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1. 发明授权

US06538158B2 Process for preparing 1,4-diaminonaphthalene and/or 1,5-diaminoNaphthalene 有权
标题翻译：制备1,4-二氨基萘和/或1,5-二氨基萘的方法
公开(公告)号：US06538158B2
公开(公告)日：2003-03-25
申请号：US10138542
申请日：2002-05-03
申请人： Joachim Zechlin , Lothar Duda , Gerhard Wegener , Andreas Hoffmann , Bodo Temme
发明人： Joachim Zechlin , Lothar Duda , Gerhard Wegener , Andreas Hoffmann , Bodo Temme
IPC分类号： C07C20900
CPC分类号： C07C17/12 , C07C17/395 , C07C209/10 , C07C263/10 , C07C25/22 , C07C265/14 , C07C211/58
摘要： 1,4-diaminonaphthalene and/or 1,5-diaminonaphthalene are produced by (a) reacting naphthalene with a halogen, (b) optionally, separating 1,4-dihalogen naphthalene or 1,5-dihalogen naphthalene from the mixture from step (a), and (c) reacting the mixture from step (a) or the 1,4-dihalogen naphthalene or the 1,5-dihalogen naphthalene from step (b) with ammonia and/or an organic amine in the presence of a catalyst.
摘要翻译：通过（a）使萘与卤素反应制备1,4-二氨基萘和/或1,5-二氨基萘，（b）任选地，从步骤（a）的混合物中分离出1,4-二卤代萘或1,5-二卤代萘， a），和（c）使来自步骤（b）的步骤（a）或1,4-二卤代萘或来自步骤（b）的1,5-二卤代萘的混合物与氨和/或有机胺在催化剂存在下反应。

2. 发明授权

US06218489B1 Polymerization process using a monocyclopentadienyl compound as a catalyst component 失效
标题翻译：使用单环戊二烯基化合物作为催化剂组分的聚合方法
公开(公告)号：US06218489B1
公开(公告)日：2001-04-17
申请号：US09238992
申请日：1999-01-28
申请人： Michael Riedel , Gerhard Erker , Lothar Duda
发明人： Michael Riedel , Gerhard Erker , Lothar Duda
IPC分类号： C08F444
CPC分类号： C07F17/00 , C08F4/61916 , C08F4/6192 , C08F10/00 , Y10S526/943
摘要： The present invention relates to a process to prepare an olefin using a transition metal compound of the formula I as a catalyst component where M1 is a metal of group IIIb, IVb or Vb of the Periodic Table of the Elements, R1, R2, R3 and R4 are identical or different and are each a hydrogen atom or a substituent, R5 are identical or different and are a substituent, Y are identical or different and are each a hydrogen atom, a C1-C40-hydrocarbon-containing group, an OH group, a halogen atom or an NR52 group, where R5 are identical or different and are each a halogen atom, a C1-C10-alkyl group or a C6-C10-aryl group, k is an integer which corresponds to the valence of the transition metal atom M1 minus two and if Y is a butadiene unit, k is 1, A is a bridge. R8 is a hydrogen atom, a halogen atom, a C1-C40-group, an —SiR53, —NR52, —Si(OR5)3, —Si(SR53 or —PR52 radical, where R5 are identical or different and are each a halogen atom, a C1-C10-alkyl group or a C6-C10-alkyl group or a C6-C10-aryl group, and X is an element of group Va or VIa of the Periodic Table of the Elements, where if X is an element of group Va, X bears a radical R9 which is a hydrogen atom, a halogen atom, a Cx-C40-group, an —SiR53, —NR52, —Si(OR5)3, —Si(SR5)3 or —PR52 radical, where R5 are identical or different and are each a halogen atom, a C1-C10-alkyl group or a C6-C10-aryl group.
摘要翻译：本发明涉及使用式I的过渡金属化合物作为催化剂组分制备烯烃的方法，其中M1是元素周期表IIIb，IVb或Vb族的金属，R1，R2，R3和R4 相同或不同，分别为氢原子或取代基，R5相同或不同，为取代基，Y相同或不同，为氢原子，含C1-C40烃基，OH基，卤素原子或NR52基团，其中R5相同或不同，并且各自为卤素原子，C1-C10烷基或C6-C10-芳基，k为对应于过渡金属化合价的整数原子M1减2，如果Y是丁二烯单元，则k是1，A是桥.R 8是氢原子，卤原子，C 1 -C 40基，-SiR 53，-NR 52，-Si（OR 5） 3，-Si（SR53或-PR52基团，其中R5相同或不同，各自为卤素原子，C1-C10烷基或C6-C10-烷基或C6-C10-芳基）并且X是元素周期表的Va或VIa族的元素，其中如果X是Va族的元素，X具有作为氢原子的基团R 9，卤素原子，C x -C 40 - 基团，-SiR 53，-NR 52，-Si（OR 5）3，-Si（SR 5）3或-PR 52基团，其中R 5相同或不同，各自为卤素原子，C1-C10-烷基或C6- C10-芳基。

