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1. 发明申请

US20130066009A1 Silicone Resins And Their Use In Polymer Compositions 有权
标题翻译：硅树脂及其在聚合物组合物中的应用
公开(公告)号：US20130066009A1
公开(公告)日：2013-03-14
申请号：US13698852
申请日：2011-05-16
申请人： Michael Backer , Pierre Chevalier , Zhihua Liu , Ana Marques , Satoshi Onodera , Vincent Rerat , Motoshi Sasaki
发明人： Michael Backer , Pierre Chevalier , Zhihua Liu , Ana Marques , Satoshi Onodera , Vincent Rerat , Motoshi Sasaki
IPC分类号： C08G77/18 , C08K3/36 , C08L83/08 , C08G77/395 , C08L69/00
CPC分类号： C08G77/395 , C08G77/26 , C08G77/30 , C08G77/388
摘要： Branched silicone (organopolysiloxane) resins and preparation method and use thereof are provided, which contain at least one group selected from phosphonate and phosphinate groups and at least one organic group containing nitrogen. Such silicone resins can be used in thermoplastic, thermosetting or rubber organic polymer compositions to reduce the flammability of the organic polymer compositions.
摘要翻译：提供了分支硅氧烷（有机聚硅氧烷）树脂及其制备方法和用途，其含有至少一种选自膦酸酯和次膦酸酯基团和至少一种含氮的有机基团。这种有机硅树脂可用于热塑性，热固性或橡胶有机聚合物组合物中以降低有机聚合物组合物的可燃性。

2. 发明授权

US09006372B2 Silicone resins and their use in polymer compositions 有权
标题翻译：硅树脂及其在聚合物组合物中的用途
公开(公告)号：US09006372B2
公开(公告)日：2015-04-14
申请号：US13698852
申请日：2011-05-16
申请人： Michael Backer , Pierre Chevalier , Zhihua Liu , Ana Marques , Satoshi Onodera , Vincent Rerat , Motoshi Sasaki
发明人： Michael Backer , Pierre Chevalier , Zhihua Liu , Ana Marques , Satoshi Onodera , Vincent Rerat , Motoshi Sasaki
IPC分类号： C08G77/26 , C08G77/395 , C08G77/30 , C08G77/388
CPC分类号： C08G77/395 , C08G77/26 , C08G77/30 , C08G77/388
摘要： Branched silicone (organopolysiloxane) resins and preparation method and use thereof are provided, which contain at least one group selected from phosphonate and phosphinate groups and at least one organic group containing nitrogen. Such silicone resins can be used in thermoplastic, thermosetting or rubber organic polymer compositions to reduce the flammability of the organic polymer compositions.
摘要翻译：提供了分支硅氧烷（有机聚硅氧烷）树脂及其制备方法和用途，其含有至少一种选自膦酸酯和次膦酸酯基团和至少一种含氮的有机基团。这种有机硅树脂可用于热塑性，热固性或橡胶有机聚合物组合物中以降低有机聚合物组合物的可燃性。

3. 发明申请

US20130065993A1 Polymer Compositions Containing Alkoxysilanes 审中-公开
标题翻译：含有烷氧基硅烷的聚合物组合物
公开(公告)号：US20130065993A1
公开(公告)日：2013-03-14
申请号：US13698828
申请日：2011-05-16
申请人： Michael Backer , Pierre Chevalier , Zhihua Liu , Ana Marques , Satoshi Onodera , Vincent Rerat , Motoshi Sasaki
发明人： Michael Backer , Pierre Chevalier , Zhihua Liu , Ana Marques , Satoshi Onodera , Vincent Rerat , Motoshi Sasaki
IPC分类号： C08K5/544 , C08K3/36 , C08L69/00 , C08L83/08 , C08K5/5419
CPC分类号： C08G77/26 , C08G77/30
摘要： The invention provides a process for improving the fire resistance of a thermoplastic or thermoset organic polymer composition, characterised in that an alkoxysilane containing at least one organic nitrogen-containing group and an alkoxysilane or silicone resin containing at least one group selected from phosphonate and phosphinate groups are added to a thermoplastic or thermosetting organic polymer composition and heated in the presence of moisture to cause hydrolysis and siloxane condensation of the alkoxysilane or alkoxysilanes. The alkoxysilanes, or alkoxysilane(s) and silicone resin, of the invention are particularly effective in increasing the fire resistance of polycarbonates and blends of polycarbonate with other resins such as polycarbonate/ABS blends.
摘要翻译：本发明提供一种改善热塑性或热固性有机聚合物组合物的耐火性的方法，其特征在于含有至少一种含有机氮基团的烷氧基硅烷和含有至少一种选自膦酸酯和次膦酸基团的烷氧基硅烷或硅氧烷树脂加入到热塑性或热固性有机聚合物组合物中并在水分存在下加热以引起烷氧基硅烷或烷氧基硅烷的水解和硅氧烷缩合。本发明的烷氧基硅烷或烷氧基硅烷和有机硅树脂在增加聚碳酸酯和聚碳酸酯与其它树脂如聚碳酸酯/ ABS共混物的共混物的耐火性方面特别有效。

