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1. 发明授权

US06559197B2 Optical fiber coating 有权
标题翻译：光纤涂层
公开(公告)号：US06559197B2
公开(公告)日：2003-05-06
申请号：US09819300
申请日：2001-03-28
申请人： Edward J. Fewkes , Gregory F. Jacobs , Michael J. Winningham
发明人： Edward J. Fewkes , Gregory F. Jacobs , Michael J. Winningham
IPC分类号： C08F242
CPC分类号： C03C17/30 , C03C25/106 , C03C25/1065 , C03C25/25 , C03C25/40 , G02B6/02395 , Y10T428/2938 , Y10T428/2956 , Y10T428/2962 , Y10T428/2967
摘要： The invention disclosed includes a coating composition for siliceous surfaces. The coating includes at least one component from the group consisting of poly(alkoxy)silane, poly(halo)silane, alkoxysilane, halosilane, and mixtures thereof and a catalyst compound which generates a proton to hydrolyze the component when exposed to radiation. Preferably, the catalyst is a photo-acid. The invention also includes a method of coating the optical fiber. The aforementioned coating is applied to an exterior surface of the fiber. A proton is generated to promote the hydrolysis of the component. The invention further includes a method of accelerating adhesion between the exterior surface of the article and the coating. The inventive coating is applied to the surface of the fiber and the coating is exposed to a radiation source.
摘要翻译：公开的发明包括用于硅质表面的涂料组合物。该涂层包括至少一种由聚（烷氧基）硅烷，聚（卤代）硅烷，烷氧基硅烷，卤代硅烷及其混合物组成的组分，以及当暴露于辐射时产生质子水解该组分的催化剂化合物。优选地，催化剂是光酸。本发明还包括涂覆光纤的方法。将上述涂层施加到纤维的外表面。产生质子以促进组分的水解。本发明还包括加速制品的外表面和涂层之间的粘附的方法。将本发明的涂层施加到纤维的表面，并将涂层暴露于辐射源。

2. 发明授权

US06326416B1 Coating composition for optical fibers 失效
标题翻译：光纤用涂料组合物
公开(公告)号：US06326416B1
公开(公告)日：2001-12-04
申请号：US09476151
申请日：1999-12-30
申请人： Ching-Kee Chien , Edward J. Fewkes , Gregory F. Jacobs , Kenneth R. Jones , Eric H. Urruti , Michael J. Winningham
发明人： Ching-Kee Chien , Edward J. Fewkes , Gregory F. Jacobs , Kenneth R. Jones , Eric H. Urruti , Michael J. Winningham
IPC分类号： C08F248
CPC分类号： C09D4/06 , C03C25/106 , Y10T428/2938 , C08F290/14 , C08F290/128 , C08F290/147
摘要： The present invention relates to a composition for coating optical fibers which contains an oligomer capable of being polymerized, a monomer suitable to control the viscosity of the composition, and an adhesion promoter which includes a compound containing a cyclic structure interposed between at least two reactive silanes which are independently an alkoxysilane or a halosilane. Another composition of the present invention includes an oligomer capable of being polymerized, a monomer suitable to control the viscosity of the composition, an adhesion promoter which includes a compound containing a reactive silane group, and a carrier. The present invention also relates to optical fibers and methods of making such optical fibers using the compositions of the present invention.
摘要翻译：本发明涉及一种包含可聚合的低聚物的光纤组合物，适用于控制组合物粘度的单体，以及一种粘合促进剂，其包括插入在至少两个反应性硅烷之间的包含环状结构的化合物它们独立地是烷氧基硅烷或卤代硅烷。本发明的另一种组合物包括能够聚合的低聚物，适用于控制组合物粘度的单体，包含含有活性硅烷基团的化合物和载体的粘合促进剂。本发明还涉及使用本发明组合物制造这种光纤的光纤和方法。

