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1. 发明授权

US06835775B2 Thermoplastic molding compounds with improved impact resistance 有权
标题翻译：具有改善耐冲击性的热塑性模塑料
公开(公告)号：US06835775B2
公开(公告)日：2004-12-28
申请号：US10275012
申请日：2002-10-31
申请人： Michael Breulmann , Sabine Oepen , Norbert Niessner , Norbert Güntherberg , Wil Duijzings , Graham Edmund Mc Kee , Peter Rossmanith
发明人： Michael Breulmann , Sabine Oepen , Norbert Niessner , Norbert Güntherberg , Wil Duijzings , Graham Edmund Mc Kee , Peter Rossmanith
IPC分类号： C08F25500
CPC分类号： C08L25/12 , C08F265/04 , C08F279/02 , C08F279/04 , C08F291/02 , C08L51/04 , C08L55/02 , C08F2/22 , C08L2666/24 , C08L2666/02
摘要： The graft copolymer made from a1: from 10 to 90% by weight of a particulate graft base A1, made from a particulate emulsion polymer with a glass transition temperature below 0° C. made from a11: from 70 to 100% by weight of butadiene or of at least one C1-8-alkyl acrylate, or of mixtures of these, as component A11, a12: from 0 to 20% by weight of at least one polyfunctional crosslinking monomer, as component A12, a13: from 0 to 30% by weight of other copolymerizable monomers, as component A13, the total amount of these being 100% by weight, a2: from 10 to 90% by weight of a graft A2 made from the following monomers, the amounts being based on A2, a21: from 60 to 100% by weight of at least one vinylaromatic monomer, or of a (meth)acrylic ester or of mixtures of these, as component A21, and a22: from 0 to 40% by weight of at least one ethylenically unsaturated monomer, as component A22, has a median particle diameter of from 130 to 500 nm and has polymodal particle size distribution in which less than 40% by weight of the particles are present in any particle size range of width 50 nm.
摘要翻译：由a1制得的接枝共聚物：10至90重量％的微粒接枝基质A1，其由玻璃化转变温度低于0℃的颗粒状乳液聚合物制成，由11：70至100重量％的丁二烯或至少一种丙烯酸C 1-8 - 或它们的混合物，作为组分A11，a12：0-20重量％的至少一种多官能交联单体，作为组分A12，a13：0-30重量％的其它可共聚单体作为组分A13，其总量为100重量％，a2：10至90重量％的由以下单体制备的接枝A2，其量基于A2，a21：60 至100重量％的至少一种乙烯基芳族单体或（甲基）丙烯酸酯或它们的混合物作为组分A21和a22：0至40重量％的至少一种烯属不饱和单体作为组分A22 具有130-500nm的中值粒径，并且具有多模态粒度分布，其中le 超过40重量％的颗粒存在于宽度为50nm的任何粒度范围内。

2. 发明授权

US06774167B1 Method for reducing cold stress whitening 有权
标题翻译：降低冷应激白化的方法
公开(公告)号：US06774167B1
公开(公告)日：2004-08-10
申请号：US10111469
申请日：2002-04-25
申请人： Sabine Oepen , Norbert Niessner , Michael Breulmann , Norbert Güntherberg , Wil Duijzings
发明人： Sabine Oepen , Norbert Niessner , Michael Breulmann , Norbert Güntherberg , Wil Duijzings
IPC分类号： C08K55415
CPC分类号： C08L55/02 , C08F279/04 , C08L51/04 , C08L2666/04 , C08L2666/02
摘要： Undesirable changes in shade brought about by low temperatures (Cold Stress Whitening) in impact-modified thermoplastic molding compositions F which comprise at least one elastomeric graft polymer A and at least one thermoplastic polymer B are reduced by adding from 10 to 200 ppm, based on the molding compositions F, of at least one polyorganosiloxane S to the impact-modified thermoplastic molding composition F.
摘要翻译：在冲击改性的热塑性成型组合物F中，通过低温（冷应力增白）引起的不利影响的变化包括至少一种弹性体接枝聚合物A和至少一种热塑性聚合物B，通过加入10至200ppm，基于至少一种聚有机硅氧烷S的成型组合物F与冲击改性热塑性模塑组合物F。

