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1. 发明授权

US6068835A Cosmetic compositions for hair treatment containing dendrimers or dendrimer conjugates 失效
标题翻译：含有树枝状大分子或树枝状聚合物共轭物的头发处理化妆品组合物
公开(公告)号：US6068835A
公开(公告)日：2000-05-30
申请号：US883924
申请日：1997-06-27
申请人： Michael Franzke , Karin Steinbrecht , Thomas Clausen , Sabine Baecker , Jurgen Titze
发明人： Michael Franzke , Karin Steinbrecht , Thomas Clausen , Sabine Baecker , Jurgen Titze
IPC分类号： A61K8/00 , A61K8/44 , A61K8/46 , A61K8/72 , A61K8/73 , A61K8/81 , A61K8/86 , A61K8/97 , A61Q5/00 , A61Q5/02 , A61Q5/04 , A61Q5/06 , A61Q5/10 , A61Q5/12 , A61Q7/00 , A61K7/11
CPC分类号： A61Q5/12 , A61K8/44 , A61K8/46 , A61K8/731 , A61K8/736 , A61K8/8111 , A61K8/8152 , A61K8/8158 , A61K8/8176 , A61K8/8182 , A61K8/86 , A61K8/97 , A61Q5/00 , A61Q5/006 , A61Q5/02 , A61Q5/04 , A61Q5/06 , A61K2800/54 , A61K2800/57 , F02D2200/0606 , Y10S424/01 , Y10S424/16
摘要： The hair treatment compositions are in a variety of forms including permanent shaping compositions, oxidative after-treatment compositions, hair fixing compositions, hair bleaching compositions, hair cleansing compositions, hair care compositions or hair dye compositions containing direct-dyeing dye compounds and/or a combination of at least one developer and coupler and are characterized by 0.1 to 35 percent by weight of at least one dendrimer, preferably a poly(iminopropane-1,3-diyl)-dendrimer with nitrile and/or amino end groups. Methods of hair treatment based on these hair treatment compositions are described.
摘要翻译：头发处理组合物是各种形式，包括永久成形组合物，氧化后处理组合物，头发定影组合物，毛发漂白组合物，毛发清洁组合物，护发组合物或含有直接染色染料化合物的染发剂组合物和/或至少一种显影剂和成色剂的组合，其特征在于0.1至35重量％的至少一种树枝状聚合物，优选具有腈和/或氨基端基的聚（亚氨基丙烷-1,3-二基） - 缔结聚合物。描述了基于这些头发处理组合物的头发处理方法。

2. 发明授权

US5512276A Composition for fixing hair based on lignin or lignin derivatives as well as dihydroxypropyl lignin 失效
标题翻译：用于固定基于木质素或木质素衍生物以及二羟丙基木质素的毛发的组合物
公开(公告)号：US5512276A
公开(公告)日：1996-04-30
申请号：US211797
申请日：1994-04-18
申请人： Gunther Lang , Thomas Clausen , Hans-Jugen Titze , Karin Steinbrecht , Wolfgang Keil
发明人： Gunther Lang , Thomas Clausen , Hans-Jugen Titze , Karin Steinbrecht , Wolfgang Keil
IPC分类号： A61K8/00 , A61K8/34 , A61K8/72 , A61K8/97 , A61Q5/00 , A61Q5/06 , A61Q5/10 , C08H99/00 , C08L1/28 , C08L5/08 , C08L31/04 , C08L35/08 , C08L39/06 , C08L97/00 , A61K7/11
CPC分类号： C08H6/00 , A61K8/72 , A61K8/97 , A61Q5/06 , C08L97/005 , C08L1/284 , C08L31/04 , C08L35/08 , C08L39/06 , C08L5/08 , Y10S514/944
摘要： The aqueous, alcoholic or aqueous/alcoholic composition for fixing hair includes from 1.0 to 10 percent by weight of a sulfur-free lignin, which can be hydroxypropyl lignin, hydroxybutyl lignin, dihydroxypropyl lignin and/or mixtures thereof; from 1 to 15% by weight of a film-forming polymer; and a solvent including water, an alcohol having one to four carbon atoms and/or mixtures thereof. It can be in the form of an aerosol hair spray, a non-aerosol hair spray, a non-aerosol foam or a non-aerosol hair lacquer. The composition can also include 2 to 80 percent by weight of a propellant.
摘要翻译： PCT No.PCT / EP93 / 01990 Sec。 371日期1994年04月18日 102（e）1994年4月18日PCT PCT 1993年7月27日PCT公布。公开号WO94 / 05249 日期为1994年3月17日。用于固定毛发的含水，醇或水/醇组合物包括1.0至10重量％的无硫木质素，其可以是羟丙基木质素，羟丁基木质素，二羟丙基木质素和/或其混合物 ; 1至15重量％的成膜聚合物; 和包含水，具有1-4个碳原子的醇和/或其混合物的溶剂。它可以是气溶胶发胶，非气溶胶发胶，非气溶胶泡沫或非气溶胶发胶的形式。组合物还可以包括2-80重量％的推进剂。