3. 发明授权

US07221842B2 Coated optical fiber and optical fiber coating system including a fast-gelling primary coating 有权
标题翻译：包覆光纤和光纤涂层系统，包括快速胶凝初级涂层
公开(公告)号：US07221842B2
公开(公告)日：2007-05-22
申请号：US11368205
申请日：2006-03-02
申请人： Linda S. Baker , Kevin R. McCarthy , Michael J. Winningham , Lung-Ming Wu
发明人： Linda S. Baker , Kevin R. McCarthy , Michael J. Winningham , Lung-Ming Wu
IPC分类号： G02B6/02 , G02B1/10 , B05D5/06 , C03C17/00 , B29D11/00
CPC分类号： C03C25/106 , C03C25/1065 , C09D133/14 , G02B6/02395
摘要： The present invention provides optical fiber coating systems and coated optical fibers. According to one embodiment of the invention, a coated optical fiber includes an optical fiber having a core and a cladding; and a primary coating encapsulating the optical fiber, the primary coating having a Young's modulus of about 5 MPa or less, the primary coating being the cured reaction product of a primary curable composition having a gel time less than about 1.4 seconds at a UV intensity of 3.4 mW/cm2.
摘要翻译：本发明提供了光纤涂层系统和涂覆光纤。根据本发明的一个实施例，涂覆光纤包括具有芯和包层的光纤; 以及包封所述光纤的初级涂层，所述初级涂层的杨氏模量为约5MPa或更低，所述初级涂层是在UV强度下具有凝胶时间小于约1.4秒的主要可固化组合物的固化反应产物 3.4mW / cm 2。

4. 发明授权

US07010205B2 Coated optical fiber and optical fiber coating system including a hydrophilic primary coating 有权
标题翻译：包覆光纤和光纤涂层系统，包括亲水性初级涂层
公开(公告)号：US07010205B2
公开(公告)日：2006-03-07
申请号：US10675720
申请日：2003-09-29
申请人： Michelle D. Fabian , Kevin R. McCarthy , Michael J. Winningham
发明人： Michelle D. Fabian , Kevin R. McCarthy , Michael J. Winningham
IPC分类号： G02B6/02 , G02B6/16 , G02B6/22
CPC分类号： C03C25/1065 , G02B6/02395
摘要： The present invention provides optical fiber coating systems and coated optical fibers having hydrophilic primary coatings. According to one embodiment of the invention, a coated optical fiber includes an optical fiber having a core and a cladding; a hydrophilic primary coating encapsulating the optical fiber, the primary coating having a Young's modulus less than about 2 MPa; and a secondary coating encapsulating the primary coating, wherein the primary coating exhibits substantially no water bubble formation and substantially no delamination when the coated optical fiber is soaked in water at 23° C. for 30 days.
摘要翻译：本发明提供了具有亲水性初级涂层的光纤涂层系统和涂覆光纤。根据本发明的一个实施例，涂覆光纤包括具有芯和包层的光纤; 包封光纤的亲水性初级涂层，初级涂层的杨氏模量小于约2MPa; 以及包封初级涂层的二次涂层，其中当涂布的光纤在23℃的水中浸泡30天时，初级涂层基本上不显示水泡形成，并且基本上不脱层。

5. 发明授权

US06775451B1 Secondary coating composition for optical fibers 有权
标题翻译：光纤二次涂料组合物
公开(公告)号：US06775451B1
公开(公告)日：2004-08-10
申请号：US09722895
申请日：2000-11-27
申请人： John W. Botelho , Gregory F. Jacobs , Huan-Hung Sheng , Michael J. Winningham
发明人： John W. Botelho , Gregory F. Jacobs , Huan-Hung Sheng , Michael J. Winningham
IPC分类号： G02B602
CPC分类号： C09D4/00 , C03C25/106 , G02B6/02014 , G02B6/02285 , G02B6/02395 , C08F222/20
摘要： The present invention relates to a composition for coating optical fibers that includes an oligomeric component present in an amount of about 15 weight percent or less and a monomeric component present in an amount of about 75 weight percent or more, where the cured product of the composition has a Young's modulus of at least about 650 MPa. When the composition is substantially devoid of the oligomeric component, the monomeric component preferably includes two or more monomers. Also disclosed are the cured products of the compositions of the present invention, optical fibers that contain secondary coatings prepared from the compositions of the present invention, methods of making such optical fibers, as well as fiber optic ribbons containing a matrix prepared from the compositions of the present invention. The invention further relates to a composition for coating optical fibers that includes an oligomeric component present in an amount of more than about 15 weight percent and a monomeric component present in an amount of less than about 82 weight percent, where the cured product of the composition has a Young's modulus of at least about 900 MPa.
摘要翻译：本发明涉及用于涂覆光纤的组合物，其包含以约15重量％或更少的量存在的低聚组分和存在量为约75重量％或更多的单体组分，其中组合物的固化产物具有至少约650MPa的杨氏模量。当组合物基本上不含低聚组分时，单体组分优选包括两种或更多种单体。还公开了本发明组合物的固化产物，含有由本发明组合物制备的二次涂层的光纤，制备这种光纤的方法，以及含有由以下组合物制备的基质的光纤带：本发明。本发明还涉及用于涂覆光纤的组合物，其包含以大于约15重量％的量存在的低聚组分和以小于约82重量％的量存在的单体组分，其中组合物的固化产物具有至少约900MPa的杨氏模量。