4. 发明申请

US20130065992A1 Polymer Compositions Containing Oxazine-Based Alkoxysilanes 审中-公开
标题翻译：含有基于恶嗪的烷氧基硅烷的聚合物组合物
公开(公告)号：US20130065992A1
公开(公告)日：2013-03-14
申请号：US13698806
申请日：2011-05-16
申请人： Michael Backer , Pierre Chevalier , Ana Marques
发明人： Michael Backer , Pierre Chevalier , Ana Marques
IPC分类号： C08K5/357 , C08L69/00 , C08K3/36
CPC分类号： C08L83/04 , C08G77/26 , C08K5/5442 , C08K9/08 , C08L69/00 , C08L83/08 , C08L83/00
摘要： The invention provides a process for improving the fire resistance of a thermoplastic, thermoset or rubber organic polymer composition, characterised in that an alkoxysilane is added to a thermoplastic, thermosetting and rubber organic polymer composition and is heated to cause hydrolysis and condensation of the alkoxysilane. For example the alkoxysilane is a Benzoxazine triethoxysilane.
摘要翻译：本发明提供一种改善热塑性，热固性或橡胶有机聚合物组合物的耐火性的方法，其特征在于将烷氧基硅烷加入到热塑性，热固性和橡胶状有机聚合物组合物中，并加热以使烷氧基硅烷水解和缩合。例如，烷氧基硅烷是苯并恶嗪三乙氧基硅烷。

5. 发明授权

US09181379B2 Modified polyolefins 有权
标题翻译：改性聚烯烃
公开(公告)号：US09181379B2
公开(公告)日：2015-11-10
申请号：US13520859
申请日：2010-12-22
申请人： Michael Backer , Francois De Buyl , Damien Deheunynck , Jean De La Croix Habimana , Vincent Rerat , Valerie Smits
发明人： Michael Backer , Francois De Buyl , Damien Deheunynck , Jean De La Croix Habimana , Vincent Rerat , Valerie Smits
IPC分类号： C08L23/26 , C08F255/02 , C08F212/14 , C08F230/08
CPC分类号： C08F255/02 , C08F212/14 , C08F230/08 , C08F236/14
摘要： The invention provides a process for grafting silane or silicone functionality onto a polyolefin, comprising reacting the polyolefin with an unsaturated monomer (A) containing an olefinic —C═C— bond or acetylenic —C≡C— bond and a reactive functional group X in the presence of means capable of generating free radical sites in the polyolefin and with an organosilicon compound (B) having a functional group Y which is reactive with the functional group X of the unsaturated monomer (A), characterized in that the unsaturated monomer (A) contains an aromatic ring or a further olefinic double bond or acetylenic unsaturation, the aromatic ring or the further olefinic double bond or acetylenic unsaturation being conjugated with the olefinic —C═C— or acetylenic —C≡C— unsaturation of the unsaturated monomer (A).
摘要翻译：本发明提供将硅烷或硅氧烷官能度接枝到聚烯烃上的方法，包括使聚烯烃与含有烯烃-C≡C-键或炔属-C≡C-键和反应性官能团X的不饱和单体（A）反应存在能够在聚烯烃中产生自由基位点的装置和具有与不饱和单体（A）的官能团X反应的官能团Y的有机硅化合物（B）的存在，其特征在于不饱和单体（A ）含有芳环或另外的烯属双键或炔属不饱和键，芳环或其它烯属双键或炔属不饱和键与不饱和单体的烯属-C≡C-或炔属-C≡C-不饱和键相结合（一个）。