3. 发明授权

US5879669A Aqueous hair fixing composition containing a water-soluble hair fixing polymer and a thickener 失效
标题翻译：含有水溶性头发定影聚合物和增稠剂的水性头发定影组合物
公开(公告)号：US5879669A
公开(公告)日：1999-03-09
申请号：US664115
申请日：1996-06-14
申请人： Thomas Clausen , Gunther Lang , Wolfgang Keil , Michael Franzke , Jurgen Schmenger , Dieter Schonert
发明人： Thomas Clausen , Gunther Lang , Wolfgang Keil , Michael Franzke , Jurgen Schmenger , Dieter Schonert
IPC分类号： A61K8/00 , A61K8/25 , A61K8/26 , A61K8/41 , A61K8/65 , A61K8/73 , A61K8/81 , A61K8/86 , A61K8/92 , A61Q5/00 , A61Q5/02 , A61Q5/06 , A61Q5/10 , A61Q5/12 , A61Q7/00 , A61K7/06
CPC分类号： A61K8/731 , A61K8/26 , A61K8/41 , A61K8/65 , A61K8/73 , A61K8/732 , A61K8/8147 , A61K8/8158 , A61K8/8164 , A61K8/8182 , A61K8/86 , A61K8/922 , A61Q5/02 , A61Q5/06 , A61Q5/12 , A61K2800/594
摘要： The aqueous hair fixing composition contains 0.1 to 30 percent by weight of at least one thickener, e.g. acrylic acid polymer; 0.1 to 25 percent by weight of a film-forming polymer ingredient which consists of vinyl acetate/crotonic acid copolymer, acrylic acid/acrylamide copolymer and/or methyl vinyl ether/maleic anhydride copolymer and 45 to 99.8 percent by weight water. This aqueous hair fixing composition necessarily contains no organic solvents, no cationic surfactants and no cationic polymers and a physiologically acceptable acid or base is added to it to adjust its pH so that the film-forming polymer ingredient is at least partially precipitated.
摘要翻译：水性头发定影组合物含有0.1〜30重量％的至少一种增稠剂，例如，丙烯酸聚合物; 0.1〜25重量％的由乙酸乙烯酯/巴豆酸共聚物，丙烯酸/丙烯酰胺共聚物和/或甲基乙烯基醚/马来酸酐共聚物和45〜99.8重量％水组成的成膜聚合物成分。该水性头发定影组合物不一定不含有机溶剂，不添加阳离子表面活性剂和阳离子聚合物，并且向其中加入生理上可接受的酸或碱以调节其pH，使成膜聚合物成分至少部分沉淀。

4. 发明授权

US5380340A Hair dye containing aminopyrazole derivatives as well as pyrazole derivatives 失效
标题翻译：含有氨基吡唑衍生物的染发剂以及吡唑衍生物
公开(公告)号：US5380340A
公开(公告)日：1995-01-10
申请号：US27171
申请日：1993-03-04
申请人： Hans Neunhoeffer , Stefan Gerstung , Thomas Clausen , Wolfgang R. Balzer
发明人： Hans Neunhoeffer , Stefan Gerstung , Thomas Clausen , Wolfgang R. Balzer
IPC分类号： A61K8/49 , A61Q5/10 , C07D487/04 , A61K7/13 , C07D487/02
CPC分类号： A61Q5/10 , A61K8/494 , C07D487/04
摘要： The composition for oxidative dyeing of hair contains at least one coupler and 0.010 to 3.0 percent by weight of at least one developer selected from the group consisting of aminopyrazole derivatives of the formula (I): ##STR1## wherein R is selected from the group consisting of hydrogen and alkyl groups having one to four carbon atoms; n=2 or 3; and physiologically tolerated, water-soluble salts thereof. The developer and coupler substances are present in the composition in a total amount of from 0.1 to 5.0 percent. New pyrazole derivative compounds are also part of the invention.
摘要翻译： PCT No.PCT / EP92 / 01887第 371日期：1993年3月4日 102（e）1993年3月4日PCT提交1992年8月19日PCT公布。出版物WO93 / 07849 日期：1993年4月29日。头发氧化染色组合物含有至少一种成色剂和0.010-3.0％重量的至少一种显影剂，其选自式（I）的氨基吡唑衍生物：（ I）其中R选自氢和具有1-4个碳原子的烷基; n = 2或3; 和其生理上耐受的水溶性盐。显影剂和成色剂物质在组合物中的总量为0.1-5.0％。新的吡唑衍生物化合物也是本发明的一部分。

