrazols, their synthesis, keratin fibre dyeing compositions containing them, keratin fibre dyeing methods 失效
标题翻译：二氨基吡唑，它们的合成，含有它们的角蛋白纤维染色组合物，角蛋白纤维染色方法
公开(公告)号：US6118008A
公开(公告)日：2000-09-12
申请号：US180183
申请日：1999-05-07
申请人： Gerard Malle , Laurent Vidal , Agnes Burande , Mireille Maubru
发明人： Gerard Malle , Laurent Vidal , Agnes Burande , Mireille Maubru
IPC分类号： A61K8/00 , A61K8/20 , A61K8/22 , A61K8/23 , A61K8/31 , A61K8/34 , A61K8/36 , A61K8/365 , A61K8/38 , A61K8/41 , A61K8/49 , A61Q5/10 , C07D231/38 , C09B57/00 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/494 , C07D231/38
摘要： The invention discloses new 5-substituted 3,4-diamino pyrazols, their methods of preparation, compositions for keratin fiber oxidation dyeing containing them as an oxidizing base, and the dyeing methods using same.
摘要翻译： PCT No.PCT / FR97 / 00750 Sec。 371日期1999年5月7日 102（e）日期1999年5月7日PCT 1997年4月25日PCT公布。公开号WO97 / 42173 日期1997年11月13日本发明公开了新的5-取代的3,4-二氨基吡唑，它们的制备方法，将它们作为氧化性碱的角蛋白纤维氧化染色的组合物和使用它们的染色方法。

2. 发明授权

US6099592A Composition for dyeing keratin fibers which contain at least one diaminopyrazole, dyeing process, novel diaminopyrazoles and process for their preparation 失效
公开(公告)号：US6099592A
公开(公告)日：2000-08-08
申请号：US642622
申请日：1996-05-03
申请人： Laurent Vidal , Agnes Burande , Gerard Malle , Michel Hocquaux
发明人： Laurent Vidal , Agnes Burande , Gerard Malle , Michel Hocquaux
IPC分类号： A61K8/35 , A61K8/00 , A61K8/19 , A61K8/23 , A61K8/33 , A61K8/34 , A61K8/41 , A61K8/49 , A61Q5/10 , B65D81/32 , C07D231/38 , C09B57/00 , C09B67/42 , D06P3/08 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/494 , C07D231/38
摘要： The invention relates to novel compositions for the oxidation dyeing of keratin fibers, comprising at least one specific diaminopyrazole derivative, to the dyeing process using this composition, to novel diaminopyrazole derivatives and to a process for their preparation.

3. 发明授权

US6063136A Compositions containing pyrrolo-oxazole couplers for dyeing keratin fibers and dyeing methods 失效
标题翻译：含有用于染色角蛋白纤维的吡咯 - 恶唑成色剂和染色方法的组合物
公开(公告)号：US6063136A
公开(公告)日：2000-05-16
申请号：US242932
申请日：1999-02-26
申请人： Laurent Vidal , Gerard Malle
发明人： Laurent Vidal , Gerard Malle
IPC分类号： A61K8/00 , A61K8/20 , A61K8/22 , A61K8/23 , A61K8/34 , A61K8/36 , A61K8/41 , A61K8/46 , A61K8/49 , A61Q5/10 , C09B57/00 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/49
摘要： The present invention relates to a composition and a dyeing process for the dyeing of keratinous fibers, in particular of human hair, having,as coupler, at least one compound of formula: ##STR1## where Z.sub.a and Z.sub.b, which are different from one another, represent an oxygen or nitrogen atom,and at least one oxidation base.
摘要翻译： PCT No.PCT / FR97 / 01522 Sec。 371日期1999年2月26日 102（e）1999年2月26日PCT 1997年8月22日提交PCT公布。公开号WO98 / 08487 日期：1998年3月5日本发明涉及用于染色角质纤维，特别是人发的组合物和染色方法，其具有作为成色剂的至少一种下式的化合物：其中Za和Zb不同于彼此表示氧或氮原子，和至少一个氧化基。

