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1. 发明授权

US07050688B2 Fiber optic articles, assemblies, and cables having optical waveguides 有权
标题翻译：具有光波导的光纤制品，组件和电缆
公开(公告)号：US07050688B2
公开(公告)日：2006-05-23
申请号：US10623219
申请日：2003-07-18
申请人： Gregory A. Lochkovic , Sheila A. Cooper , Leigh R. Josey , James A. Register, III , Larry W. Self , Edward J. Fewkes , Michael J. Winningham , Huan-Hung Sheng , Michelle D. Fabian
发明人： Gregory A. Lochkovic , Sheila A. Cooper , Leigh R. Josey , James A. Register, III , Larry W. Self , Edward J. Fewkes , Michael J. Winningham , Huan-Hung Sheng , Michelle D. Fabian
IPC分类号： G02B6/44
CPC分类号： G02B6/4433 , G02B6/4402 , G02B6/4404 , G02B6/441 , G02B6/4422 , G02B6/4482
摘要： Fiber optic articles, assemblies, and cables preserve optical performance by using optical waveguides having a core, a cladding, and a coating system according to the present invention. Moreover, the optical articles, assemblies, and cables of the present invention may achieve performance levels that were previously unattainable, for instance, the present invention contemplates acceptable optical performance for wavelengths such as 1625 nm and higher. Additionally, articles, assemblies, and/or cables of the present invention advantageously preserve optical performance, i.e., have relatively low delta attenuation, when subjected to manufacturing processes and/or environmental conditions such as temperature cycling. In other words, the articles, assemblies, and cables can withstand increased stress/strain before having significant attenuation.
摘要翻译：光纤制品，组件和电缆通过使用根据本发明的具有芯，包层和涂层系统的光波导来保持光学性能。此外，本发明的光学制品，组件和电缆可以实现以前不可实现的性能水平，例如，本发明考虑了对于诸如1625nm和更高的波长的可接受的光学性能。另外，当经受制造工艺和/或诸如温度循环的环境条件时，本发明的制品，组件和/或电缆有利地保持光学性能，即具有相对低的Δ衰减。换句话说，物品，组件和电缆可以在有明显的衰减之前承受增加的应力/应变。

2. 发明授权

US06539152B1 Composition containing tackifier and method of modifying time-sensitive rheological properties of optical fiber coating 失效
标题翻译：含有增粘剂的组合物和改善光纤涂层的时间敏感流变性能的方法
公开(公告)号：US06539152B1
公开(公告)日：2003-03-25
申请号：US09747044
申请日：2000-12-21
申请人： Edward J. Fewkes , Gregory F. Jacobs , Kenneth R. Jones , Huan-Hung Sheng , Frederic C. Wagner , Michael J. Winningham
发明人： Edward J. Fewkes , Gregory F. Jacobs , Kenneth R. Jones , Huan-Hung Sheng , Frederic C. Wagner , Michael J. Winningham
IPC分类号： G02B600
CPC分类号： C09D4/00 , C03C25/106 , C03C25/1065 , C09D4/06 , Y10T428/2938 , C08F290/067
摘要： The present invention relates to a composition for preparing optical fiber coatings, the composition including a polymerizable base composition, containing at least one monomer and optionally at least one oligomer, wherein the polymerizable base composition is substantially free of unsaturated epoxidized diene polymers, and a tackifier present in an amount effective to modify a time-sensitive rheological property of a polymerization product of the composition. Another aspect of the present invention relates to a method of modifying a time-sensitive rheological property of an optical fiber coating by introducing into a polymerizable composition a tackifier in an amount effective to modify a time-sensitive rheological property of the polymerization product of the polymerizable composition. Also disclosed are an optical fiber, a fiber optic ribbon, and a fiber bundle that contain coating(s) prepared from a composition of the present invention.
摘要翻译：本发明涉及一种用于制备光纤涂层的组合物，该组合物包括含有至少一种单体和任选的至少一种低聚物的可聚合基础组合物，其中可聚合基础组合物基本上不含不饱和环氧化二烯聚合物，和增粘剂以有效地改变组合物的聚合产物的时间敏感性流变性的量存在。本发明的另一方面涉及一种通过向可聚合组合物中引入增粘剂以有效改变可聚合的聚合物的聚合产物的时间敏感性流变性的方法来改变光纤涂层的时间敏感性流变学性能的方法组成。还公开了包含由本发明的组合物制备的涂层的光纤，光纤带和纤维束。

