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1. 发明授权

US5750752A Transition metal compound 失效
标题翻译：过渡金属化合物
公开(公告)号：US5750752A
公开(公告)日：1998-05-12
申请号：US668790
申请日：1996-06-21
申请人： Michael Riedel , Frank Kuber , Michael Aulbach , Gerhard Erker , Martin Konemann
发明人： Michael Riedel , Frank Kuber , Michael Aulbach , Gerhard Erker , Martin Konemann
IPC分类号： C07F17/00 , C08F4/60 , C08F4/602 , C08F4/6192 , C08F4/622 , C08F4/642 , C08F4/74 , C08F10/00 , B01J31/00
CPC分类号： C07F17/00 , C08F10/00 , C08F4/6192 , Y10S526/943
摘要： The present invention relates to a stereorigid transition metal compound having as ligands a cyclopentadienyl group and a substituted or unsubstituted heteroatom which are connected to one another via a monocyclic or polycyclic ring system, with the cyclopentadienyl group being fused onto the monocyclic or polycyclic ring system. The transition metal compound of the invention is suitable as a catalyst component for olefin polymerization.
摘要翻译：本发明涉及一种具有环戊二烯基配位体和取代或未取代的杂原子的立体刚性过渡金属化合物，它们通过单环或多环系统相互连接，环戊二烯基被稠合在单环或多环系统上。本发明的过渡金属化合物适合用作烯烃聚合的催化剂组分。

2. 发明授权

US5792819A Process for the preparation of an olefin polymer 失效
标题翻译：制备烯烃聚合物的方法
公开(公告)号：US5792819A
公开(公告)日：1998-08-11
申请号：US475940
申请日：1995-06-07
申请人： Gerhard Erker , Bodo Temme , Michael Aulbach , Bernd Bachmann , Frank Kuber
发明人： Gerhard Erker , Bodo Temme , Michael Aulbach , Bernd Bachmann , Frank Kuber
IPC分类号： C07F7/08 , C07F17/00 , C08F4/44 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/62 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F4/68 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/02 , C08F210/16
CPC分类号： C08F10/00 , C07F17/00 , C08F110/02 , C08F110/06 , C08F210/02 , C08F210/16 , C08F4/61908 , C08F4/61912 , C08F4/61922 , C08F4/65916 , C08F4/65922 , Y10S526/943
摘要： The present invention relates to zwitterionic neutral transition metal compounds. The compounds are suitable as catalyst components for the polymerization of olefins.
摘要翻译：本发明涉及两性离子中性过渡金属化合物。该化合物适用于烯烃聚合的催化剂组分。

3. 发明授权

US5990254A Metallocenes as catalysts in the preparation of cycloolefin copolymers 失效
标题翻译：金属茂作为制备环烯烃共聚物的催化剂
公开(公告)号：US5990254A
公开(公告)日：1999-11-23
申请号：US780179
申请日：1996-12-26
申请人： Thomas Weller , Michael Aulbach , Frank Kuber , Gerhard Erker , Christian Psiorz , Bernd Bachmann , Frank Osan
发明人： Thomas Weller , Michael Aulbach , Frank Kuber , Gerhard Erker , Christian Psiorz , Bernd Bachmann , Frank Osan
IPC分类号： B01J31/06 , B01J31/22 , C07C13/15 , C07F5/00 , C07F5/06 , C07F7/00 , C07F7/02 , C07F9/00 , C07F17/00 , C08F4/42 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F210/18 , C08F232/04
CPC分类号： C08F10/00 , C07F17/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F210/18 , C08F4/61912 , C08F4/61927 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： The present invention relates to a stereorigid metallocene compound containing, as ligands, at least two substituted or unsubstituted cyclopentadienyl groups which are bonded to one another via a monocyclic or polycyclic ring system, where at least one cyclopentadienyl group is fused to the monocyclic or polycyclic ring system, and to a process for the preparation of a cycloolefin copolymer. The cycloolefin copolymers obtained in this way have high tear strengths and are suitable for the production of extrusion parts and injection moldings.
摘要翻译：本发明涉及一种立体刚性茂金属化合物，其含有通过单环或多环系统彼此键合的至少两个取代或未取代的环戊二烯基作为配体，其中至少一个环戊二烯基与单环或多环稠合系统，以及制备环烯烃共聚物的方法。以这种方式获得的环烯烃共聚物具有很高的撕裂强度，适用于生产挤出部件和注射成型品。