5. 发明授权

US5037446A 2-nitroaniline derivatives and hair dyeing compositions containing same 失效
标题翻译： 2-硝基苯胺衍生物和含有它们的染发组合物
公开(公告)号：US5037446A
公开(公告)日：1991-08-06
申请号：US283311
申请日：1988-12-12
申请人： Eugen Konrad , Thomas Clausen , Hans-Jurgen Braun , Herbert Mager
发明人： Eugen Konrad , Thomas Clausen , Hans-Jurgen Braun , Herbert Mager
IPC分类号： A61K8/41 , A61Q5/06 , A61Q5/10
CPC分类号： A61K8/418 , A61Q5/065 , A61Q5/10
摘要： The composition for dyeing hair yellow contains 2-nitroaniline derivatives of the general formula I: ##STR1## in which, R.sup.1 and R.sup.2 represent, independent of one another, hydrogen an alkyl of 1 to 4 carbon atoms, a monohydroxyallkyl of 2 to 4 carbon atoms or a dihydroxyalkyl of 3 or 4 carbon atoms, provided that R.sup.1 and R.sup.2 do not simultaneously represent alkyl groups of 1 to 4 carbon atoms, and X denotes an alkyl, monohydroxyalkyl, perfluoroalkyl or halogen. Also disclosed are new 2-nitroanitrile derivatives of the general formula II: ##STR2## in which R.sup.a and R.sup.b denote, independent of one another, ethyl, a monohydroxylalkyl of 2 to 4 carbon atoms or a dihydroxyalkyl of 3 or 4 carbon atoms, when Z is methyl, Cl or Br; or when Z is CH.sub.2 OH or a perfluoroalkyl, R.sup.a denotes hydrogen, a monohydroxyalkyl of 2 to 4 carbon atoms or a dihydroxyalkyl of 3 or 4 carbon atoms, and R.sup.b represents 2-hydroxyethyl or 2,3-dihydroxypropyl.
摘要翻译：用于染发黄黄色的组合物含有通式I的2-硝基苯胺衍生物：其中，R 1和R 2彼此独立地表示氢，具有1至4个碳原子的烷基，2个单羟基烷基至4个碳原子或3或4个碳原子的二羟基烷基，条件是R 1和R 2不同时表示1至4个碳原子的烷基，X表示烷基，单羟基烷基，全氟烷基或卤素。还公开了通式II的新的2-硝基腈衍生物：其中R a和R b彼此独立地表示乙基，2至4个碳原子的单羟基烷基或3或4个碳的二羟基烷基当Z是甲基时，Cl或Br; 或当Z为CH 2 OH或全氟烷基时，R a表示氢，2至4个碳原子的一羟基烷基或3或4个碳原子的二羟基烷基，R b表示2-羟乙基或2,3-二羟丙基。