3. 发明授权

US06584263B2 Optical fiber coating compositions and coated optical fibers 有权
标题翻译：光纤涂层组合物和涂覆光纤
公开(公告)号：US06584263B2
公开(公告)日：2003-06-24
申请号：US10024271
申请日：2001-12-17
申请人： Edward J. Fewkes , Inna I. Kouzmina , Huan-Hung Sheng
发明人： Edward J. Fewkes , Inna I. Kouzmina , Huan-Hung Sheng
IPC分类号： G02B602
CPC分类号： C03C25/106 , G02B6/02014 , G02B6/02285 , G02B6/02395 , G02B6/4403
摘要： One aspect of the present invention relates to an optical fiber coating compositions having, when cured, a Young's modulus of greater than about 950 MPa and a film to film coefficient of friction of less than about 0.44. Another aspect of the present invention relates to an coated optical fiber having a coating having a modulus of greater than about 950 MPa and a fiber to fiber coefficient of friction of less than about 0.74 measured at a speed of about 0.423 cm/sec and with a weight of about 100 grams. The coatings may include additives such as surfactants, surface agents, slip additives, waxes, and micronized polytetrafluoroethylene. The coated optical fibers of the present invention can be freely and smoothly wound on a spool without the formation of fiber loops, crossovers, or other defects.
摘要翻译：本发明的一个方面涉及一种光纤涂层组合物，其在固化时具有大于约950MPa的杨氏模量和小于约0.44的膜与膜摩擦系数。本发明的另一方面涉及具有大于约950MPa的模量的涂层和约0.423cm /秒的速度测量的纤维与纤维摩擦系数小于约0.74的涂覆光纤，并且具有重量约100克。涂层可以包括添加剂，例如表面活性剂，表面剂，滑爽添加剂，蜡和微粉化的聚四氟乙烯。本发明的涂覆光纤可以自由而平滑地卷绕在卷轴上，而不会形成纤维环，交叉或其他缺陷。

4. 发明授权

US06869981B2 Optical fiber coatings with pressure sensitive adhesive characteristics 失效
标题翻译：光纤涂层具有压敏胶特性
公开(公告)号：US06869981B2
公开(公告)日：2005-03-22
申请号：US10087481
申请日：2002-03-01
申请人： Edward J. Fewkes , Gregory F. Jacobs , Inna I. Kouzmina , Kevin R. McCarthy , Huan-Hung Sheng , Kristi L. Simonton
发明人： Edward J. Fewkes , Gregory F. Jacobs , Inna I. Kouzmina , Kevin R. McCarthy , Huan-Hung Sheng , Kristi L. Simonton
IPC分类号： G02B6/44 , C03C25/10 , C09D4/00 , C09D5/00 , C09D153/02 , C09D157/02 , C09D175/04 , C09D193/04 , C09D201/00 , C08F2/46
CPC分类号： C03C25/106 , Y10T428/2938 , Y10T428/2942 , Y10T428/2947
摘要： The invention includes an optical fiber coating that exhibits the characteristics of a pressure sensitive adhesive. A viscoelastic window for the coating will include at least one set of coordinates that is within Quadrants 2, 3, or 4 or the Transition Flow Region of the Chang viscoelastic of the rheological master curves or will not include at least one set of coordinates that is not within Quadrant 1 of the Chang viscoelastic of the rheological master curves.
摘要翻译：本发明包括具有压敏粘合剂特性的光纤涂层。用于涂层的粘弹窗将包括位于象限2,3或4内的至少一组坐标或流变主曲线的Chang粘弹性的过渡流动区域，或将不包括至少一组坐标不是在流体主曲线的Chang粘弹的象限1内。