4. 发明授权

US6139589A Compositions for dyeing keratin fibers containing pyrazolo[3, 4-d]thiazoles as couplers and dyeing methods 失效
标题翻译：用于染色含有吡唑并[3,4-d]噻唑的角蛋白纤维作为成色剂和染色方法的组合物
公开(公告)号：US6139589A
公开(公告)日：2000-10-31
申请号：US242902
申请日：1999-02-26
申请人： Laurent Vidal , Gerard Malle
发明人： Laurent Vidal , Gerard Malle
IPC分类号： A61K8/00 , A61K8/22 , A61K8/33 , A61K8/34 , A61K8/38 , A61K8/41 , A61K8/49 , A61Q5/10 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/49
摘要： The present invention relates to a composition and dyeing process for the dyeing of keratinous fibers using the composition, where the composition has as coupler, at least one compound of formula: ##STR1## where R.sub.1 denotes in particular hydrogen, halogen; alkoxy, aryloxy; acyloxy; arylthio; alkylthio; an NR.sup.III R.sup.IV radical with R.sup.III and R.sup.IV, which are identical or different, representing a C.sub.1 -C.sub.4 alkyl, and the like; R.sub.2 denotes hydrogen; halogen; acyl; sulphonyl; sulphinyl; phosphonyl; carbamoyl; sulphamoyl; cyano; siloxy; amino; acylamino; acyloxy; carbamoyloxy; sulphonamido; imido; ureido; sulphamoylamino; alkoxycarbonylamino; aryloxycarbonylamino; alkoxycarbonyl; aryloxycarbonyl; carboxyl; alkyl; or aryl; or a 5- or 6-membered heterocycle having at least one nitrogen, oxygen or sulphur atom; when R.sub.2 denotes an alkyl radical, an aryl radical or a 5- or 6-membered heterocycle, it can be connected to the carbon atom of the nucleus via an oxygen, a nitrogen or sulphur atom; and at least one oxidation base.
摘要翻译： PCT No.PCT / FR97 / 01521 Sec。 371日期1999年2月26日 102（e）1999年2月26日PCT 1997年8月22日提交PCT公布。公开号WO98 / 08486 1998年3月5日本发明涉及使用组合物染色角质纤维的组合物和染色方法，其中组合物具有成色剂，至少一种下式化合物：其中R1表示特别是氢，卤素; 烷氧基，芳氧基酰氧基芳硫基烷硫基具有RIII和RIV的NRIIIRIV基团，其相同或不同，表示C1-C4烷基等; R2表示氢; 卤素; 酰基; 磺酰基; 亚磺酰基; 膦酰基; 氨基甲酰基; 氨磺酰; 氰基; 甲氧基氨基; 酰氨基; 酰氧基氨基甲酰氧基磺胺亚胺酸脲基氨磺酰氨基; 烷氧基羰基氨基; 芳氧基羰基氨基; 烷氧基羰基芳氧基羰基; 羧基; 烷基; 或芳基; 或具有至少一个氮，氧或硫原子的5-或6-元杂环; 当R2表示烷基，芳基或5-或6-元杂环时，它可以通过氧，氮或硫原子与核的碳原子相连; 和至少一个氧化基。