6. 发明授权

US5674476A Process for making a persulfate-containing granulate for decolorizing or bleaching hair 失效
标题翻译：制造含过硫酸盐的颗粒以脱色或漂白毛发的方法
公开(公告)号：US5674476A
公开(公告)日：1997-10-07
申请号：US612533
申请日：1996-03-08
申请人： Thomas Clausen , Wolfgang R. Balzer , Volker Port , Jolanthe Kujawa
发明人： Thomas Clausen , Wolfgang R. Balzer , Volker Port , Jolanthe Kujawa
IPC分类号： A61K8/00 , A45D19/00 , A61K8/04 , A61K8/21 , A61K8/34 , A61K8/86 , A61Q5/08 , B01J2/10 , C08L39/06 , C08L71/02 , A61K7/135
CPC分类号： A61Q5/08 , A61K8/0275 , A61K2800/51
摘要： The method of making a granulate composition for decolorizing or bleaching hair consists of preparing a powdery mixture consisting of from 30 to 65% by weight of one or more inorganic persulfates, from 1 to 20% by weight of a binding agent selected from the group consisting of polyvinylpyrrolidone and polyethylene glycols having molecular weights of 200 to 10,000; of 15 to 45% by weight of at least one salt selected from the group consisting of alkali metal carbonates, alkaline earth metal carbonates, alkali metal hydrogen carbonates, alkali metal silicates and from 0.1 to 3 percent by weight of a chelating agent, and one or more auxiliary and additive substance selected from the group consisting of perfume oils, hair dyes, amphoteric, anionic, cationic and nonionic surface-active substances and water-soluble thickeners; after making this powdery mixture, spraying ethanol and/or isopropanol in a weight ratio from 13:1 to 4:1 (powdery mixture to alcohol) into the powdery mixture to form a moistened mixture; granulating the moistened mixture formed during the spraying in a granulating apparatus to form a moist granulate; and after the granulating, drying the moist granulate to remove the alcohol or alcohols and to form the granulate composition.
摘要翻译：制备用于脱色或漂白毛发的颗粒组合物的方法包括制备由30至65重量％的一种或多种无机过硫酸盐，1至20重量％的选自以下的粘合剂组成的粉末混合物：的聚乙烯吡咯烷酮和分子量为200至10,000的聚乙二醇; 15至45重量％的至少一种选自碱金属碳酸盐，碱土金属碳酸盐，碱金属碳酸氢盐，碱金属硅酸盐和0.1至3重量％螯合剂的盐，以及一种或更多选自香水油，染发剂，两性，阴离子，阳离子和非离子表面活性物质和水溶性增稠剂的辅助和添加剂物质; 在制备该粉末混合物之后，将重量比为13:1至4:1的乙醇和/或异丙醇（粉末混合物至醇）喷入粉末混合物中以形成润湿的混合物; 将在喷雾期间形成的润湿混合物造粒在造粒设备中以形成湿颗粒; 在造粒后，干燥湿颗粒以除去醇或醇并形成颗粒组合物。

7. 发明授权

US5430159A N-phenylaminopyrazole derivatives as well as composition and process for the dyeing of hair 失效
标题翻译： N-苯基氨基吡唑衍生物以及头发染色的组成和方法
公开(公告)号：US5430159A
公开(公告)日：1995-07-04
申请号：US244069
申请日：1994-05-09
申请人： Hans Neunhoeffer , Stefan Gerstung , Thomas Clausen , Wolfgang R. Balzer
发明人： Hans Neunhoeffer , Stefan Gerstung , Thomas Clausen , Wolfgang R. Balzer
IPC分类号： A61K8/00 , A61K8/49 , A61Q5/10 , C07D231/38 , C09B57/00 , D06P3/08 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/494 , C07D231/38
摘要： The hair dye composition includes at least one N-phenylaminopyrazole compound of the formula (V) ##STR1## wherein R.sup.1 is hydrogen, an alkyl group having from one to four carbon atoms or a hydroxyalkyl group having from two to four carbon atoms; R.sup.2 and R.sup.3 are each independently either a hydrogen, an amino groups or an alkyl group having from one to four carbon atoms; and R.sup.4 is hydrogen, an alkyl group having from one to four carbon atoms, an alkoxy group having from one to four carbon atoms or a halogen; and at least one conventional ingredient for hair dye compositions selected from the group consisting of emollients; preservatives; perfume oils; solvents; anionic, cationic, amphoteric and nonionic surfactants; thickeners; starch derivatives; cellulose derivatives; petrolatum; paraffin oil; fatty acids; conditioners; lanolin derivatives; cholesterol; pantothenic acid and betaines.
摘要翻译：染发剂组合物包含至少一种式（V）的N-苯基氨基吡唑化合物其中R1是氢，具有1-4个碳原子的烷基或具有2-4个碳原子的羟基烷基 ; R2和R3各自独立地为氢，氨基或具有1-4个碳原子的烷基; R4是氢，具有1-4个碳原子的烷基，具有1-4个碳原子的烷氧基或卤素; 和至少一种用于染发组合物的常规成分，其选自润肤剂; 防腐剂香水油; 溶剂阴离子，阳离子，两性和非离子表面活性剂; 增稠剂淀粉衍生物; 纤维素衍生物; 凡士林石蜡油; 脂肪酸; 调理器羊毛脂衍生物; 胆固醇; 泛酸和甜菜碱。