4. 发明授权

US5710297A Metallocenes, and their use as catalysts 失效
标题翻译：金属茂及其作为催化剂的用途
公开(公告)号：US5710297A
公开(公告)日：1998-01-20
申请号：US712681
申请日：1996-09-13
申请人： Thomas Weller , Michael Aulbach , Frank Kuber , Gerhard Erker , Christian Psiorz , Bernd Bachmann , Frank Osan
发明人： Thomas Weller , Michael Aulbach , Frank Kuber , Gerhard Erker , Christian Psiorz , Bernd Bachmann , Frank Osan
IPC分类号： B01J31/06 , B01J31/22 , C07C13/15 , C07F5/00 , C07F5/06 , C07F7/00 , C07F7/02 , C07F9/00 , C07F17/00 , C08F4/42 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F210/18 , B01J31/00 , C07F7/28
CPC分类号： C08F10/00 , C07F17/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F210/18 , C08F4/61912 , C08F4/61927 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： The present invention relates to a stereorigid metallocene compound containing, as ligands, at least two substituted or unsubstituted cyclopentadienyl groups which are bonded to one another via a monocyclic or polycyclic ring system, where at least one cyclopentadienyl group is fused to the monocyclic or polycyclic ring system, and to a process for the preparation of a cycloolefin copolymer. The cycloolefin copolymers obtained in this way have high tear strengths and are suitable for the production of extrusion parts and injection moldings.
摘要翻译：本发明涉及一种立体刚性茂金属化合物，其含有通过单环或多环系统彼此键合的至少两个取代或未取代的环戊二烯基作为配体，其中至少一个环戊二烯基与单环或多环稠合系统，以及制备环烯烃共聚物的方法。以这种方式获得的环烯烃共聚物具有很高的撕裂强度，适用于生产挤出部件和注射成型品。

5. 发明授权

US6002032A Transition metal compound 失效
标题翻译：过渡金属化合物
公开(公告)号：US6002032A
公开(公告)日：1999-12-14
申请号：US478900
申请日：1995-06-07
申请人： Gerhard Erker , Bodo Temme , Michael Aulbach , Bernd Bachmann , Frank Kuber
发明人： Gerhard Erker , Bodo Temme , Michael Aulbach , Bernd Bachmann , Frank Kuber
IPC分类号： C07F5/02 , C07F7/00 , C07F7/08 , C07F17/00 , C08F4/602 , C08F4/619 , C08F4/6192 , C08F4/643 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/02 , C08F210/16
CPC分类号： C08F10/00 , C07F17/00 , C08F110/02 , C08F110/06 , C08F210/02 , C08F210/16 , C08F4/61908 , C08F4/61912 , C08F4/61922 , C08F4/65916 , C08F4/65922
摘要： The present invention relates to zwitterionic neutral transition metal compounds. The compounds are suitable as catalyst components for the polymerization of olefins.
摘要翻译：本发明涉及两性离子中性过渡金属化合物。该化合物适用于烯烃聚合的催化剂组分。