3. 发明授权

US06852797B2 Method for producing polybutadiene latex with an optimized thermal current profile 失效
标题翻译：具有优化的热电流分布的聚丁二烯胶乳的生产方法
公开(公告)号：US06852797B2
公开(公告)日：2005-02-08
申请号：US10257717
申请日：2001-04-24
申请人： Sabine Oepen , Michael Breulmann , Norbert Güntherberg , Klaus-Dieter Hungenberg , Norbert Niessner , Bernhard Czauderna , Wil Duijzings
发明人： Sabine Oepen , Michael Breulmann , Norbert Güntherberg , Klaus-Dieter Hungenberg , Norbert Niessner , Bernhard Czauderna , Wil Duijzings
IPC分类号： C08F2/22 , C08F2/32 , C08F236/06 , C08F279/02 , C08F279/04
CPC分类号： C08F279/02 , C08F236/06 , Y10S525/942 , C08F2/22
摘要： A polybutadiene latex is prepared by a process in which butadiene is polymerized by free radical emulsion polymerization in the presence of initiator and, if required, dispersants and further conventional assistants, the polymerization being carried out in the presence of reactive comonomers in such a way that the heat flow of 43 watt/kg solids content of the polymerization mixture is not exceeded. Owing to the presence of reactive comonomers, the reaction rate at the beginning of the reaction is increased, with the result that an overall flatter heat flow profile is obtained. A preferred reactive comonomer is styrene. Preferably, the process is carried out by a semi-batch procedure in which (a) in a first stage, a portion of butadiene and at least one portion of reactive comonomer in the form of an aqueous emulsion are initially taken with a thermal polymerization initiator and, if required, dispersants and further conventional assistants and the polymerization is initiated, (b) in a second stage, the remaining amount of butadiene and, if required, the remaining amount of reactive comonomer are added undiluted or in the form of an aqueous emulsion, if required with dispersants and, if required, further conventional assistants, as a feed.
摘要翻译：聚丁二烯胶乳是通过一种方法制备的，其中丁二烯在引发剂存在下通过自由基乳液聚合聚合，如果需要的话，通过分散剂和其它常规助剂，聚合反应在反应性共聚单体的存在下进行，使得不超过聚合混合物的43瓦特/千克固体含量的热流。由于反应性共聚单体的存在，反应开始时的反应速率增加，结果得到整体平坦的热流分布。优选的反应性共聚单体是苯乙烯。优选地，该方法通过半间歇方法进行，其中（a）在第一阶段中，一部分丁二烯和至少一部分水性乳液形式的反应性共聚单体最初用热聚合引发剂并且如果需要，分散剂和其它常规助剂并开始聚合，（b）在第二阶段中，剩余量的丁二烯和如果需要的话，反应性共聚单体的剩余量未稀释或以水性形式加入乳液，如果需要与分散剂，并且如果需要，作为进料的其它常规助剂。