8. 发明授权

US5382702A Process for the production of 5-alkoxy-2,4-dinitro-alkylbenzenes 失效
标题翻译： 5-烷氧基-2,4-二硝基 - 烷基苯的制备方法
公开(公告)号：US5382702A
公开(公告)日：1995-01-17
申请号：US142383
申请日：1993-11-19
申请人： Wolfgang R. Balzer , Thomas Clausen , Alexa Weinges
发明人： Wolfgang R. Balzer , Thomas Clausen , Alexa Weinges
IPC分类号： C07C201/08 , C07C201/12 , C07C205/12 , C07C205/37 , C07C43/205
CPC分类号： C07C201/08 , C07C201/12
摘要： Process for producing 5-alkoxy-2,4-dinitroalkylbenzenes of the general formula (I) ##STR1## R.sup.1 =C.sub.1 to C.sub.4 alkyl; R=C.sub.1 to C.sub.6 alkyl group, C.sub.2 to C.sub.4 hydroxyalkyl, C.sub.3 to C.sub.4 dihydroxyalkyl,in which a 3-fluoroalkylbenzene is nitrated and the obtained 2,4-dinitro-5-fluoroalkylbenzene is then reacted with a suitable alcohol at -5.degree. C. to +25.degree. C. with the addition of sodium hydroxide or potassium hydroxide.
摘要翻译： PCT No.PCT / EP93 / 00678 Sec。 371日期：1993年11月19日 102（e）1993年11月19日PCT 1993年3月20日PCT PCT。出版物WO93 / 2551200 日本1993年12月23日。通式（I）的5-烷氧基-2,4-二硝基烷基苯的制备方法（Ⅰ）R1 = C1〜C4烷基; R = C1至C6烷基，C2至C4羟基烷基，C3至C4二羟基烷基，其中3-氟烷基苯被硝化，所得2,4-二硝基-5-氟烷基苯然后与适当的醇在-5℃下反应至+ 25℃，加入氢氧化钠或氢氧化钾。

9. 发明授权

US5303722A Apparatus for bleaching hair under the influence of light 失效
标题翻译：用于在光线下漂白头发的装置
公开(公告)号：US5303722A
公开(公告)日：1994-04-19
申请号：US001799
申请日：1993-01-08
申请人： Robin E. Godfrey , Thomas Clausen , Wolfgang R. Balzer
发明人： Robin E. Godfrey , Thomas Clausen , Wolfgang R. Balzer
IPC分类号： A45D7/04 , A45D19/00 , A45D19/02 , A45D24/00 , A45D24/10 , A61K8/00 , A61K8/02 , A61K8/33 , A61K8/34 , A61K8/35 , A61K8/36 , A61K8/368 , A61K8/41 , A61N5/06 , A61Q5/08
CPC分类号： A45D19/00 , A45D19/02 , A45D24/10 , A61K8/02 , A61N5/0617 , A61Q5/08 , A45D2019/0066 , A61K2800/434 , A61N5/062
摘要： The apparatus for bleaching hair has a light comb with a comb back, a plurality of comb teeth extending from the comb back, a device for guiding light from a light source through the comb back into the comb teeth, and a device for radiating the light from the comb teeth and parallel to the comb back, this radiating device receiving the light from the light guiding device.
摘要翻译：用于漂白头发的装置具有梳梳梳，梳梳延伸的多个梳齿，用于将来自光源的光通过梳梳引导到梳齿中的装置，以及用于辐射光的装置这个辐射装置从梳齿平行于梳子，接收来自导光装置的光。

10. 发明授权

US4960955A Process for making 4-chloro-2-methyl-5-nitro-phenol 失效
标题翻译：制备4-氯-2-甲基-5-硝基 - 苯酚的方法
公开(公告)号：US4960955A
公开(公告)日：1990-10-02
申请号：US353799
申请日：1989-05-17
申请人： Thomas Clausen , David Rose
发明人： Thomas Clausen , David Rose
IPC分类号： C07C205/26
CPC分类号： C07C201/12 , C07C201/16
摘要： The process of making 4-chloro-2-methyl-5-nitro phenol (I) ##STR1## comprises nitrating a 4-chloro-2-methyl-phenyl sulfonate of the formula (II) at the 5 position ##STR2## in which R is a residue selected from the group consisting of methyl-, ethyl-, trifluoromethyl-, phenyl- and tolyl and the sulfonyl residue comprises --SO.sub.2 R at the position 5 to form 4-chloro-2-methyl-5-nitro-phenyl-sulfonate and then cleaving the sulfonyl residue of the 4-chloro-2-methyl-5-nitro-phenyl-sulfonate to form the 4-chloro-2-methyl-5-nitro-phenyl. The process uses technically available and economical starting materials and allows an isomerically pure product to be made in very good yield.
摘要翻译：制备4-氯-2-甲基-5-硝基苯酚（I）的方法（I）包括将式（II）的4-氯-2-甲基 - 苯基磺酸盐在5位

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