5. 发明授权

US06810187B2 Optical waveguide thermoplastic elastomer coating 失效
标题翻译：光波导热塑性弹性体涂层
公开(公告)号：US06810187B2
公开(公告)日：2004-10-26
申请号：US09917459
申请日：2001-07-27
申请人： Michelle D. Fabian , Edward J. Fewkes , Gregory F. Jacobs , Frederic C. Wagner , Inna I. Kouzmina , Michael L. Sorensen
发明人： Michelle D. Fabian , Edward J. Fewkes , Gregory F. Jacobs , Frederic C. Wagner , Inna I. Kouzmina , Michael L. Sorensen
IPC分类号： G02B602
CPC分类号： C09D4/00 , C03C25/106 , C03C25/1065 , C09D4/06 , C08F220/00 , C08F287/00
摘要： A coated optical fiber and a curable coating composition for coating an optical fiber, includes a block copolymer comprising at least one hard block and at least one soft block, wherein said hard block has a Tg greater than the Tg of the soft block. The coating may further include at least one reactive monomer. A method for making a coated optical fiber, includes providing an optical fiber; coating the optical fiber with a polymerizable composition including a block copolymer comprising at least one hard block and at least one soft block, wherein said hard block has a Tg greater than the Tg of the soft block. The coating may further include at least one reactive monomer. The method further includes polymerizing the composition under conditions effective to form a coating over the optical fiber.
摘要翻译：涂覆光纤和用于涂覆光纤的可固化涂料组合物包括包含至少一个硬嵌段和至少一个软嵌段的嵌段共聚物，其中所述硬嵌段的Tg大于软嵌段的Tg。该涂层可进一步包括至少一种反应性单体。一种制造涂覆光纤的方法，包括提供光纤; 用包括至少一个硬块和至少一个软嵌段的嵌段共聚物的可聚合组合物涂覆光纤，其中所述硬块的Tg大于软嵌段的Tg。该涂层可进一步包括至少一种反应性单体。该方法还包括在有效地在光纤上形成涂层的条件下聚合该组合物。

6. 发明授权

US07207732B2 Coated optical fiber and curable compositions suitable for coating optical fiber 有权
标题翻译：适用于涂覆光纤的涂层光纤和可固化组合物
公开(公告)号：US07207732B2
公开(公告)日：2007-04-24
申请号：US11027861
申请日：2004-12-30
申请人： Michelle D. Fabian , Edward J. Fewkes , Gregory S. Glaesemann
发明人： Michelle D. Fabian , Edward J. Fewkes , Gregory S. Glaesemann
IPC分类号： G02B6/22 , G02B6/036
CPC分类号： G02B6/2558 , C03C25/106 , C03C25/1065 , C03C25/12 , C08G18/672 , C08G18/758 , C08G18/7621 , C08G18/765 , G02B6/255 , C08G18/48 , C08G18/62
摘要： The present invention provides materials suitable for use as secondary coatings of optical fibers or the re-coating of spliced optical fiber junctions. With regard to the latter use, the coating materials a preferably characterized by a Young's modulus that is at least about 1200 MPa, and an interfacial strength as measured by the rod and tube method of greater than 25 MPa.
摘要翻译：本发明提供了适合用作光纤的二次涂层或接合的光纤接头的再涂层的材料。关于后一种用途，涂层材料a优选的特征在于杨氏模量为至少约1200MPa，并且通过棒和管法测量的界面强度大于25MPa。

7. 发明授权

US06559197B2 Optical fiber coating 有权
标题翻译：光纤涂层
公开(公告)号：US06559197B2
公开(公告)日：2003-05-06
申请号：US09819300
申请日：2001-03-28
申请人： Edward J. Fewkes , Gregory F. Jacobs , Michael J. Winningham
发明人： Edward J. Fewkes , Gregory F. Jacobs , Michael J. Winningham
IPC分类号： C08F242
CPC分类号： C03C17/30 , C03C25/106 , C03C25/1065 , C03C25/25 , C03C25/40 , G02B6/02395 , Y10T428/2938 , Y10T428/2956 , Y10T428/2962 , Y10T428/2967
摘要： The invention disclosed includes a coating composition for siliceous surfaces. The coating includes at least one component from the group consisting of poly(alkoxy)silane, poly(halo)silane, alkoxysilane, halosilane, and mixtures thereof and a catalyst compound which generates a proton to hydrolyze the component when exposed to radiation. Preferably, the catalyst is a photo-acid. The invention also includes a method of coating the optical fiber. The aforementioned coating is applied to an exterior surface of the fiber. A proton is generated to promote the hydrolysis of the component. The invention further includes a method of accelerating adhesion between the exterior surface of the article and the coating. The inventive coating is applied to the surface of the fiber and the coating is exposed to a radiation source.
摘要翻译：公开的发明包括用于硅质表面的涂料组合物。该涂层包括至少一种由聚（烷氧基）硅烷，聚（卤代）硅烷，烷氧基硅烷，卤代硅烷及其混合物组成的组分，以及当暴露于辐射时产生质子水解该组分的催化剂化合物。优选地，催化剂是光酸。本发明还包括涂覆光纤的方法。将上述涂层施加到纤维的外表面。产生质子以促进组分的水解。本发明还包括加速制品的外表面和涂层之间的粘附的方法。将本发明的涂层施加到纤维的表面，并将涂层暴露于辐射源。