6. 发明授权

US06563996B1 Optical fibers prepared with a primary coating composition including a monomer with a pendant hydroxyl functional group 有权
标题翻译：用包含具有侧羟基官能团的单体的初级涂料组合物制备的光纤
公开(公告)号：US06563996B1
公开(公告)日：2003-05-13
申请号：US09712565
申请日：2000-11-14
申请人： Michael J. Winningham
发明人： Michael J. Winningham
IPC分类号： G02B602
CPC分类号： C09D4/00 , C03C25/106 , C03C25/1065 , C09D4/06 , C08F220/28 , C08F222/20 , C08F290/067
摘要： The present invention relates to an optical fiber including a glass fiber and a primary coating encapsulating and in contact with the glass fiber, the primary coating being the cured product of a polyrnerizable composition which includes a monomer with a pendant hydroxyl functional group which can bond with a surface of the optical fiber and is present in an amount effective to promote adhesion. The present invention also relates to methods of making such optical fibers.
摘要翻译：本发明涉及包含玻璃纤维和初级涂层的光纤，其包封并与玻璃纤维接触，初级涂层是可聚合组合物的固化产物，其包含具有侧基羟基官能团的单体，其可与光纤的表面并且以有效促进粘附的量存在。本发明还涉及制造这种光纤的方法。

7. 发明授权

US06531522B1 Fast curing primary optical fiber coating 失效
标题翻译：快速固化主光纤涂层
公开(公告)号：US06531522B1
公开(公告)日：2003-03-11
申请号：US09712603
申请日：2000-11-14
申请人： Michael J. Winningham
发明人： Michael J. Winningham
IPC分类号： C08F246
CPC分类号： C09D175/16 , C03C25/106 , C03C25/1065 , C09D4/00 , C09D4/06 , Y10T428/2938 , Y10T428/2942 , Y10T428/2967 , Y10T428/2987 , Y10T428/31551 , C08F220/32 , C08F222/20 , C08F290/147
摘要： The present invention relates to a coating for an optical fiber. The coating includes a monomer. The monomer includes an oxyglycidyl (meth)acrylate component. A coating with the monomeric component has exhibited an excellent polymerization rate. The present invention also relates to methods of making such optical fibers coated in accordance with the invention and the coated glass article.
摘要翻译：本发明涉及一种光纤用涂层。涂层包括单体。单体包括（甲基）丙烯酸羟基缩水甘油酯组分。具有单体组分的涂层具有优异的聚合速率。本发明还涉及制造根据本发明涂覆的这种光纤和涂覆的玻璃制品的方法。

8. 发明授权

US07239785B2 Method of preventing optical fiber failure in high power application 有权
标题翻译：防止高功率应用中的光纤故障的方法
公开(公告)号：US07239785B2
公开(公告)日：2007-07-03
申请号：US11026458
申请日：2004-12-30
申请人： Steven E. DeMartino , Michael E. DeRosa , Gregory S. Glaesemann , Stephan L. Logunov , Ulrich W. H. Neukirch , Michael J. Winningham
发明人： Steven E. DeMartino , Michael E. DeRosa , Gregory S. Glaesemann , Stephan L. Logunov , Ulrich W. H. Neukirch , Michael J. Winningham
IPC分类号： G02B6/02 , G02B6/036
CPC分类号： C03C25/106 , C03C25/1065 , G02B6/02395 , G02B6/03633 , G02B6/03694
摘要： A method of minimizing localized heating of, or minimizing signal losses across a source of loss in, an optical fiber used in transmission of a high power optical signal at an operating wavelength. These methods include the steps of: providing an optical fiber which comprises either (i) a coating characterized by an absorbance of less than about 4.5 dB/cm at the operating wavelength or (ii) a refractive index lower than the refractive index of a cladding layer of the optical fiber by more than about 3×10−3 at the operating wavelength, or (iii) both (i) and (ii); and transmitting a optical signal having a power greater than about 250 mW through the optical fiber, wherein the coating, cladding layer, or combination thereof are selected to minimize localized heating of the optical fiber or to result in a signal loss across a source of loss that is less than about 250 mW at the operating wavelength.
摘要翻译：一种使在工作波长的高功率光信号传输中使用的光纤中的损耗源的局部加热的局部加热或减少信号损失最小化的方法。这些方法包括以下步骤：提供光纤，其包括（i）在工作波长处的吸光度小于约4.5dB / cm的涂层，或（ii）低于包层的折射率的折射率（iii）（i）和（ii）两者之间的光纤层超过约3×10 -3 -3。并且通过光纤传输具有大于约250mW的功率的光信号，其中选择涂层，包层或其组合以使光纤的局部加热最小化或导致跨越损耗源的信号损失在工作波长处小于约250mW。