6. 发明授权

US5565534A Process for the preparation of polyolefins 失效
标题翻译：制备聚烯烃的方法
公开(公告)号：US5565534A
公开(公告)日：1996-10-15
申请号：US360609
申请日：1994-12-21
申请人： Michael Aulbach , Bernd Bachmann , Gerhard Erker , Christian Psiorz , Frank Kuber , Frank Osan , Thomas Weller , Hans-Friedrich Herrmann
发明人： Michael Aulbach , Bernd Bachmann , Gerhard Erker , Christian Psiorz , Frank Kuber , Frank Osan , Thomas Weller , Hans-Friedrich Herrmann
IPC分类号： C07F17/00 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F4/76 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F210/18
CPC分类号： C08F210/18 , C07F17/00 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F4/61912 , C08F4/61916 , C08F4/61927 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： The present invention relates to a process for the preparation of a polyolefin by polymerization of at least one olefin in the presence of a stereorigid metallocene compound containing, as ligands, at least two substituted or unsubstituted cyclopentadienyl groups bonded to one another via a monocyclic or polycyclic ring system, in which at least one cyclopentadienyl group is fused to the monocyclic or polycyclic ring system.
摘要翻译：本发明涉及一种制备聚烯烃的方法，该方法是通过在含有作为配位体的至少两个取代或未取代的环戊二烯基的立体刚性茂金属化合物存在下聚合至少一种烯烃，所述环戊二烯基通过单环或多环其中至少一个环戊二烯基与单环或多环系稠合。

7. 再颁专利

USRE40121E1 Transition metal compound 有权
标题翻译：过渡金属化合物
公开(公告)号：USRE40121E1
公开(公告)日：2008-02-26
申请号：US09851643
申请日：2001-05-08
申请人： Gerhard Erker , Bodo Temme , Michael Aulbach , Bernd Bachmann , Frank Küber
发明人： Gerhard Erker , Bodo Temme , Michael Aulbach , Bernd Bachmann , Frank Küber
IPC分类号： C07F7/08 , C07F17/00 , B01J31/00
CPC分类号： C08F10/00 , C07F17/00 , C08F4/61908 , C08F4/61912 , C08F4/61922 , C08F4/65916 , C08F4/65922 , C08F110/02 , C08F110/06 , C08F210/02 , C08F210/16 , C08F4/65908 , C08F2500/03 , C08F2500/17 , C08F2500/15 , C08F2500/12 , C08F2500/16 , C08F232/00 , C08F2500/25 , C08F210/14
摘要： The present invention relates to zwitterionic neutral transition metal compounds. The compounds are suitable as catalyst components for the polymerization of olefins.
摘要翻译：本发明涉及两性离子中性过渡金属化合物。该化合物适用于烯烃聚合的催化剂组分。

8. 发明授权

US5194619A Process for the preparation of substituted indenes 失效
标题翻译：制备替代品的方法
公开(公告)号：US5194619A
公开(公告)日：1993-03-16
申请号：US837367
申请日：1992-02-14
申请人： Dieter Reuschling , Jurgen Rohrmann , Gerhard Erker , Reiner Nolte , Michael Aulbach , Astrid Weiss
发明人： Dieter Reuschling , Jurgen Rohrmann , Gerhard Erker , Reiner Nolte , Michael Aulbach , Astrid Weiss
IPC分类号： C07C1/207 , C07C1/24 , C07C2/86 , C07C13/465 , C07C17/26 , C07C22/08 , C07C25/22 , C07C43/21 , C07C43/267 , C07C43/29 , C07D213/06 , C07D213/16 , C07D307/36 , C07D333/08 , C07D335/02 , C07F7/08
CPC分类号： C07D213/16 , C07C17/2637 , C07C2/867 , C07D307/36 , C07D333/08 , C07C2102/08
摘要： The compounds of the formula I or Ia ##STR1## in which R.sup.1 is alkyl, aryl, alkoxy, alkenyl, arylalkyl, alkylaryl, aryloxy, fluoroalkyl, halogenoaryl, alkynyl, trialkylsilyl or a heteroaromatic radical,R.sup.2, R.sup.3 and R.sup.4, in addition to hydrogen, have the meanings given under R.sup.1 andR.sup.5 is hydrogen, alkyl, fluoroalkyl or alkenyl, can be obtained in a one-stage process by reaction of a compound II ##STR2## with (substituted) cyclopentadiene in the presence of a base. The compounds I and Ia are suitable as ligands for metallocene complexes which are used as catalysts in olefin polymerization.
摘要翻译：其中R 1是烷基，芳基，烷氧基，烯基，芳基烷基，烷基芳基，芳氧基，氟代烷基，卤代芳基，炔基，三烷基甲硅烷基或杂芳族基团的式I或Ia化合物（Ⅰ） R 2，R 3和R 4除氢之外，具有R 1和R 5为氢，烷基，氟烷基或烯基的含义，可以通过化合物II与（取代的）反应在一步法中获得，环戊二烯在碱的存在下反应。化合物I和Ia适合用作茂金属络合物的配体，其用作烯烃聚合中的催化剂。