4. 发明授权

US06723774B2 Method for producing caoutchouc particles 有权
标题翻译：橡胶颗粒的制备
公开(公告)号：US06723774B2
公开(公告)日：2004-04-20
申请号：US10221080
申请日：2002-09-10
申请人： Norbert Güntherberg , Bernhard Czauderna , Michael Breulmann , Sabine Oepen , Wil Duijzings , Norbert Niessner
发明人： Norbert Güntherberg , Bernhard Czauderna , Michael Breulmann , Sabine Oepen , Wil Duijzings , Norbert Niessner
IPC分类号： C08F3600
CPC分类号： C08F36/04 , Y10S525/902 , C08F2/24
摘要： The invention relates to a method for producing caoutchouc particles (K) by means of emulsion polymerisation in the presence of an emulsifier and a polymerisation initiator. Said particles contain A) 80 to 100 wt. % of one or more conjugated diene monomers (A) in relation to (K) and B) 0 to 20 wt. % of one or more monoethylenically unsaturated comonomers (B) in relation to (K) in the polymerised form. The inventive method is characterised in that 1) a mixture (M1) containing water and an emulsifier is provided, 2) a mixture (M2) containing one or more monomers in the monomer or polymerised form selected from styrole, &agr;-methylstyrole, butadiene, n-butylacrylate, MMA and acrylnitrile and optionally comonomers is added, 3) polymerisation of the obtained mixture starts in the presence of a polymerisation initiator at temperature of 5 to 95° C., 4) a mixture (M3) containing 0 to 100 wt. % of the comonomers (B) in relation to (B) and 0 to 25 wt. % of the diene monomers (A) in relation to (A) is added, 5) a mixture (M4) containing the (remaining) diene monomers (A) and the (remaining) comonomers (B) is proportioned and polymerised and 6) polymerisation is terminated when there is conversion of more than 90 and less than 95% in relation to the sum of the monomers.
摘要翻译：本发明涉及一种在乳化剂和聚合引发剂存在下，通过乳液聚合来生产酚醛树脂颗粒（K）的方法。所述颗粒包含A）80至100重量％一个或多个共轭二烯单体（A）相对于（K）和B）的％为0-20重量％％的一种或多种单烯属不饱和共聚单体（B）相对于聚合形式的（K）。本发明的方法的特征在于：1）提供含有水和乳化剂的混合物（M1），2）含有一种或多种选自苯乙烯，α-甲基苯甲醛，丁二烯的单体或聚合形式的单体的混合物（M2）丙烯酸正丁酯，MMA和丙烯腈和任选的共聚单体; 3）所得混合物的聚合在聚合引发剂存在下开始，温度为5至95℃，4）含有0-100重量份的混合物。共聚单体（B）的相对于（B）和0-25重量％加入相对于（A）的二烯单体（A）的％，5）含有（剩余的）二烯单体（A）和（剩余的）共聚单体（B）的混合物（M4）成比例和聚合，和6）当相对于单体的总和转化率大于90且小于95％时，聚合终止。

5. 发明授权

US06812283B2 Method for agglomerating dispersed rubber 有权
标题翻译：聚集分散橡胶的方法
公开(公告)号：US06812283B2
公开(公告)日：2004-11-02
申请号：US10333612
申请日：2003-01-22
申请人： Wil Duijzings , Sabine Oepen , Norbert Niessner , Michael Breulmann , Hardy Korb
发明人： Wil Duijzings , Sabine Oepen , Norbert Niessner , Michael Breulmann , Hardy Korb
IPC分类号： C08L3102
CPC分类号： C08C1/07
摘要： A process for the agglomeration of at least one rubber (A), dispersed in an aqueous phase, by the addition of a dispersion of at least one agglomerating polymer (B) in aqueous phase, in which the agglomerating polymer B used is one containing substantially no free acid groups and the agglomeration is carried out in the presence of at least one basic electrolyte.
摘要翻译：通过在水相中加入至少一种附聚聚合物（B）的分散体，使分散在水相中的至少一种橡胶（A）凝聚的方法，其中使用的附聚聚合物B是基本上含有不存在游离酸基团并且在至少一种碱性电解质的存在下进行附聚。