8. 发明授权

US06326416B1 Coating composition for optical fibers 失效
标题翻译：光纤用涂料组合物
公开(公告)号：US06326416B1
公开(公告)日：2001-12-04
申请号：US09476151
申请日：1999-12-30
申请人： Ching-Kee Chien , Edward J. Fewkes , Gregory F. Jacobs , Kenneth R. Jones , Eric H. Urruti , Michael J. Winningham
发明人： Ching-Kee Chien , Edward J. Fewkes , Gregory F. Jacobs , Kenneth R. Jones , Eric H. Urruti , Michael J. Winningham
IPC分类号： C08F248
CPC分类号： C09D4/06 , C03C25/106 , Y10T428/2938 , C08F290/14 , C08F290/128 , C08F290/147
摘要： The present invention relates to a composition for coating optical fibers which contains an oligomer capable of being polymerized, a monomer suitable to control the viscosity of the composition, and an adhesion promoter which includes a compound containing a cyclic structure interposed between at least two reactive silanes which are independently an alkoxysilane or a halosilane. Another composition of the present invention includes an oligomer capable of being polymerized, a monomer suitable to control the viscosity of the composition, an adhesion promoter which includes a compound containing a reactive silane group, and a carrier. The present invention also relates to optical fibers and methods of making such optical fibers using the compositions of the present invention.
摘要翻译：本发明涉及一种包含可聚合的低聚物的光纤组合物，适用于控制组合物粘度的单体，以及一种粘合促进剂，其包括插入在至少两个反应性硅烷之间的包含环状结构的化合物它们独立地是烷氧基硅烷或卤代硅烷。本发明的另一种组合物包括能够聚合的低聚物，适用于控制组合物粘度的单体，包含含有活性硅烷基团的化合物和载体的粘合促进剂。本发明还涉及使用本发明组合物制造这种光纤的光纤和方法。

9. 发明授权

US06316516B1 Coating composition for optical fibers 失效
公开(公告)号：US06316516B1
公开(公告)日：2001-11-13
申请号：US09301814
申请日：1999-04-29
申请人： Ching Kee Chien , Edward J. Fewkes , Eric H. Urruti , Michael J. Winningham
发明人： Ching Kee Chien , Edward J. Fewkes , Eric H. Urruti , Michael J. Winningham
IPC分类号： C08F248
CPC分类号： C09D4/06 , C03C25/106 , Y10T428/2938 , C08F290/14 , C08F290/147 , C08F290/128
摘要： The present invention relates to a composition for coating optical fibers which contains an oligomer capable of being polymerized, a monomer suitable to control the viscosity of the composition, and an adhesion promoter which includes a compound containing a cyclic structure interposed between at least two reactive silanes which are independently an alkoxysilane or a halosilane. Another composition of the present invention includes an oligomer capable of being polymerized, a monomer suitable to control the viscosity of the composition, an adhesion promoter which includes a compound containing a reactive silane group, and a carrier. The present invention also relates to optical fibers and methods of making such optical fibers using the compositions of the present invention.

10. 发明授权

US06602601B2 Optical fiber coating compositions 有权
标题翻译：光纤涂层组合物
公开(公告)号：US06602601B2
公开(公告)日：2003-08-05
申请号：US09747480
申请日：2000-12-22
申请人： Edward J. Fewkes , Himanshu C. Shah , Frederic C. Wagner
发明人： Edward J. Fewkes , Himanshu C. Shah , Frederic C. Wagner
IPC分类号： C08F246
CPC分类号： C09D4/06 , C03C25/105 , C03C25/1065 , Y10T428/2938 , Y10T428/2942 , Y10T428/2947 , C08F290/14 , C08F290/064
摘要： The disclosed invention includes a composition for an optical fiber coating. The cured composition includes at least one monomer and at least one compound from the following group of compounds that consist of an ultra-violet light absorber, a hindered amine light stabilizer, and an optical brightener. The invention also includes an optical fiber coated with the inventive coating.
摘要翻译：所公开的发明包括用于光纤涂层的组合物。固化的组合物包括至少一种单体和至少一种由紫外光吸收剂，受阻胺光稳定剂和荧光增白剂组成的化合物组中的至少一种。本发明还包括涂覆有本发明涂层的光纤。

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