9. 发明授权

US6090739A Transition metal compound 失效
标题翻译：过渡金属化合物
公开(公告)号：US6090739A
公开(公告)日：2000-07-18
申请号：US877832
申请日：1997-06-18
申请人： Michael Riedel , Gerhard Erker , Lothar Duda
发明人： Michael Riedel , Gerhard Erker , Lothar Duda
IPC分类号： C07F7/00 , C07F7/28 , C07F17/00 , C08F4/02 , C08F4/619 , C08F4/6192 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , B01J31/00
CPC分类号： C07F17/00 , C08F10/00 , C08F4/61916 , C08F4/6192 , Y10S526/943
摘要： The present invention relates to a transition metal compound of the formula I ##STR1## where M.sup.1 is a metal of group IIIb, IVb or Vb of the Periodic Table of the Elements,R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are identical or different and are each a hydrogen atom, a halogen atom, a C.sub.1 -C.sub.40 -hydrocarbon-containing group, an --SiR.sup.5.sub.3, --NR.sup.5.sub.2, --Si(OR.sup.5).sub.3, --Si(SR.sup.5).sub.3 or --PR.sup.5.sub.2 radical, where R.sup.5 are identical or different and are each a halogen atom, a C.sub.1 -C.sub.10 -alkyl group or a C.sub.6 -C.sub.10 -aryl group, or two or more radicals R.sup.1, R.sup.2, R.sup.3 or R.sup.4 together with the atoms connecting them form a ring system,Y are identical or different and are each a hydrogen atom, a C.sub.1 -C.sub.40 -hydrocarbon-containing group, an OH group, a halogen atom or an NR.sup.5.sub.2 group,k is an integer which corresponds to the valence of the transition metal atom M.sup.1 minus two and if Y is a butadiene unit, k is 1,A is a bridge,R.sup.8 is a hydrogen atom, a halogen atom, a C.sub.1 -C.sub.40 -group, an --SiR.sup.5.sub.3, --NR.sup.5.sub.2, --Si(OR.sup.5).sub.3, --Si(SR.sup.5).sub.3 or --PR.sup.5.sub.2 radical, and X is an element of group Va or Vla of the Periodic Table of the Elements.The transition metal compound is suitable as a catalyst component for olefin polymerization.
摘要翻译：本发明涉及式I的过渡金属化合物，其中M1是元素周期表Ⅲb族，Ⅳb族或Ⅴb族金属，R1，R2，R3和R4相同或不同，各自为氢原子，卤素原子，含C 1 -C 40烃的基团，-SiR 53，-NR 52，-Si（OR 5）3，-Si（SR 5）3或-PR 52基团，其中R 5相同或不同，各自为卤素原子，C 1 -C 10 - 烷基或C 6 -C 10 - 芳基，或两个或更多个基团R 1，R 2，R 3或R 4与连接它们的原子一起形成环系，Y相同或不同，各自相同或不同氢原子，含C1-C40烃基，OH基，卤素原子或NR52基团，k为对应于过渡金属原子M1的化合价减去2的整数，如果Y为丁二烯单元，k为1，A为桥，R8为氢原子，卤素原子，C1-C40基，-SiR53，-NR52，-Si（OR5）3，-Si（SR5）3或-PR52 激进，X是Va或Vla o的元素元素周期表。过渡金属化合物适合用作烯烃聚合的催化剂组分。