5. 发明授权

US6165229A Imidazoloazole-containing compositions for dyeing keratin fibers; their use in dyeing as couplers; dyeing process 失效
标题翻译：用于染色角蛋白纤维的含咪唑并唑组合物; 它们用作染色剂作为成色剂; 染色工艺
公开(公告)号：US6165229A
公开(公告)日：2000-12-26
申请号：US155193
申请日：1999-02-08
申请人： Laurent Vidal , Gerard Malle
发明人： Laurent Vidal , Gerard Malle
IPC分类号： A61K8/00 , A45D19/00 , A61K8/20 , A61K8/22 , A61K8/34 , A61K8/41 , A61K8/49 , A61Q5/10 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/4946
摘要： The present invention relates to a composition for dyeing keratin fibers, in particular human hair, containing, in a medium which is suitable for dyeing, at least:as coupler, at least one compound of formula: ##STR1## in which: R.sub.1 denotes, in particular, hydrogen, alkyl, phenyl, substituted phenyl, cyano; carbonyl; etc.R.sub.2 denotes, in particular, hydrogen, halogen, alkoxy, aryloxy, acyloxy, acetamido, dialkylamino, etc.Z.sub.a and Z.sub.b denote a nitrogen atom or a carbon bearing a group R.sub.3 or R.sub.4 or R.sub.5, with the proviso that at least one of the two is a carbon atom;R.sub.3 and R.sub.4, which are independent, denote cyano; trifluoroalkyl; alkoxycarbonyl; aryloxycarbonyl, hydrogen; alkyl; carboxyl; etc.R.sub.5 denotes, in particular, hydrogen, aryl, alkoxy, alkylthio, etc.at least one oxidation base.
摘要翻译：本发明涉及用于染色角蛋白纤维，特别是人类头发的组合物，其在适合于染色的介质中至少包含：作为成色剂的至少一种下式化合物：其中：R1表示，特别是，氢，烷基，苯基，取代的苯基，氰基; 羰; 等等，R2表示特别是氢，卤素，烷氧基，芳氧基，酰氧基，乙酰氨基，二烷基氨基等。Za和Zb表示氮原子或带有R3或R4或R5基团的碳，条件是至少一个两个是碳原子; 独立的R 3和R 4表示氰基; 三氟烷基烷氧羰基芳氧基羰基，氢; 烷基; 羧基; R5表示特别是氢，芳基，烷氧基，烷硫基等至少一个氧化基。

6. 发明授权

US5931973A 4,5-dIiminopyrazolines, processes for their preparation, and their application in keratin fiber dyeing compositions and processes 失效
标题翻译： 4,5-二咪唑啉，其制备方法及其在角蛋白纤维染色组合物和方法中的应用
公开(公告)号：US5931973A
公开(公告)日：1999-08-03
申请号：US828295
申请日：1997-03-21
申请人： Gerard Malle , Laurent Vidal , Henri Samain
发明人： Gerard Malle , Laurent Vidal , Henri Samain
IPC分类号： A61K8/49 , A61Q5/06 , C07D231/38 , A61K7/13 , C07D231/10
CPC分类号： C07D231/38 , A61K8/494 , A61Q5/065
摘要： Dyes selected from 4,5-diiminopyrazolines or their 4-ylideneamino-5-aminopyrazole tautomeric forms, a process for their preparation, and their use as direct dyes in dye compositions for keratin fibers, in particular for human keratin fibers. The dyes may also be used in lightening or non-lightening dye compositions for the direct dyeing of keratin fibers, and in dyeing processes using these compositions.
摘要翻译：选自4,5-二亚氨基吡唑啉或其4-亚基氨基-5-氨基吡唑互变异构体的染料，其制备方法，以及它们作为角蛋白纤维，特别是人角蛋白纤维的染料组合物中的直接染料的用途。染料还可以用于减轻或不减轻染色组合物中直接染色角蛋白纤维，以及使用这些组合物的染色方法。