3. 发明授权

US6090739A Transition metal compound 失效
标题翻译：过渡金属化合物
公开(公告)号：US6090739A
公开(公告)日：2000-07-18
申请号：US877832
申请日：1997-06-18
申请人： Michael Riedel , Gerhard Erker , Lothar Duda
发明人： Michael Riedel , Gerhard Erker , Lothar Duda
IPC分类号： C07F7/00 , C07F7/28 , C07F17/00 , C08F4/02 , C08F4/619 , C08F4/6192 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , B01J31/00
CPC分类号： C07F17/00 , C08F10/00 , C08F4/61916 , C08F4/6192 , Y10S526/943
摘要： The present invention relates to a transition metal compound of the formula I ##STR1## where M.sup.1 is a metal of group IIIb, IVb or Vb of the Periodic Table of the Elements,R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are identical or different and are each a hydrogen atom, a halogen atom, a C.sub.1 -C.sub.40 -hydrocarbon-containing group, an --SiR.sup.5.sub.3, --NR.sup.5.sub.2, --Si(OR.sup.5).sub.3, --Si(SR.sup.5).sub.3 or --PR.sup.5.sub.2 radical, where R.sup.5 are identical or different and are each a halogen atom, a C.sub.1 -C.sub.10 -alkyl group or a C.sub.6 -C.sub.10 -aryl group, or two or more radicals R.sup.1, R.sup.2, R.sup.3 or R.sup.4 together with the atoms connecting them form a ring system,Y are identical or different and are each a hydrogen atom, a C.sub.1 -C.sub.40 -hydrocarbon-containing group, an OH group, a halogen atom or an NR.sup.5.sub.2 group,k is an integer which corresponds to the valence of the transition metal atom M.sup.1 minus two and if Y is a butadiene unit, k is 1,A is a bridge,R.sup.8 is a hydrogen atom, a halogen atom, a C.sub.1 -C.sub.40 -group, an --SiR.sup.5.sub.3, --NR.sup.5.sub.2, --Si(OR.sup.5).sub.3, --Si(SR.sup.5).sub.3 or --PR.sup.5.sub.2 radical, and X is an element of group Va or Vla of the Periodic Table of the Elements.The transition metal compound is suitable as a catalyst component for olefin polymerization.
摘要翻译：本发明涉及式I的过渡金属化合物，其中M1是元素周期表Ⅲb族，Ⅳb族或Ⅴb族金属，R1，R2，R3和R4相同或不同，各自为氢原子，卤素原子，含C 1 -C 40烃的基团，-SiR 53，-NR 52，-Si（OR 5）3，-Si（SR 5）3或-PR 52基团，其中R 5相同或不同，各自为卤素原子，C 1 -C 10 - 烷基或C 6 -C 10 - 芳基，或两个或更多个基团R 1，R 2，R 3或R 4与连接它们的原子一起形成环系，Y相同或不同，各自相同或不同氢原子，含C1-C40烃基，OH基，卤素原子或NR52基团，k为对应于过渡金属原子M1的化合价减去2的整数，如果Y为丁二烯单元，k为1，A为桥，R8为氢原子，卤素原子，C1-C40基，-SiR53，-NR52，-Si（OR5）3，-Si（SR5）3或-PR52 激进，X是Va或Vla o的元素元素周期表。过渡金属化合物适合用作烯烃聚合的催化剂组分。

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