6. 发明授权

US06515079B2 Preparation of thermoplastic molding compositions 失效
标题翻译：热塑性成型组合物的制备
公开(公告)号：US06515079B2
公开(公告)日：2003-02-04
申请号：US09734026
申请日：2000-12-12
申请人： Graham Edmund McKee , Falko Ramsteiner , Peter Barghoorn , Michael Breulmann , Norbert Niessner
发明人： Graham Edmund McKee , Falko Ramsteiner , Peter Barghoorn , Michael Breulmann , Norbert Niessner
IPC分类号： C08J300
CPC分类号： C08L51/04 , C08F265/04 , C08F279/02 , C08L55/02 , C08L2666/04
摘要： In a process for preparing thermoplastic molding compositions by a) polymerizing, in aqueous emulsion, dienes, C1-C12-alkyl acrylates or mixtures of these, where from 0 to 30% by weight of these monomers may have been replaced by other copolymerizable monomers, and where from 0 to 10 by weight of these monomers may have been replaced by crosslinking monomers, to give a rubber latex with a glass transition temperature below −10° C., b) agglomerating, at least to some extent, the rubber latex obtained in a), by adding, as agglomerating agent, a dispersion of a polymer made from 80 to 100% by weight of C1-C12-alkyl acrylates and from to 20% by weight of comonomers forming water-soluble polymers, where from 0 to 50% by weight of these monomers may have been replaced by other copolymerizable monomers, c) polymerizing, in aqueous emulsion, from 10 to 90 parts by weight of styrene, &agr;-methylstyrene, (meth)acrylonitril, C1-C12-alkyl acrylate, C1-C6-alkyl methacrylate or mixtures of these, where up to 30% by weight of these monomers may have been replaced by other copolymerizable monomers, in the presence of from 10 to 90% by weight of the agglomerated latex obtained in b), based on the solid, to give a graft polymer, the agglomerating agent is prepared by polymerizing the monomers mentioned in b) in the presence of from 0.001 to 10% by weight of a molecular weight regulator, based on the amount of the monomers mentioned in b).
摘要翻译：在制备热塑性模塑组合物的方法中，a）在水乳液中聚合二烯，丙烯酸C 1 -C 12烷基酯或这些的混合物，其中0至30重量％的这些单体可能已被其它可共聚单体替代，以及其中0至10重量份的这些单体可能已被交联单体代替，得到玻璃化转变温度低于-10℃的橡胶胶乳，b）至少在一定程度上聚集所得橡胶胶乳 a）通过作为附聚剂添加由80-100重量％的丙烯酸C 1 -C 12烷基酯和20重量％的形成水溶性聚合物的共聚单体制成的聚合物的分散体，其中0至50 这些单体的重量百分比可能已被其他可共聚单体所取代，c）在水性乳液中聚合10至90份重量的苯乙烯，α-甲基苯乙烯，（甲基）丙烯腈，丙烯酸C1-C12-烷基酯，C1 甲基丙烯酸C 1-6烷基酯或它们的混合物基于固体，在至少30重量％的这些单体可以被其它可共聚的单体替代，其中以10重量％至90重量％的在b）中获得的聚集胶乳为基础，得到接枝聚合物，基于b）中提到的单体的量，通过在0.001-10重量％的分子量调节剂的存在下，将b）中所述的单体聚合来制备附聚剂。