7. 发明授权

US5958382A 4,4-dihydroxy-5-pyrazolinones and cosmetic/dermatological compositions comprised thereof 失效
标题翻译： 4,4-二羟基-5-吡唑啉酮及其组合的化妆品/皮肤病学组合物
公开(公告)号：US5958382A
公开(公告)日：1999-09-28
申请号：US157412
申请日：1998-09-21
申请人： Laurent Vidal , Gerard Malle , Jean-Claude Garson
发明人： Laurent Vidal , Gerard Malle , Jean-Claude Garson
IPC分类号： C07D231/14 , A61K8/00 , A61K8/49 , A61Q1/02 , A61Q1/12 , A61Q5/06 , A61Q5/10 , A61Q17/04 , A61Q19/00 , A61Q19/04 , C07D231/28 , C07D231/40 , C07D231/52 , A61K7/42 , A61K7/44
CPC分类号： C07D231/52 , A61K8/494 , A61Q19/04 , A61Q5/065 , C07D231/28 , Y10S514/844 , Y10S514/847
摘要： Novel 4,4-dihydroxy-5-pyrazolinones having the structural formula (I): ##STR1## and cosmetic/dermatological formulations comprised thereof are useful for artificially coloring, e.g., tanning/browning, human skin and/or hair, and are well suited for imparting a healthy appearance to facial skin by enhancing the radiance of the complexion, while at the same time retaining transparency.
摘要翻译：具有结构式（I）的新型4,4-二羟基-5-吡唑啉酮及其包含的化妆品/皮肤病学制剂可用于人造着色，例如鞣/褐变，人皮肤和/或毛发，并且非常适合于赋予通过增强肤色的光泽，同时保持透明度，使面部皮肤健康的外观。

8. 发明申请

US20130039862A1 COMPOUNDS OF DIBENZYLIDENE SORBITOL ESTER TYPE, PROCESS OF PREPARATION, USE, COMPOSITIONS COMPRISING THEM AND COSMETIC TREATMENT METHOD 有权
标题翻译：二苯醚类化合物类型的化合物，制备方法，用途，包含它们的组合物和化妆处理方法
公开(公告)号：US20130039862A1
公开(公告)日：2013-02-14
申请号：US13581915
申请日：2011-02-25
申请人： Gerard Malle , Tiina Luukas
发明人： Gerard Malle , Tiina Luukas
IPC分类号： C07D493/04 , A61K8/49 , A61K8/58 , A61K47/22 , A61K47/24 , A61K8/97 , A61K47/46 , A61K8/98 , A61K8/92 , A61Q19/00 , A61Q1/00 , A61Q3/00 , A61Q5/00 , A61Q17/04 , C07F7/18
CPC分类号： C07D493/04 , C07D519/00
摘要： The invention relates to novel compounds of dibenzylidene sorbitol ester type corresponding to the following formulae (I) and (II): in which: R, R′ and R″ represent a hydrogen atom or a —C(O)Y radical in which Y represents a C2-C25 hydrocarbon radical or an optionally substituted aryl radical; the R1, R2, R3, R4, R5, R′1, R′2, R′3, R′4 and R′5 radicals represent a hydrogen atom; a C1-C18 alkyl radical; a C1-C18 alkoxy radical; a phenoxy radical; an optionally substituted phenyl radical; or a benzyl radical; the divalent radical A represents, in the formula (II), a C1-C52 hydrocarbon radical; an optionally substituted arylene radical; or a silicone radical. The invention also relates to their process of preparation, to their use in structuring lipophilic media, in particular oils, to the cosmetic or pharmaceutical compositions comprising them and to a cosmetic treatment method employing them.
摘要翻译：本发明涉及对应于下式（I）和（II）的二亚苄基山梨醇酯型的新化合物：其中：R，R'和R“表示氢原子或-C（O）Y基团，其中Y 表示C2-C25烃基或任选取代的芳基; R1，R2，R3，R4，R5，R'1，R'2，R'3，R'4和R'5基团代表氢原子; C1-C18烷基; C1-C18烷氧基; 苯氧基; 任选取代的苯基; 或苄基; 二价基团A在式（II）中表示C1-C52烃基; 任选取代的亚芳基; 或硅酮基。本发明还涉及其制备方法，其用于将亲脂性介质，特别是油结构化成包含它们的化妆品或药物组合物以及使用它们的美容治疗方法。