6. 发明申请

US20120283346A1 Modified Polyolefins 有权
标题翻译：改性聚烯烃
公开(公告)号：US20120283346A1
公开(公告)日：2012-11-08
申请号：US13520859
申请日：2010-12-22
申请人： Michael Backer , Francois De Buyl , Damien Deheunynck , Jean De La Croix Habimana , Vincent Rerat , Valerie Smits
发明人： Michael Backer , Francois De Buyl , Damien Deheunynck , Jean De La Croix Habimana , Vincent Rerat , Valerie Smits
IPC分类号： C08L23/36 , C08L23/26 , C08J9/00
CPC分类号： C08F255/02 , C08F212/14 , C08F230/08 , C08F236/14
摘要： The invention provides a process for grafting silane or silicone functionality onto a polyolefin, comprising reacting the polyolefin with an unsaturated monomer (A) containing an olefinic —C═C— bond or acetylenic —C≡C— bond and a reactive functional group X in the presence of means capable of generating free radical sites in the polyolefin and with an organosilicon compound (B) having a functional group Y which is reactive with the functional group X of the unsaturated monomer (A), characterized in that the unsaturated monomer (A) contains an aromatic ring or a further olefinic double bond or acetylenic unsaturation, the aromatic ring or the further olefinic double bond or acetylenic unsaturation being conjugated with the olefinic —C═C— or acetylenic —C≡C— unsaturation of the unsaturated monomer (A).
摘要翻译：本发明提供将硅烷或硅氧烷官能度接枝到聚烯烃上的方法，包括使聚烯烃与含有烯烃-C≡C-键或炔属-C≡C-键和反应性官能团X的不饱和单体（A）反应存在能够在聚烯烃中产生自由基位点的装置和具有与不饱和单体（A）的官能团X反应的官能团Y的有机硅化合物（B）的存在，其特征在于不饱和单体（A ）含有芳环或另外的烯属双键或炔属不饱和键，芳环或其它烯属双键或炔属不饱和键与不饱和单体的烯属-C≡C-或炔属-C≡C-不饱和键相结合（一个）。

7. 发明申请

US20120283388A1 POLYOLEFINS MODIFIED BY SILICONES 审中-公开
标题翻译：硅改性聚硅氧烷
公开(公告)号：US20120283388A1
公开(公告)日：2012-11-08
申请号：US13520855
申请日：2010-12-22
申请人： Michael Backer , Thomas Chausse , Francois De Buyl , Damien Deheunynck , Satoshi Onodera , Valerie Smits
发明人： Michael Backer , Thomas Chausse , Francois De Buyl , Damien Deheunynck , Satoshi Onodera , Valerie Smits
IPC分类号： C08F255/02 , C08F8/00
CPC分类号： C08L23/06 , C08F8/42 , C08F290/04 , C08F290/042 , C08F299/08 , C08L23/12 , C08L51/06 , C08L83/10 , C08F10/00 , C08L2666/24 , C08L2666/06 , C08F230/08 , C08F236/14
摘要： The invention provides a process for grafting silicone onto a polyolefin comprising reacting the polyolefin with a silicon compound containing an unsaturated group in the presence of means capable of generating free radical sites in the polyolefin, characterized in that the silicon compound is a branched silicone resin containing at least one group of the formula —X—CH═CH—R″ (I) or —X—C≡C—R″ (II), in which X represents a divalent organic linkage having an electron withdrawing effect with respect to the —CH═CH— or —C≡C-bond and/or containing an aromatic ring or a further olefinic double bond or acetylenic unsaturation, the aromatic ring or the further olefinic double bond or acetylenic unsaturation being conjugated with the olefinic unsaturation of —X—CH═CH—R″ or with the acetylenic unsaturation of —X—C≡C—R″, X being bonded to the branched silicone resin by a C—Si bond, and R″ represents hydrogen or a group having an electron withdrawing effect or any other activation effect with respect to the —CH═CH— or —C□C-bond. The polyolefin is reinforced by grafting the branched silicone resin onto it.
摘要翻译：本发明提供一种将聚硅氧烷接枝到聚烯烃上的方法，包括使聚烯烃与含有不饱和基团的硅化合物在能够在聚烯烃中产生自由基位点的方式存在下反应，其特征在于硅化合物是含有至少一个式-X-CH = CH-R“（I）或-X-C≡C-R”（II）的基团，其中X表示具有相对于 -CH = CH-或-C≡C-键和/或含有芳环或另外的烯属双键或炔属不饱和键，所述芳环或其它烯属双键或炔属不饱和键与-X 1的烯属不饱和键 -CH = CH-R“或-X-C≡C-R”的炔属不饱和度，X通过C-Si键与支链硅氧烷树脂键合，R“表示氢或具有吸电子基团翼效应或相对于-CH = CH-或-C≡C-键的任何其它活化效应。通过将支化硅树脂接枝到其上来增强聚烯烃。