7. 发明申请

US20060258805A1 Mixtures containing thermoplastic polyurethane and acrylonitrile-styrene-acrylic ester copolymer (asa) 有权
标题翻译：含有热塑性聚氨酯和丙烯腈 - 苯乙烯 - 丙烯酸酯共聚物（asa）的混合物
公开(公告)号：US20060258805A1
公开(公告)日：2006-11-16
申请号：US10554685
申请日：2004-05-05
申请人： Michael Breulmann , Matteo Uslenghi , Graham Mckee , Frank Uhlhorn , Stephan Friederichs , Johann Brand
发明人： Michael Breulmann , Matteo Uslenghi , Graham Mckee , Frank Uhlhorn , Stephan Friederichs , Johann Brand
IPC分类号： C08F8/30
CPC分类号： B32B21/08 , B32B27/06 , B32B2479/00 , C08F257/02 , C08F265/04 , C08L51/003 , C08L55/00 , C08L75/04 , C09D151/00 , C09D155/00 , C08L2666/14 , C08L2666/02 , C08L2666/24
摘要： Mixture (1) comprising from 1 to 40% by weight of (A) thermoplastic polyurethane based on aliphatic isocyanate and from 60 to 99% by weight of (B) acrylonitrile-styrene-acrylate copolymer (ASA) and/or acrylonitrile-ethylene homo- or copolymer-styrene (AES) material, based in each case on the total weight of the mixture (1).
摘要翻译：混合物（1）包含1至40重量％的（A）基于脂族异氰酸酯的热塑性聚氨酯和60至99重量％的（B）丙烯腈 - 苯乙烯 - 丙烯酸酯共聚物（ASA）和/或丙烯腈 - 乙烯共聚物 - 或共聚物 - 苯乙烯（AES）材料，基于混合物（1）的总重量。

8. 发明申请

US20050233130A1 Shaped part comprising a laminate panel or laminate film and a supporting layer 审中-公开
标题翻译：成形部分包括层压板或层压膜和支撑层
公开(公告)号：US20050233130A1
公开(公告)日：2005-10-20
申请号：US10519190
申请日：2003-06-20
申请人： Achim Grefenstein , Michael Breulmann
发明人： Achim Grefenstein , Michael Breulmann
IPC分类号： B62D25/06 , B29C69/00 , B32B25/02 , B32B25/08 , B32B25/14 , B32B27/30 , B32B27/36 , B60R19/03 , B62D37/02 , C08L25/12 , C08L51/04 , C08L55/02 , C08L69/00 , B29C47/06 , B32B5/16
CPC分类号： C08L51/04 , B32B25/08 , B32B25/14 , C08L25/12 , C08L55/02 , C08L69/00 , Y10T428/25 , C08L2666/18 , C08L2666/06 , C08L2666/02 , C08L51/00
摘要： The invention relates to moldings encompassing a composite layered sheet or composite layered film and a backing layer made from plastic injection-molded, foamed, or cast onto the back of the material, where the composite layered sheet or composite layered film encompasses (1) a substrate layer comprising, based on the total of the amounts of components A and B, and, where appropriate, C and/or D, which give 100% by weight in total, a from 1-99% by weight of an elastomeric graft copolymer as component A, b from 1-99% by weight of one or more hard copolymers containing units which derive from vinylaromatic monomers, as component B, c from 0-80% by weight of polycarbonates, as component C, and d from 0-50% by weight of fibrous or particulate fillers, or a mixture of these, as component D, Wherein component B contains, based us the total weight of units deriving from vinylaromatic monomers, from 40-100% by weight of units deriving from α-methylstyrene and from 0-60% by weight of units deriving from styrene. The invention further relates to a process for producing these moldings, to their use as bodywork components or motor vehicles, and also to motor vehicle bodywork components comprising these moldings.
摘要翻译：本发明涉及包含复合层状片或复合层状膜的模制品以及由塑料注塑，发泡或浇铸在材料背面上制成的背衬层，其中复合层压片或复合层压膜包括（1）基于组合物A和B的总量，以及适当地包含总共100重量％的C和/或D的总计的1-99重量％的弹性体接枝共聚物作为组分A的b，1-99重量％的一种或多种含有衍生自乙烯基芳族单体的单元的硬共聚物作为组分B，c为0-80重量％的聚碳酸酯，作为组分C，d为0- 50重量％的纤维或颗粒填料，或它们的混合物，作为组分D，其中组分B含有基于衍生自乙烯基芳族单体的单元的总重量，40-100重量％衍生自α- 甲基苯乙烯和0-60重量％的单位衍生自苯乙烯。本发明还涉及一种用于制造这些模制品的方法，其用作车身部件或机动车辆，以及包括这些模制品的机动车辆车身部件。