9. 发明申请

US20120085364A1 METHOD FOR MAKING UP EYELASHES 审中-公开
标题翻译：用于制作眼镜的方法
公开(公告)号：US20120085364A1
公开(公告)日：2012-04-12
申请号：US13263381
申请日：2010-04-02
申请人： Gerard Malle , Stephane Arditty , Nathalie Jager Lezer
发明人： Gerard Malle , Stephane Arditty , Nathalie Jager Lezer
IPC分类号： A45D7/04 , A45D44/00 , A61Q1/10 , A45D7/00
CPC分类号： A61Q1/10 , A61K8/8152 , A61K2800/81 , A61K2800/88 , A61K2800/95
摘要： One subject of the invention is a method for making up eyelashes, consisting in: a) coating the eyelashes with a deposit of at least one composition comprising, in a physiologically acceptable medium, at least one compound enabling the composition to attain, in the at least partially dry state, a modulus of rigidity Gp greater than or equal to 1 GPa, b) in the presence of a stimulus to which said compound is sensitive, placing a shaping tool in contact with the thus coated eyelashes so as to modify the curvature of the eyelashes, said contact being maintained until the modulus of rigidity Gp of the composition is at least equal to 1 GPa, the stimulus being chosen so that the modulus of rigidity of at least 1 GPa is obtained in a time t that is less than the time t0 that would be needed to obtain it by leaving the deposit to dry at room temperature.
摘要翻译：本发明的一个主题是一种用于制造睫毛的方法，其包括：a）用至少一种组合物的沉积物涂覆睫毛，所述组合物在生理学上可接受的介质中包含至少一种化合物，使组合物在最小部分干燥状态，刚性模量Gp大于或等于1GPa，b）在存在所述化合物敏感的刺激的情况下，将成形工具与如此涂覆的睫毛接触以改变曲率的睫毛，所述接触保持直到组合物的刚度Gp至少等于1GPa，所述刺激被选择为使得在小于1的时间t获得至少1GPa的刚度模量通过将沉积物在室温下干燥而获得的时间t0。

10. 发明授权

US5531987A Method for extracting malodorous compounds present in a formulation containing at least one compound carrying a thiol group and deodorized compositions thus obtained 失效
标题翻译：用于提取含有至少一种带有硫醇基的化合物的制剂中存在的恶臭化合物的方法和由此获得的除臭组合物
公开(公告)号：US5531987A
公开(公告)日：1996-07-02
申请号：US285541
申请日：1994-08-02
申请人： Daniel Bauer , Francoise Richard , Muriel Hassoun , Gerard Malle , Henri Samain
发明人： Daniel Bauer , Francoise Richard , Muriel Hassoun , Gerard Malle , Henri Samain
IPC分类号： A61K8/00 , A61K8/46 , A61K8/97 , A61L9/01 , A61Q5/00 , A61Q5/04 , A61Q15/00 , B01D15/00 , C07C319/28 , C07C323/24 , C07C323/25 , C07C323/52 , C07C323/58 , A61K7/11
CPC分类号： A61Q5/04 , A61K8/46 , A61K8/97 , A61Q15/00 , C07C319/28
摘要： Method for extracting malodorous compounds present in a liquid formulation containing at least one compound bearing a thiol functional group of formula:HS--A--Y--B (I)in which said formulation is placed in contact with a pulverulent absorbing agent, in order to obtain a deodorized composition, intended for a subsequent use, said absorbing agent being such that, when it is suspended in an aqueous solution containing 92 g/l of thioglycolic acid, said aqueous solution also contains at least 30% by weight of the initial thioglycolic acid after contact for 15 minutes.
摘要翻译：用于提取含有至少一种含有式HS-AYB（I）的硫醇官能团的化合物的液体制剂中存在的恶臭化合物的方法，其中所述制剂与粉状吸收剂接触，以获得除臭组合物用于随后的使用，所述吸收剂使得当其悬浮在含有92g / l巯基乙酸的水溶液中时，所述水溶液还含有至少30重量％的接触后的初始巯基乙酸， 15分钟。

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