8. 发明授权

US08580886B2 Method for the preparation and use of bis (alkoxysilylorgano)-dicarboxylates 有权
标题翻译：制备和使用双（烷氧基甲硅烷基有机） - 二羧酸酯的方法
公开(公告)号：US08580886B2
公开(公告)日：2013-11-12
申请号：US13310004
申请日：2011-12-02
申请人： Michael Backer , John Gohndrone , Don Kleyer , Xiaobing Zhou
发明人： Michael Backer , John Gohndrone , Don Kleyer , Xiaobing Zhou
IPC分类号： C08K5/5419 , C07F7/18
CPC分类号： B01J31/0239 , B01J2231/4288 , B01J2531/985 , C07F7/1804
摘要： A method for preparing a bis(alkoxysilylorgano)dicarboxylate includes reacting a haloorganoalkoxysilane, a dimetal salt of a dicarboxyl functional compound, and a phase transfer catalyst. A quaternary iminium compound of a polyaza, polycycloalkene is useful as the phase transfer catalyst. The product may be a bis(alkoxysilylalkyl)fumarate, which is useful as a coupling agent in rubber compositions for tire applications.
摘要翻译：制备双（烷氧基甲硅烷基有机）二羧酸酯的方法包括使卤代有机烷氧基硅烷，二羧基官能化合物的二盐和相转移催化剂反应。多氮化合物的季铵化合物，聚环烯烃可用作相转移催化剂。产物可以是富马酸双（烷氧基甲硅烷基）烷基酯，其可用作轮胎用橡胶组合物中的偶联剂。

9. 发明申请

US20110172367A1 Grafted Polyethylene 审中-公开
标题翻译：接枝聚乙烯
公开(公告)号：US20110172367A1
公开(公告)日：2011-07-14
申请号：US13001660
申请日：2009-07-02
申请人： Michael Backer , Francois De Buyl
发明人： Michael Backer , Francois De Buyl
IPC分类号： C08F8/00
CPC分类号： C08F255/00 , C08F255/02 , C08L51/06 , F16L9/12 , C08L2666/02 , C08L2666/04
摘要： A process for grafting hydrolysable silane groups to polyethylene includes reacting polyethylene with an unsaturated silane having at least one hydrolysable group bonded to Si, in the presence of a compound capable of generating free radical sites in the polyethylene. The grafted polyethylene prepared by the process can be shaped into a pipe and crosslinked by water flowing through the pipe.
摘要翻译：将可水解硅烷基团接枝到聚乙烯的方法包括使聚乙烯与在聚乙烯中能够产生自由基位点的化合物存在下使具有至少一个与Si结合的可水解基团的不饱和硅烷反应。通过该方法制备的接枝聚乙烯可以成形为管，并通过流过管的水交联。

10. 发明授权

US07727579B2 Process for the production of highly-textured, band-shaped, high-temperature superconductors 有权
标题翻译：生产高纹理，带状，高温超导体的工艺
公开(公告)号：US07727579B2
公开(公告)日：2010-06-01
申请号：US11671120
申请日：2007-02-05
申请人： Michael Backer , Brigitte Schlobach , Kerstin Knoth , Barbara Schupp-Niewa , Ruben Huhne , Martina Falter
发明人： Michael Backer , Brigitte Schlobach , Kerstin Knoth , Barbara Schupp-Niewa , Ruben Huhne , Martina Falter
IPC分类号： B05D5/12 , H01L39/24
CPC分类号： C23C18/1216 , C23C18/06 , C23C18/1225 , C23C18/1241 , C23C18/1283 , H01L39/2461 , Y10S505/741
摘要： The formation of band-shaped HTSL on a metal substrate is disclosed. The HTSL includes at least one buffer layer comprising zirconates and/or rare-earth oxides. The HTSL layer is formed on the buffer layer. The buffer layer has a texturing that in the case of a RHEED measurement results in discrete reflexes and not only in diffraction rings. In particular, the buffer layer may be textured along its interface with the HTSL layer.
摘要翻译：公开了在金属基底上形成带状HTSL。 HTSL包括至少一个包含锆酸盐和/或稀土氧化物的缓冲层。 HTSL层形成在缓冲层上。缓冲层具有纹理，在RHEED测量的情况下，导致离散的反射，并且不仅在衍射环中。特别地，缓冲层可以沿其与HTSL层的界面纹理化。

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