10. 发明授权

US6069264A Transition metal compound 失效
标题翻译：过渡金属化合物
公开(公告)号：US6069264A
公开(公告)日：2000-05-30
申请号：US874024
申请日：1997-06-12
申请人： Michael Riedel , Gerhard Erker , Martin Konnemann
发明人： Michael Riedel , Gerhard Erker , Martin Konnemann
IPC分类号： C07F7/00 , C07F7/02 , C07F7/12 , C07F9/50 , C07F17/00 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/64 , C08F4/642 , C08F4/6592 , C08F10/00
CPC分类号： C07F17/00 , C08F10/00 , C08F4/61912 , C08F4/61916 , C08F4/61927
摘要： The present invention relates to a transition metal compound of the formula I ##STR1## where M.sup.1 is a transition metal of group IIIb, IVb, Vb or VIb of the Periodic Table of the Elements,Y are identical or different and are each a hydrogen atom, an OH group, a halogen atom, a C.sub.1 -C.sub.40 -hydrocarbon-containing group or an NR.sup.15.sub.2 group, where R.sup.15 is a halogen atom, a C.sub.1 -C.sub.10 -alkyl group or a C.sub.6 -C.sub.10 -aryl group, k is an integer which corresponds to the valence of the transition metal atom M.sup.1 minus two and, if Y is a butadiene unit, k is 1,R.sup.1, R.sup.2, R.sup.3, R.sup.7, R.sup.8 and R.sup.9 are identical or different and are each a hydrogen atom, a halogen atom, a C.sub.1 -C.sub.40 -hydrocarbon-containing group, an --SiR.sup.15.sub.3, --NR.sup.15.sub.2, --SiOR.sup.15.sub.3, --SiSR.sup.15.sub.3 or --PR.sup.15.sub.2 radical, where R.sup.15 is a halogen atom, a C.sub.1 -C.sub.10 -alkyl group or a C.sub.6 -C.sub.10 -aryl group, or two or more adjacent radicals R.sup.1, R.sup.2 and R.sup.3 or R.sup.7, R.sup.8 and R.sup.9 together with the atoms connecting them form a ring system,.sup.1 H-NMR (200 MHz, CD.sub.2 Cl.sub.2): 7.4-7.2 (m, 10H, Ph-H); 7.1-6.6 (m, 6H, Cp-H); 2.7 (m, 2H, CH.sub.2); 1.9-0.8 (m, 6H, CH.sub.2); 1.3 (s, 6H, CH.sub.3); 1.2 (s, 6H, CH.sub.3).
摘要翻译：本发明涉及式I的过渡金属化合物，其中M1是元素周期表IIIb，IVb，Vb或VIb族的过渡金属，Y相同或不同，各自为氢原子，OH 基团，卤素原子，含C1-C40烃基或NR152基团，其中R15是卤素原子，C1-C10烷基或C6-C10-芳基，k是对应于过渡金属原子M1的价数减去2，如果Y是丁二烯单元，则k是1，R1，R2，R3，R7，R8和R9相同或不同，分别为氢原子，卤原子，含C1-C40烃基的基团，-SiR153，-NR152，-SiOR153，-SiSR153或-PR152基团，其中R15是卤素原子，C1-C10-烷基或C6-C10-芳基，或两个或更多个相邻基团R 1，R 2和R 3或R 7，R 8和R 9与连接它们的原子一起形成环系，1 H-NMR（200MHz，CD 2 Cl 2）：7.4-7.2（m，10H，Ph-H）; 7.1-6.6（m，6H，Cp-H）; 2.7（m，2H，CH 2）; 1.9-0.8（m，6H，CH2）; 1.3（s，6H，CH 3）; 1.2（s，6H，CH 3）。

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