9. 发明授权

US08097677B2 Mixtures containing thermoplastic polyurethane and acrylonitrile-styrene-acrylic ester copolymer (ASA) 有权
标题翻译：含有热塑性聚氨酯和丙烯腈 - 苯乙烯 - 丙烯酸酯共聚物（ASA）的混合物
公开(公告)号：US08097677B2
公开(公告)日：2012-01-17
申请号：US10554685
申请日：2004-05-05
申请人： Michael Breulmann , Matteo Uslenghi , Graham Edmund Mckee , Frank Uhlhorn , Stephan Friederichs , Johann Diedrich Brand
发明人： Michael Breulmann , Matteo Uslenghi , Graham Edmund Mckee , Frank Uhlhorn , Stephan Friederichs , Johann Diedrich Brand
IPC分类号： C08F8/30
CPC分类号： B32B21/08 , B32B27/06 , B32B2479/00 , C08F257/02 , C08F265/04 , C08L51/003 , C08L55/00 , C08L75/04 , C09D151/00 , C09D155/00 , C08L2666/14 , C08L2666/02 , C08L2666/24
摘要： Mixture (1) comprising from 1 to 40% by weight of (A) thermoplastic polyurethane based on aliphatic isocyanate and from 60 to 99% by weight of (B) acrylonitrile-styrene-acrylate copolymer (ASA) and/or acrylonitrile-ethylene homo- or copolymer-styrene (AES) material, based in each case on the total weight of the mixture (1).
摘要翻译：混合物（1）包含1至40重量％的（A）基于脂族异氰酸酯的热塑性聚氨酯和60至99重量％的（B）丙烯腈 - 苯乙烯 - 丙烯酸酯共聚物（ASA）和/或丙烯腈 - 乙烯共聚物 - 或共聚物 - 苯乙烯（AES）材料，基于混合物（1）的总重量。

10. 发明申请

US20090069476A1 Stabilised thermoplastic moulding compounds 审中-公开
标题翻译：稳定的热塑性模塑料
公开(公告)号：US20090069476A1
公开(公告)日：2009-03-12
申请号：US11667003
申请日：2005-10-28
申请人： Martin Stork , Bernd Bruchmann , Hauke Malz , Michael Breulmann
发明人： Martin Stork , Bernd Bruchmann , Hauke Malz , Michael Breulmann
IPC分类号： C08L51/06 , C08K5/36 , C08K5/56
CPC分类号： C08G18/3844 , C08F279/02 , C08F279/04 , C08G18/3206 , C08G18/348 , C08K5/13 , C08K5/29 , C08K5/3435 , C08L33/10 , C08L33/18 , C08L35/06 , C08L51/04 , C08L53/00 , C08L55/02 , C08L2666/24 , C08L2666/04 , C08L2666/02
摘要： Thermoplastic molding compositions, processes for making the same and articles made therewith are described wherein the compositions include at least one stabilizer comprising one or more polyisocyanates having an average of 2 to 10 isocyanate groups per molecule, wherein at least one active ingredient group is coupled to the one or more polyisocyanates in an amount of 0.1 to 1.0 mole per mole of isocyanate groups, the at least one active ingredient group selected from phenolic compounds, sterically hindered amines and mixture thereof; and wherein up to 0.9 mole of one or more auxiliary groups is coupled to the one or more polyisocyanates.
摘要翻译：描述了热塑性模制组合物，其制备方法和制备的制品，其中组合物包括至少一种稳定剂，其包含每分子平均具有2至10个异氰酸酯基团的一种或多种多异氰酸酯，其中至少一种活性成分基团与所述一种或多种多异氰酸酯的量为每摩尔异氰酸酯基团为0.1至1.0摩尔，所述至少一种活性成分基团选自酚类化合物，空间位阻胺及其混合物; 并且其中至多0.9摩尔的一种或多种辅助基团与一种或多种多异氰酸酯偶联。

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