9. 发明授权

US07050688B2 Fiber optic articles, assemblies, and cables having optical waveguides 有权
标题翻译：具有光波导的光纤制品，组件和电缆
公开(公告)号：US07050688B2
公开(公告)日：2006-05-23
申请号：US10623219
申请日：2003-07-18
申请人： Gregory A. Lochkovic , Sheila A. Cooper , Leigh R. Josey , James A. Register, III , Larry W. Self , Edward J. Fewkes , Michael J. Winningham , Huan-Hung Sheng , Michelle D. Fabian
发明人： Gregory A. Lochkovic , Sheila A. Cooper , Leigh R. Josey , James A. Register, III , Larry W. Self , Edward J. Fewkes , Michael J. Winningham , Huan-Hung Sheng , Michelle D. Fabian
IPC分类号： G02B6/44
CPC分类号： G02B6/4433 , G02B6/4402 , G02B6/4404 , G02B6/441 , G02B6/4422 , G02B6/4482
摘要： Fiber optic articles, assemblies, and cables preserve optical performance by using optical waveguides having a core, a cladding, and a coating system according to the present invention. Moreover, the optical articles, assemblies, and cables of the present invention may achieve performance levels that were previously unattainable, for instance, the present invention contemplates acceptable optical performance for wavelengths such as 1625 nm and higher. Additionally, articles, assemblies, and/or cables of the present invention advantageously preserve optical performance, i.e., have relatively low delta attenuation, when subjected to manufacturing processes and/or environmental conditions such as temperature cycling. In other words, the articles, assemblies, and cables can withstand increased stress/strain before having significant attenuation.
摘要翻译：光纤制品，组件和电缆通过使用根据本发明的具有芯，包层和涂层系统的光波导来保持光学性能。此外，本发明的光学制品，组件和电缆可以实现以前不可实现的性能水平，例如，本发明考虑了对于诸如1625nm和更高的波长的可接受的光学性能。另外，当经受制造工艺和/或诸如温度循环的环境条件时，本发明的制品，组件和/或电缆有利地保持光学性能，即具有相对低的Δ衰减。换句话说，物品，组件和电缆可以在有明显的衰减之前承受增加的应力/应变。

10. 发明授权

US07010206B1 Coated optical fiber and optical fiber coating system including a fast-gelling primary coating 有权
公开(公告)号：US07010206B1
公开(公告)日：2006-03-07
申请号：US10937069
申请日：2004-09-08
申请人： Linda S. Baker , Kevin R. McCarthy , Michael J. Winningham , Lung-Ming Wu
发明人： Linda S. Baker , Kevin R. McCarthy , Michael J. Winningham , Lung-Ming Wu
IPC分类号： G00B6/02 , B05D5/06 , C03C17/00 , G02B1/10
CPC分类号： C03C25/106 , C03C25/1065 , C09D133/14 , G02B6/02395
摘要： The present invention provides optical fiber coating systems and coated optical fibers. According to one embodiment of the invention, a coated optical fiber includes an optical fiber having a core and a cladding; and a primary coating encapsulating the optical fiber, the primary coating having a Young's modulus of about 5 MPa or less, the primary coating being the cured reaction product of a primary curable composition having a gel time less than about 1.4 seconds at a UV intensity of 3.4 mW/cm2.

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